methyl cyclogeranate (Firmenich)
2,6,6-trimethyl-2-cyclohexene-1-carboxylic acid, methyl ester

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  Azelis UK Ltd.

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  936915 CYCLOGERANIATE DE METHYLE for fragrance
  Mild intensity ingredient that can be used in most fragrances bringing rosy, fresh and fruity tonalities.

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  Lluch Essence S.L.

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  502812 Methyl Cyclogeranate

Fragrance Demo Formulas Name: methyl 2,6,6-trimethylcyclohex-2-ene-1-carboxylate CAS Number: 28043-10-9 3D/inchi Other(deleted CASRN): 88269-68-5 ECHA EINECS - REACH Pre-Reg: 248-792-9 FDA UNII: Search Nikkaji Web: J250.635A XlogP3-AA: 2.60 (est) Molecular Weight: 182.26286000 Formula: C11 H18 O2 NMR Predictor: Predict (works with chrome, Edge or firefox) Category:fragrance agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search   Physical Properties: Appearance: colorless clear liquid (est) Assay: 95.00 to 100.00 Food Chemicals Codex Listed: No Specific Gravity: 0.95790 to 0.96820 @ 25.00 °C. Pounds per Gallon - (est).: 7.971 to 8.056 Refractive Index: 1.49100 to 1.49900 @ 20.00 °C. Boiling Point: 212.00 to 214.00 °C. @ 760.00 mm Hg Vapor Pressure: 0.151000 mmHg @ 25.00 °C. (est) Vapor Density: 6.3 ( Air = 1 ) Flash Point: 171.00 °F. TCC ( 77.22 °C. ) logP (o/w): 3.372 (est) Soluble in:   alcohol   water, 27.88 mg/L @ 25 °C (est) Insoluble in:   water Similar Items:note isoamyl geranate ethyl geranate (E)-methyl geranate   Organoleptic Properties: Odor Type: herbal Odor Strength:medium Substantivity:1 hour(s) at 100.00 % natural herbal floral fruity woody camphoreous Odor Description:at 100.00 %. natural herbal floral fruity woody camphor Luebke, William tgsc, (1985) Odor sample from: Firmenich Inc. Odor and/or flavor descriptions from others (if found).   Cosmetic Information: CosIng: cosmetic data Cosmetic Uses: perfuming agents   Suppliers: Azelis UK METHYL CYCLO GERANIATE Ernesto Ventós METHYL CYCLOGERANIATE FIRMENICH 936915 Odor: FLORAL,HERBAL,FRUITY,AROMATIC Firmenich CYCLOGERANIATE DE METHYLE for fragrance Odor: METHYL CYCLOGERANATE is a floral, rose, fruity note that also brings an earthy, camphor and damascone like character to fragrances. Use: Mild intensity ingredient that can be used in most fragrances bringing rosy, fresh and fruity tonalities. Lluch Essence METHYL CYCLOGERANATE Odor: FRUITY, FLORAL, HERBACEOUS Moellhausen METHYL CYCLO GERANATE Organica Aromatics METHYL CYCLO GERANATE Penta International METHYL-2,6,6-TRIMETHYL-2-CYCLOHEXENE-1-CARBOXYLATE Vigon International Methyl Cyclogeranate Odor: Natural herbal floral fruity woody camphor   Safety Information:   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: oral-rat LD50 4150 mg/kg Firmenich Inc. Dermal Toxicity: skin-rabbit LD50 > 2000 mg/kg Firmenich Inc. Inhalation Toxicity: Not determined   Safety in Use Information: Category: fragrance agents RIFM Fragrance Material Safety Assessment: Search IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice Recommendation for methyl cyclogeranate (Firmenich) usage levels up to:   5.0000 % in the fragrance concentrate.   