EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

S-furfuryl thioformate
2-furanmethanethiolformate

Supplier Sponsors

Name:S-(furan-2-ylmethyl) methanethioate
CAS Number: 59020-90-5Picture of molecule3D/inchi
FDA UNII: JK1M930RJC
Nikkaji Web:J308.593G
MDL:MFCD00209507
CoE Number:11770
XlogP3-AA:1.30 (est)
Molecular Weight:142.17722000
Formula:C6 H6 O2 S
NMR Predictor:Predict (works with chrome, Edge or firefox)
EFSA/JECFA Comments:
Register name to be changed to: S-Furfuryl thioformate.
Category:flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
JECFA Food Flavoring:1073 S-furfuryl thioformate
DG SANTE Food Flavourings:13.051 S-furfuryl thioformate
FEMA Number:3158 S-furfuryl thioformate
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):59020-90-5 ; 2-FURANMETHANETHIOL FORMATE
 
Physical Properties:
Appearance:colorless to yellow brown clear liquid (est)
Assay: 97.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:1.21300 to 1.22300 @ 20.00 °C.
Pounds per Gallon - (est).: 10.105 to 10.188
Refractive Index:1.53900 to 1.54900 @ 20.00 °C.
Boiling Point: 66.00 °C. @ 15.00 mm Hg
Boiling Point: 80.00 to 87.00 °C. @ 10.00 mm Hg
Vapor Pressure:0.102000 mmHg @ 25.00 °C. (est)
Flash Point:> 230.00 °F. TCC ( > 110.00 °C. )
logP (o/w): 1.051 (est)
Soluble in:
 alcohol
 water, 5723 mg/L @ 25 °C (est)
Insoluble in:
 water
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Organoleptic Properties:
Odor Type: sulfurous
sulfurous coffee nutty
Odor Description:at 0.10 % in dipropylene glycol. sulfurous coffee nutty
Flavor Type: sulfurous
coffee
Taste Description: coffee
Odor and/or flavor descriptions from others (if found).
 
Cosmetic Information:
None found
 
Suppliers:
Ambles Nature et Chimie
FURFURYL THIOFORMATE
BOC Sciences
For experimental / research use only.
2-Furanmethanethiol formate 98.0%
Endeavour Specialty Chemicals
2-Furanmethanethiol formate
Speciality Chemical Product Groups
Jinan Enlighten Chemical Technology(Wutong Aroma )
S-Furfuryl thioformate Kosherk
Kingchem Laboratories
FURFURYL THIOFORMATE (2-Furanmethanethiol formate)
M&U International
FURFURYL THIOFORMATE, Kosher
Penta International
2-FURANMETHANETHIOL FORMATE
R C Treatt & Co Ltd
2-Furanmethanethiol formate
Halal, Kosher
Odor: coffee
Flavor: coffee
Used in coffee, meat and nut flavours, for meat products at 1ppm, bakery and soft/frozen confectionery at 0.5ppm, and desserts at 0.2ppm.
Robinson Brothers
2-Furanmethanethiol formate
https://www.robinsonbrothers.uk/chemistry-competences
Santa Cruz Biotechnology
For experimental / research use only.
S-Furfuryl Thioformate
Sigma-Aldrich
2-Furanmethanethiol formate, ≥97%, FG
Odor: butterscotch; horseradish; tropical; ethereal; coffee; wine-like
Certified Food Grade Products
Sunaux International
Furfuryl Thioformate
Synerzine
2-Furanmethanethiol Formate
TCI AMERICA
For experimental / research use only.
S-Furfuryl Thioformate >95.0%(GC)
Tengzhou Jitian Aroma Chemiclal
S-Furfuryl Thioformate
Tengzhou Xiang Yuan Aroma Chemicals
Furfuryl Thioformate
United International
Furfuryl Thioformate
 
