lily pentanal
mefranal (Givaudan)

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  Indukern, S.A. F&F Ingredients Division

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  The John D. Walsh Company, Inc

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  Vigon International

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  503238 Mefranal

Fragrance Demo Formulas Name: 3-methyl-5-phenylpentanal CAS Number: 55066-49-4 3D/inchi ECHA ELINCS - REACH Pre-Reg: 433-900-0 FDA UNII: 00RZ3F0O1X Nikkaji Web: J1.574.283F XlogP3-AA: 3.00 (est) Molecular Weight: 176.25872000 Formula: C12 H16 O NMR Predictor: Predict (works with chrome, Edge or firefox) Category: fragrance agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search   Physical Properties: Appearance: colorless clear liquid (est) Assay: 97.00 to 100.00 Food Chemicals Codex Listed: No Specific Gravity: 0.96000 to 0.96500 @ 25.00 °C. Pounds per Gallon - (est).: 7.988 to 8.030 Refractive Index: 1.50500 to 1.50700 @ 20.00 °C. Boiling Point: 121.00 to 123.00 °C. @ 14.00 mm Hg Vapor Pressure: 0.005000 mmHg @ 25.00 °C. (est) Flash Point: 212.00 °F. TCC ( 100.00 °C. ) logP (o/w): 3.238 (est) Soluble in:   alcohol   water, slightly   water, 67.2 mg/L @ 25 °C (est) Insoluble in:   water   Organoleptic Properties: Odor Type: aldehydic Odor Strength:medium Substantivity:184 hour(s) at 100.00 % aldehydic lily green fresh waxy woody Odor Description:at 100.00 %. aldehydic lily green fresh waxy woody Luebke, William tgsc, (1989) Odor sample from: Quest International Odor and/or flavor descriptions from others (if found). Givaudan Mefranal Odor Description:Citrus, Aldehydic, Geranium Mefranal has a refreshing lemon geranium note with an aldehydic floral heart. Indukern F&F CITRALIS PQ Odor Description:CITRUS, ALDEHYDIC, FLORAL, GREEN   Cosmetic Information: CosIng: cosmetic data Cosmetic Uses: fragrance perfuming agents   Suppliers: BOC Sciences For experimental / research use only. 3-METHYL-5-PHENYL-1-PENTANAL Emerald Kalama Chemical Kalama® Citralis PQ Odor: Fresh, rosy-citrus-ozone Givaudan Mefranal Odor: Citrus, Aldehydic, Geranium Use: Mefranal has a refreshing lemon geranium note with an aldehydic floral heart. Indukern F&F CITRALIS PQ Odor: CITRUS, ALDEHYDIC, FLORAL, GREEN Lluch Essence CITRALIS PQ 97% Odor: ALDEHYDIC, GREEN Lluch Essence MEFRANAL PCW France Phenyl Hexanal Steps to a fragranced product Penta International 3-METHYL-5-PHENYL-1-PENTANAL Taytonn ASCC Citralis PQ Odor: Citrus, Floral, Fresh, Ozone/Ozonic The John D. Walsh Company Citralis PQ sds Vigon International Mefranal Odor: ALDEHYDIC, LILY OF THE VALLEY   Safety Information: European information : Most important hazard(s): Xn N - Harmful, Dangerous for the environment. R 22 - Harmful if swallowed. R 38 - Irritating to skin. R 51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S 02 - Keep out of the reach of children. S 20/21 - When using do not eat, drink or smoke. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 - Wear suitable clothing, gloves and eye/face protection. S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet.   