2-methoxy-5-methyl pyrazine
2-methoxy-5-methylpyrazine

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  CODE146415 CODE146415
  Product(s):
  2882-22-6 Pyrazine,2-methoxy-5-methyl-

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  Synerzine, Inc.

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  CODE146415 CODE146415
  Product(s):
  6250_B 2-methoxy-5-methylpyrazine (single isomer)

Name: 2-methoxy-5-methylpyrazine CAS Number: 2882-22-6 3D/inchi Other(deleted CASRN): 2822-22-6 ECHA EINECS - REACH Pre-Reg: 220-738-9 FDA UNII: LJ792258CD Nikkaji Web: J29.013K CoE Number: 2266 XlogP3: 0.40 (est) Molecular Weight: 124.14296000 Formula: C6 H8 N2 O NMR Predictor: Predict (works with chrome, Edge or firefox) EFSA/JECFA Comments: JECFA evaluated (2,5 or 6)-methoxy-3-methylpyrazine (CASrn 2847-30-5, 2882-22-6, 2882-21-5). Register CASrn refers to methoxymethylpyrazine. Category:flavoring agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search DG SANTE Food Flavourings: 14.025 2-methoxy-5-methylpyrazine FEMA Number: 3183 2-methoxy-5-methylpyrazine FDA: No longer provide for the use of these seven synthetic flavoring substances   Physical Properties: Appearance: colorless clear liquid (est) Food Chemicals Codex Listed: No Boiling Point: 167.00 to 168.00 °C. @ 760.00 mm Hg Vapor Pressure: 2.203000 mmHg @ 25.00 °C. (est) Flash Point: 143.00 °F. TCC ( 61.67 °C. ) logP (o/w): 1.193 (est) Soluble in:   alcohol   water   water, 5445 mg/L @ 25 °C (est)   Organoleptic Properties: Odor and/or flavor descriptions from others (if found).   Cosmetic Information: None found   Suppliers: BOC Sciences For experimental / research use only. Pyrazine,2-methoxy-5-methyl- Parchem 2-methoxy-5-methyl pyrazine Synerzine 2-methoxy-5-methylpyrazine (single isomer)   Safety Information:   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: Not determined Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: flavoring agents Recommendation for 2-methoxy-5-methyl pyrazine usage levels up to:   not for fragrance use.   Maximised Survey-derived Daily Intakes (MSDI-EU): 2.20 (μg/capita/day) Maximised Survey-derived Daily Intakes (MSDI-USA): 15.00 (μg/capita/day) Structure Class: II Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library publication number: 4 Click here to view publication 4   average usual ppm average maximum ppm baked goods: - 4.00000 beverages(nonalcoholic): - - beverages(alcoholic): - - breakfast cereal: - - cheese: - - chewing gum: - - condiments / relishes: - - confectionery froastings: - - egg products: - - fats / oils: - - fish products: - - frozen dairy: - 2.00000 fruit ices: - 2.00000 gelatins / puddings: - 2.00000 granulated sugar: - - gravies: - - hard candy: - 4.00000 imitation dairy: - - instant coffee / tea: - - jams / jellies: - - meat products: - - milk products: - - nut products: - - other grains: - - poultry: - - processed fruits: - - processed vegetables: - - reconstituted vegetables: - - seasonings / flavors: - - snack foods: - - soft candy: - - soups: - - sugar substitutes: - - sweet sauces: - -   Safety References: European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... European Food Safety Authority (EFSA) reference(s): Safety and efficacy of pyrazine derivatives including saturated ones belonging to chemical group 24 when used as flavourings for all animal species View page or View pdf EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA Substance Registry Services (TSCA):2882-22-6 EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :76153 National Institute of Allergy and Infectious Diseases:Data 2-methoxy-5-methylpyrazine Chemidplus:0002882226   References:   2-methoxy-5-methylpyrazine NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 2882-22-6 Pubchem (cid): 76153 Pubchem (sid): 135033167 Pherobase: View   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements FDA Substances Added to Food (formerly EAFUS): View HMDB (The Human Metabolome Database): HMDB40141 FooDB: FDB019838 VCF-Online: VCF Volatile Compounds in Food ChemSpider: View   Potential Blenders and core components note For Odor No odor group found for these sulfuryl octanoate FL/FR sulfuryl butyrate FL/FR sulfuryl decanoate FL/FR sulfuryl hexanoate FL/FR sulfuryl isobutyrate FL/FR sulfuryl propionate FL/FR valeraldehyde dibutyl acetal FL/FR valeraldehyde propylene glycol acetal FL/FR amber amber cistus ladaniferus resinoid FL/FR animal iso butyl quinoline FR iso butyl quinoline FR anisic ortho- acetanisole FL/FR ortho- anisaldehyde FL/FR para- anisaldehyde FL/FR balsamic 2- acetyl furan FL/FR iso amyl benzoate FL/FR iso amyl cinnamate FL/FR amyl cinnamate FL/FR amyl phenyl acetate FL/FR amyris wood oil FL/FR siam benzoin resinoid FL/FR benzyl cinnamate FL/FR benzyl salicylate FL/FR iso butyl benzoate FL/FR iso butyl cinnamate FL/FR butyl cinnamate FL/FR cinnamyl alcohol FL/FR ethyl cinnamate FL/FR methyl cinnamate FL/FR peru balsam oil FL/FR 3- phenyl propyl alcohol FL/FR prenyl benzoate FL/FR propyl benzoate FL/FR berry raspberry ketone FL/FR raspberry ketone acetate FL/FR raspberry ketone methyl ether FL/FR bready coffee furanone FL/FR furfural FL/FR buttery acetyl propionyl FL/FR 3,4- hexane dione FL/FR camphoreous bornyl isobutyrate FL/FR caramellic cyclotene FL/FR ethyl 2-hydroxy-2-methyl butyrate FL/FR ethyl maltol FL/FR fenugreek oleoresin FL/FR geranyl crotonate FR immortelle absolute FL/FR maltol FL/FR strawberry furanone FL/FR chocolate iso amyl phenyl acetate FL/FR iso butyl phenyl acetate FL/FR cocoa hexenal FL/FR cocoa oleoresin FL/FR cocoa pentenal FL/FR 2,6- dimethyl pyrazine FL/FR 2,5- dimethyl pyrazine FL/FR 2- methoxy-3-methyl pyrazine FL/FR 2- methoxypyrazine FL/FR 2,4,5- trimethyl thiazole FL/FR cocoa 2-iso butyl-3,5-(and 