Safety Information:
Preferred SDS: View
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
Not determined
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for S-furfuryl thioformate usage levels up to:
  0.0200 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 1.30 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.02 (μg/capita/day)
NOEL (No Observed Effect Level): 0.83 (mg/kg bw per day)
Structure Class: III
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 4
Click here to view publication 4
 average usual ppmaverage maximum ppm
baked goods: --
beverages(nonalcoholic): -1.00000
beverages(alcoholic): --
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: --
egg products: --
fats / oils: --
fish products: --
frozen dairy: -1.00000
fruit ices: -1.00000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: -1.00000
imitation dairy: --
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: --
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: --
soups: --
sugar substitutes: --
sweet sauces: --
 
Safety References:
European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 13 (FGE.13); Furfuryl and furan derivatives with and without additional side-chain substituents and heteroatoms from chemical group 14 (Commission Regulation (EC) No 1565/2000 of 18
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 13Rev1: Furfuryl and furan derivatives with and without additional side-chain substituents and heteroatoms from chemical group 14
View page or View pdf

Consideration of sulfur-substituted furan derivatives used as flavouring agents evaluated by JECFA (59th meeting) structurally related to a subgroup of substances within the group of “Furfuryl and furan derivatives with and without additional side-chain substituents and heteroatoms from chemical group 14” evaluated by EFSA in FGE.13Rev1 (2009)
View page or View pdf

Flavouring Group Evaluation 67 (FGE.67): Consideration of 40 furan-substituted aliphatic hydrocarbons, alcohols, aldehydes, ketones, carboxylic acids and related esters, sulfides, disulfides and ethers evaluated by JECFA at the 65th meeting (JECFA, 2006b) and re-evaluated at the 69th meeting (JECFA, 2009c)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 67, Revision 1 (FGE.67Rev.1): Consideration of 40 furan-substituted aliphatic hydrocarbons, alcohols, aldehydes, ketones, carboxylic acids and related esters, sulfides, disulfides and ethers evaluated by JECFA at the 65th meeting (JECFA, 2006b) and re-evaluated at the 69th meeting (JECFA, 2009c)
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 65, Revision 1 (FGE.65Rev1): Consideration of sulfur-substituted furan derivatives used as flavouring agents evaluated by JECFA (59th meeting) structurally related to a subgroup of substances within the group of ‘Furfuryl and furan derivatives with and without additional side-chain substituents and heteroatoms from chemical group 14’ evaluated by EFSA in FGE.13Rev2 (2011)
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):59020-90-5
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :62144
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:3
S-(furan-2-ylmethyl) methanethioate
Chemidplus:0059020905
 
References:
 S-(furan-2-ylmethyl) methanethioate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:59020-90-5
Pubchem (cid):62144
Pubchem (sid):135019981
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
HMDB (The Human Metabolome Database):HMDB37731
FooDB:FDB016861
Export Tariff Code:2932.19.1000
ChemSpider:View
EFSA Update of results on the monitoring of furan levels in food:Read Report
EFSA Previous report: Results on the monitoring of furan levels in food:Read Report
EFSA Report of the CONTAM Panel on provisional findings on furan in food:Read Report
 
