[(Z)-hex-3-enyl] 2-hydroxypropanoate (Click)
IUPAC Name: [(Z)-hex-3-enyl] 2-hydroxypropanoate
Std.InChI: InChI=1S/C9H16O3/c1-3-4-5-6-7-12-9(11)8(2)10/h4-5,8,10H,3,6-7H2,1-2H3/b5-4-
InChI: InChI=1/C9H16O3/c1-3-4-5-6-7-12-9(11)8(2)10/h4-5,8,10H,3,6-7H2,1-2H3/b5-4-
Std.InChIKey: NNLLMULULOBXBY-PLNGDYQASA-N
InChIKey: NNLLMULULOBXBY-PLNGDYQABR
SMILES: CC\C=C/CCOC(=O)C(C)O
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CAS Number: | 61931-81-5 |
ECHA EC Number: | 263-337-4 |
FDA UNII: | 55ET6N4SAG |
MDL: | MFCD00036495 |
FEMA Number: | 3690 |
CoE Number: | 10681 |
XlogP3-AA: | 1.60 (est) |
Molecular Weight: | 172.22412000 |
Formula: | C9 H16 O3 |
NMR Predictor: | Predict |
Category: | flavor and fragrance agents |
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US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: |
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JECFA Food Flavoring: | 934 cis-3-hexenyl lactate |
Flavis Number: | 09.545 (Old) |
EU SANCO Food Flavourings: | 09.545 hex-(3Z)-enyl lactate
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FEMA Number: | 3690 cis-3-hexenyl lactate |
FDA Mainterm: | CIS-3-HEXENYL LACTATE |
Physical Properties:
Appearance: | colorless clear liquid (est) |
Assay: | 95.00 to 100.00 % sum of isomers
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 0.96800 to 0.98400 @ 25.00 °C.
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Pounds per Gallon - (est).: | 8.055 to 8.188
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Refractive Index: | 1.44100 to 1.45100 @ 20.00 °C.
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Boiling Point: | 71.00 °C. @ 0.70 mm Hg
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Boiling Point: | 96.00 °C. @ 7.00 mm Hg
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Acid Value: | 1.00 max. KOH/g
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Vapor Pressure: | 0.003000 mm/Hg @ 25.00 °C. (est) |
Flash Point: | 235.00 °F. TCC ( 112.78 °C. )
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logP (o/w): | 1.575 (est) |
Shelf Life: | 24.00 month(s) or longer if stored properly. |
Storage: | store in cool, dry place in tightly sealed containers, protected from heat and light. |
Organoleptic Properties:
Odor Type: | green |
Odor Strength: | medium |
Odor Description: at 100.00 %. | green leafy sweet melon waxy violet leaf tropical fruity Luebke, William tgsc, (2009) |
Odor sample from: | Bedoukian Research, Inc. |
Odor Description:
| Green leafy, sweet with melon and vegetable nuances Mosciano, Gerard P&F 14, No. 6, 47, (1989) |
Taste Description: at 50.00 ppm. | Green leafy waxy with fruity tropical nuances Mosciano, Gerard P&F 14, No. 6, 47, (1989) |
Substantivity: | 21 hour(s) at 100.00 % |
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Cosmetic Information:
Suppliers:
A.C.S. International |
cis-3-Hexenyl Lactate
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Advanced Biotech |
cis-3-HEXENYL LACTATE NATURAL
98% min. (mixed isomers) |
Alfrebro |
cis-3-HEXENYL LACTATE NATURAL
Odor: Green, Fruity, Sweet, Green Bean, Melon |
Apiscent Labs |
C3 HEXENYL LACTATE
Odor: Very mild green, fruity sweet |
Apple Flavor & Fragrance |
cis-3-Hexenyl lactate
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Aurochemicals |
cis-3-HEXENYL LACTATE, Natural
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Bedoukian Research |
cis-3-HEXENYL LACTATE
≥97.0% (cis), Kosher Odor: A green, waxy odor with melon undertones Use: Provides a mild, fruity topnote to fragrances. Flavor: green Can be used in strawberry, tomato, pear, caramel, apple, melon and vegetable flavors. |