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) Acute toxicity, Oral (Category 4), H302 Skin irritation (Category 2), H315 Skin sensitisation (Category 1), H317 Chronic aquatic toxicity (Category 2), H411 GHS Label elements, including precautionary statements   Pictogram   Signal word Warning Hazard statement(s) H302 - Harmful if swallowed H315 - Causes skin irritation H317 - May cause an allergic skin reaction H411 - Toxic to aquatic life with long lasting effects Precautionary statement(s) P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash skin thouroughly after handling. P270 - Do not eat, drink or smoke when using this product. P272 - Contaminated work clothing should not be allowed out of the workplace. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301 + P312 - IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P302 + P352 - IF ON SKIN: wash with plenty of soap and water. P330 - Rinse mouth. P333 + P313 - IF SKIN irritation or rash occurs: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P391 - Collect spillage. Hazardous to the aquatic environment P501 - Dispose of contents/ container to an approved waste disposal plant. Oral/Parenteral Toxicity: Not determined Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: fragrance agents RIFM Fragrance Material Safety Assessment: Search IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice Recommendation for lily pentanal usage levels up to:   3.0000 % in the fragrance concentrate.   Recommendation for lily pentanal flavor usage levels up to:   not for flavor use.   Safety References: EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA Substance Registry Services (TSCA):55066-49-4 EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :108313 National Institute of Allergy and Infectious Diseases:Data WISER:UN 3082 WGK Germany:3 3-methyl-5-phenylpentanal Chemidplus:0055066494   References: Leffingwell: Chirality or Article   3-methyl-5-phenylpentanal NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 55066-49-4 Pubchem (cid): 108313 Pubchem (sid): 135065527   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements HMDB (The Human Metabolome Database): Search ChemSpider: View   Potential Blenders and core components note For Odor aldehydic citronellyl oxyacetaldehyde FL/FR 9- decenal FL/FR dodecanal (aldehyde C-12 lauric) FL/FR 10- undecenal (aldehyde C-11 undecylenic) FL/FR animal para- cresyl isobutyrate FL/FR anisic para- anisaldehyde FL/FR balsamic iso amyl benzoate FL/FR amyris wood oil FL/FR siam benzoin resinoid FL/FR benzyl cinnamate FL/FR benzyl salicylate FL/FR iso butyl cinnamate FL/FR cinnamyl alcohol FL/FR clover nitrile FR ethyl cinnamate FL/FR fir balsam absolute FR linalyl cinnamate FL/FR methyl (E)-cinnamate FL/FR 3- phenyl propyl alcohol FL/FR annus wormwood oil france FL/FR berry raspberry ketone FL/FR raspberry ketone acetate FL/FR raspberry ketone methyl ether FL/FR caramellic strawberry furanone FL/FR citrus benzyl anthranilate FR bergamot oil bergaptene reduced italy FL/FR citrus ocimenol FR lime pyran FR methyl indole-1-carboxylate FR myrmac aldehyde FR sweet orange peel oil c.p. brazil FL/FR beta- sinensal FL/FR tetrahydromyrcenol FR fatty decanol FL/FR floral aeolanthus graveolens oil FR alpha- amyl cinnamaldehyde FL/FR alpha- amyl cinnamaldehyde dimethyl acetal FL/FR iso amyl salicylate FL/FR benzyl acetate FL/FR bois de rose oil brazil FL/FR alpha- butyl cinnamaldehyde FL/FR 4-iso butyl cyclohexane propanal FR iso butyl salicylate FL/FR citronellol FL/FR citronellyl (R)-lactate FR citronellyl acetate FL/FR citronellyl ethoxalate FR citrus propanol FR coriander seed oil FL/FR corps popinal FR cumin carbinol FR cuminyl acetaldehyde FL/FR cyclamen aldehyde FL/FR cyclamen homoaldehyde FR cyclohexyl ethyl alcohol FL/FR cyclohexyl propanol FR 2- decalinol FR 9- decen-1-ol