4,5-dimethyl-2-ethyl-3-thiazoline
2-ethyl-4,5-dimethyl-3-thiazoline

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  Endeavour Specialty Chemicals Ltd

  Expertise in high impact aroma chemicals
  Endeavour Speciality Chemicals offers high-impact aroma chemicals, at small to medium scale.
  Speciality Chemical has more than 25 years experience of manufacturing high-impact aroma chemicals. With our core expertise in sulfur and heterocyclic chemistries, Endeavours products have applications in a range of industry sectors including flavours and fragrances, pharmaceutical research and material sciences. Endeavour also offer custom synthesis and contract manufacturing services at their UK manufacturing site.
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  TZ0170 4,5-Dimethyl-2-ethyl-3-thiazoline 99% F&F

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  Robinson Brothers Limited

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  Synerzine, Inc.

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  T245 4,5-Dimethyl-2-Ethyl-3-Thiazoline
  W0449 4,5-DIMETHYL-2-ETHYL-3-THIAZOLINE

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  R C Treatt and Co Ltd

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  2-Ethyl-4,5-dimethylthiazoline Halal, Kosher

Name: 2-ethyl-4,5-dimethyl-2,5-dihydro-1,3-thiazole CAS Number: 76788-46-0 3D/inchi ECHA EINECS - REACH Pre-Reg: 278-551-3 FDA UNII: G7XZR26U8K Nikkaji Web: J309.326C Beilstein Number: 0108717 MDL: MFCD01680821 XlogP3-AA: 1.80 (est) Molecular Weight: 143.25261000 Formula: C7 H13 N S NMR Predictor: Predict (works with chrome, Edge or firefox) EFSA/JECFA Comments: JECFA evaluated 4,5-dimethyl-2-ethyl-3-thiazoline (CASrn as in Register). (R)- or (S)- enantiomer not specified by CASrn in Register. Mixture of diastereoisomers, each of them racemic (EFFA, 2013b). Category:flavor and fragrance agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search JECFA Food Flavoring: 1058 4,5-dimethyl-2-ethyl-3-thiazoline DG SANTE Food Flavourings: 15.030 4,5-dimethyl-2-ethyl-3-thiazoline FEMA Number: 3620 2-ethyl-4,5-dimethyl-3-thiazoline FDA: No longer provide for the use of these seven synthetic flavoring substances FDA Mainterm (SATF): 76788-46-0 ; 4,5-DIMETHYL-2-ETHYL-3-THIAZOLINE   Physical Properties: Appearance: colorless to pale yellow clear liquid (est) Assay: 98.00 to 100.00 Food Chemicals Codex Listed: No Boiling Point: 198.00 to 200.00 °C. @ 760.00 mm Hg Vapor Pressure: 0.468000 mmHg @ 25.00 °C. (est) Flash Point: 150.00 °F. TCC ( 65.56 °C. ) logP (o/w): 3.071 (est) Shelf Life: 12.00 month(s) or longer if stored properly. Storage: store in cool, dry place in tightly sealed containers, protected from heat and light. Soluble in:   alcohol   water, 61.77 mg/L @ 25 °C (est) Insoluble in:   water   Organoleptic Properties: Odor Type: nutty meaty nutty musty sulfurous coffee chocolate raw vegetable Odor Description:at 0.10 % in dipropylene glycol. meat nut musty sulfury coffee chocolate raw vegetable Flavor Type: nutty nut skin raw vegetable nutty cocoa earthy musty Taste Description: nut skin raw vegetable nutty cocoa earthy musty Odor and/or flavor descriptions from others (if found).   