Bedoukian Research |
cis-3-HEXENYL LACTATE, NO ANTIOXIDANT
≥98.0% (sum of isomers), Special Order Odor: A green, waxy odor with melon undertones Use: Provides a mild, fruity topnote to fragrances. Flavor: green Can be used in strawberry, tomato, pear, caramel, apple, melon and vegetable flavors. |
Berjé |
cis-3-Hexenyl Lactate
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CTC Organics |
cis-3-hexenyl lactate
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Fleurchem |
cis-3-hexenyl lactate natural
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Indukern F&F |
CIS-3-HEXENYL LACTATE
Odor: FRUITY, SWEET, MELON |
Inoue Perfumery |
CIS-3-HEXENYL LACTATE
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Lluch Essence |
cis-3-HEXENYL LACTATE
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M&U International |
cis 3-HEXENYL LACTATE, Kosher
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PCW France |
cis-3-Hexenyl Lactate
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Penta International |
cis-3-HEXENYL LACTATE, Kosher
| Penta International |
cis-3-HEXENYL LACTATE, NATURAL, Kosher
| Reincke & Fichtner |
cis-3-Hexenyl Lactate
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Robertet |
HEXENYL CIS-3 LACTATE (HYDROXYPROPANOATE)
Pure & Nat (EU) |
Crops calendar |
SAFC Global |
cis-3-Hexenyl lactate
≥98%, Kosher Odor: fruity; green |
Shanghai Vigen Fine Chemical |
cis-3-Hexenyl Lactate
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The Lermond Company |
cis-3-Hexenyl Lactate
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ZEON Chemicals |
cis-3-Hexenyl lactate
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Safety Information:
European information : |
Most important hazard(s): | Xi - Irritant |
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R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: | |
Not determined
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Dermal Toxicity: | |
Not determined
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Inhalation Toxicity: | |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
Maximised Survey-derived Daily Intakes (MSDI-EU): | 33.00 (μg/capita/day) |
Maximised Survey-derived Daily Intakes (MSDI-USA): | 5.00 (μg/capita/day) |
Structure Class: | I |
Recommendation for (Z)-3-hexen-1-yl lactate usage levels up to: | | 10.0000 % in the fragrance concentrate.
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Recommendation for (Z)-3-hexen-1-yl lactate flavor usage levels up to: | | 50.0000 ppm in the finished product.
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Safety References:
References:
Other Information:
Potential Blenders and core components note
| acetaldehyde ethyl phenethyl acetal | FL/FR |
2- | acetyl-3-methyl pyrazine | FL/FR |
| allyl amyl glycolate | FR |
iso | amyl acetate | FL/FR |
iso | amyl butyrate | FL/FR |
iso | amyl isovalerate | FL/FR |
iso | amyl salicylate | FL/FR |
| amyris wood oil | FL/FR |
para- | anisyl acetate | FL/FR |
para- | anisyl alcohol | FL/FR |
| benzyl acetate | FL/FR |
| benzyl alcohol | FL/FR |
| benzyl benzoate | FL/FR |
| benzyl isobutyrate | FL/FR |
| benzyl propionate | FL/FR |
| benzyl salicylate | FL/FR |
| bergamot oil | FL/FR |
blood | orange oil italy | FL/FR |
| bois de rose oil brazil | FL/FR |
| butyl isobutyrate | FL/FR |
2-(2- | butyl)-4,5-dimethyl-3-thiazoline | FL |
| cinnamyl isovalerate | FL/FR |
| citronellol | FL/FR |
| citronellyl acetate | FL/FR |
| citrus carbaldehyde | FR |
| clary sage oil france | FL/FR |
| clover nitrile | FR |
| coriander seed oil | FL/FR |
