2,4-dimethyl-3-cyclohexene-1-methanyl acetate
citrolate (IFF)

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Fragrance Demo Formulas Name: (3,5-dimethyl-1-cyclohex-3-enyl)methyl acetate CAS Number: 67634-25-7 3D/inchi ECHA EINECS - REACH Pre-Reg: 266-830-2 FDA UNII: Search Nikkaji Web: J333.259D XlogP3-AA: 2.10 (est) Molecular Weight: 182.26286000 Formula: C11 H18 O2 NMR Predictor: Predict (works with chrome, Edge or firefox) Also(can) Contains: 2,4-dimethyl cyclohex-3-ene-1-methyl acetate Category: fragrance agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search   Physical Properties: Appearance: pale yellow clear liquid (est) Assay: 90.00 to 100.00 sum of isomers Food Chemicals Codex Listed: No Specific Gravity: 0.96000 to 0.96900 @ 25.00 °C. Pounds per Gallon - (est).: 7.988 to 8.063 Specific Gravity: 0.96100 to 0.97000 @ 20.00 °C. Pounds per Gallon - est.: 8.006 to 8.081 Refractive Index: 1.46200 to 1.46700 @ 20.00 °C. Boiling Point: 225.75 °C. @ 760.00 mm Hg (est) Vapor Pressure: 0.085000 mmHg @ 25.00 °C. (est) Flash Point: 185.00 °F. TCC ( 85.00 °C. ) logP (o/w): 3.480 Shelf Life: 36.00 month(s) or longer if stored properly. Storage: store in cool, dry place in tightly sealed containers, protected from heat and light. Soluble in:   alcohol   water, 25.89 mg/L @ 25 °C (est) Insoluble in:   water Stability:   alcoholic lotion   antiperspirant   deo stick   detergent   fabric softener   hard surface cleaner   shampoo   soap   Organoleptic Properties: Odor Type: citrus Odor Strength:medium Substantivity:24 hour(s) at 100.00 % citrus floral green grapefruit gardenia petal Odor Description:at 100.00 %. citrus floral green grapefruit gardenia petal Luebke, William tgsc, (1988) Odor sample from: International Flavors & Fragrances Inc. Odor and/or flavor descriptions from others (if found). IFF Citrolate™ Odor Description:Citrus, grapefruit note also reminiscent of the dry notes of bitter orange oil and melon. Useful in colognes as a freshener to overcome the candy-sweet notes of orange and lemon oil Lluch Essence JAFFARAL Odor Description:GRAPEFRUIT, RHUBARB , GREEN Perfumery Laboratory CITROLATE ™ IFF (CITROLATE ™ IFF) Odor Description:Fresh, citrus fragrance with notes of grapefruit, melon and bitter orange Tadimety Aromatics Agrumenyl Acetate Odor Description:Citrus, Neroli, Grape Fruit   Cosmetic Information: CosIng: cosmetic data Cosmetic Uses: perfuming agents   Suppliers: Augustus Oils Floralate Services Azelis UK Citrolate™ Ernesto Ventós FLORALATE IFF Odor: CITRUS, FRUITY, GRAPEFRUIT, DRY Global Essence Jaffaral IFF Citrolate™ Odor: Citrus, grapefruit note also reminiscent of the dry notes of bitter orange oil and melon. Useful in colognes as a freshener to overcome the candy-sweet notes of orange and lemon oil Kun Shan P&A Floralate Lluch Essence JAFFARAL Odor: GRAPEFRUIT, RHUBARB , GREEN M&U International Citrolate (Floralate) Penta International 2,4-DIMETHYL-3-CYCLOHEXENE-1-METHANYL ACETATE Perfumery Laboratory CITROLATE ™ IFF (CITROLATE ™ IFF) Odor: Fresh, citrus fragrance with notes of grapefruit, melon and bitter orange Tadimety Aromatics