Cosmetic Information: None found   Suppliers: BOC Sciences For experimental / research use only. 4,5-Dimethyl-2-ethyl-3-thiazoline Endeavour Specialty Chemicals 4,5-Dimethyl-2-ethyl-3-thiazoline 99% F&F Speciality Chemical Product Groups Jinan Enlighten Chemical Technology(Wutong Aroma ) 4,5-Dimethyl-2-ethyl-3-thiazoline Penta International 4,5-DIMETHYL-2-ETHYL-3-THIAZOLINE R C Treatt & Co Ltd 2-Ethyl-4,5-dimethylthiazoline Halal, Kosher Robinson Brothers 4,5-Dimethyl-2-ethyl-3-thiazoline F&F https://www.robinsonbrothers.uk/chemistry-competences Santa Cruz Biotechnology For experimental / research use only. 2-Ethyl-4,5-dimethyl-3-thiazoline, cis + trans Synerzine 4,5-Dimethyl-2-Ethyl-3-Thiazoline Synerzine 4,5-DIMETHYL-2-ETHYL-3-THIAZOLINE   Safety Information: European information : Most important hazard(s): Xn - Harmful. R 22 - Harmful if swallowed. S 02 - Keep out of the reach of children. S 20/21 - When using do not eat, drink or smoke. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: gavage-mouse LD50 [sex: M,F] 1265 mg/kg (Moran et al., 1980) oral-mouse LD50 1265 mg/kg Drug and Chemical Toxicology. Vol. 3, Pg. 249, 1980. Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: flavor and fragrance agents RIFM Fragrance Material Safety Assessment: Search IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice Recommendation for 4,5-dimethyl-2-ethyl-3-thiazoline usage levels up to:   0.0500 % in the fragrance concentrate.   Maximised Survey-derived Daily Intakes (MSDI-EU): 0.012 (μg/capita/day) Maximised Survey-derived Daily Intakes (MSDI-USA): 0.01 (μg/capita/day) Structure Class: III Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library publication number: 12 Click here to view publication 12   average usual ppm average maximum ppm baked goods: - - beverages(nonalcoholic): - - beverages(alcoholic): - - breakfast cereal: - - cheese: - - chewing gum: - - condiments / relishes: - - confectionery froastings: - - egg products: - - fats / oils: - - fish products: - 10.00000 frozen dairy: - - fruit ices: - - gelatins / puddings: - - granulated sugar: - - gravies: - 10.00000 hard candy: - - imitation dairy: - - instant coffee / tea: - - jams / jellies: - - meat products: - 10.00000 milk products: - - nut products: - - other grains: - - poultry: - 10.00000 processed fruits: - - processed vegetables: - - reconstituted vegetables: - - seasonings / flavors: - - snack foods: - 10.00000 soft candy: - - soups: - 10.00000 sugar substitutes: - - sweet sauces: - -   Safety References: European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... European Food Safety Authority (EFSA) reference(s): Flavouring Group Evaluation 21: Thiazoles, thiophene, thiazoline and thienyl derivatives from chemical group 29. Miscellaneous substances from chemical group 30. (Commission Regulation (EC) No 1565/2000 of 18 July 2000) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) View page or View pdf Flavouring Group Evaluation 76, (FGE.76)[1] - Consideration of sulphur-containing heterocyclic compounds evaluated by JECFA (59th meeting) structurally related to thiazoles, thiophene, thiazoline and thienyl derivatives from chemical group 29, miscellaneous substances from chemical group 30 evaluated by EFSA in FGE.21 - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food View page or View pdf Flavouring Group Evaluation 21, Revision 1 (FGE.21Rev1): Thiazoles, thiophene, thiazoline and thienyl derivatives from chemical group 29 Miscellaneous substances from chemical group 30 View page or View pdf Statement on List of Representative Substances for Testing. The current Statement lays down a list of substances in sub-groups with representative substances for which additional data are required