| cortex pyridine | FL/FR |
| costus root absolute | FL |
| costus root oil | FL |
| costus root resinoid | FL |
| cyclamen aldehyde | FL/FR |
| cyclohexyl ethyl alcohol | FL/FR |
| cyclopentyl mercaptan | FL |
(E,E)-2,4- | decadienal | FL |
2,4- | decadien-1-ol | FL/FR |
| decanal (aldehyde C-10) | FL/FR |
| diethyl sebacate | FL/FR |
3,5- | diethyl-2-methyl pyrazine | FL |
| dihydroxyacetophenone (mixed isomers) | FL |
| diisopropyl sulfide | FL |
| dimethyl benzyl carbinol | FL/FR |
| dimethyl disulfide | FL/FR |
| dimethyl sulfide | FL/FR |
4,5- | dimethyl-2-ethyl-3-thiazoline | FL/FR |
2,4- | dimethyl-3-cyclohexene-1-methanyl acetate | FR |
(E,Z)-2,6- | dodecadienal | FL/FR |
2- | ethoxythiazole | FL |
| ethyl (E,Z)-2,4-decadienoate | FL/FR |
| ethyl (E)-2-hexenoate | FL/FR |
| ethyl 3-(furfuryl thio) propionate | FL |
| ethyl acetoacetate | FL/FR |
| ethyl cinnamate | FL/FR |
| ethyl heptanoate | FL/FR |
| ethyl pyruvate | FL/FR |
2- | ethyl-4,5-dimethyl oxazole | FL |
| floral pyranol | FR |
| furfuryl methyl sulfide | FL |
1- | furfuryl pyrrole | FL/FR |
| gardenia oxide | FR |
| geraniol | FL/FR |
| geranium thiazole | FL/FR |
| geranyl acetate | FL/FR |
(E)- | geranyl acetone | FL/FR |
| grapefruit menthane | FL/FR |
| grapefruit pentanol | FR |
| green acetate | FR |
| green heptenal | FR |
| hazelnut pyrazine | FL/FR |
| heliotropyl acetone | FL/FR |
(E,E)-2,4- | heptadienal | FL |
(E)-2- | heptenal | FL |
(Z)-4- | heptenal | FL/FR |
(Z)-3- | hepten-1-ol | FL/FR |
| hexanal propylene glycol acetal | FL/FR |
(E)-4- | hexenal | FL |
2- | hexenal | FL |
3- | hexenal | FL/FR |
(Z)-3- | hexen-1-ol | FL/FR |
4- | hexenol | FL/FR |
(Z)-3- | hexen-1-yl (E)-crotonate | FL/FR |
(Z)-3- | hexen-1-yl (Z)-3-hexenoate | FL/FR |
(Z)-3- | hexen-1-yl 2-methyl butyrate | FL/FR |
(Z)-3- | hexen-1-yl acetate | FL/FR |
(Z)-3- | hexen-1-yl benzoate | FL/FR |
(Z)-3- | hexen-1-yl formate | FL/FR |
(Z)-3- | hexen-1-yl phenyl acetate | FL/FR |
(Z)-3- | hexen-1-yl pyruvate | FL/FR |
(Z)-3- | hexen-1-yl salicylate | FL/FR |
(Z)-3- | hexen-1-yl tiglate | FL/FR |
| hexyl 2-methyl butyrate | FL/FR |
| hexyl 2-methyl-3-pentenoate | FL/FR |
| hexyl acetate | FL/FR |
alpha- | hexyl cinnamaldehyde | FL/FR |
| hexyl hexanoate | FL/FR |
| hexyl tiglate | FL/FR |
| ho leaf oil | FR |
| hyacinth ether | FR |
2'- | hydroxyacetophenone | FL/FR |
2,4- | ivy carbaldehyde | FL/FR |
| jalapeno oleoresin | FL |
| leerall | FR |
| linalool | FL/FR |
laevo- | linalool | FL/FR |
| linalool oxide | FL/FR |
| linalyl acetate | FL/FR |
| lychee mercaptan acetate | FL/FR |
| marine pyridine | FR |
| melon acetal | FL/FR |
| melon carboxaldehyde | FR |
| melon heptenal | FL/FR |
| melon nonenoate | FL/FR |
| manzanate | FL/FR |
3- | mercapto-3-methyl butanol | FL |
3- | mercaptohexyl butyrate | FL |
| mesityl oxide | FL/FR |
| methional | FL/FR |
| methoxycitronellal | FR |
| methoxymelonal | FL/FR |
| methyl (E)-3-nonenoate | FL |
| methyl 2-methyl valerate | FL/FR |
| methyl 2-methyl-3-furyl disulfide | FL |
| methyl 3-(methyl thio) propionate | FL/FR |
| methyl 3-nonenoate | FL/FR |
| methyl benzyl disulfide | FL |
| methyl cinnamate | FL/FR |
| methyl dihydrojasmonate | FL/FR |
| methyl furfuryl disulfide | FL/FR |
| methyl heptenone | FL/FR |
| methyl heptine carbonate | FL/FR |
| methyl octanoate | FL/FR |
| methyl octine carbonate | FL/FR |
para- | methyl phenoxyacetaldehyde | FR |
2- | methyl thiazole | FL |
1- | methyl thio-2-propanone | FL |
2- | methyl thio-3,5 or 6-methyl pyrazine | FL/FR |
4-( | methyl thio) butanol | FL |
3-( | methyl thio) hexanol | FL/FR |
2- | methyl thioacetaldehyde | FL |
