cyclamen aldehyde / methyl anthranilate schiff's base
methyl anthranilate / cyclamen aldehyde schiff's base

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  91-50-9 Cyclantine

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  SCHIFF BASE CYCLAMEN ALD./METHYL ANTHRANILATE

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  500811 Methyl Anthranilate / Cyclamen Aldehyde Schiff Base

Name: methyl 2-[[2-methyl-3-(4-propan-2-ylphenyl)propylidene]amino]benzoate CAS Number: 91-50-9 3D/inchi ECHA EINECS - REACH Pre-Reg: 202-072-0 FDA UNII: 78J2J6IE6R Nikkaji Web: J60.374K XlogP3-AA: 5.00 (est) Molecular Weight: 323.43565000 Formula: C21 H25 N O2 NMR Predictor: Predict (works with chrome, Edge or firefox) Category:fragrance agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search   Physical Properties: Appearance: yellow viscous liquid to solid (est) Assay: 98.00 to 100.00 Food Chemicals Codex Listed: No Specific Gravity: 1.03760 to 1.04670 @ 25.00 °C. Pounds per Gallon - (est).: 8.634 to 8.710 Refractive Index: 1.53500 to 1.54630 @ 20.00 °C. Boiling Point: 460.00 to 461.00 °C. @ 760.00 mm Hg Flash Point: > 200.00 °F. TCC ( > 93.33 °C. ) logP (o/w): 7.249 (est) Soluble in:   alcohol   water, 0.08299 mg/L @ 25 °C (est) Insoluble in:   water   Organoleptic Properties: Odor Type: floral Odor Strength:medium , recommend smelling in a 50.00 % solution or less Substantivity:208 hour(s) at 100.00 % fresh lily of the valley neroli orangeflower Odor Description:at 50.00 % in dipropylene glycol. fresh lily of the valley neroli orange flower Luebke, William tgsc, (1985) Odor sample from: Nickstadt Moeller, Inc. Odor and/or flavor descriptions from others (if found).   Cosmetic Information: CosIng: cosmetic data Cosmetic Uses: perfuming agents   Suppliers: BOC Sciences For experimental / research use only. Cyclantine Inoue Perfumery CYCLANTINE Lluch Essence SCHIFF BASE CYCLAMEN ALD./METHYL ANTHRANILATE Penta International METHYL ANTHRANILATE/CYCLAMEN ALDEHYDE SCHIFF BASE Vigon International Methyl Anthranilate / Cyclamen Aldehyde Schiff Base Odor: SWEET, FRESH-FLORAL   Safety Information: European information : Most important hazard(s): Xi - Irritant R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing.   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: Not determined Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: fragrance agents RIFM Fragrance Material Safety Assessment: Search IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice Recommendation for cyclamen aldehyde / methyl anthranilate schiff's base usage levels up to:   6.0000 % in the fragrance concentrate.   Recommendation for cyclamen aldehyde / methyl anthranilate schiff's base flavor usage levels up to:   not for flavor use.   Safety References: EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA Substance Registry Services (TSCA):91-50-9 EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :101555 National Institute of Allergy and Infectious Diseases:Data WGK Germany:2 methyl 2-[[2-methyl-3-(4-propan-2-ylphenyl)propylidene]amino]benzoate Chemidplus:0000091509   References:   methyl 2-[[2-methyl-3-(4-propan-2-ylphenyl)propylidene]amino]benzoate NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 91-50-9 Pubchem (cid): 101555 Pubchem (sid): 135058826   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements HMDB (The Human Metabolome Database): Search ChemSpider: View   Potential Blenders and core components note For Odor aldehydic lily pentanal FR nonanal (aldehyde C-9) FL/FR animal para- cresyl isobutyrate FL/FR para- cresyl phenyl acetate FL/FR balsamic linalyl cinnamate FL/FR citrus benzyl anthranilate FR citral / methyl anthranilate schiff's base FR citrus ocimenol FR (Z)-4- decenal FL/FR lime oil distilled terpeneless FL/FR mandarin oil italy FL/FR alpha- terpinyl methyl ether FL/FR tetrahydromyrcenol FR clean clean nitrile FR coumarinic tonka ketone FR floral acetyl tetralin FR alpha- amyl cinnamaldehyde dimethyl acetal FL/FR bigarade oxide FR alpha- butyl cinnamaldehyde FL/FR champaca absolute FR citronellyl anthranilate FL/FR citronellyl ethoxalate FR para- cresyl propionaldehyde CS cyclohexyl ethyl alcohol FL/FR decanal / methyl anthranilate schiff's base FR decyl anthranilate FR decyl formate FR dimethyl anthranilate FL/FR ethyl anthranilate FL/FR ethyl ethyl anthranilate FL/FR (E,E)- farnesol FL/FR pink frangipani absolute FR freesia acetate FR gardenia decalone FR geranyl anthranilate FR geranyl formate FL/FR hydroxycitronellal FL/FR hydroxycitronellal / methyl anthranilate schiff's