anisyl propanal / methyl anthranilate schiff's base
canthoxal / methyl anthranilate schiff's base

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  BOC Sciences

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  Product(s):
  111753-62-9 Benzoic acid 2-[[3-(4-methoxyphenyl)-2-methylpropylidene]amino]-, methyl ester

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  Prodasynth

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  CANTHOXALIA (SUM OF ISOMERS > 92%)

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  99230050 Schiff canthoxal

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  Vigon International

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  501952 Methyl Anthranilate / Anisyl Propanal Schiff Base

Name: methyl 2-[[3-(4-methoxyphenyl)-2-methylpropylidene]amino]benzoate CAS Number: 111753-62-9 3D/inchi FDA UNII: Search Nikkaji Web: J1.558.078J XlogP3-AA: 3.80 (est) Molecular Weight: 311.38097000 Formula: C19 H21 N O3 NMR Predictor: Predict (works with chrome, Edge or firefox) Category:fragrance agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search   Physical Properties: Appearance: yellow solid paste (est) Assay: 90.00 to 100.00 sum of isomers Food Chemicals Codex Listed: No Specific Gravity: 1.09950 to 1.10750 @ 25.00 °C. Pounds per Gallon - (est).: 9.149 to 9.216 Refractive Index: 1.54800 to 1.55700 @ 20.00 °C. Boiling Point: 465.00 to 466.00 °C. @ 760.00 mm Hg Flash Point: 230.00 °F. TCC ( 110.00 °C. ) logP (o/w): 5.163 (est) Shelf Life: 48.00 month(s) or longer if stored properly. Soluble in:   alcohol   water, 1.461 mg/L @ 25 °C (est) Insoluble in:   water   Organoleptic Properties: Odor Type: floral Odor Strength:medium , recommend smelling in a 50.00 % solution or less Substantivity:400 hour(s) at 100.00 % sweet anise hawthorn green floral cortex mimosa spicy powdery Odor Description:at 50.00 % in dipropylene glycol. sweet anise hawthorn green floral cortex mimosa absolute spicy powdery Luebke, William tgsc, (1988) Odor sample from: Bedoukian Research, Inc. Odor and/or flavor descriptions from others (if found). Bedoukian Research SCHIFF'S BASE CANTHOXAL-METHYL ANTHRANILATE ≥92.0% (sum of isomers), Kosher Odor Description:A floral, powdery, spicy note Used in fine perfumes for its mimosa absolute character. Prodasynth CANTHOXALIA (SUM OF ISOMERS > 92%) Odor Description:SWEET, ANISE, GREEN, FLORAL Robertet Schiff canthoxal Odor Description:Floral, orange flower, marine   Cosmetic Information: None found   Suppliers: BOC Sciences For experimental / research use only. Benzoic acid 2-[[3-(4-methoxyphenyl)-2-methylpropylidene]amino]-, methyl ester Charabot Schiff canthoxal Odor: Floral, orange flower, marine Prodasynth CANTHOXALIA (SUM OF ISOMERS > 92%) Odor: SWEET, ANISE, GREEN, FLORAL Robertet Schiff canthoxal Odor: Floral, orange flower, marine Seasons and Harvest / Crop calendar Vigon International Methyl Anthranilate / Anisyl Propanal Schiff Base Odor: SWEET, FLORAL   Safety Information: European information : Most important hazard(s): Xi - Irritant R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: Not determined Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: fragrance agents RIFM Fragrance Material Safety Assessment: Search IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice IFRA Critical Effect: Sensitization IFRA fragrance material specification:   The IFRA Scientific Committee examined the physicochemical properties of Schiff bases and concluded that, based on the available information, these materials should be considered under contributions from other sources. By default, the stoichiometric presence of the aldehydes of the Schiff bases is taken into account assuming 100% dissociation. An indicative list of Schiff bases incorporating aldehydes covered by an IFRA Standard of restriction is reported at page 2. These Schiff bases must be taken into account for determination of the maximum use level of the respective aldehydes. contains the following IFRA (Annex) restricted components: (non-analysis max. level reference only) para-anisyl propanal Max. Found: 57.3 % and Reason: Sensitization Recommendation for anisyl propanal / methyl anthranilate schiff's base usage levels up to:   8.0000 % in the fragrance concentrate.   Recommendation for anisyl propanal / methyl anthranilate schiff's base flavor usage levels up to:   not for flavor use.   Safety References: EPI System: View EPA Substance Registry Services (TSCA):111753-62-9 EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :3034267 National Institute of Allergy and Infectious Diseases:Data WGK Germany:3 methyl 2-[[3-(4-methoxyphenyl)-2-methylpropylidene]amino]benzoate Chemidplus:0111753629   References:   methyl 2-[[3-(4-methoxyphenyl)-2-methylpropylidene]amino]benzoate NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 111753-62-9 Pubchem (cid): 3034267 Pubchem (sid): 135042434   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements HMDB (The Human Metabolome Database): Search Export Tariff Code: 2922.49.8050 ChemSpider: View   Potential Blenders and core components note For Odor aldehydic iso butyraldehyde FL/FR 6,7,8- decen-1-ol FR dodecanal (aldehyde C-12 lauric) FL/FR 3- methyl-4-hexyl oxybutyraldehyde FR 10- undecenal (aldehyde C-11 undecylenic) FL/FR amber cistus ladaniferus resinoid FL/FR anise anise seed oil FL/FR anisic para- anisaldehyde FL/FR balsamic 2- acetyl furan FL/FR iso amyl benzoate FL/FR amyris wood oil FL/FR siam benzoin resinoid FL/FR benzyl cinnamate FL/FR iso butyl cinnamate FL/FR cinnamyl alcohol FL/FR cinnamyl formate FL/FR clover nitrile FR ethyl cinnamate FL/FR fir balsam absolute FR methyl (E)-cinnamate FL/FR 3- phenyl propyl alcohol FL/FR berry raspberry ketone acetate FL/FR raspberry ketone methyl ether FL/FR caramellic cyclotene FL/FR maltol FL/FR strawberry furanone FL/FR chocolate iso amyl phenyl acetate FL/FR chocolate pyrazine A FL/FR citrus bergamot acetoacetate FR bergamot oil FL/FR bergamot oil bergaptene reduced italy FL/FR bergamot oil turkey FL/FR citral dimethyl acetal FL/FR citrus floral green fragrance FR 2,4- dimethyl-3-cyclohexene-1-methanyl acetate FR grapefruit pentanol FR nonanal dimethyl acetal FL/FR blood orange oil italy FL/FR sweet orange peel oil c.p. brazil FL/FR (E)-2- tetradecenal FL/FR 2- tetradecenal