Agrumenyl Acetate Odor: Citrus, Neroli, Grape Fruit Taytonn ASCC Floralate The John D. Walsh Company Floralate sds Tianjin Danjun International (3,5-Dimethyl-1-cyclohex-3-enyl)methyl acetat   Safety Information: European information : Most important hazard(s): Xi - Irritant R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: Not determined Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: fragrance agents RIFM Fragrance Material Safety Assessment: Search IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice Recommendation for 2,4-dimethyl-3-cyclohexene-1-methanyl acetate usage levels up to:   5.0000 % in the fragrance concentrate.   Recommendation for 2,4-dimethyl-3-cyclohexene-1-methanyl acetate flavor usage levels up to:   not for flavor use.   Safety References: EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA Substance Registry Services (TSCA):67634-25-7 EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :106748 National Institute of Allergy and Infectious Diseases:Data WGK Germany:2 (3,5-dimethyl-1-cyclohex-3-enyl)methyl acetate Chemidplus:0067634257   References:   (3,5-dimethyl-1-cyclohex-3-enyl)methyl acetate NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 67634-25-7 Pubchem (cid): 106748 Pubchem (sid): 135062617   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements HMDB (The Human Metabolome Database): Search Export Tariff Code: 2915.39.9050 ChemSpider: View   Potential Blenders and core components note For Odor No odor group found for these 2- ethyl-N-methyl-N-(3-methyl phenyl) butyramide FR aldehydic aldehydic iso butyraldehyde FL/FR decanal (aldehyde C-10) FL/FR 6,7,8- decen-1-ol FR dodecanal (aldehyde C-12 lauric) FL/FR (Z)-4- dodecenal FL/FR mandarine undecenal FL/FR 3- methyl-4-hexyl oxybutyraldehyde FR nonanal (aldehyde C-9) FL/FR TMH aldehyde FR tridecanal FL/FR balsamic abies alba cone oil FR cinnamyl formate FL/FR citronella 4,8- dimethyl-7-nonen-2-ol FR citrus acetaldehyde citronellyl methyl acetal FR benzyl anthranilate FR bergamot oil FL/FR bergamot oil bergaptene reduced italy FL/FR bergamot oil turkey FL/FR beta- bisabolol FL/FR citral diethyl acetal FL/FR citral dimethyl acetal FL/FR citrus floral green fragrance FR citrus ocimenol FR citrus specialty FR dihydromyrcenol FL/FR dimethyl octenone FR dodecane nitrile FR 2- dodecanone FL/FR citrus floral fragrance FR grapefruit indene FR grapefruit mercaptan FL/FR grapefruit nitrile FR grapefruit oil c.p. california FL/FR grapefruit oil CO2 extract (citrus paradisi macf. var. falvedo) FL/FR grapefruit oil terpeneless FL/FR grapefruit pentanol FR lime octadienal FR lime oil distilled mexico FL/FR mandarin oil FL/FR mandarin oil italy FL/FR 3- methyl-4-(2-methyl butyl oxy) butyraldehyde FR myrmac aldehyde FR nonanal dimethyl acetal FL/FR (+)- nootkatone FL/FR sweet orange peel oil c.p. brazil FL/FR sweet orange peel oil terpeneless FL/FR rhubafuran FR alpha- terpinyl methyl ether FL/FR (E)-2- tetradecenal FL/FR 2- tetradecenal FL/FR (±)-2,4,8- trimethyl-7-nonen-2-ol FL/FR valencene FL/FR verbena fragrance FR ethereal ethyl acetate FL/FR fatty 2- decenal FL/FR (Z)-3- octen-1-ol FL/FR floral acetaldehyde dibutyl acetal FL/FR amyl benzoate FL/FR amyl salicylate FL/FR anisyl propanal / methyl anthranilate schiff's base FR bois de rose oil brazil FL/FR boronia concrete FL/FR alpha- butyl cinnamaldehyde FL/FR cassis oxime 10% FR citronellyl acetate FL/FR citronellyl propionate FL/FR coriander seed oil CO2 extract FL/FR cumin carbinol FR dictamnus hispanicus oil FR dihydrocarvyl acetate FL/FR (±)-2,3- dihydrofarnesol FL/FR dihydroisojasmonate methyl ester FR dimethyl benzyl carbinol FL/FR dimethyl benzyl carbinyl butyrate FL/FR 6,8- dimethyl-2-nonanol FR 2,4- dimethyl-3-cyclohexene-1-methanol FR ethyl phenoxyacetate FR farnesol FL/FR farnesyl acetate FL/FR floral butanal FR floral undecenone FR gardenia absolute FR gardenia acetal FR gardenia amide FR gardenia concrete FR gardenia decalone FR gardenia pentyl acetate FR geranium oil FL/FR geranium oil africa FL/FR geranyl acetone FL/FR geranyl formate FL/FR (Z)-4- hepten-2-yl salicylate FR (Z)-3- hexen-1-yl salicylate FL/FR alpha- hexyl cinnamaldehyde FL/FR hexyl lactate FL/FR hyacinth oil FR hydrangea fragrance FR hydroxycitronellal diethyl acetal FL/FR hydroxycitronellal propylene glycol acetal FL/FR jasmin cyclopentanol FR jonquil absolute FR lilac absolute FR lily fragrance FR lily propanol FR linalool FL/FR linalyl phenyl acetate FL/FR lotus fragrance FR magnolia indene FR (2- methoxy-1-methyl propyl) benzene FR (3- methoxy-2-methyl propyl) benzene FR methoxycitronellal FR 1-(2- methyl allyl oxy)-2-methyl butane FR mimosa absolute FL/FR mimosa absolute france FL/FR mimosa absolute india FL/FR muguet dienal FR muguet nitrile FR nerol FL/FR neroli oil CO2 extract FL/FR neroli oil tunisia FL/FR nerolidol FL/FR (E)- nerolidol FL/FR nerolidyl acetate FL/FR neryl acetate FL/FR neryl isovalerate FL/FR ocean propanal FL/FR ocean propanal / methyl anthranilate schiff's base FR orange leaf absolute FL/FR bitter orangeflower absolute tunisia FL/FR orchid specialty FR palmarosa oil FL/FR papaya isobutyrate FL/FR peony acetonitrile FR petitgrain concrete FR petitgrain lemon oil FL/FR petitgrain oil morocco FL/FR phenyl acetaldehyde dicitronellyl acetal FR phenyl acetaldehyde diisobutyl acetal FL/FR 2- phenyl propionaldehyde ethylene glycol acetal FR rhodinyl formate FL/FR rose butanoate FL/FR laevo- rose oxide FL/FR (Z)- rose oxide FL/FR rose pyran FR styralyl formate FL/FR sweet pea absolute FR terpinyl formate FL/FR terpinyl isobutyrate FL/FR tetrahydrolinalyl acetate FR 5- tricyclodecenyl acetate FR (E)-2,5,9- trimethyl-4,9-decadien-1-al FR undecanal dimethyl acetal FR verdyl acetate FR violet methyl carbonate FR ylang ylang flower oil III FL/FR fresh 3-(3- propen-2-yl phenyl) butanal FR fruity benzyl methyl ether FL/FR iso butyl methyl anthranilate FL/FR citronellyl isobutyrate FL/FR cyclohexyl crotonate FR diethyl sebacate FL/FR dimethyl succinate FL/FR ethyl 3-hydroxyhexanoate FL/FR ethyl isobutyrate FL/FR ethyl methyl-para-tolyl glycidate FL/FR grape butyrate FL/FR grapefruit acetal FR heptanal cyclic ethylene acetal FR peach pivalate FR solanone FL/FR tropical ionone FL/FR 