FL/FR dihydrojasmone FL/FR dimethyl anthranilate FL/FR dimethyl benzyl carbinol FL/FR dimethyl benzyl carbinyl acetate FL/FR 2,5- dimethyl-2-indan methanol FR 4- ethyl cyclohexane propanal FR ethyl linalyl acetal FR ethyl phenyl acetate FL/FR farnesol FL/FR (E,E)- farnesol FL/FR floral butanal FR floral pyranol FR floral specialty FR freesia acetate FR gardenia oxide FR geraniol FL/FR geranyl acetate FL/FR ginger lily fragrance FR hawthorn ethanol FR heliotropin FL/FR heliotropyl acetone FL/FR heliotropyl diethyl acetal FR (Z)-4- hepten-2-yl salicylate FR (Z)-3- hexen-1-yl salicylate FL/FR alpha- hexyl cinnamaldehyde FL/FR hyacinth ether FR hydrangea fragrance FR 3-(4- hydroxy-4-methyl cyclohexyl) butanal FR hydroxycitronellal FL/FR hydroxycitronellal / methyl anthranilate schiff's base FR hydroxycitronellal diethyl acetal FL/FR hydroxycitronellal dimethyl acetal FL/FR hydroxycitronellal distillation residue distillates FR hydroxycitronellal nitrile FR hydroxycitronellal propylene glycol acetal FL/FR hydroxycitronellal residue FR hydroxycitronellol FL/FR iris specialty FR jasimia FR leerall FR leerall / methyl anthranilate schiff's base FR lily flower absolute FR lily fragrance FR calla lily fragrance FR water lily fragrance FR lily of the valley fragrance FR lily of the valley specialty FR lilyall FR lilyall / methyl anthranilate schiff's base FR lilyall substitute FR linalool FL/FR laevo- linalool FL/FR linalool oxide FL/FR linalyl benzoate FL/FR lotus fragrance FR magnolia cyclohexanol FR magnolia decadienal FR methoxycitronellal FR 4- methyl cyclohexane propanal FR methyl dihydrojasmonate FL/FR 2- methyl octanal FL/FR 1- methyl-3-(2-methyl propyl) cyclohexanol FR 4-(4- methyl-4-hydroxyamyl)-delta3-cyclohexenecarboxaldehyde FR 3- methyl-6-ethyl-5-octen-1-ol FR mimosa absolute FL/FR mimosa absolute france FL/FR mimosa absolute india FL/FR muguet butanal FR muguet butanol FR muguet carbaldehyde FR muguet carbinol FL/FR muguet carboxaldehyde FR muguet dienal FR muguet ethanol FR muguet nitrile FR muguet octadienol FR muguet propanol FR muguet shiseol FL/FR cis- muguet shiseol FL/FR muguet specialty FR nerol FL/FR nerolidol FL/FR (E)- nerolidol FL/FR neryl acetate FL/FR nonanol FL/FR ocean propanal FL/FR octahydro-4,7-methano-1H-indene-5-acetaldehyde FR octahydro-4,7-methano-1H-indene-5-acetaldehyde + 6-methyl-octahydro-4,7-methano-indene-5-carbaldehyd FR orchid specialty FR orris pyridine 25% IPM FR 2- pentyl-2-cyclohexen-1-one FR peony alcohol FR petitgrain oil paraguay FL/FR phenethyl acetate FL/FR phenethyl alcohol FL/FR phenethyl isobutyrate FL/FR phenethyl phenyl acetate FL/FR phenethyl propionate FL/FR phenethyl salicylate FL/FR phenyl glycol diacetate FR 4- propyl cyclohexane propanal FR rhodinol FL/FR rose absolute pentanol FR rose butanoate FL/FR alpha- terpinyl anthranilate FL/FR tetrahydrolinalool FL/FR (E)-2- undecen-1-ol FL/FR violet methyl carbonate FR ylang ylang flower oil FL/FR ylang ylang flower oil CO2 extract FL/FR ylang ylang flower oil fractions FR ylang ylang flower oil I FL/FR ylang ylang flower oil II FL/FR ylang ylang oil III fractions FR ylang ylang oil replacer FR fruity allyl amyl glycolate FR allyl cyclohexyl propionate FL/FR artemisia pallens herb oil FL/FR benzyl propionate FL/FR berry hexanoate FR (E)-beta- damascone FL/FR (E)-alpha- damascone FL/FR dimethyl benzyl carbinyl isobutyrate FR green acetate FR methyl anthranilate FL/FR strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR green acetaldehyde ethyl phenethyl acetal FL/FR ethyl (E,Z)-2,4-decadienoate FL/FR (Z)-3- hexen-1-yl acetate FL/FR (Z)-3- hexen-1-yl benzoate FL/FR (Z)-3- hexen-1-yl propionate FL/FR (Z)-3- hexen-1-yl tiglate FL/FR hexyl 2-methyl butyrate FL/FR hexyl tiglate FL/FR 2,4- ivy carbaldehyde FL/FR (Z)- leaf acetal FL/FR melon nonenoate FL/FR methyl heptine carbonate FL/FR methyl octine carbonate FL/FR (E,Z)-2,6- nonadien-1-ol FL/FR (E,Z)-2,6- nonadienal FL/FR phenethyl acetal FR phenyl acetaldehyde diethyl acetal FL/FR phenyl acetaldehyde dimethyl acetal FL/FR 3- phenyl propionaldehyde FL/FR styralyl acetate FL/FR violet decenol FR violet leaf absolute FL/FR hay beeswax absolute FL/FR hay absolute FR herbal bornyl salicylate FR carum carvi fruit oil FL/FR clary sage oil france FL/FR dimethyl benzyl carbinyl formate FL/FR beta- elemene FL/FR lavender absolute bulgaria FL/FR linalyl acetate FL/FR nopyl acetate FR marine ozone propanal FR melon watermelon ketone FR mossy oakmoss absolute FL/FR veramoss (IFF) FR muguet 4-iso butyl 1-(3-methoxy-2-propen-1-yl) benzene FR 4- ethyl 1-(3-methoxy-2-propen-1-yl) benzene FR 4- methyl 1-(3-methoxy-2-propen-1-yl) benzene FR 4- propyl 1-(3-methoxy-2-propen-1-yl) benzene FR powdery para- anisyl acetate FL/FR para- anisyl alcohol FL/FR spicy benzyl isoeugenol FL/FR carnation absolute FR cassia bark oil china FL/FR clove bud oil FL/FR black currant bud absolute FL/FR iso eugenyl acetate FL/FR galangal root oil FL/FR alpha- methyl cinnamaldehyde FL/FR methyl isoeugenol FL/FR terpenic frankincense oil FL/FR alpha- terpineol FL/FR tonka tonka bean absolute FR vanilla ethyl vanillin FL/FR vanilla bean absolute (vanilla planifolia) FL/FR vanillyl acetate FL/FR waxy decyl acetate FL/FR 1- dodecanol FL/FR ethyl laurate FL/FR woody amber dioxane FR guaiacwood oil FL/FR gurjun balsam oil FR hydroxycitronellal diisotridecyl acetal FR methyl cedryl ketone FL/FR patchouli ethanone FR sandal butenol FR sandalrome FR santall FR tobacarol (IFF) FR woody acetate FR For Flavor No flavor group found for these alpha- amyl cinnamaldehyde dimethyl acetal FL/FR 9- decenal FL/FR dimethyl benzyl carbinyl formate FL/FR beta- elemene FL/FR (E,E)- farnesol FL/FR hydroxycitronellal propylene glycol acetal FL/FR methyl (E)-cinnamate FL/FR 2- methyl octanal FL/FR phenyl acetaldehyde diethyl acetal FL/FR beta- sinensal FL/FR alpha- terpinyl anthranilate FL/FR (E)-2- undecen-1-ol FL/FR annus wormwood oil france FL/FR alpha- butyl cinnamaldehyde FL/FR apple apple (E,Z)-2,6- nonadien-1-ol FL/FR aromatic para- cresyl isobutyrate FL/FR balsamic siam benzoin resinoid FL/FR benzyl salicylate FL/FR iso butyl cinnamate FL/FR ethyl cinnamate FL/FR berry heliotropyl acetone FL/FR raspberry ketone FL/FR raspberry ketone acetate FL/FR raspberry ketone methyl ether FL/FR brown beeswax absolute FL/FR caramellic caramel furanone FL strawberry furanone FL/FR cherry heliotropin FL/FR citrus bergamot oil bergaptene reduced italy FL/FR citronellyl oxyacetaldehyde FL/FR linalool FL/FR laevo- linalool FL/FR nerol FL/FR sweet orange peel oil c.p. brazil FL/FR alpha- terpineol FL/FR cooling iso butyl salicylate FL/FR creamy para- anisaldehyde FL/FR gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR fatty (Z)-3- hexen-1-yl benzoate FL/FR 10- undecenal (aldehyde C-11 undecylenic) FL/FR floral bois de rose oil brazil FL/FR citronellol FL/FR citronellyl acetate FL/FR dihydrojasmone FL/FR dimethyl benzyl carbinyl acetate FL/FR farnesol FL/FR geraniol