FL/FR coconut gamma- heptalactone FL/FR fatty decanol FL/FR 2- decenal FL/FR floral acetaldehyde dibutyl acetal FL/FR amyl benzoate FL/FR alpha- amyl cinnamaldehyde FL/FR amyl salicylate FL/FR iso amyl salicylate FL/FR benzyl acetate FL/FR benzyl isobutyrate FL/FR bois de rose oil brazil FL/FR boronia concrete FL/FR alpha- butyl cinnamaldehyde FL/FR citronellol FL/FR citronellyl acetate FL/FR citronellyl propionate FL/FR coriander seed oil FL/FR coriander seed oil CO2 extract FL/FR cumin carbinol FR cyclohexyl ethyl alcohol FL/FR 9- decen-1-ol FL/FR dictamnus hispanicus oil FR dihydrocarvyl acetate FL/FR (±)-2,3- dihydrofarnesol FL/FR dihydroisojasmonate methyl ester FR dimethyl anthranilate FL/FR dimethyl benzyl carbinol FL/FR dimethyl benzyl carbinyl acetate FL/FR dimethyl benzyl carbinyl butyrate FL/FR 6,8- dimethyl-2-nonanol FR ethyl phenoxyacetate FR ethyl phenyl acetate FL/FR farnesol FL/FR farnesyl acetate FL/FR floral butanal FR floral pyranol FR floral undecenone FR gardenia absolute FR gardenia acetal FR gardenia concrete FR geraniol FL/FR geranium oil FL/FR geranium oil africa FL/FR geranyl acetone FL/FR geranyl formate FL/FR hawthorn acetate FR heliotropin FL/FR heliotropyl acetate FL/FR heliotropyl acetone FL/FR (Z)-4- hepten-2-yl salicylate FR (Z)-3- hexen-1-yl salicylate FL/FR alpha- hexyl cinnamaldehyde FL/FR hexyl lactate FL/FR hyacinth ether FR hyacinth oil FR hydrangea fragrance FR hydroxycitronellal FL/FR hydroxycitronellal diethyl acetal FL/FR hydroxycitronellal propylene glycol acetal FL/FR jasmin cyclopentanol FR jonquil absolute FR leerall FR lilac absolute FR lily fragrance FR lily propanol FR laevo- linalool FL/FR linalool oxide FL/FR linalyl phenyl acetate FL/FR lotus fragrance FR magnolia indene FR (2- methoxy-1-methyl propyl) benzene FR (3- methoxy-2-methyl propyl) benzene FR 1-(2- methyl allyl oxy)-2-methyl butane FR methyl dihydrojasmonate FL/FR mimosa absolute FL/FR mimosa absolute france FL/FR mimosa absolute india FL/FR muguet carboxaldehyde FR muguet dienal FR nerol FL/FR neroli oil CO2 extract FL/FR nerolidol FL/FR (E)- nerolidol FL/FR nonanol FL/FR ocean propanal FL/FR ocean propanal / methyl anthranilate schiff's base FR orange leaf absolute FL/FR bitter orangeflower absolute tunisia FL/FR orchid specialty FR orris pyridine 25% IPM FR papaya isobutyrate FL/FR peony alcohol FR phenethyl acetate FL/FR phenethyl isobutyrate FL/FR phenethyl phenyl acetate FL/FR phenethyl propionate FL/FR phenyl acetaldehyde dicitronellyl acetal FR phenyl acetaldehyde diisobutyl acetal FL/FR 2- phenyl propionaldehyde ethylene glycol acetal FR rhodinol FL/FR rhodinyl formate FL/FR rose butanoate FL/FR (Z)- rose oxide FL/FR laevo- rose oxide FL/FR rose pyran FR styralyl formate FL/FR sweet pea absolute FR terpinyl isobutyrate FL/FR 5- tricyclodecenyl acetate FR verdyl acetate FR violet methyl carbonate FR ylang ylang flower oil FL/FR ylang ylang flower oil III FL/FR fresh 3-(3- propen-2-yl phenyl) butanal FR fruity allyl amyl glycolate FR allyl cyclohexyl propionate FL/FR iso amyl butyrate FL/FR benzyl methyl ether FL/FR benzyl propionate FL/FR citronellyl isobutyrate FL/FR cyclohexyl