2- undecenal FL/FR (E)-2- undecenal FL/FR fungal jasmin nonane FR green iso amyl 3-(2-furan) propionate FL/FR iso butyl benzyl carbinol FL/FR chrysanthemum oxide FL/FR citrus carbaldehyde / methyl anthranilate schiff's base FR 3,7- dimethyl-6-octenoic acid FL/FR earthy acetal FL/FR flower hexene FR green carboxylate FR green cyclopropionate FR (Z)-3- hexen-1-yl acetoacetate FL/FR (Z)-3- hexen-1-yl angelate FR hexen-1-yl oxypropane nitrile FR (Z)-3- hexen-1-yl pyruvate FL/FR hexyl (Z)-tiglate FL/FR hyacinth absolute FL/FR ivy dioxolane FR melon acetal FL/FR melon nonenoate FL/FR (2- methoxy-1-methyl butyl) benzene FR [(4E,4Z)-5- methoxy-3-methyl-4-penten-1-yl] benzene FR methyl cyclocitrone (IFF) FR para- methyl hydratropaldehyde FL/FR methyl octine carbonate FL/FR 4- methyl-4-phenyl pentanone FR (Z)-5- octen-1-ol FL/FR octyl oxyacetaldehyde FR pelargonium graveolens stem leaf extract FR phenyl acetaldehyde solution FL/FR herbal 6- acetoxydihydrotheaspirane FL/FR chrysanthemum ketone FR clary sage absolute FL/FR coriander oleoresin FL/FR dihexyl (E)-fumarate FR linalyl acetate FL/FR 2- methyl butyl salicylate FL/FR (1S,5R)- myrtenyl acetate FL/FR 3- octyl acetate FL/FR phenyl acetaldehyde diisoamyl acetal FR alpha- terpinyl acetate FL/FR medicinal kunzea ericoides leaf oil FR melon (Z)-6- nonen-1-yl acetate FL/FR (Z)-6- nonenal FL/FR spicy cinnamyl propionate FL/FR iso cyclogeraniol (IFF) FR spicy carbonate FR sulfurous grapefruit menthane FL/FR tea camellia oleifera leaf extract FL/FR terpenic (E,E)-2,6-allo ocimene FL/FR waxy decanal dimethyl acetal FL/FR 3- decanone FL/FR 1- undecanol FL/FR For Flavor No flavor group found for these acetaldehyde dibutyl acetal FL/FR 6- acetoxydihydrotheaspirane FL/FR amyl benzoate FL/FR boronia concrete FL/FR iso butyl methyl anthranilate FL/FR beta- cubebene FL decanal dimethyl acetal FL/FR 3- decanone FL/FR dihydronootkatone FL (Z)-4- dodecenal FL/FR earthy acetal FL/FR (Z)-3- hexen-1-yl acetoacetate FL/FR hexyl (Z)-tiglate FL/FR hyacinth absolute FL/FR hydroxycitronellal propylene glycol acetal FL/FR linalyl phenyl acetate FL/FR 4- mercapto-4-methyl-2-pentanol FL 2- methyl butyl salicylate FL/FR nerolidyl acetate FL/FR (E,E)-2,6-allo ocimene FL/FR phenyl acetaldehyde solution FL/FR solanone FL/FR styralyl formate FL/FR terpinyl isobutyrate FL/FR 2- tetradecenal FL/FR iso amyl 3-(2-furan) propionate FL/FR alpha- butyl cinnamaldehyde FL/FR aldehydic aldehydic iso butyraldehyde FL/FR nonanal (aldehyde C-9) FL/FR 1- undecanol FL/FR amber iso butyl benzyl carbinol FL/FR aromatic amyl salicylate FL/FR citrus bergamot oil FL/FR bergamot oil bergaptene reduced italy FL/FR bergamot oil turkey FL/FR beta- bisabolol FL/FR citral diethyl acetal FL/FR citral dimethyl acetal FL/FR dehydronootkatone FL grapefruit mercaptan FL/FR grapefruit oil c.p. california FL/FR grapefruit oil CO2 extract (citrus paradisi macf. var. falvedo) FL/FR grapefruit oil terpeneless FL/FR lime oil distilled mexico FL/FR linalool FL/FR mandarin oil FL/FR mandarin oil italy FL/FR nerol FL/FR neroli oil tunisia FL/FR (+)- nootkatone FL/FR sweet orange peel oil c.p. brazil