alpha-terpinyl methyl ether
orange flower ether (IFF)

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  Very nice top-note that adds a floral quality as well as citrus: distinctly grapefruit in character. Original IFF material “Description from IFF: Citrus (grapefruit) note also reminiscent of bergamot. Occurs naturally in orange flowers.”

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  ORANGE FLOWER ETHER IFF
  TERPINYL METHYL ETHER

Name: 4-(2-methoxypropan-2-yl)-1-methylcyclohexene CAS Number: 14576-08-0 3D/inchi ECHA EINECS - REACH Pre-Reg: 238-620-0 FDA UNII: J85U4SDI1I Nikkaji Web: J138.274H MDL: MFCD00217034 XlogP3-AA: 2.40 (est) Molecular Weight: 168.27960000 Formula: C11 H20 O BioActivity Summary: listing NMR Predictor: Predict (works with chrome, Edge or firefox) EFSA/JECFA Comments: Racemate. Category: flavor and fragrance agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search DG SANTE Food Flavourings: 03.020 alpha-terpinyl methyl ether   Physical Properties: Appearance: colorless to pale yellow clear liquid (est) Assay: 95.00 to 100.00 sum of isomers Food Chemicals Codex Listed: No Specific Gravity: 0.89600 to 0.90400 @ 25.00 °C. Pounds per Gallon - (est).: 7.456 to 7.522 Specific Gravity: 0.89700 to 0.90500 @ 20.00 °C. Pounds per Gallon - est.: 7.473 to 7.539 Refractive Index: 1.46400 to 1.46800 @ 20.00 °C. Boiling Point: 216.00 °C. @ 760.00 mm Hg Vapor Pressure: 0.458000 mmHg @ 25.00 °C. (est) Flash Point: 180.00 °F. TCC ( 82.22 °C. ) logP (o/w): 3.540 Shelf Life: 24.00 month(s) or longer if stored properly. Storage: store in cool, dry place in tightly sealed containers, protected from heat and light. Soluble in:   alcohol   water, 22.61 mg/L @ 25 °C (est) Insoluble in:   water Stability:   alcoholic lotion   antiperspirant   bleach   deo stick   detergent   fabric softener   shampoo   soap   Organoleptic Properties: Odor Type: citrus Odor Strength:medium Substantivity: < 4 hour(s) at 100.00 % citrus grapefruit bergamot orangeflower vegetable celery spicy earthy Odor Description:at 100.00 %. citrus grapefruit bergamot orangeflower vegetable celery spicy earthy Flavor Type: woody woody celery earthy sweet spicy Taste Description: woody celery earthy sweet spicy Odor and/or flavor descriptions from others (if found). IFF Orange Flower Ether Odor Description:Citrus (grapefruit) note also reminiscent of bergamot. Occurs naturally in orange flowers Taytonn ASCC Orange Flower Ether Odor Description:citrus grapefruit bergamot orangeflower Pell Wall Perfumes Orange Flower Ether Odor Description:Citrus-grapefruit and bergamot, fresh, neroli, orange flower Very nice top-note that adds a floral quality as well as citrus: distinctly grapefruit in character. Original IFF material “Description from IFF: Citrus (grapefruit) note also reminiscent of bergamot. Occurs naturally in orange flowers.”   Cosmetic Information: CosIng: cosmetic data Cosmetic Uses: perfuming agents   Suppliers: Azelis UK ORANGE FLOWER ETHER BOC Sciences For experimental / research use only. 4-(1-Methoxy-1-methylethyl)-1-methylcyclohexene Creatingperfume.com Orange Flower Ether (IFF) Odor: Citrus (grapefruit) note also reminiscent of bergamot Ernesto Ventós ORANGE FLOWER ETHER IFF Odor: CITRIC, GRAPEFRUIT, FLORAL, NEROLI Ernesto Ventós TERPINYL METHYL ETHER Odor: FLORAL, ORANGE BLOSSOM IFF Orange Flower Ether Odor: Citrus (grapefruit) note also reminiscent of bergamot. Occurs naturally in orange flowers Indukern F&F ORANGE FLOWER ETHER Odor: CITRUS, GRAPEFRUIT, FLORAL, NEROLI Kun Shan P&A Orange flower ether Lluch Essence TERPINYL METHYL ETHER M&U International Orange Flower Ether(IFF# : 202929) Pell Wall Perfumes Orange Flower Ether Odor: Citrus-grapefruit and bergamot, fresh, neroli, orange flower Use: Very nice top-note that adds a floral quality as well as citrus: distinctly grapefruit in character. Original IFF material “Description from IFF: Citrus (grapefruit) note also reminiscent of bergamot. Occurs naturally in orange flowers.” Penta International ORANGE FLOWER ETHER