crotonate FR (E)-beta- damascone FL/FR (E)-alpha- damascone FL/FR gamma- decalactone FL/FR dimethyl benzyl carbinyl isobutyrate FR dimethyl succinate FL/FR ethyl heptanoate FL/FR ethyl methyl-para-tolyl glycidate FL/FR green acetate FR hexyl isovalerate FL/FR methyl 2-methyl valerate FL/FR peach pivalate FR strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR tropical ionone FL/FR gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR fungal jasmin nonane FR green acetaldehyde ethyl phenethyl acetal FL/FR iso amyl 3-(2-furan) propionate FL/FR iso butyl benzyl carbinol FL/FR chrysanthemum oxide FL/FR 3,7- dimethyl-6-octenoic acid FL/FR earthy acetal FL/FR flower hexene FR green cyclopropionate FR (Z)-3- hexen-1-yl acetate FL/FR (Z)-3- hexen-1-yl acetoacetate FL/FR (Z)-3- hexen-1-yl angelate FR (Z)-3- hexen-1-yl butyrate FL/FR hexen-1-yl oxypropane nitrile FR (Z)-3- hexen-1-yl propionate FL/FR hexyl (Z)-tiglate FL/FR hexyl 2-methyl butyrate FL/FR hyacinth absolute FL/FR ivy dioxolane FR melon nonenoate FL/FR (2- methoxy-1-methyl butyl) benzene FR [(4E,4Z)-5- methoxy-3-methyl-4-penten-1-yl] benzene FR methyl cyclocitrone (IFF) FR methyl heptine carbonate FL/FR para- methyl hydratropaldehyde FL/FR methyl octine carbonate FL/FR 4- methyl-4-phenyl pentanone FR octyl oxyacetaldehyde FR pelargonium graveolens stem leaf extract FR phenoxyacetaldehyde 50% in peomosa FR phenyl acetaldehyde solution FL/FR hay beeswax absolute FL/FR hay absolute FR herbal chrysanthemum ketone FR clary sage absolute FL/FR clary sage oil france FL/FR coriander oleoresin FL/FR dihexyl (E)-fumarate FR linalyl acetate FL/FR 2- methyl butyl salicylate FL/FR (1S,5R)- myrtenyl acetate FL/FR phenyl acetaldehyde diisoamyl acetal FR honey phenyl acetic acid FL/FR medicinal kunzea ericoides leaf oil FR melon (Z)-6- nonenal FL/FR watermelon ketone FR mossy veramoss (IFF) FR naphthyl beta- naphthyl ethyl ether FL/FR beta- naphthyl methyl ether FL/FR powdery para- anisyl acetate FL/FR para- anisyl alcohol FL/FR spicy cassia bark oil china FL/FR cinnamyl propionate FL/FR clove bud oil FL/FR black currant bud absolute FL/FR iso cyclogeraniol (IFF) FR iso eugenyl acetate FL/FR alpha- methyl cinnamaldehyde FL/FR nutmeg oil FL/FR spicy carbonate FR tea camellia oleifera leaf extract FL/FR terpenic alpha- terpineol FL/FR tonka gamma- hexalactone FL/FR tonka bean absolute FR vanilla ethyl vanillin FL/FR vanilla bean absolute (vanilla planifolia) FL/FR vanillyl acetate FL/FR waxy 3- decanone FL/FR 1- dodecanol FL/FR woody guaiacwood oil FL/FR gurjun balsam oil FR santall FR tobacarol (IFF) FR woody acetate FR (Z)- woody amylene FR woody propanol FR For Flavor No flavor group found for these acetaldehyde dibutyl acetal FL/FR amyl benzoate FL/FR boronia concrete FL/FR chocolate pyrazine A FL/FR cistus ladaniferus resinoid FL/FR 3- decanone FL/FR earthy acetal FL/FR (Z)-3- hexen-1-yl acetoacetate FL/FR hexyl (Z)-tiglate FL/FR hyacinth absolute FL/FR hydroxycitronellal propylene glycol acetal FL/FR linalyl phenyl acetate FL/FR methyl (E)-cinnamate FL/FR 2- methyl butyl salicylate FL/FR phenyl acetaldehyde solution FL/FR styralyl formate FL/FR terpinyl