Recommendation for methyl cyclogeranate (Firmenich) flavor usage levels up to:   not for flavor use.   Safety References: EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA Substance Registry Services (TSCA):28043-10-9 EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :119800 National Institute of Allergy and Infectious Diseases:Data WGK Germany:2 methyl 2,6,6-trimethylcyclohex-2-ene-1-carboxylate Chemidplus:0028043109   References:   methyl 2,6,6-trimethylcyclohex-2-ene-1-carboxylate NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 28043-10-9 Pubchem (cid): 119800 Pubchem (sid): 135077844   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements HMDB (The Human Metabolome Database): Search ChemSpider: View   Potential Blenders and core components note For Odor No odor group found for these (E+Z)-4,8- dimethyl-3,7-nonadien-2-one FL/FR (E)-beta- methyl ionone FL/FR aldehydic aldehydic 3- methyl-4-hexyl oxybutyraldehyde FR anisic amyl furoate FL/FR balsamic benzyl benzoate FL/FR benzyl cinnamate FL/FR benzyl salicylate FL/FR dextro,laevo- borneol FL/FR laevo- borneol FL/FR iso bornyl methyl ether FL/FR iso bornyl propionate FL/FR cinnamyl formate FL/FR cyclohexyl benzoate FL/FR fir carboxylate FR scotch pine wood/needles resinoid FR berry raspberry ketone methyl ether FL/FR burnt lepidine FL/FR camphoreous 2,6- dimethyl-3-oxatricyclo(4.2.1.0*2,4*)nonane FR caramellic diethyl malate FL/FR citrus acetaldehyde citronellyl methyl acetal FR bergamot oil bergaptene reduced italy FL/FR beta- bisabolol FL/FR (R)- citronellyl nitrile FR citronitrile (Symrise) FR 2- heptanol FL/FR myrcenyl acetate FL/FR earthy (-)-alpha- fenchol FL/FR (Z)- linalool oxide (furanoid) FL/FR fatty butyl undecylenate FL/FR hexyl pivalate FR fermented methyl decanoate FL/FR floral acetal 318 FR ortho- acetyl-para-cresol FL/FR iso amyl angelate FL/FR alpha- amyl cinnamaldehyde FL/FR amyl salicylate FL/FR iso amyl salicylate FL/FR anise indene FR benzaldehyde propylene glycol acetal FL/FR benzyl acetate FL/FR benzyl acetoacetate FL/FR benzyl formate FL/FR benzyl isobutyrate FL/FR benzyl pivalate FL/FR blue lagoon fragrance FR bois de rose oil peru FL/FR boronia absolute FL/FR bursera graveolens wood oil FL/FR 4-tert- butyl cyclohexane carboxaldehyde FR butyl tiglate FR cassie absolute replacer FL/FR cassis cyclohexene FR citronellal FL/FR (S)- citronellyl acetate FL/FR citronellyl butyrate FL/FR citronellyl hexanoate FL/FR (E)- citronellyl tiglate FL/FR coriander seed oil FL/FR 3- cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester FR cymbopogon validus leaf oil FR dihydromyrcene FR 2',4'- dimethyl acetophenone FL/FR dimethyl benzyl carbinyl acetate FL/FR 2,4- dimethyl cyclohexyl methyl acetate FR 2,4- dimethyl-3-cyclohexene-1-methanol FR 3,6- dimethyl-3-octyl acetate FR eau de brouts absolute FR ethyl anthranilate FL/FR ethyl ethyl anthranilate FL/FR ethyl linalool FR ethyl linalyl acetal FR eucalyptus macarthurii oil FR floral pyranol FR geraniol FL/FR geranyl isobutyrate FL/FR geranyl tiglate FL/FR heather fragrance FR heliotrope absolute FR herbal pyran FR hibiscus fragrance FR ho leaf oil FR ilex paraguariensis oleoresin FL/FR beta- ionol FL/FR alpha- ionone FL/FR (E)-beta- ionone FL/FR beta- ionone FL/FR