| methyl thiomethyl butyrate | FL |
2- | methyl-1,3-dithiolane | FL |
3-(5- | methyl-2-furyl) butanal | FL |
2- | methyl-3-(methyl thio) pyrazine | FL/FR |
5- | methyl-5-hexen-2-one | FL/FR |
2- | methyl-5-methoxythiazole | FL |
| mimosa absolute france | FL/FR |
| muguet carbaldehyde | FR |
| muguet carboxaldehyde | FR |
| nerol | FL/FR |
| nerolidol | FL/FR |
| neryl acetate | FL/FR |
(E,E)-2,6- | nonadienal | FL |
(E,Z)-2,6- | nonadien-1-ol | FL/FR |
(E,Z)-3,6- | nonadien-1-ol | FL/FR |
(Z,Z)-3,6- | nonadien-1-ol | FL/FR |
2,4- | nonadien-1-ol | FL/FR |
2,6- | nonadien-1-ol | FL/FR |
(E,Z)-3,6- | nonadien-1-yl acetate | FL/FR |
3,6- | nonadien-1-yl acetate | FL/FR |
| nonanal (aldehyde C-9) | FL/FR |
| nonanol | FL/FR |
(Z)-6- | nonenal | FL/FR |
(E)-2- | nonen-1-ol | FL/FR |
(Z)-2- | nonen-1-ol | FL/FR |
(Z)-3- | nonen-1-ol | FL/FR |
(Z)-6- | nonen-1-ol | FL/FR |
(Z)-6- | nonen-1-yl acetate | FL/FR |
| ocean propanal | FL/FR |
(E,E)-2,4- | octadienal | FL |
2,4- | octadienal | FL |
3- | octanol | FL/FR |
(Z)-3- | octen-1-ol | FL/FR |
(Z)-5- | octen-1-ol | FL/FR |
2- | octen-1-ol | FL/FR |
(Z)-3- | octen-1-yl propionate | FL/FR |
(Z)-5- | octen-1-yl propionate | FL/FR |
3- | octen-2-ol | FL/FR |
1- | octen-3-ol | FL/FR |
(E)-2- | octenoic acid | FL |
4- | penten-1-yl acetate | FL |
1- | penten-3-ol | FL/FR |
2- | pentyl furan | FL/FR |
| peony alcohol | FR |
| petitgrain oil paraguay | FL/FR |
| phenethyl acetate | FL/FR |
| phenyl acetaldehyde dimethyl acetal | FL/FR |
3- | phenyl propionaldehyde | FL/FR |
| potato butanone | FL |
| propyl 2,4-decadienoate | FL/FR |
| propyl isobutyrate | FL/FR |
| propyl nonanoate | FL/FR |
2- | propyl pyrazine | FL |
| propyl thioacetate | FL |
iso | propyl tiglate | FL/FR |
2-iso | propyl-3-(methyl thio) pyrazine | FL |
| propylene glycol acetone ketal | FL |
| radish isothiocyanate | FL |
| raspberry ketone methyl ether | FL/FR |
| rhodinol | FL/FR |
| rose butanoate | FL/FR |
| santall | FR |
| styralyl acetate | FL/FR |
alpha- | terpineol | FL/FR |
| tetrahydrofurfuryl alcohol | FL/FR |
| tetrahydrolinalool | FL/FR |
3- | tetrahydrothiophenone | FL |
2,4,5- | trimethyl thiazole | FL/FR |
| tropical indene | FR |
| tropical thiazole | FL/FR |
| tuberose absolute (from pommade) | FL/FR |
gamma- | undecalactone (aldehyde C-14 (so-called)) | FL/FR |
| veramoss | FR |
| vinyl sulfurol | FL/FR |
| violet leaf absolute | FL/FR |
| violet methyl carbonate | FR |
| watermelon ketone | FR |
(Z)- | woody amylene | FR |
| yeast thiazoline | FL |
Potential Uses:
Natural Occurrence in: note
Synonyms:
| hex-(3Z)-enyl lactate | (3Z)- | hex-3-en-1-yl 2-hydroxypropanoate | (Z)- | hex-3-enyl lactate | [(Z)- | hex-3-enyl] 2-hydroxypropanoate | (Z)-3- | hexen-1-yl 2-hydroxypropanoate | cis-3- | hexen-1-yl 2-hydroxypropanoate | (Z)-3- | hexen-1-yl lactate | cis-3- | hexen-1-yl lactate | cis-3- | hexenyl 2-hydroxypropanoate | 3- | hexenyl 2-hydroxypropanoate, cis- | | hexenyl cis-3 lactate (hydroxypropanoate) | (Z)-3- | hexenyl lactate | C3 | hexenyl lactate | cis-3- | hexenyl lactate | cis-3- | hexenyl lactate natural | 3- | hexenyl lactate, (Z)- | 3- | hexenyl lactate, cis- | cis-3- | hexenyl lactate, no antioxidant | 2- | hydroxypropanoic acid (3Z)-3-hexen-1-yl ester | (Z)- | hydroxypropanoic acid 3-hexen-1-yl ester | | lactic acid cis-3-hexen-1-yl ester | | lactic acid cis-3-hexenyl ester | | leaf lactate | | popanoic acid, 2-hydroxy-, (3Z)-3-hexenyl ester | | propanoic acid, 2-hydroxy-, (3Z)-3-hexen-1-yl ester | | propanoic acid, 2-hydroxy-, 3-hexenyl ester, (Z)- |
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