Potential Blenders and core components note
For Odor
No odor group found for these
2,3,5-
trimethyl phenol
FR
alliaceous
alliaceous
methyl furfuryl disulfide
FL/FR
balsamic
2-
acetyl furan
FL/FR
burnt
2-
ethyl-3,5(or 6)-dimethyl pyrazine
FL/FR
caramellic
coffee dione
FL/FR
cyclotene
FL/FR
fenugreek absolute
FL/FR
fenugreek oleoresin
FL/FR
iso
propenyl pyrazine
FL/FR
chocolate
cocoa hexenal
FL/FR
2,6-
dimethyl pyrazine
FL/FR
2,4,5-
trimethyl thiazole
FL/FR
cocoa
2-
methyl butyraldehyde
FL/FR
coffee
cichorium intybus root extract
FL/FR
cichorium intybus root solid extract
FL/FR
roasted
coffea arabica seed extract
FL/FR
coffea arabica seed extract
FL/FR
coffea arabica seed oil
FL/FR
coffee absolute
FL/FR
arabica
coffee bean butter
FL/FR
roasted arabica
coffee bean essence
FL/FR
roasted
coffee bean extract
FL/FR
roasted arabica
coffee bean oil
FL/FR
roasted arabica
coffee bean oil CO2 extract
FL/FR
coffee bean oil extract
FL/FR
coffee difuran
FL/FR
coffee resinoid
FL/FR
furfuryl mercaptan
FL/FR
1-
hydroxy-2-butanone
FL/FR
2-
methyl-3-,5 or 6-(furfuryl thio) pyrazine
FL/FR
earthy
nutty pyrazine
FL/FR
fruity
tropical thiazole
FL/FR
herbal
thymyl methyl ether
FL/FR
medicinal
2,6-
xylenol
FL/FR
musty
menthofuran
FL/FR
nutty
3,5-
cocoa pyrazine
FL/FR
2,3-
dimethyl pyrazine
FL/FR
4,5-
dimethyl-2-ethyl-3-thiazoline
FL/FR
2-
ethyl-4-methyl thiazole
FL/FR
filbert heptenone
FL/FR
2,6-
lutidine
FL/FR
5-
methyl quinoxaline
FL/FR
2-
methyl thio-3,5 or 6-methyl pyrazine
FL/FR
2,3,5,6-
tetramethyl pyrazine
FL/FR
2,3,5-
trimethyl pyrazine
FL/FR
popcorn
2-
acetyl pyrazine
FL/FR
sulfurous
benzothiazole
FL/FR
furfuryl thioacetate
FL/FR
2-
methyl 5-(methyl thio) furan
FL/FR
O-
methyl S-1-methoxyhexan-3-yl carbonothioate
FL/FR
vegetable
1-
furfuryl pyrrole
FL/FR
tetrahydrofurfuryl alcohol
FL/FR
woody
juniper berry oleoresin
FL/FR
For Flavor
No flavor group found for these
2,5-
dimethyl-3-thiofuroyl furan
FL
2-
ethyl-3,5(or 6)-dimethyl pyrazine
FL/FR
2-
methyl-3-,5 or 6-(furfuryl thio) pyrazine
FL/FR
absinthe
absinthe
absinthe flavor
FL
alliaceous
benzyl mercaptan
FL
dicyclohexyl disulfide
FL
tropical thiazole
FL/FR
brown
fenugreek oleoresin
FL/FR
1-
hydroxy-2-butanone
FL/FR
burnt
furfuryl alcohol
FL
1-(2-
furfuryl thio) propanone
FL
2-
methyl quinoxaline
FL
iso
propenyl pyrazine
FL/FR
2,6-
xylenol
FL/FR
caramellic
caramel furanone
FL
cyclotene
FL/FR
fenugreek absolute
FL/FR
fenugreek distillates
FL
chocolate
mocha cream flavor
FL
cocoa
cocoa hexenal
FL/FR
2-
methyl furan
FL
coffee
cappuccino flavor
FL
chicory flavor
FL
chicory root distillates
FL
chicory root essence
FL
roasted
chicory root oil
FL
chicory tincture
FL
cichorium intybus root extract
FL/FR
cichorium intybus root solid extract
FL/FR
coffea arabica seed extract
FL/FR
roasted
coffea arabica seed extract
FL/FR
coffea arabica seed oil
FL/FR
coffea canephora seed extract
FL
coffee absolute
FL/FR
arabica
coffee bean butter
FL/FR
roasted
coffee bean concentrate
FL
roasted
coffee bean essence
FL
roasted robusta
coffee bean essence
FL
roasted arabica
coffee bean essence
FL/FR
roasted robusta
coffee bean extract
FL
dried roasted