prior to their evaluation through the Procedure (Regulation (EC) No 1565/2000). View page or View pdf Scientific Opinion on Flavouring Group Evaluation 76, Revision 1 (FGE.76Rev1): Consideration of sulphur-containing heterocyclic compounds evaluated by JECFA (59th meeting) structurally related to thiazoles, thiophene, thiazoline and thienyl derivatives from chemical group 29 and miscellaneous substances from chemical group 30 evaluated by EFSA in FGE.21Rev3 View page or View pdf EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :5362584 National Institute of Allergy and Infectious Diseases:Data WGK Germany:3 2-ethyl-4,5-dimethyl-2,5-dihydro-1,3-thiazole Chemidplus:0076788460 RTECS:XJ6642500 for cas# 76788-46-0   References:   2-ethyl-4,5-dimethyl-2,5-dihydro-1,3-thiazole NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 76788-46-0 Pubchem (cid): 5362584 Pubchem (sid): 135324312   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements FDA Substances Added to Food (formerly EAFUS): View HMDB (The Human Metabolome Database): HMDB37176 FooDB: FDB016172 Export Tariff Code: 2934.10.0090 ChemSpider: View   Potential Blenders and core components note For Odor No odor group found for these sulfuryl octanoate FL/FR sulfuryl butyrate FL/FR sulfuryl decanoate FL/FR sulfuryl hexanoate FL/FR sulfuryl isobutyrate FL/FR sulfuryl propionate FL/FR valeraldehyde dibutyl acetal FL/FR valeraldehyde propylene glycol acetal FL/FR aldehydic aldehydic iso valeraldehyde FL/FR alliaceous methyl furfuryl disulfide FL/FR balsamic 2- acetyl furan FL/FR iso amyl cinnamate FL/FR amyl cinnamate FL/FR butyl cinnamate FL/FR propyl benzoate FL/FR buttery acetyl propionyl FL/FR 3,4- hexane dione FL/FR camphoreous bornyl isobutyrate FL/FR caramellic coffee dione FL/FR cyclotene FL/FR ethyl 2-hydroxy-2-methyl butyrate FL/FR fenugreek oleoresin FL/FR chocolate iso amyl phenyl acetate FL/FR chocolate pyrazine A FL/FR cocoa hexenal FL/FR cocoa oleoresin FL/FR cocoa pentenal FL/FR 2,5- dimethyl pyrazine FL/FR 2,6- dimethyl pyrazine FL/FR 2- methoxypyrazine FL/FR 2,4,5- trimethyl thiazole FL/FR cocoa 2-iso butyl-3,5-(and 3,6)-dimethyl pyrazine FL/FR 2- methyl butyraldehyde FL/FR coconut alpha- angelica lactone FL/FR gamma- heptalactone FL/FR coffee coffee difuran FL/FR furfuryl mercaptan FL/FR 1- hydroxy-2-butanone FL/FR 2- methyl-3-,5 or 6-(furfuryl thio) pyrazine FL/FR coumarinic coumane FL/FR tonka bean resinoid FR earthy 2- ethyl-3-methoxypyrazine FL/FR ethereal iso propyl formate FL/FR fatty coconut absolute FL/FR fermented 3- methyl-1-pentanol FL/FR valeraldehyde FL/FR floral boronia butenal FR para- cresyl laurate FL/FR ethyl phenyl acetate FL/FR fruity allyl 2-ethyl butyrate FL/FR iso amyl nonanoate FL/FR butyl 2-methyl butyrate FL/FR methyl valerate FL/FR 3- methyl-2-butenal FL/FR green 2- heptyl furan FL/FR phenyl acetaldehyde FL/FR tiglaldehyde FL/FR herbal saffron pyranone FR gamma- valerolactone FL/FR medicinal 2,6- xylenol FL/FR milky laevo- glutamine CS musty 2- acetyl pyrrole FL/FR 3- acetyl-2,5-dimethyl furan FL/FR cocoa butenal FL/FR hazelnut pyrazine FL/FR menthofuran FL/FR naphthyl ortho- methyl anisole FL/FR para- methyl anisole FL/FR nutty 3- acetyl pyridine FL/FR 2- acetyl-3-ethyl pyrazine FL/FR 2- acetyl-3-methyl pyrazine FL/FR 2- acetyl-3,5-dimethyl pyrazine FL/FR 2- acetyl-5-methyl furan FL/FR 3,5- cocoa pyrazine FL/FR 3,6- cocoa pyrazine FL/FR 2,3- dimethyl pyrazine FL/FR 2- ethyl pyrazine FL/FR 2- ethyl-4-methyl