ivy dioxolane
glycolierral (Givaudan)

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  BOC Sciences

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  94087-23-7 1,3-Dioxolane,2-[5-methyl-7-(1-methylethyl)bicyclo[2.2.2]oct-5-en-2-yl]- 95%

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  Indukern, S.A. F&F Ingredients Division

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  GLYCOLIERRAL

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  05-68000 ETHYL-2,3,6,6-TETRAMETHYL-2-CYCLOHEXENECARBOXYLATE (MIXED ISOMERS

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  Vigon International

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  500894 Glycolierral

Fragrance Demo Formulas Name: 2-(2-methyl-5-propan-2-yl-7-bicyclo[2.2.2]oct-2-enyl)-1,3-dioxolane CAS Number: 68901-32-6 3D/inchi ECHA EINECS - REACH Pre-Reg: 272-669-9 FDA UNII: Search Nikkaji Web: J332.720E MDL: MFCD00672180 XlogP3-AA: 3.00 (est) Molecular Weight: 236.35468000 Formula: C15 H24 O2 NMR Predictor: Predict (works with chrome, Edge or firefox) Name: 2-(2-methyl-5-propan-2-yl-8-bicyclo[2.2.2]oct-2-enyl)-1,3-dioxolane CAS Number: 94087-23-7 3D/inchi ECHA EINECS - REACH Pre-Reg: 301-916-6 FDA UNII: Search Nikkaji Web: J368.035E XlogP3-AA: 3.00 (est) Molecular Weight: 236.35468000 Formula: C15 H24 O2 NMR Predictor: Predict (works with chrome, Edge or firefox) Category: fragrance agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search   Physical Properties: Appearance: colorless to pale yellow clear liquid (est) Assay: 98.00 to 100.00 sum of isomers Food Chemicals Codex Listed: No Boiling Point: 308.80 °C. @ 760.00 mm Hg (est) Vapor Pressure: 0.001000 mmHg @ 25.00 °C. (est) Flash Point: 284.00 °F. TCC ( 140.00 °C. ) logP (o/w): 4.007 (est) Soluble in:   alcohol   water, 4.73 mg/L @ 25 °C (est) Stability:   alcoholic - good   antiperspirant spray - moderate   APC (pH = 10) - good   candles - untested   damp fabric - moderate   dry fabric - poor   liquid bleach - poor   pH = 2 - good   powder detergent - moderate   powder detergent + activator - moderate   soap - good   toiletries - good   Organoleptic Properties: Odor Type: green Odor Strength:medium Substantivity:32 hour(s) at 100.00 % floral green milky privet cortex woody Odor Description:at 100.00 %. floral green milky privet cortex woody Luebke, William tgsc, (1985) Odor sample from: Roure Bertrand Dupont Inc. Odor and/or flavor descriptions from others (if found). Givaudan Glycolierral Odor Description:Soft Floral, Green, Milky, Ivy leaves, Woody Glycolierral offers a powerful yet soft, green, milky nuance when used as a green top note modifier. Moellhausen GLYCOLIERRAL Odor Description:fresh, herbaceous, soft floral-green, reminiscent of ivy leaves, woody Taste Description:fresh, herbaceous, somewhat floral, slightly woody   Cosmetic Information: CosIng: cosmetic data2 CosIng: cosmetic data Cosmetic Uses: perfuming agents   Suppliers: BOC Sciences For experimental / research use only. 1,3-Dioxolane,2-[5-methyl-7-(1-methylethyl)bicyclo[2.2.2]oct-5-en-2-yl]- 95% Givaudan Glycolierral Odor: Soft Floral, Green, Milky, Ivy leaves, Woody Use: Glycolierral offers a powerful yet soft, green, milky nuance when used as a green top note modifier. Global Essence Glycolierral Indukern F&F GLYCOLIERRAL Odor: FLORAL, FRUITY, GREEN Moellhausen GLYCOLIERRAL Odor: fresh, herbaceous, soft floral-green, reminiscent of ivy leaves, woody Flavor: fresh, herbaceous, somewhat floral, slightly woody Penta International ETHYL-2,3,6,6-TETRAMETHYL-2-CYCLOHEXENECARBOXYLATE (MIXED ISOMERS Vigon International Glycolierral Odor: Soft Floral, Green, Milky, Ivy leaves, Woody   Safety Information: European information : Most important hazard(s): Xi - Irritant R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: oral-rat LD50 8000 mg/kg Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: fragrance agents RIFM Fragrance Material Safety Assessment: Search IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice Recommendation for ivy dioxolane usage levels up to:   8.0000 % in the fragrance concentrate.   Recommendation for ivy dioxolane flavor usage levels up to:   not for flavor use.   Safety References: EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA Substance Registry Services (TSCA):68901-32-6 EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :111418 National Institute of Allergy and Infectious Diseases:Data WGK Germany:2 2-(2-methyl-5-propan-2-yl-7-bicyclo[2.2.2]oct-2-enyl)-1,3-dioxolane Chemidplus:0068901326 2-(2-methyl-5-propan-2-yl-8-bicyclo[2.2.2]oct-2-enyl)-1,3-dioxolane Chemidplus:094087237   References:   2-(2-methyl-5-propan-2-yl-7-bicyclo[2.2.2]oct-2-enyl)-1,3-dioxolane NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 68901-32-6 Pubchem (cid): 111418 Pubchem (sid): 135068141   2-(2-methyl-5-propan-2-yl-8-bicyclo[2.2.2]oct-2-enyl)-1,3-dioxolane NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 94087-23-7 Pubchem (cid): 44152860 Pubchem (sid): 3796315   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements HMDB (The Human Metabolome Database): Search ChemSpider: View   Potential Blenders and core components note For Odor aldehydic iso butyraldehyde FL/FR citrus carbaldehyde FR 6,7,8- decen-1-ol FR dodecanal (aldehyde C-12 lauric) FL/FR 3- methyl-4-hexyl oxybutyraldehyde FR animal para- cresyl caprylate FL/FR para- cresyl isobutyrate FL/FR para- cresyl phenyl acetate FL/FR anise sweet fennel seed oil FL/FR anisic ocimum basilicum herb oil FL/FR balsamic iso amyl benzoate FL/FR benzyl salicylate FL/FR cinnamyl alcohol FL/FR cinnamyl formate FL/FR ethyl cinnamate FL/FR 3- phenyl propyl alcohol FL/FR berry raspberry ketone methyl ether FL/FR citrus bergamot oil FL/FR bergamot oil bergaptene reduced italy FL/FR bergamot oil turkey FL/FR citral dimethyl acetal FL/FR citrus floral green fragrance FR dihydromyrcenol FL/FR 2,4- dimethyl-3-cyclohexene-1-methanyl acetate FR grapefruit pentanol FR mandarin oil (citrus reticulata var. ponkan) FL/FR methyl heptenone FL/FR nonanal dimethyl acetal FL/FR blood orange oil italy FL/FR (E)-2- tetradecenal FL/FR 2- tetradecenal FL/FR tetrahydromyrcenol FR fatty 2- decenal FL/FR floral acetaldehyde dibutyl acetal FL/FR amyl benzoate FL/FR alpha- amyl cinnamaldehyde FL/FR amyl salicylate FL/FR iso amyl salicylate FL/FR anisyl propanal / methyl anthranilate schiff's base FR benzyl acetate FL/FR benzyl alcohol FL/FR benzyl isobutyrate FL/FR bois de rose oil brazil FL/FR boronia concrete FL/FR alpha- butyl cinnamaldehyde FL/FR iso butyl salicylate FL/FR citronellol FL/FR citronellyl acetate FL/FR citronellyl propionate FL/FR coriander seed oil FL/FR coriander seed oil CO2 extract FL/FR para- cresyl acetate FL/FR cumin