Perfumer Supply House Orange Flower Ether (Terpinyl Methyl Ether) Odor: Citrus, floral, grapefruit, bergamot, orange blossom Reincke & Fichtner Terpinyl Methyl Ether Taytonn ASCC Orange Flower Ether The John D. Walsh Company Orange Flower Ether sds Tianjin Danjun International Alpha-terpinyl methyl ether   Safety Information: European information : Most important hazard(s): Xi - Irritant R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: Not determined Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: flavor and fragrance agents RIFM Fragrance Material Safety Assessment: Search IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice Recommendation for alpha-terpinyl methyl ether usage levels up to:   5.0000 % in the fragrance concentrate.   Maximised Survey-derived Daily Intakes (MSDI-EU): 4.10 (μg/capita/day) Modified Theoretical Added Maximum Daily Intake (mTAMDI): 3200 (μg/person/day) Threshold of Concern: 90 (μg/person/day) Structure Class: III   Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.   average usage mg/kg maximum usage mg/kg Dairy products, excluding products of category 02.0 (01.0): 3.00000 15.00000 Fats and oils, and fat emulsions (type water-in-oil) (02.0): 2.00000 10.00000 Edible ices, including sherbet and sorbet (03.0): 3.00000 15.00000 Processed fruit (04.1): 2.00000 10.00000 Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): - - Confectionery (05.0): 10.00000 50.00000 Chewing gum (05.3): - - Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 5.00000 25.00000 Bakery wares (07.0): 10.00000 50.00000 Meat and meat products, including poultry and game (08.0): 2.00000 10.00000 Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): 2.00000 10.00000 Eggs and egg products (10.0): - - Sweeteners, including honey (11.0): - - Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 5.00000 25.00000 Foodstuffs intended for particular nutritional uses (13.0): 10.00000 50.00000 Non-alcoholic ("soft") beverages, excl. dairy products (14.1): 3.00000 15.00000 Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 10.00000 50.00000 Ready-to-eat savouries (15.0): 15.00000 75.00000 Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): 5.00000 25.00000   Safety References: European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... European Food Safety Authority (EFSA) reference(s): Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 23 (FGE.23): Aliphatic, alicyclic and aromatic ethers including anisole derivatives From chemical groups 15, 16 and 26 (Commission Regulation (EC) No 1565/2000 of 18 July 2000 View page or View pdf Flavouring Group Evaluation 59 (FGE.59): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 (2006) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) View page or View pdf Flavouring Group Evaluation 23, Revision 1 (FGE.23Rev1): Aliphatic, alicyclic and aromatic ethers including anisole derivatives from chemical groups 15, 16, 26 and 30[1] - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food View page or View pdf Scientific Opinion on Flavouring Group Evaluation 23, Revision 2 (FGE.23Rev2): Aliphatic, alicyclic and aromatic ethers including anisole derivatives from chemical groups 15, 16, 22, 26 and 30 View page or View pdf Scientific Opinion on Flavouring Group Evaluation 59, Revision 1 (FGE.59Rev1): Consideration of aliphatic and aromatic ethers evaluated by JECFA (61st meeting and 63rd meeting) structurally related to aliphatic, alicyclic and aromatic ethers including anisole derivatives evaluated by EFSA in FGE.23 Rev2 (2010) View page or View pdf Scientific Opinion on Flavouring Group Evaluation 23, Revision 3 (FGE.23Rev3): Aliphatic, alicyclic and aromatic ethers including anisole derivatives from chemical groups 15, 16, 22, 26 and 30 View page or View pdf Scientific Opinion on Flavouring Group Evaluation 23, Revision 4 (FGE.23Rev4): Aliphatic, alicyclic and aromatic ethers including anisole derivatives from chemical groups 15, 16, 22, 26 and 30 View page or View pdf EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA Substance Registry Services (TSCA):14576-08-0 EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :85755 National Institute of Allergy and Infectious Diseases:Data WGK Germany:2 4-(2-methoxypropan-2-yl)-1-methylcyclohexene Chemidplus:0014576080   References:   4-(2-methoxypropan-2-yl)-1-methylcyclohexene NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 14576-08-0 Pubchem (cid): 85755 Pubchem (sid): 135044717 Pherobase: View   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements HMDB (The Human Metabolome Database): Search VCF-Online: VCF Volatile Compounds in Food ChemSpider: View   Potential Blenders and core components note For Odor No odor group found for these (Z)-2- penten-1-yl hexanoate FL/FR aldehydic aldehydic decanal (aldehyde C-10) FL/FR tridecanal FL/FR balsamic ethyl cinnamate FL/FR 3- phenyl propyl cinnamate FL/FR citrus benzyl anthranilate FR bergamot acetoacetate FR bergamot oil bergaptene reduced italy FL/FR beta- bisabolol FL/FR citral / methyl anthranilate schiff's base FR (Z)-4- decenal FL/FR dihydromyrcenyl acetate FR dimethyl octenone FR 2,4- dimethyl-3-cyclohexene-1-methanyl acetate FR 2- dodecanone FL/FR 2- ethyl-1-hexanol FL/FR grapefruit indene FR grapefruit mercaptan FL/FR grapefruit nitrile FR grapefruit oil c.p. california FL/FR grapefruit oil CO2 extract (citrus paradisi macf. var. falvedo) FL/FR grapefruit oil terpeneless FL/FR grapefruit pentanol FR lemon oil residues FL/FR mandarin oil (citrus reticulata nova var. mandarin) uruguay FL/FR alpha- methylene citronellal FR myrcenyl acetate FL/FR myrmac aldehyde FR (+)- nootkatone FL/FR pamplemousse specialty FR philodendron solimoesense specialty FR rhubafuran FR (±)-2,4,8- trimethyl-7-nonen-2-ol FL/FR 10- undecen-1-ol FL/FR valencene FL/FR clean clean nitrile FR coumarinic tonka ketone FR dry 3,4- xylenol FL/FR floral cassis oxime 10% FR champaca absolute FR citronellyl formate FL/FR cyclamen aldehyde / methyl anthranilate schiff's base FR decanal / methyl anthranilate schiff's base FR decyl formate FR ethyl anthranilate FL/FR ethyl linalool FR gardenia amide FR gardenia decalone FR gardenia pentyl acetate FR honeysuckle absolute FR hydroxycitronellal / methyl anthranilate schiff's base FR leerall / methyl anthranilate schiff's base FR lilyall / methyl anthranilate schiff's base FR linalyl anthranilate FL/FR linalyl benzoate FL/FR linalyl butyrate FL/FR linalyl propionate FL/FR magnolia indene FR alpha- naphthyl methyl ketone FL/FR beta- naphthyl methyl ketone FL/FR neroli oil bigarde FL/FR neroli oil CO2 extract FL/FR nerolin fragarol FL/FR neryl acetate FL/FR neryl isovalerate FL/FR nonanal / methyl anthranilate schiff's base FR ocean propanal / methyl anthranilate schiff's base FR bitter orangeflower absolute morocco FL/FR peony acetonitrile FR petitgrain bigarade oil FL/FR propyl anthranilate FL/FR surfleurs d'oranger oil FL/FR alpha- terpinyl anthranilate FL/FR terpinyl isobutyrate FL/FR tetrahydrolinalyl acetate FR tuberose absolute (from pommade) FL/FR undecanal dimethyl acetal FR wallflower absolute FR fruity iso butyl methyl anthranilate FL/FR cyclohexyl anthranilate FL/FR ethyl 3-(2-furyl) propanoate FL/FR grapefruit acetal FR hexyl (E)-tiglate FL/FR linalyl isobutyrate FL/FR methyl anthranilate FL/FR nerolidyl isobutyrate FR ocimen-1-yl acetate FR para- tolualdehyde FL/FR green dextro- linalyl acetate FL/FR laevo- linalyl acetate FL/FR (2- methoxy-1-methyl butyl) benzene FR nerol oxide FL/FR herbal 6- acetoxydihydrotheaspirane FL/FR bergamot mint herb oil FR cuminyl acetate FL/FR linalyl acetate FL/FR linalyl formate FL/FR linalyl isovalerate FL/FR 3- octyl acetate FL/FR terpineol acetate FL/FR naphthyl beta- naphthyl ethyl ether FL/FR beta- naphthyl methyl ether FL/FR spicy iso butyl angelate FL/FR cassia bark oil china FL/FR cassia bark oil replacer FL/FR cinnamaldehyde FL/FR cinnamon bark absolute FL/FR cinnamon bark oil FL/FR cinnamon bark oil ceylon FL/FR 4- ethyl guaiacol FL/FR eugenol FL/FR iso eugenol FL/FR iso eugenyl acetate FL/FR