isobutyrate FL/FR 2- tetradecenal FL/FR iso amyl 3-(2-furan) propionate FL/FR alpha- butyl cinnamaldehyde FL/FR aldehydic aldehydic iso butyraldehyde FL/FR amber iso butyl benzyl carbinol FL/FR anise anise seed oil FL/FR aromatic amyl salicylate FL/FR balsamic siam benzoin resinoid FL/FR iso butyl cinnamate FL/FR ethyl cinnamate FL/FR berry heliotropyl acetone FL/FR raspberry ketone acetate FL/FR raspberry ketone methyl ether FL/FR brown beeswax absolute FL/FR caramellic cyclotene FL/FR maltol FL/FR strawberry furanone FL/FR cherry heliotropin FL/FR citrus bergamot oil FL/FR bergamot oil bergaptene reduced italy FL/FR bergamot oil turkey FL/FR citral dimethyl acetal FL/FR laevo- linalool FL/FR nerol FL/FR blood orange oil italy FL/FR sweet orange peel oil c.p. brazil FL/FR alpha- terpineol FL/FR creamy para- anisaldehyde FL/FR gamma- hexalactone FL/FR gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR fatty 2- decenal FL/FR 10- undecenal (aldehyde C-11 undecylenic) FL/FR floral iso amyl phenyl acetate FL/FR bois de rose oil brazil FL/FR cinnamyl propionate FL/FR citronellol FL/FR citronellyl acetate FL/FR citronellyl propionate FL/FR dihydrocarvyl acetate FL/FR (±)-2,3- dihydrofarnesol FL/FR dimethyl benzyl carbinyl acetate FL/FR dimethyl benzyl carbinyl butyrate FL/FR 3,7- dimethyl-6-octenoic acid FL/FR farnesol FL/FR farnesyl acetate FL/FR geraniol FL/FR geranium oil FL/FR geranium oil africa FL/FR geranyl acetone FL/FR heliotropyl acetate FL/FR linalyl acetate FL/FR methyl dihydrojasmonate FL/FR neroli oil CO2 extract FL/FR ocean propanal FL/FR orange leaf absolute FL/FR bitter orangeflower absolute tunisia FL/FR phenethyl propionate FL/FR phenyl acetic acid FL/FR rhodinol FL/FR laevo- rose oxide FL/FR tropical ionone FL/FR ylang ylang flower oil FL/FR ylang ylang flower oil III FL/FR fruity allyl cyclohexyl propionate FL/FR iso amyl benzoate FL/FR para- anisyl acetate FL/FR para- anisyl alcohol FL/FR benzyl acetate FL/FR benzyl isobutyrate FL/FR benzyl methyl ether FL/FR benzyl propionate FL/FR citronellyl isobutyrate FL/FR (E)-beta- damascone FL/FR (E)-alpha- damascone FL/FR gamma- decalactone FL/FR dimethyl anthranilate FL/FR dimethyl succinate FL/FR ethyl heptanoate FL/FR ethyl methyl-para-tolyl glycidate FL/FR hexyl lactate FL/FR methyl 2-methyl valerate FL/FR rhodinyl formate FL/FR rose butanoate FL/FR strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR green acetaldehyde ethyl phenethyl acetal FL/FR iso amyl salicylate FL/FR chrysanthemum oxide FL/FR cinnamyl alcohol FL/FR cyclohexyl ethyl alcohol FL/FR geranyl formate FL/FR (Z)-3- hexen-1-yl acetate FL/FR (Z)-3- hexen-1-yl butyrate FL/FR (Z)-3- hexen-1-yl propionate FL/FR (Z)-3- hexen-1-yl salicylate FL/FR hexyl 2-methyl butyrate FL/FR hexyl isovalerate FL/FR linalool oxide FL/FR melon nonenoate FL/FR methyl heptine carbonate FL/FR para- methyl hydratropaldehyde FL/FR methyl octine carbonate FL/FR (E)- nerolidol FL/FR nerolidol FL/FR nonanal dimethyl acetal FL/FR (Z)-6- nonenal FL/FR papaya isobutyrate FL/FR phenyl acetaldehyde diisobutyl acetal FL/FR (Z)- rose oxide FL/FR herbal clary sage absolute FL/FR clary sage oil france FL/FR