3,6)-dimethyl pyrazine FL/FR 2- methyl butyraldehyde FL/FR coconut alpha- angelica lactone FL/FR gamma- heptalactone FL/FR gamma- nonalactone (aldehyde C-18 (so-called)) FL/FR corn chip popcorn pyrimidine FL/FR coumarinic coumane FL/FR tonka bean resinoid FR earthy 2- ethyl-3-methoxypyrazine FL/FR ethereal iso propyl formate FL/FR fatty coconut absolute FL/FR fermented 3- methyl-1-pentanol FL/FR valeraldehyde FL/FR floral acetophenone FL/FR alpha- amyl cinnamaldehyde FL/FR alpha- amyl cinnamyl acetate FL/FR amyl salicylate FL/FR bois de rose oil brazil FL/FR boronia butenal FR para- cresyl laurate FL/FR dimethyl anthranilate FL/FR ethyl phenyl acetate FL/FR heliotropin FL/FR (Z)-3- hexen-1-yl salicylate FL/FR alpha- hexyl cinnamaldehyde FL/FR ho leaf oil FR para- methyl acetophenone FL/FR methyl dihydrojasmonate FL/FR ocean propanal FL/FR orris pyridine 25% IPM FR phenethyl phenyl acetate FL/FR phenyl acetaldehyde diisobutyl acetal FL/FR tetrahydrolinalool FL/FR ylang ylang flower oil FL/FR fruity allyl 2-ethyl butyrate FL/FR bitter almond oil FL/FR iso amyl nonanoate FL/FR benzaldehyde FL/FR benzaldehyde / methyl anthranilate schiff's base FR benzaldehyde glycrol acetal FL/FR 2- benzofuran carboxaldehyde FL/FR bread thiophene FL/FR butyl 2-methyl butyrate FL/FR cyclohexyl cinnamate FL/FR gamma- decalactone FL/FR 4- ethyl benzaldehyde FL/FR methyl valerate FL/FR 3- methyl-2-butenal FL/FR tolualdehyde glyceryl acetal FL/FR tropical thiazole FL/FR green benzaldehyde dimethyl acetal FL/FR 2- heptyl furan FL/FR (E,Z)-2,6- nonadien-1-yl acetate FL/FR phenyl acetaldehyde FL/FR phenyl acetaldehyde diethyl acetal FL/FR tiglaldehyde FL/FR hay beeswax absolute FL/FR hay absolute FR herbal clary sage oil france FL/FR saffron pyranone FR tricyclodecenyl isobutyrate FR gamma- valerolactone FL/FR honey butyl phenyl acetate FL/FR methyl phenyl acetate FL/FR phenyl acetic acid FL/FR phenyl pyruvic acid FL/FR milky laevo- glutamine CS mossy oakmoss absolute FL/FR veramoss (IFF) FR musty 2- acetyl pyrrole FL/FR 3- acetyl-2,5-dimethyl furan FL/FR cocoa butenal FL/FR hazelnut pyrazine FL/FR menthofuran FL/FR naphthyl 2,4- dimethyl benzaldehyde FL/FR ortho- methyl anisole FL/FR para- methyl anisole FL/FR nutty 3- acetyl pyridine FL/FR 2- acetyl-3-ethyl pyrazine FL/FR 2- acetyl-3-methyl pyrazine FL/FR 2- acetyl-3,5-dimethyl pyrazine FL/FR 2- acetyl-5-methyl furan FL/FR 3,6- cocoa pyrazine FL/FR 3,5- cocoa pyrazine FL/FR 2,3- dimethyl pyrazine FL/FR 4,5- dimethyl-2-ethyl-3-thiazoline FL/FR 2- ethyl pyrazine FL/FR 2- ethyl-4-methyl thiazole FL/FR filbert heptenone FL/FR filbert pyrazine FL/FR 2,6- lutidine FL/FR maraniol CS 2- methyl pyrazine FL/FR 5- methyl quinoxaline FL/FR 2- methyl thio-3,5 or 6-methyl pyrazine FL/FR 2- methyl-3-(methyl thio) pyrazine FL/FR 2- methyl-3-ethoxypyrazine FL/FR 2- methyl-3-propyl pyrazine FL/FR nutty cyclohexenone FL/FR