FL/FR linalyl acetate FL/FR methyl dihydrojasmonate FL/FR muguet carbinol FL/FR cis- muguet shiseol FL/FR muguet shiseol FL/FR neryl acetate FL/FR ocean propanal FL/FR phenethyl alcohol FL/FR phenethyl propionate FL/FR rhodinol FL/FR tetrahydrolinalool FL/FR ylang ylang flower oil FL/FR ylang ylang flower oil CO2 extract FL/FR ylang ylang flower oil I FL/FR ylang ylang flower oil II FL/FR fruity allyl cyclohexyl propionate FL/FR iso amyl benzoate FL/FR para- anisyl acetate FL/FR para- anisyl alcohol FL/FR artemisia pallens herb oil FL/FR benzyl acetate FL/FR benzyl propionate FL/FR (E)-alpha- damascone FL/FR (E)-beta- damascone FL/FR dimethyl anthranilate FL/FR linalyl benzoate FL/FR linalyl cinnamate FL/FR methyl anthranilate FL/FR rose butanoate FL/FR strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR styralyl acetate FL/FR green acetaldehyde ethyl phenethyl acetal FL/FR iso amyl salicylate FL/FR cinnamyl alcohol FL/FR cuminyl acetaldehyde FL/FR cyclamen aldehyde FL/FR cyclohexyl ethyl alcohol FL/FR ethyl (E,Z)-2,4-decadienoate FL/FR geranyl acetate FL/FR (Z)-3- hexen-1-yl acetate FL/FR (Z)-3- hexen-1-yl propionate FL/FR (Z)-3- hexen-1-yl salicylate FL/FR (Z)-3- hexen-1-yl tiglate FL/FR hexyl 2-methyl butyrate FL/FR hexyl tiglate FL/FR 2,4- ivy carbaldehyde FL/FR (Z)- leaf acetal FL/FR linalool oxide FL/FR melon nonenoate FL/FR methyl heptine carbonate FL/FR methyl octine carbonate FL/FR (E)- nerolidol FL/FR nerolidol FL/FR (E,Z)-2,6- nonadienal FL/FR oakmoss absolute FL/FR phenyl acetaldehyde dimethyl acetal FL/FR 3- phenyl propionaldehyde FL/FR violet leaf absolute FL/FR herbal carum carvi fruit oil FL/FR clary sage oil france FL/FR coriander seed oil FL/FR lavender absolute bulgaria FL/FR petitgrain oil paraguay FL/FR honey ethyl phenyl acetate FL/FR phenethyl acetate FL/FR phenethyl isobutyrate FL/FR phenethyl phenyl acetate FL/FR medicinal dimethyl benzyl carbinol FL/FR phenethyl salicylate FL/FR melon hydroxycitronellal diethyl acetal FL/FR powdery hydroxycitronellol FL/FR soapy dodecanal (aldehyde C-12 lauric) FL/FR 1- dodecanol FL/FR spicy benzyl cinnamate FL/FR benzyl isoeugenol FL/FR cassia bark oil china FL/FR clove bud oil FL/FR black currant bud absolute FL/FR iso eugenyl acetate FL/FR galangal root oil FL/FR alpha- methyl cinnamaldehyde FL/FR methyl isoeugenol FL/FR 3- phenyl propyl alcohol FL/FR tropical alpha- amyl cinnamaldehyde FL/FR vanilla ethyl vanillin FL/FR vanilla bean absolute (vanilla planifolia) FL/FR vanillyl acetate FL/FR waxy decanol FL/FR 9- decen-1-ol FL/FR decyl acetate FL/FR ethyl laurate FL/FR alpha- hexyl cinnamaldehyde FL/FR hydroxycitronellal FL/FR hydroxycitronellal dimethyl acetal FL/FR mimosa absolute FL/FR mimosa absolute france FL/FR mimosa absolute india FL/FR nonanol FL/FR woody amyris wood oil FL/FR frankincense oil FL/FR guaiacwood oil FL/FR methyl cedryl ketone FL/FR   Potential Uses: FR animal FR apple blossom   clean FR floral FR green FR lily FR lily of the valley FR musk FR rose   waxy FR woody   Occurrence (nature, food, other):note   not found in nature   Synonyms:   benzenepentanal, beta-methyl-   citralis PQ (Indukern)   lily pentanal   mefranal (Givaudan) beta- methyl benzene pentanal 3- methyl-5-phenyl-1-pentanal 3- methyl-5-phenyl-pentanal 3- methyl-5-phenylpentanal beta- methylbenzenepentanal   phenyl methyl pentanal   Articles: US Patents:8,168,163 - [(4E, 4Z)-5-methoxy-3-methyl-4-pentenyl]-benzene and its use in perfume compositions

Notes: None found