ionone mixed isomers FL/FR alpha- irone FL/FR jasmin cyclopentanone FR iso jasmone FL/FR (Z)- jasmone FL/FR iso jasmone FL/FR karo karounde absolute FR lavandin concrete decolorized FR lavandin oil FL/FR lavandula angustifolia flower oil FL/FR lavender absolute replacer FR lavender oil FL/FR lavender oil bulgaria FL/FR lavender oil france FL/FR lavender oil greece FL/FR lavender oil replacer FR linaloe wood oil mexico FL/FR laevo- linalool FL/FR linalool oxide FL/FR linalyl butyrate FL/FR linalyl propionate FL/FR magnolia flower oil CO2 extract FL/FR magnolia specialty FR menthadienyl formate FR ortho- methoxybenzyl ethyl ether FR methoxymelonal FL/FR 1-(2- methyl allyl oxy)-3-methoxy-3-methyl-1-butane FR para- methyl benzyl acetate FL/FR methyl benzyl acetate (mixed ortho-,meta-,para-) FL/FR beta-iso methyl ionone FL/FR N- methyl ionone FR alpha-iso methyl ionone (50% min.) FL/FR alpha-iso methyl ionone (90% min.) FL/FR methyl ionyl acetate FL/FR muguet shiseol FL/FR pink nelumbo nucifera flower absolute FR white nelumbo nucifera flower absolute FR white nelumbo nucifera flower concrete FR 3- nonanon-1-yl acetate FL/FR nonisyl propionate FR (Z)-beta- ocimene FL/FR bitter orangeflower concrete morocco FR orris rhizome absolute (iris pallida) FL/FR orris rhizome concrete butter (iris pallida) FL/FR osmanthus absolute replacer FR osmanthus concrete FL/FR pelargonium graveolens flower water FR petitgrain cedrat oil FL/FR petitgrain lemon oil FL/FR petitgrain mandarin oil FL/FR phenethyl isobutyrate FL/FR phenethyl isovalerate FL/FR 1- phenyl propyl butyrate FL/FR 2- phenyl propyl isobutyrate FL/FR 4- phenyl-3-buten-2-ol FL/FR iso phytol FL/FR prenyl salicylate FL/FR iso propyl benzoate FL/FR rhodinyl butyrate FL/FR rose carboxylate FR rose undecene FR sambucus nigra flower oil CO2 extract FR souroubea specialty FR star fruit oil cuba FL/FR styralyl formate FL/FR styralyl propionate FL/FR terpinyl isobutyrate FL/FR terpinyl valerate FL/FR tetrahydroionyl acetate FR tetrahydrolinalyl acetate FR vetiver pentanone FR fruity allyl benzoate FR 3- allyl oxy-1,4-dimethyl bicyclo(3.2.1)octane FR apricot essence FL/FR benzaldehyde / methyl anthranilate schiff's base FR benzyl propionate FL/FR benzyl valerate FL/FR berry hexanoate FR buchu wood specialty FL/FR butyl 2-naphthyl ether FL/FR iso butyl furyl propionate FL/FR citronellyl isobutyrate FL/FR (Z)-beta- damascone FL/FR beta- damascone FL/FR (E)-beta- damascone FL/FR 1-(3,3- dimethyl bicyclo(2.2.1)hept-2-yl)-2-methyl cyclohex-3-ene carbaldehyde FR 1,4- dimethyl bicyclo(3.2.1)oct-3-yl acetate FR 1,2- dimethyl butyl 2-butenoate FR (R)-gamma- dodecalactone FL/FR eriocephalus punctulatus flower oil FR trans-1- ethyl-2-methyl propyl 2-butenoate FL/FR geranyl acetoacetate FL/FR ginsene FR green acetate FR heptyl isovalerate FL/FR linalool oxide acetates FL/FR para- menth-1-ene-9-ol FL/FR 3- mercaptohexyl acetate FL/FR methyl (Z)-5-octenoate FL/FR methyl bicycloheptenyl methyloxirane carboxylate FR methyl isobutyrate FL/FR (E)-7- methyl-3-octen-2-one FL/FR (±)-3- methyl-gamma-decalactone FL/FR myrascone FR 2- nonanone propylene glycol acetal FL/FR alpha- ocimene FL/FR octyl propionate FL/FR peach nitrile FR 2- pentanone FL/FR perillyl acetate FL/FR