carbinol FR cyclamen aldehyde FL/FR cyclohexyl ethyl alcohol FL/FR dictamnus hispanicus oil FR dihydrocarvyl acetate FL/FR (±)-2,3- dihydrofarnesol FL/FR dihydroisojasmonate methyl ester FR dihydrojasmone FL/FR dimethyl anthranilate FL/FR dimethyl benzyl carbinol FL/FR dimethyl benzyl carbinyl butyrate FL/FR 6,8- dimethyl-2-nonanol FR ethyl phenoxyacetate FR farnesol FL/FR farnesyl acetate FL/FR floral butanal FR floral pyranol FR floral undecenone FR gardenia absolute FR gardenia acetal FR gardenia concrete FR geraniol FL/FR geranium oil FL/FR geranium oil africa FL/FR geranyl acetate FL/FR geranyl acetone FL/FR geranyl formate FL/FR heliotropyl acetone FL/FR (Z)-4- hepten-2-yl salicylate FR (Z)-3- hexen-1-yl salicylate FL/FR alpha- hexyl cinnamaldehyde FL/FR hexyl lactate FL/FR hyacinth ether FR hyacinth oil FR hydrangea fragrance FR hydroxycitronellal diethyl acetal FL/FR hydroxycitronellal propylene glycol acetal FL/FR jasmin cyclopentanol FR jonquil absolute FR leerall FR lilac absolute FR lily fragrance FR lily propanol FR laevo- linalool FL/FR linalool FL/FR linalool oxide FL/FR linalyl phenyl acetate FL/FR lotus fragrance FR magnolia indene FR (2- methoxy-1-methyl propyl) benzene FR (3- methoxy-2-methyl propyl) benzene FR 1-(2- methyl allyl oxy)-2-methyl butane FR methyl dihydrojasmonate FL/FR mimosa absolute FL/FR mimosa absolute france FL/FR mimosa absolute india FL/FR muguet dienal FR muguet octadienol FR nerol FL/FR neroli oil CO2 extract FL/FR (E)- nerolidol FL/FR nerolidol FL/FR neryl acetate FL/FR ocean propanal FL/FR ocean propanal / methyl anthranilate schiff's base FR orange leaf absolute FL/FR bitter orangeflower absolute tunisia FL/FR orchid specialty FR orris pyridine 25% IPM FR papaya isobutyrate FL/FR peony alcohol FR petitgrain oil paraguay FL/FR phenethyl acetate FL/FR phenethyl propionate FL/FR phenyl acetaldehyde dicitronellyl acetal FR phenyl acetaldehyde diisobutyl acetal FL/FR 2- phenyl propionaldehyde ethylene glycol acetal FR rhodinol FL/FR rhodinyl formate FL/FR rose butanoate FL/FR laevo- rose oxide FL/FR (Z)- rose oxide FL/FR rose pyran FR styralyl formate FL/FR sweet pea absolute FR terpinyl isobutyrate FL/FR tetrahydrolinalool FL/FR 5- tricyclodecenyl acetate FR tuberose absolute (from pommade) FL/FR verdyl acetate FR violet methyl carbonate FR ylang ylang flower oil FL/FR ylang ylang flower oil III FL/FR fresh 3-(3- propen-2-yl phenyl) butanal FR fruity allyl amyl glycolate FR allyl cyclohexyl propionate FL/FR benzyl methyl ether FL/FR benzyl propionate FL/FR citronellyl isobutyrate FL/FR cyclohexyl crotonate FR gamma- decalactone FL/FR dimethyl succinate FL/FR ethyl methyl-para-tolyl glycidate FL/FR green acetate FR peach pivalate FR strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR tropical ionone FL/FR gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR fungal jasmin nonane FR green iso amyl 3-(2-furan) propionate FL/FR iso butyl benzyl carbinol FL/FR chrysanthemum oxide FL/FR cortex pyridine FL/FR para- dimethyl hydroquinone FL/FR 3,7- dimethyl-6-octenoic acid FL/FR diphenyl oxide FL/FR earthy acetal FL/FR flower hexene FR galbanum oil FL/FR green cyclopropionate FR (Z)-3- hexen-1-ol FL/FR (Z)-3- hexen-1-yl acetate FL/FR (Z)-3- hexen-1-yl acetoacetate FL/FR (Z)-3- hexen-1-yl angelate FR (Z)-3- hexen-1-yl benzoate FL/FR (Z)-3- hexen-1-yl formate FL/FR