coffee bean extract
FL
roasted
coffee bean extract
FL/FR
roasted arabica
coffee bean oil CO2 extract
FL/FR
coffee bean oil extract
FL/FR
coffee creme brulee flavor
FL
coffee difuran
FL/FR
coffee dione
FL/FR
coffee distillates
FL
espresso
coffee distillates
FL
coffee enhancers
FL
espresso
coffee essence
FL
espresso
coffee extract
FL
coffee flavor
FL
espresso
coffee flavor
FL
irish
coffee flavor
FL
dark roast
coffee flavor
FL
coffee liqueur flavor
FL
coffee pyrazine
FL
coffee resinoid
FL/FR
coffee royale flavor
FL
difurfuryl ether
FL
diisoamyl thiomalate
FL
2,4-
dimethyl thiazole
FL
2-
ethyl-4-methyl thiazole
FL/FR
furfuryl mercaptan
FL/FR
methyl furfuryl disulfide
FL/FR
methyl furfuryl mercaptopropionate
FL
2-
methyl-5-vinyl pyrazine
FL
2-iso
propyl pyrazine
FL
2-
thiophene thiol
FL
dairy
creme brulle coffee flavor
FL
earthy
difurfuryl sulfide
FL
fruity
furfuryl propionate
FL
fusel
2-
methyl butyraldehyde
FL/FR
green
3,4-
dimethoxystyrene
FL
2-
methyl-5-isopropyl pyrazine
FL
malty
malt flavor
FL
meaty
benzothiazole
FL/FR
2,6-
dimethyl pyrazine
FL/FR
3-
mercapto-2-butanone
FL
2-
methyl 3-(methyl thio) furan
FL
mustard
furfuryl methyl ether
FL
musty
2-
ethoxythiazole
FL
menthofuran
FL/FR
2-
methyl 5-(methyl thio) furan
FL/FR
thymyl methyl ether
FL/FR
2,3,5-
trimethyl pyrazine
FL/FR
nutty
2-
acetyl furan
FL/FR
3,5(6)-
cocoa pyrazine
FL
3,5-
cocoa pyrazine
FL/FR
2,3-
dimethyl pyrazine
FL/FR
4,5-
dimethyl-2-ethyl-3-thiazoline
FL/FR
filbert heptenone
FL/FR
hazelnut flavor
FL
hazelnut paste
FL
2,6-
lutidine
FL/FR
5-
methyl quinoxaline
FL/FR
2-
methyl thio-3,5 or 6-methyl pyrazine
FL/FR
nutty pyrazine
FL/FR
nutty thiazole
FL
tetrahydrofurfuryl alcohol
FL/FR
2,3,5,6-
tetramethyl pyrazine
FL/FR
2,4,5-
trimethyl thiazole
FL/FR
onion
furfuryl isopropyl sulfide
FL
roasted
2-
acetyl pyrazine
FL/FR
roasted arabica
coffee bean oil
FL/FR
ethyl 3-(furfuryl thio) propionate
FL
furfuryl thioacetate
FL/FR
O-
methyl S-1-methoxyhexan-3-yl carbonothioate
FL/FR
smoky
dextro-
xylose
FL
spicy
cinnamon hazelnut cappuccino flavor
FL
sulfurous
butyl mercaptan
FL
ethyl methyl sulfide
FL
S-
ethyl thioacetate
FL
furfuryl thiopropionate
FL
3-
methyl-2-butane thiol
FL
2-
thienyl mercaptan
FL
vegetable
1-
furfuryl pyrrole
FL/FR
woody
juniper berry oleoresin
FL/FR
 
Potential Uses:
FLcoffee
FLmeat
FLnut
 
Occurrence (nature, food, other):note
 not found in nature
 
Synonyms:
2-furan methane thiol formate
S-(furan-2-ylmethyl) methanethioate
2-furanmethanethiol formate
2-2-furanmethanethiol formate
2-furanmethanethiolformate
3-(2-furanyl methyl) methane thioate
S-(2-furanyl methyl) methane thioate
3-(2-furanylmethyl) methanethioate
 furfuryl thioformate
 furfuryl thioformate (2-furanmethanethiol formate)
 furfuryl thiol formate
 furfurylthioformate
 furfurylthiol butyrate
 furfurylthiol formate
2-furyl methyl sulfanyl formaldehyde
 methane thioic acid 3-(2-furanyl methyl) ester
 methane thioic acid S-(2-furanyl methyl) ester
 methanethioic acid, 3-(2-furanylmethyl) ester
 methanethioic acid, S-(2-furanylmethyl) ester
 
 
Notes:
Flavouring ingredient
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