iso eugenyl phenyl acetate FL/FR (E)- propyl 2-furan acrylate FL/FR sulfurous grapefruit menthane FL/FR 5- mercapto-5-methyl-3-hexanone FL/FR terpenic alpha- terpineol FL/FR vanilla vanillylidene acetone FL/FR waxy 1- undecanol FL/FR woody alpha- farnesene FL/FR juniper berry oleoresin FL/FR labdanum ethanone FR 2- methoxy-4-vinyl phenol FL/FR For Flavor No flavor group found for these 6- acetoxydihydrotheaspirane FL/FR iso butyl methyl anthranilate FL/FR cuminyl acetate FL/FR dihydronootkatone FL lemon oil residues FL/FR laevo- linalyl acetate FL/FR dextro- linalyl acetate FL/FR 4- mercapto-4-methyl-2-pentanol FL alpha- naphthyl methyl ketone FL/FR (Z)-2- penten-1-yl hexanoate FL/FR propyl anthranilate FL/FR surfleurs d'oranger oil FL/FR terpineol acetate FL/FR alpha- terpinyl anthranilate FL/FR terpinyl isobutyrate FL/FR 10- undecen-1-ol FL/FR aldehydic aldehydic 1- undecanol FL/FR alliaceous cyclopentyl mercaptan FL balsamic ethyl cinnamate FL/FR vanillylidene acetone FL/FR citrus bergamot oil bergaptene reduced italy FL/FR beta- bisabolol FL/FR (Z)-4- decenal FL/FR dehydronootkatone FL grapefruit mercaptan FL/FR grapefruit oil c.p. california FL/FR grapefruit oil CO2 extract (citrus paradisi macf. var. falvedo) FL/FR grapefruit oil terpeneless FL/FR mandarin oil (citrus reticulata nova var. mandarin) uruguay FL/FR myrcenyl acetate FL/FR (+)- nootkatone FL/FR petitgrain bigarade oil FL/FR alpha- terpineol FL/FR (±)-2,4,8- trimethyl-7-nonen-2-ol FL/FR valencene FL/FR fatty (E,E)-2,4- dodecadienal FL 2- dodecanone FL/FR 2- ethyl-1-hexanol FL/FR floral pseudo ionone FL linalyl acetate FL/FR linalyl anthranilate FL/FR linalyl butyrate FL/FR linalyl isobutyrate FL/FR beta- naphthyl methyl ketone FL/FR neroli oil bigarde FL/FR neroli oil CO2 extract FL/FR neryl acetate FL/FR bitter orangeflower absolute morocco FL/FR tuberose absolute (from pommade) FL/FR fruity citronellyl formate FL/FR cyclohexyl anthranilate FL/FR ethyl 3-(2-furyl) propanoate FL/FR ethyl anthranilate FL/FR linalyl benzoate FL/FR linalyl isovalerate FL/FR methyl anthranilate FL/FR nerolin fragarol FL/FR neryl isovalerate FL/FR (E)- propyl 2-furan acrylate FL/FR green iso butyl angelate FL/FR alpha- farnesene FL/FR (E,E)-2,4- hexadienal FL hexyl (E)-tiglate FL/FR nerol oxide FL/FR 3- octyl acetate FL/FR herbal coriander distillates FL coriander flavor FL linalyl formate FL/FR linalyl propionate FL/FR naphthyl beta- naphthyl methyl ether FL/FR powdery beta- naphthyl ethyl ether FL/FR smoky barbecue flavor FL 2- methoxy-4-vinyl phenol FL/FR 3,4- xylenol FL/FR spicy cassia bark oil china FL/FR cassia bark oil replacer FL/FR cassia flavor FL cinnamaldehyde FL/FR cinnamon bark absolute FL/FR cinnamon bark oil FL/FR cinnamon bark oil ceylon FL/FR cinnamon flavor FL iso eugenol FL/FR eugenol FL/FR iso eugenyl acetate FL/FR iso eugenyl phenyl acetate FL/FR 3- phenyl propyl cinnamate FL/FR para- tolualdehyde FL/FR sulfurous grapefruit menthane FL/FR 5- mercapto-5-methyl-3-hexanone FL/FR sweet brown sugar cinnamon flavor FL waxy decanal (aldehyde C-10) FL/FR tridecanal FL/FR woody 4- ethyl guaiacol FL/FR juniper berry oleoresin FL/FR yerba mate concentrate FL   Potential Uses: FR bergamot FR celery FR citrus FR grapefruit FR lilac FR neroli FR orange blossom FR petitgrain FL vegetable   Occurrence (nature, food, other):note   orangeflower absolute Search Trop Picture   oregon grape-holly Search Trop Picture   Synonyms:   cyclohexene, 4-(1-methoxy-1-methylethyl)-1-methyl- p- menth-1-en-8-yl methyl ether para- menth-1-en-8-yl methyl ether 4-(1- methoxy-1-methyl ethyl)-1-methyl cyclohexene 4-(1- methoxy-1-methylethyl)-1-methylcyclohexene   methoxyisopropyl methyl cyclohexene 4-(2- methoxypropan-2-yl)-1-methylcyclohexene   methyl 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl ether   orange flower ether (IFF)   orangeflower ether (IFF) a- terpineol methyl ether a- terpineol, methyl ether   terpinyl methyl ether alpha- terpinyl methyl ether   Articles:   None found yet. Try the PubMed Search.

Notes: None found