nutty quinoxaline FL/FR shoyu pyrazine FL/FR 2,3,5,6- tetramethyl pyrazine FL/FR 2,3,5- trimethyl pyrazine FL/FR vinyl sulfurol FL/FR phenolic methyl benzoate FL/FR popcorn 2- acetyl pyrazine FL/FR 2- acetyl pyridine FL/FR 2- acetyl thiazole FL/FR powdery para- anisyl alcohol FL/FR dibenzyl ketone FL/FR roasted fenugreek resinoid FL/FR spicy allspice oil FL/FR benzyl isoeugenol FL/FR carnation absolute FR cassia bark oil china FL/FR clove bud oil FL/FR 4- ethyl guaiacol FL/FR eugenol FL/FR 3-(2- furyl) acrolein FL/FR alpha- methyl cinnamaldehyde FL/FR methyl isoeugenol FL/FR nutmeg oil FL/FR black pepper oil FL/FR sulfurous benzothiazole FL/FR furfuryl thioacetate FL/FR terpenic alpha- terpineol FL/FR tobacco veltonal (Bedoukian) FR tonka coumarin FR gamma- hexalactone FL/FR tonka bean absolute FR whiskey lactone FL/FR vanilla ethyl vanillin FL/FR ethyl vanillin isobutyrate FL/FR vanilla bean absolute (vanilla planifolia) FL/FR vanillin FL/FR vanillyl acetate FL/FR vanillyl isobutyrate FL/FR waxy phenethyl octanoate FL/FR woody guaiacwood oil FL/FR gurjun balsam oil FR patchouli ethanone FR sandalwood oil FL/FR santall FR tobacarol (IFF) FR vetiver oil haiti FL/FR woody acetate FR (Z)- woody amylene FR For Flavor No flavor group found for these acetyl acetaldehyde dimethyl acetal FL amyl phenyl acetate FL/FR bornyl isobutyrate FL/FR butyl cinnamate FL/FR 2-iso butyl-3,5-(and 3,6)-dimethyl pyrazine FL/FR 2(4)-iso butyl-4(2),6-dimethyl dihydro-4H-1,3,5-dithiazine FL butyramide FL cistus ladaniferus resinoid FL/FR coumane FL/FR cyclohexyl methyl pyrazine FL 2,5- diethyl thiazole FL 2,5- diethyl-4-methyl thiazole FL 6,7- dihydro-2,3-dimethyl-5H-cyclopentapyrazine FL dimethyl dihydrocyclopentapyrazine FL 2,5- dimethyl thiazole FL 4,5- dimethyl-2-ethyl thiazole FL ethyl 2-hydroxy-2-methyl butyrate FL/FR 4- ethyl benzaldehyde FL/FR 5- ethyl-2-thiophene carboxaldehyde FL 2- ethyl-3-methoxypyrazine FL/FR (Z+E)-5- ethyl-4-methyl-2-(2-butyl) thiazoline FL (Z+E)-5- ethyl-4-methyl-2-(2-methyl propyl) thiazoline FL 3-(2- furyl) acrolein FL/FR (E,E)-2,4- heptadien-1-ol FL 2- hexenal FL 2- hexyl-5 or 6-keto-1,4-dioxane FL 2- methoxypyrazine FL/FR methyl 2-(methyl thio) acetate FL 4- methyl salicylaldehyde FL 2- methyl-3-(methyl thio) pyrazine FL/FR 2- methyl-3-ethoxypyrazine FL/FR peanut dithiazine FL phenyl acetaldehyde diethyl acetal FL/FR prenyl benzoate FL/FR 2- propyl pyridine FL para- salicylic acid FL sulfuryl butyrate FL/FR sulfuryl decanoate FL/FR sulfuryl hexanoate FL/FR sulfuryl isobutyrate FL/FR tolualdehyde glyceryl acetal FL/FR valeraldehyde propylene glycol acetal FL/FR 5- acetyl-2,3-dihydro-1,4-thiazine FL sulfuryl formate FL sulfuryl octanoate FL/FR sulfuryl propionate FL/FR valeraldehyde dibutyl acetal FL/FR alliaceous alliaceous 2- methyl thioacetaldehyde FL tropical thiazole FL/FR anisic ortho- anisaldehyde FL/FR aromatic amyl