base FR hydroxycitronellal diethyl acetal FL/FR hydroxycitronellal dimethyl acetal FL/FR hydroxycitronellol FL/FR leerall / methyl anthranilate schiff's base FR lily propanol FR lilyall / methyl anthranilate schiff's base FR linalyl anthranilate FL/FR linalyl benzoate FL/FR linalyl phenyl acetate FL/FR linalyl propionate FL/FR magnolia decadienal FR methoxycitronellal FR 2- methyl octanal FL/FR muguet carbaldehyde FR muguet carbinol FL/FR muguet nitrile FR muguet octadienol FR muguet propanol FR muguet shiseol FL/FR beta- naphthyl anthranilate FL/FR alpha- naphthyl methyl ketone FL/FR beta- naphthyl methyl ketone FL/FR nerol FL/FR neroli oil bigarde FL/FR neroli oil CO2 extract FL/FR nerolidyl acetate FL/FR nerolin fragarol FL/FR nonanal / methyl anthranilate schiff's base FR ocean propanal / methyl anthranilate schiff's base FR bitter orangeflower absolute morocco FL/FR petitgrain bigarade oil FL/FR petitgrain oil paraguay FL/FR (E)-2- phenyl-1(2)-propene-1-yl acetate FR iso propyl anthranilate FL/FR propyl anthranilate FL/FR surfleurs d'oranger oil FL/FR alpha- terpinyl anthranilate FL/FR tetrahydrolinalool FL/FR ylang ylang flower oil FL/FR ylang ylang flower oil CO2 extract FL/FR ylang ylang flower oil fractions FR ylang ylang flower oil I FL/FR ylang ylang flower oil II FL/FR ylang ylang oil replacer FR fruity cyclohexyl anthranilate FL/FR methyl anthranilate FL/FR green nerol oxide FL/FR herbal dimethyl benzyl carbinyl formate FL/FR marine ozone propanal FR medicinal meta- dimethyl hydroquinone FL/FR naphthyl beta- naphthyl ethyl ether FL/FR beta- naphthyl methyl ether FL/FR terpenic cassis bud oil FL/FR waxy decanal dimethyl acetal FL/FR woody alpha- farnesene FL/FR labdanum ethanone FR For Flavor No flavor group found for these alpha- amyl cinnamaldehyde dimethyl acetal FL/FR decanal dimethyl acetal FL/FR dimethyl benzyl carbinyl formate FL/FR ethyl ethyl anthranilate FL/FR (E,E)- farnesol FL/FR linalyl phenyl acetate FL/FR 2- methyl octanal FL/FR alpha- naphthyl methyl ketone FL/FR nerolidyl acetate FL/FR iso propyl anthranilate FL/FR propyl anthranilate FL/FR surfleurs d'oranger oil FL/FR alpha- terpinyl anthranilate FL/FR alpha- butyl cinnamaldehyde FL/FR aldehydic aldehydic nonanal (aldehyde C-9) FL/FR aromatic para- cresyl isobutyrate FL/FR chemical meta- dimethyl hydroquinone FL/FR citrus (Z)-4- decenal FL/FR lime oil distilled terpeneless FL/FR mandarin oil italy FL/FR nerol FL/FR petitgrain bigarade oil FL/FR floral linalyl anthranilate FL/FR muguet carbinol FL/FR muguet shiseol FL/FR beta- naphthyl methyl ketone FL/FR neroli oil bigarde FL/FR neroli oil CO2 extract FL/FR bitter orangeflower absolute morocco FL/FR tetrahydrolinalool FL/FR ylang ylang flower oil FL/FR ylang ylang flower oil CO2 extract FL/FR ylang ylang flower oil I FL/FR ylang ylang flower oil II FL/FR fruity cassis bud oil FL/FR citronellyl anthranilate FL/FR cyclohexyl anthranilate FL/FR dimethyl anthranilate FL/FR ethyl anthranilate FL/FR linalyl benzoate FL/FR linalyl cinnamate FL/FR methyl anthranilate FL/FR beta- naphthyl anthranilate FL/FR nerolin fragarol FL/FR green cyclohexyl ethyl alcohol FL/FR alpha- farnesene FL/FR geranyl formate FL/FR nerol oxide FL/FR herbal linalyl propionate FL/FR petitgrain oil paraguay FL/FR melon hydroxycitronellal diethyl acetal FL/FR naphthyl beta- naphthyl methyl ether FL/FR phenolic para- cresyl phenyl acetate FL/FR powdery hydroxycitronellol FL/FR beta- naphthyl ethyl ether FL/FR waxy hydroxycitronellal FL/FR hydroxycitronellal dimethyl acetal FL/FR woody alpha- terpinyl methyl ether FL/FR   Potential Uses: FR berry   chanel #5 FR citrus FR grape FR jasmin FR jonquil FR lilac FR lily FR lily of the valley FR melon FR neroli FR orange blossom FR strawberry   Occurrence (nature, food, other):note   not found in nature   Synonyms:   benzoic acid, 2-((2-methyl-3-(4-(1-methylethyl)phenyl)propylidene)amino)-, methyl ester   cyclantine   methyl 2-((2-methyl-3-(4-(1-methyl ethyl)phenyl)propylidene)amino) benzoate   methyl 2-((2-methyl-3-(4-(1-methylethyl)phenyl)propylidene)amino)benzoate   methyl 2-[[2-methyl-3-(4-propan-2-ylphenyl)propylidene]amino]benzoate   methyl anthranilate / cyclamen aldehyde schiff's base   methyl anthranilate / cyclamen aldehyde schiff base 2-((2- methyl-3-(4-(1-methyl ethyl)phenyl)propylidene)amino) benzoic acid methyl ester 2-((2- methyl-3-(4-(1-methylethyl)phenyl)propylidene)amino)benzoic acid, methyl ester   Articles: US Patents:4,435,585 - Process for the preparation of dihydrocinnamaldehyde derivatives

Notes: Very good in citrus blends.