FL/FR sweet orange peel oil terpeneless FL/FR petitgrain lemon oil FL/FR petitgrain oil morocco FL/FR (±)-2,4,8- trimethyl-7-nonen-2-ol FL/FR valencene FL/FR ethereal ethyl acetate FL/FR ethyl isobutyrate FL/FR fatty 2- decenal FL/FR (E,E)-2,4- dodecadienal FL 2- dodecanone FL/FR (Z)-3- octen-1-ol FL/FR floral bois de rose oil brazil FL/FR cinnamyl propionate FL/FR citronellyl acetate FL/FR citronellyl propionate FL/FR dihydrocarvyl acetate FL/FR (±)-2,3- dihydrofarnesol FL/FR dimethyl benzyl carbinyl butyrate FL/FR 3,7- dimethyl-6-octenoic acid FL/FR farnesol FL/FR farnesyl acetate FL/FR geranium oil FL/FR geranium oil africa FL/FR geranyl acetone FL/FR linalyl acetate FL/FR neroli oil CO2 extract FL/FR neryl acetate FL/FR ocean propanal FL/FR orange leaf absolute FL/FR bitter orangeflower absolute tunisia FL/FR laevo- rose oxide FL/FR tropical ionone FL/FR ylang ylang flower oil III FL/FR fruity benzyl methyl ether FL/FR citronellyl isobutyrate FL/FR diethyl sebacate FL/FR dimethyl succinate FL/FR ethyl 3-hydroxyhexanoate FL/FR ethyl methyl-para-tolyl glycidate FL/FR hexyl lactate FL/FR neryl isovalerate FL/FR rhodinyl formate FL/FR rose butanoate FL/FR terpinyl formate FL/FR grassy palmarosa oil FL/FR green chrysanthemum oxide FL/FR dihydromyrcenol FL/FR geranyl formate FL/FR grape butyrate FL/FR (Z)-3- hexen-1-yl pyruvate FL/FR (Z)-3- hexen-1-yl salicylate FL/FR melon acetal FL/FR melon nonenoate FL/FR para- methyl hydratropaldehyde FL/FR methyl octine carbonate FL/FR (E)- nerolidol FL/FR nerolidol FL/FR nonanal dimethyl acetal FL/FR (Z)-6- nonen-1-yl acetate FL/FR (Z)-6- nonenal FL/FR (Z)-5- octen-1-ol FL/FR 3- octyl acetate FL/FR papaya isobutyrate FL/FR phenyl acetaldehyde diisobutyl acetal FL/FR (Z)- rose oxide FL/FR herbal clary sage absolute FL/FR coriander oleoresin FL/FR coriander seed oil CO2 extract FL/FR medicinal dimethyl benzyl carbinol FL/FR melon hydroxycitronellal diethyl acetal FL/FR soapy dodecanal (aldehyde C-12 lauric) FL/FR spicy cinnamyl formate FL/FR sulfurous grapefruit menthane FL/FR 1- methyl thio-2-propanone FL tea camellia oleifera leaf extract FL/FR waxy decanal (aldehyde C-10) FL/FR alpha- hexyl cinnamaldehyde FL/FR mandarine undecenal FL/FR mimosa absolute FL/FR mimosa absolute france FL/FR mimosa absolute india FL/FR (E)-2- tetradecenal FL/FR tridecanal FL/FR (E)-2- undecenal FL/FR 2- undecenal FL/FR woody (1S,5R)- myrtenyl acetate FL/FR alpha- terpinyl acetate FL/FR alpha- terpinyl methyl ether FL/FR   Potential Uses: FR citrus FR grapefruit FR green FR melon FL/FR orange bitter orange peel   Occurrence (nature, food, other):note   not found in nature   Synonyms:   agrumenyl acetate (Tadimety)   citrolate (IFF) 3- cyclohexene-1-methanol, 3,5-dimethyl-, acetate 3,5- dimethyl cyclohex-3-ene-1-methyl acetate (3,5- dimethyl-1-cyclohex-3-enyl)methyl acetate 2,4- dimethyl-3-cyclohexene-1-methanyl acetate 3,5- dimethyl-3-cyclohexene-1-methyl acetate 3,5- dimethylcyclohex-3-ene-1-methyl acetate   floralate   jaffaral   Articles:   None found yet. Try the PubMed Search.

Notes: To overcome the candy sweet notes from lemon and orange oils.