coriander oleoresin FL/FR coriander seed oil FL/FR coriander seed oil CO2 extract FL/FR honey ethyl phenyl acetate FL/FR phenethyl acetate FL/FR phenethyl isobutyrate FL/FR phenethyl phenyl acetate FL/FR lactonic gamma- heptalactone FL/FR medicinal dimethyl benzyl carbinol FL/FR melon hydroxycitronellal diethyl acetal FL/FR naphthyl beta- naphthyl methyl ether FL/FR nutty 2- acetyl furan FL/FR powdery beta- naphthyl ethyl ether FL/FR soapy dodecanal (aldehyde C-12 lauric) FL/FR 1- dodecanol FL/FR spicy benzyl cinnamate FL/FR cassia bark oil china FL/FR cinnamyl formate FL/FR clove bud oil FL/FR black currant bud absolute FL/FR iso eugenyl acetate FL/FR alpha- methyl cinnamaldehyde FL/FR nutmeg oil FL/FR 3- phenyl propyl alcohol FL/FR tea camellia oleifera leaf extract FL/FR tropical alpha- amyl cinnamaldehyde FL/FR vanilla ethyl vanillin FL/FR vanilla bean absolute (vanilla planifolia) FL/FR vanillyl acetate FL/FR waxy iso amyl butyrate FL/FR decanol FL/FR 9- decen-1-ol FL/FR alpha- hexyl cinnamaldehyde FL/FR hydroxycitronellal FL/FR mimosa absolute FL/FR mimosa absolute france FL/FR mimosa absolute india FL/FR nonanol FL/FR (E)-2- tetradecenal FL/FR woody amyris wood oil FL/FR guaiacwood oil FL/FR (1S,5R)- myrtenyl acetate FL/FR   Potential Uses: FR angel essence FR anise FR crabapple FR apple red apple FR apricot FR balsam FR banana FR basil oil replacer FR bergamot FR blackberry   blossom tropical blossom FR blueberry FR bouquet FR boysenberry FR butterscotch FR cabreuva wood FR cassia FR cherry FR cherry black cherry FR cherry blossom FL chocolate cacao FR christmas FR chypre FR colonia FL cookie FR cotton candy FR country meadow FR crabapple blossom FR cranberry FR cucumber FR currant FR daffodil FR eglantine   fantasy blends FR fennel FR fern FR fetes FR fig FR fir balsam FR fir needle oil replacer FR floral FR forest FR frangipani plumeria FR freesia   fruit dried fruit FR gardenia FR gooseberry FR grape FR hawthorn FR heliotrope FR herbal FR hibiscus FR honeysuckle FR hyacinth FL jackfruit   jam FR jasmin FR kiwi blossom FR licorice FR lilac FR lily FR lily of the valley FR linden flower FR loganberry FR lychee FR magnolia FR mango FR mango flower FL marshmallow FR melon FR mimosa FR moss FR mulberry FR musk FL nectarine FR orange blossom FR oriental FR pansy FR papaya FR passion blossom FR passion fruit FR peach FR peach blossom FR peony FR pineapple FR plum FR plum blossom FR pomegranate FR raspberry FR raspberry black raspberry FR redwood FR rose FR rose white rose   rose wild rose FR scented stock FL starfruit FR strawberry FR sweet pea FR tobacco FR toffee FL tropical FR tuberose FL/FR valerian FR vanilla FR violet FR wallflower FR wisteria FR woody   Occurrence (nature, food, other):note   not found in nature   Synonyms:   benzoic acid, 2-((3-(4-methoxyphenyl)-2-methylpropylidene)amino)-, methyl ester 2-((3-(4- methoxyphenyl)-2-methyl propylidene)amino) benzoic acid methyl ester   methyl 2-[[3-(4-methoxyphenyl)-2-methylpropylidene]amino]benzoate   methyl anthranilate / anisyl propanal schiff's base   methyl anthranilate / canthoxal schiff's base   Articles:   None found yet.

Notes: None found