salicylate FL/FR balsamic amyl cinnamate FL/FR siam benzoin resinoid FL/FR benzyl salicylate FL/FR iso butyl cinnamate FL/FR ethyl cinnamate FL/FR peru balsam oil FL/FR berry raspberry ketone FL/FR raspberry ketone acetate FL/FR raspberry ketone methyl ether FL/FR bitter dibenzyl ketone FL/FR methyl ethoxypyrazine FL bready 2- propionyl thiazole FL brown beeswax absolute FL/FR fenugreek oleoresin FL/FR furfural FL/FR burnt 2- methyl quinoxaline FL buttery butyroin FL 3,4- hexane dione FL/FR camphoreous ortho- methyl anisole FL/FR caramellic caramel furanone FL cyclotene FL/FR ethyl maltol FL/FR fenugreek resinoid FL/FR maltol FL/FR strawberry furanone FL/FR cherry heliotropin FL/FR chocolate cocoa oleoresin FL/FR cocoa propanal FL citrus alpha- terpineol FL/FR cocoa iso butyl phenyl acetate FL/FR butyraldehyde FL cocoa hexenal FL/FR 2- methyl furan FL coconut gamma- nonalactone (aldehyde C-18 (so-called)) FL/FR coffee difurfuryl ether FL 2- ethyl-4-methyl thiazole FL/FR 2-iso propyl pyrazine FL corn 2- acetyl pyridine FL/FR 2- acetyl thiazole FL/FR 2- acetyl-2-thiazoline FL popcorn pyrimidine FL/FR creamy alpha- angelica lactone FL/FR para- anisaldehyde FL/FR gamma- hexalactone FL/FR para- methyl acetophenone FL/FR earthy alpha- amyl cinnamyl acetate FL/FR 2- methyl-3-propyl pyrazine FL/FR ethereal allyl 2-ethyl butyrate FL/FR fatty coconut absolute FL/FR (E,E)-2,4- decadienal FL 2- heptyl furan FL/FR (E,E)-2,4- nonadienal FL fishy 4,5- dimethyl thiazole FL floral iso amyl cinnamate FL/FR iso amyl phenyl acetate FL/FR bois de rose oil brazil FL/FR cocoa pentenal FL/FR methyl dihydrojasmonate FL/FR methyl phenyl acetate FL/FR ocean propanal FL/FR phenyl acetic acid FL/FR tetrahydrolinalool FL/FR ylang ylang flower oil FL/FR fruity bitter almond oil FL/FR iso amyl benzoate FL/FR para- anisyl alcohol FL/FR benzaldehyde FL/FR benzaldehyde glycrol acetal FL/FR bread thiophene FL/FR butyl 2-methyl butyrate FL/FR iso butyl benzoate FL/FR cherry laurel oil FL cyclohexyl cinnamate FL/FR gamma- decalactone FL/FR dimethyl anthranilate FL/FR 2,4- hexadien-1-ol FL methyl valerate FL/FR 3- methyl-2-butenal FL/FR phenethyl octanoate FL/FR propyl benzoate FL/FR iso propyl formate FL/FR tiglaldehyde FL/FR fusel 2- methyl butyraldehyde FL/FR green benzaldehyde dimethyl acetal FL/FR cinnamyl alcohol FL/FR cocoa butenal FL/FR dihydroxyacetophenone (mixed isomers) FL 2,5- dimethyl thiophene FL 2- ethyl butyraldehyde FL (Z)-3- hexen-1-yl salicylate FL/FR immortelle absolute FL/FR 4- methyl thiazole FL 2- methyl-5-isopropyl pyrazine FL (E,Z)-2,6- nonadien-1-yl acetate FL/FR oakmoss absolute FL/FR phenyl acetaldehyde diisobutyl acetal FL/FR 2- vinyl pyrazine FL herbal clary sage oil france FL/FR honey butyl phenyl acetate FL/FR ethyl phenyl acetate FL/FR phenethyl phenyl acetate FL/FR phenyl acetaldehyde FL/FR lactonic gamma- heptalactone FL/FR meaty