thiazole FL/FR filbert heptenone FL/FR filbert pyrazine FL/FR 2,6- lutidine FL/FR maraniol CS 2- methyl pyrazine FL/FR 5- methyl quinoxaline FL/FR 2- methyl thio-3,5 or 6-methyl pyrazine FL/FR 2- methyl-3-(methyl thio) pyrazine FL/FR 2- methyl-3-ethoxypyrazine FL/FR 2- methyl-3-propyl pyrazine FL/FR nutty cyclohexenone FL/FR nutty quinoxaline FL/FR shoyu pyrazine FL/FR 2,3,5,6- tetramethyl pyrazine FL/FR 2,3,5- trimethyl pyrazine FL/FR vinyl sulfurol FL/FR popcorn 2- acetyl pyrazine FL/FR 2- acetyl thiazole FL/FR roasted fenugreek resinoid FL/FR spicy 3-(2- furyl) acrolein FL/FR sulfurous benzothiazole FL/FR furfuryl thioacetate FL/FR S- furfuryl thioformate FL/FR 2- methyl 5-(methyl thio) furan FL/FR tobacco veltonal (Bedoukian) FR tonka tonka bean absolute FR whiskey lactone FL/FR vegetable 1- furfuryl pyrrole FL/FR mesityl oxide FL/FR waxy phenethyl octanoate FL/FR woody sandalwood oil FL/FR For Flavor No flavor group found for these acetyl acetaldehyde dimethyl acetal FL (E)- aconitic acid FL bornyl isobutyrate FL/FR butyl cinnamate FL/FR 2-iso butyl-3,5-(and 3,6)-dimethyl pyrazine FL/FR 2(4)-iso butyl-4(2),6-dimethyl dihydro-4H-1,3,5-dithiazine FL butyramide FL chocolate pyrazine A FL/FR coumane FL/FR cyclohexyl methyl pyrazine FL 2,5- diethyl thiazole FL 2,5- diethyl-4-methyl thiazole FL 6,7- dihydro-2,3-dimethyl-5H-cyclopentapyrazine FL dimethyl dihydrocyclopentapyrazine FL 2,5- dimethyl thiazole FL 4,5- dimethyl-2-ethyl thiazole FL 2,5- dimethyl-3-thiofuroyl furan FL ethyl 2-hydroxy-2-methyl butyrate FL/FR 2- ethyl-3-methoxypyrazine FL/FR (Z+E)-5- ethyl-4-methyl-2-(2-butyl) thiazoline FL (Z+E)-5- ethyl-4-methyl-2-(2-methyl propyl) thiazoline FL 3-(2- furyl) acrolein FL/FR (E,E)-2,4- heptadien-1-ol FL 2- hexyl-5 or 6-keto-1,4-dioxane FL 2- methoxypyrazine FL/FR 2- methyl-2-thiazoline FL 2- methyl-3-,5 or 6-(furfuryl thio) pyrazine FL/FR 2- methyl-3-(methyl thio) pyrazine FL/FR 2- methyl-3-ethoxypyrazine FL/FR peanut dithiazine FL 2- propyl pyridine FL pyrazines mixture FL para- salicylic acid FL sulfuryl butyrate FL/FR sulfuryl decanoate FL/FR sulfuryl hexanoate FL/FR sulfuryl isobutyrate FL/FR valeraldehyde propylene glycol acetal FL/FR 5- acetyl-2,3-dihydro-1,4-thiazine FL sulfuryl formate FL sulfuryl octanoate FL/FR sulfuryl propionate FL/FR valeraldehyde dibutyl acetal FL/FR alliaceous alliaceous benzyl mercaptan FL dicyclohexyl disulfide FL 2- methyl thioacetaldehyde FL balsamic amyl cinnamate FL/FR bitter methyl ethoxypyrazine FL paullinia cupana seed extract FL bready 2- propionyl thiazole FL brown fenugreek oleoresin FL/FR 1- hydroxy-2-butanone FL/FR burnt furfuryl alcohol FL 2- methyl quinoxaline FL 2,6- xylenol FL/FR buttery 3,4- hexane dione FL/FR camphoreous ortho- methyl anisole FL/FR caramellic caramel furanone FL cyclotene FL/FR fenugreek resinoid FL/FR chocolate cocoa oleoresin FL/FR cocoa propanal FL cocoa butyraldehyde FL cocoa hexenal FL/FR coffee coffee difuran FL/FR coffee dione FL/FR coffee pyrazine FL difurfuryl ether FL diisoamyl thiomalate FL 2,4- dimethyl thiazole FL 2- ethyl-4-methyl thiazole FL/FR furfuryl mercaptan FL/FR methyl furfuryl disulfide FL/FR 2-iso propyl pyrazine FL 2- thiophene thiol FL corn chip 2- acetyl thiazole FL/FR 2- acetyl-2-thiazoline FL creamy alpha- angelica lactone FL/FR earthy camu camu distillates FL difurfuryl sulfide FL 2- methyl-3-propyl pyrazine FL/FR ethereal allyl 2-ethyl butyrate FL/FR fatty coconut absolute FL/FR 2- heptyl furan FL/FR (E,E)-2,4- nonadienal FL fishy 4,5- dimethyl thiazole FL floral iso amyl cinnamate FL/FR iso amyl phenyl acetate FL/FR cocoa pentenal FL/FR fruity butyl 2-methyl butyrate FL/FR furfuryl propionate FL 2,4- hexadien-1-ol FL methyl valerate FL/FR 3- methyl-2-butenal FL/FR phenethyl octanoate FL/FR propyl benzoate FL/FR iso propyl formate FL/FR tiglaldehyde FL/FR iso valeraldehyde FL/FR fusel 2- methyl butyraldehyde FL/FR green cocoa butenal FL/FR 2,5- dimethyl thiophene FL 2- ethyl butyraldehyde FL 2- hexyl pyridine FL 4- methyl thiazole FL 2- methyl-5-isopropyl pyrazine FL 2- vinyl pyrazine FL honey ethyl phenyl acetate FL/FR phenyl acetaldehyde FL/FR lactonic gamma- heptalactone FL/FR meaty benzothiazole FL/FR 2,6- dimethyl pyrazine FL/FR 2,6- dimethyl thiophenol FL 2- methyl 3-(methyl thio) furan FL mustard furfuryl methyl ether FL musty 2,5- dimethyl pyrazine FL/FR hazelnut pyrazine FL/FR menthofuran FL/FR 2- methyl 5-(methyl thio) furan FL/FR propionaldehyde FL shoyu pyrazine FL/FR 2,3,5- trimethyl pyrazine FL/FR naphthyl para- methyl anisole FL/FR nutty 2- acetyl furan FL/FR 3- acetyl pyridine FL/FR 2- acetyl pyrrole FL/FR 3- acetyl-2,5-dimethyl furan FL/FR 2- acetyl-3-ethyl pyrazine FL/FR 2- acetyl-3-methyl pyrazine FL/FR 2- acetyl-3,5-dimethyl pyrazine FL/FR 2- acetyl-5-methyl furan FL/FR aconitic acid FL 3,6- cocoa pyrazine FL/FR 3,5(6)- cocoa pyrazine FL 3,5- cocoa pyrazine FL/FR 3,5- diethyl-2-methyl pyrazine FL 2,5- diethyl-3-methyl pyrazine FL 2,3- dimethyl pyrazine FL/FR 2,4- dimethyl-5-vinyl thiazole FL 2- ethyl pyrazine FL/FR 1- ethyl-2-acetyl pyrrole FL filbert heptenone FL/FR filbert pyrazine FL/FR european hazelnut oleoresin FL 2,6- lutidine FL/FR 2- methyl pyrazine FL/FR 5- methyl quinoxaline FL/FR 2- methyl thio-3,5 or 6-methyl pyrazine FL/FR nutty cyclohexenone FL/FR nutty quinoxaline FL/FR nutty thiazole FL peanut oxazole FL 2,3,5,6- tetramethyl pyrazine FL/FR 2,4,5- trimethyl thiazole FL/FR vinyl sulfurol FL/FR onion furfuryl isopropyl sulfide FL popcorn 2- propionyl-2-thiazoline FL potato mesityl oxide FL/FR roasted 2- acetyl pyrazine FL/FR ethyl 3-(furfuryl thio) propionate FL furfuryl thioacetate FL/FR sulfurous butyl mercaptan FL ethyl methyl sulfide FL S- ethyl thioacetate FL S- furfuryl thioformate FL/FR furfuryl thiopropionate FL methyl 2-(methyl thio) butyrate FL methyl thiomethyl butyrate FL 2- thienyl mercaptan FL toasted acetyl propionyl FL/FR tonka gamma- valerolactone FL/FR vegetable 1- furfuryl pyrrole FL/FR waxy para- cresyl laurate FL/FR whiskey 3- methyl-1-pentanol FL/FR winey iso amyl nonanoate FL/FR 5- ethyl-2-methyl pyridine FL valeraldehyde FL/FR woody sandalwood oil FL/FR whiskey lactone FL/FR   Potential Uses: FL chocolate cacao FL chocolate cocoa FL coffee FL meat grilled meat FL milk FL nut FL peach FL potato   Occurrence (nature, food, other):note   not found in nature   Synonyms: 2- ethyl-2,5-dihydro-4,5-dimethyl thiazole 2- ethyl-2,5-dihydro-4,5-dimethylthiazole 2- ethyl-4,5-dimethyl thiazoline 2- ethyl-4,5-dimethyl-1,3-thiazoline 2- ethyl-4,5-dimethyl-2,5-dihydro-1,3-thiazole 2- ethyl-4,5-dimethyl-3-thiazoline 2- ethyl-4,5-dimethylthiazoline   thiazole, 2-ethyl-2,5-dihydro-4,5-dimethyl-   thiazole, 2,5-dihydro-4,5-dimethyl-2-ethyl- 3- thiazoline, 2-ethyl-4,5-dimethyl- 3- thiazoline, 4,5-dimethyl-2-ethyl-   Articles:   None found yet. Try the PubMed Search.

Notes: Maillard prod. in foods. Flavouring agent for meats and soups, doubtless as a mixt. of cis- and trans-forms