hexen-1-yl oxypropane nitrile FR (Z)-3- hexen-1-yl tiglate FL/FR hexyl (Z)-tiglate FL/FR hexyl 2-methyl butyrate FL/FR hexyl tiglate FL/FR hyacinth absolute FL/FR 2,4- ivy carbaldehyde FL/FR (Z)- leaf acetal FL/FR melon nonenoate FL/FR (2- methoxy-1-methyl butyl) benzene FR [(4E,4Z)-5- methoxy-3-methyl-4-penten-1-yl] benzene FR methyl cyclocitrone (IFF) FR para- methyl hydratropaldehyde FL/FR methyl octine carbonate FL/FR 4- methyl-4-phenyl pentanone FR (E,Z)-2,6- nonadien-1-ol FL/FR (Z)-5- octen-1-ol FL/FR octyl oxyacetaldehyde FR pelargonium graveolens stem leaf extract FR phenyl acetaldehyde dimethyl acetal FL/FR phenyl acetaldehyde solution FL/FR privetone FR rose leaf absolute (rosa centifolia) FL/FR styralyl acetate FL/FR violet leaf absolute FL/FR herbal carum carvi fruit oil FL/FR chrysanthemum ketone FR clary acetate FR clary sage absolute FL/FR clary sage oil france FL/FR coriander oleoresin FL/FR dihexyl (E)-fumarate FR linalyl acetate FL/FR 2- methyl butyl salicylate FL/FR (1S,5R)- myrtenyl acetate FL/FR phenyl acetaldehyde diisoamyl acetal FR marine green algae absolute FL/FR medicinal kunzea ericoides leaf oil FR melon melon heptenal FL/FR (Z)-6- nonenal FL/FR naphthyl para- methyl anisole FL/FR powdery para- anisyl alcohol FL/FR spicy cinnamyl propionate FL/FR iso cyclogeraniol (IFF) FR pimenta acris leaf oil FL/FR spicy carbonate FR tea camellia oleifera leaf extract FL/FR terpenic alpha- terpineol FL/FR waxy 3- decanone FL/FR ethyl laurate FL/FR woody santall FR (Z)- woody amylene FR For Flavor No flavor group found for these acetaldehyde dibutyl acetal FL/FR green algae absolute FL/FR amyl benzoate FL/FR boronia concrete FL/FR 3- decanone FL/FR earthy acetal FL/FR (Z)-3- hexen-1-yl acetoacetate FL/FR hexyl (Z)-tiglate FL/FR hyacinth absolute FL/FR hydroxycitronellal propylene glycol acetal FL/FR linalyl phenyl acetate FL/FR 2- methyl butyl salicylate FL/FR phenyl acetaldehyde solution FL/FR styralyl formate FL/FR terpinyl isobutyrate FL/FR 2- tetradecenal FL/FR iso amyl 3-(2-furan) propionate FL/FR alpha- butyl cinnamaldehyde FL/FR aldehydic aldehydic iso butyraldehyde FL/FR amber iso butyl benzyl carbinol FL/FR animal para- cresyl caprylate FL/FR anise sweet fennel seed oil FL/FR apple (E,Z)-2,6- nonadien-1-ol FL/FR aromatic amyl salicylate FL/FR para- cresyl acetate FL/FR para- cresyl isobutyrate FL/FR balsamic benzyl salicylate FL/FR ethyl cinnamate FL/FR berry heliotropyl acetone FL/FR raspberry ketone methyl ether FL/FR citrus bergamot oil FL/FR bergamot oil bergaptene reduced italy FL/FR bergamot oil turkey FL/FR citral dimethyl acetal FL/FR laevo- linalool FL/FR linalool FL/FR mandarin oil (citrus reticulata var. ponkan) FL/FR nerol FL/FR blood orange oil italy FL/FR alpha- terpineol FL/FR cooling iso butyl salicylate FL/FR creamy gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR fatty 2- decenal FL/FR (Z)-3- hexen-1-yl benzoate FL/FR floral bois de rose oil brazil FL/FR cinnamyl propionate FL/FR citronellol FL/FR citronellyl acetate FL/FR citronellyl propionate FL/FR dihydrocarvyl acetate FL/FR (±)-2,3- dihydrofarnesol FL/FR dihydrojasmone FL/FR dimethyl benzyl carbinyl butyrate FL/FR 3,7- dimethyl-6-octenoic acid FL/FR farnesol FL/FR farnesyl acetate FL/FR geraniol FL/FR geranium oil FL/FR geranium oil africa FL/FR geranyl acetone FL/FR linalyl acetate FL/FR methyl dihydrojasmonate