benzothiazole FL/FR 2,6- dimethyl pyrazine FL/FR musty 2,5- dimethyl pyrazine FL/FR 2- ethoxythiazole FL hazelnut pyrazine FL/FR menthofuran FL/FR shoyu pyrazine FL/FR 2,3,5- trimethyl pyrazine FL/FR naphthyl 2,4- dimethyl benzaldehyde FL/FR para- methyl anisole FL/FR nutty 2- acetyl furan FL/FR 3- acetyl pyridine FL/FR 2- acetyl pyrrole FL/FR 3- acetyl-2,5-dimethyl furan FL/FR 2- acetyl-3-ethyl pyrazine FL/FR 2- acetyl-3-methyl pyrazine FL/FR 2- acetyl-3,5-dimethyl pyrazine FL/FR 2- acetyl-5-methyl furan FL/FR 2- benzofuran carboxaldehyde FL/FR 3,5- cocoa pyrazine FL/FR 3,6- cocoa pyrazine FL/FR 3,5(6)- cocoa pyrazine FL coffee furanone FL/FR 3,5- diethyl-2-methyl pyrazine FL 2,5- diethyl-3-methyl pyrazine FL 2,3- dimethyl pyrazine FL/FR 4,5- dimethyl-2-ethyl-3-thiazoline FL/FR 2,4- dimethyl-5-vinyl thiazole FL 2- ethyl pyrazine FL/FR 1- ethyl-2-acetyl pyrrole FL filbert heptenone FL/FR filbert pyrazine FL/FR european hazelnut oleoresin FL 2,6- lutidine FL/FR 2- methoxy-3-methyl pyrazine FL/FR 2- methyl pyrazine FL/FR 5- methyl quinoxaline FL/FR 2- methyl thio-3,5 or 6-methyl pyrazine FL/FR nutty cyclohexenone FL/FR nutty quinoxaline FL/FR nutty thiazole FL peanut oxazole FL 2,3,5,6- tetramethyl pyrazine FL/FR 2,4,5- trimethyl thiazole FL/FR vinyl sulfurol FL/FR phenolic methyl benzoate FL/FR phenyl pyruvic acid FL/FR popcorn 2- propionyl-2-thiazoline FL powdery ortho- acetanisole FL/FR acetophenone FL/FR powdery ketone FL roasted 2- acetyl pyrazine FL/FR furfuryl thioacetate FL/FR solvent 2- ethyl furan FL spicy allspice oil FL/FR benzyl cinnamate FL/FR benzyl isoeugenol FL/FR cassia bark oil china FL/FR clove bud oil FL/FR eugenol FL/FR alpha- methyl cinnamaldehyde FL/FR methyl cinnamate FL/FR methyl isoeugenol FL/FR nutmeg oil FL/FR black pepper oil FL/FR 3- phenyl propyl alcohol FL/FR toasted acetyl propionyl FL/FR tonka gamma- valerolactone FL/FR tropical alpha- amyl cinnamaldehyde FL/FR vanilla ethyl vanillin FL/FR ethyl vanillin isobutyrate FL/FR vanilla bean absolute (vanilla planifolia) FL/FR vanillin FL/FR vanillyl acetate FL/FR vanillyl isobutyrate FL/FR waxy para- cresyl laurate FL/FR alpha- hexyl cinnamaldehyde FL/FR whiskey 3- methyl-1-pentanol FL/FR winey iso amyl nonanoate FL/FR 5- ethyl-2-methyl pyridine FL valeraldehyde FL/FR woody amyris wood oil FL/FR 4- ethyl guaiacol FL/FR guaiacwood oil FL/FR sandalwood oil FL/FR vetiver oil haiti FL/FR whiskey lactone FL/FR   Potential Uses: None Found   Occurrence (nature, food, other):note   chocolate Search PMC Picture   Synonyms: 6- methoxy-3-methyl pyrazine 6- methoxy-3-methylpyrazine 2- methoxy-5-methylpyrazine 2- methyl-5-methoxypyrazine   pyrazine, 2-methoxy-5-methyl-   pyrazine, 2-methyl-5-methoxy   Articles:   None found yet. 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Notes: Nut-like flavouring ingredient. Component of FEMA 3183, together with its regioisomers