FL/FR neroli oil CO2 extract FL/FR neryl acetate FL/FR ocean propanal FL/FR orange leaf absolute FL/FR bitter orangeflower absolute tunisia FL/FR phenethyl propionate FL/FR rhodinol FL/FR laevo- rose oxide FL/FR tetrahydrolinalool FL/FR tropical ionone FL/FR tuberose absolute (from pommade) FL/FR ylang ylang flower oil FL/FR ylang ylang flower oil III FL/FR fruity allyl cyclohexyl propionate FL/FR iso amyl benzoate FL/FR para- anisyl alcohol FL/FR benzyl acetate FL/FR benzyl alcohol FL/FR benzyl isobutyrate FL/FR benzyl methyl ether FL/FR benzyl propionate FL/FR citronellyl isobutyrate FL/FR gamma- decalactone FL/FR dimethyl anthranilate FL/FR dimethyl succinate FL/FR ethyl methyl-para-tolyl glycidate FL/FR hexyl lactate FL/FR rhodinyl formate FL/FR rose butanoate FL/FR strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR styralyl acetate FL/FR green iso amyl salicylate FL/FR chrysanthemum oxide FL/FR cinnamyl alcohol FL/FR cortex pyridine FL/FR cyclamen aldehyde FL/FR cyclohexyl ethyl alcohol FL/FR dihydromyrcenol FL/FR para- dimethyl hydroquinone FL/FR diphenyl oxide FL/FR galbanum oil FL/FR geranyl acetate FL/FR geranyl formate FL/FR (Z)-3- hexen-1-ol FL/FR (Z)-3- hexen-1-yl acetate FL/FR (Z)-3- hexen-1-yl formate FL/FR (Z)-3- hexen-1-yl salicylate FL/FR (Z)-3- hexen-1-yl tiglate FL/FR hexyl 2-methyl butyrate FL/FR hexyl tiglate FL/FR 2,4- ivy carbaldehyde FL/FR (Z)- leaf acetal FL/FR linalool oxide FL/FR melon heptenal FL/FR melon nonenoate FL/FR methyl heptenone FL/FR para- methyl hydratropaldehyde FL/FR methyl octine carbonate FL/FR (E)- nerolidol FL/FR nerolidol FL/FR nonanal dimethyl acetal FL/FR (Z)-6- nonenal FL/FR (Z)-5- octen-1-ol FL/FR papaya isobutyrate FL/FR phenyl acetaldehyde diisobutyl acetal FL/FR phenyl acetaldehyde dimethyl acetal FL/FR rose leaf absolute (rosa centifolia) FL/FR (Z)- rose oxide FL/FR violet leaf absolute FL/FR herbal carum carvi fruit oil FL/FR clary sage absolute FL/FR clary sage oil france FL/FR coriander oleoresin FL/FR coriander seed oil FL/FR coriander seed oil CO2 extract FL/FR ocimum basilicum herb oil FL/FR petitgrain oil paraguay FL/FR honey phenethyl acetate FL/FR medicinal dimethyl benzyl carbinol FL/FR melon hydroxycitronellal diethyl acetal FL/FR naphthyl para- methyl anisole FL/FR phenolic para- cresyl phenyl acetate FL/FR soapy dodecanal (aldehyde C-12 lauric) FL/FR spicy cinnamyl formate FL/FR 3- phenyl propyl alcohol FL/FR pimenta acris leaf oil FL/FR tea camellia oleifera leaf extract FL/FR tropical alpha- amyl cinnamaldehyde FL/FR waxy ethyl laurate FL/FR alpha- hexyl cinnamaldehyde FL/FR mimosa absolute FL/FR mimosa absolute france FL/FR mimosa absolute india FL/FR (E)-2- tetradecenal FL/FR woody (1S,5R)- myrtenyl acetate FL/FR   Potential Uses: FR floral FR green FR ivy FR woody   Occurrence (nature, food, other):note   not found in nature   Synonyms:   glycolierral (Givaudan)   ivy dioxolane 2-(2- methyl-5-propan-2-yl-7-bicyclo[2.2.2]oct-2-enyl)-1,3-dioxolane 2(6)- methyl-8-(1-methyl ethyl) bicyclo(2.2.2)oct-5-en-2(3)-yl-1,3-dioxolane 2-(7-iso propyl-5-methyl bicyclo(2.2.2)oct-5-en-2-yl)-1,3-dioxolane 7-iso propyl-5-methyl bicyclooctenyl dioxolane 2-(8-iso propyl-6-methyl bicyclo(2.2.2)oct-5-en-2-yl)-1,3-dioxolane addition 8-iso propyl-6-methyl bicyclooctenyl dioxolane   Articles:   None found yet. Try the PubMed Search.

Notes: None found