pineapple hydroxyhexanoate FL/FR plum damascone (high alpha) FR rhubarb pyran FR sambucus canadensis fruit absolute FL/FR strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR (R)- styralyl acetate FL/FR 4-(para- tolyl)-2-butanone FL/FR tropical ionone FL/FR cis- woody acetate FR green acetaldehyde di-(Z)-3-hexen-1-yl acetal FL/FR acetaldehyde ethyl phenethyl acetal FL/FR iso amyl 3-(2-furan) propionate FL/FR iso butyl benzyl carbinol FL/FR heptyl formate FL/FR (Z)-3- hexen-1-yl angelate FR hexoxyacetaldehyde dimethyl acetal FR marigold pot absolute FL/FR 1-[(3aS,7aR)-3a,4,7,7a- tetrahydro-1H-inden-6-yl]ethanone FR herbal 1- allyl-2,2,7,7-tetramethyl cycloheptanol FR iso amyl heptanoate FL/FR bornyl 2-methyl butyrate FL/FR bornyl butyrate FL/FR buchu mercaptan acetate FL/FR butyl levulinate FL/FR calendula officinalis flower oil CO2 extract FR cananga fruit oil FR carrot seed oil (daucus carota ssp. gummifer hook. fil.) spain FR chamomile isobutyrate FR chamomile propionate FR chamomile valerate FR chrysanthemum ketone FR clary propyl acetate FR coriander seed absolute FL/FR cuminyl acetate FL/FR dimethyl cyclormol (IFF) FR freesia heptanol FL/FR geranic oxide FL/FR geranium cyclohexane FR herbal dioxane FR herbal specialty FR herbal undecanone FR inula root oil FR lavandin flower water FR abrialis lavandin oil FL/FR lavender absolute bulgaria FL/FR lavender concrete FL/FR lavender oil terpeneless FL/FR lavender stem oil lithuania FR linalyl octanoate FL/FR marigold pot flower oil FL/FR 1-para- menthen-9-yl acetate FL/FR laevo- menthyl propionate FL/FR methyl ortho-anisate FL/FR myrtle oil FL/FR myrtle oil morocco FL/FR nonisyl acetate FR 3- octanon-1-ol FL/FR origanum oil FL/FR origanum oil greece FL/FR rosemary absolute FL/FR rosemary oil FL/FR rosemary oil africa FL/FR rosemary oil morocco FL/FR rosemary oil spain FL/FR rosemary oil tunisia FL/FR tagete oil madagascar FL/FR tricyclodecenyl propionate FR medicinal ortho- cresyl acetate FL/FR mentholic peppermint cyclohexanone FL/FR orris orris capronate FL/FR powdery alpha- methyl ionone FL/FR (E)-alpha- methyl ionone (50-60%) FL/FR (E)-alpha- methyl ionone (74-80%) FL/FR spicy carnation absolute FR N,N- diethyl octanamide FR green oxane FR white sassafras oil FL/FR spicy acetoacetate FL/FR thujonic cedarleaf oil terpeneless FR tropical cis- galbanum oxathiane FL/FR triflaige A (ZEON) FR waxy dihydrocitronellyl acetate FL/FR (E)- methyl geranate FL/FR orris rhizome oil CO2 extract FL/FR phytyl acetate FL/FR woody 2-tert- butyl cyclohexanone FR 2- decalinyl acetate FR hinoki root oil FR juniper berry oil terpenes FR melozol acetate FR rhubarb oxirane FR sandal octanol FR spicy pentanone FL/FR 1-(5',5',6'- trimethyl bicyclo(2.2.1)hept-2'-ylidene) propan-2-one FR zdravetz absolute FR zdravetz oil FL/FR For Flavor No flavor group found for these acetaldehyde di-(Z)-3-hexen-1-yl acetal FL/FR ortho- acetyl-para-cresol FL/FR iso amyl angelate FL/FR amyl furoate FL/FR benzyl pivalate FL/FR benzyl valerate FL/FR dextro,laevo- borneol FL/FR bornyl 2-methyl butyrate FL/FR bornyl butyrate FL/FR iso bornyl methyl ether FL/FR buchu wood specialty FL/FR bursera graveolens wood oil FL/FR butyl 2-naphthyl ether FL/FR cassie absolute replacer FL/FR ortho- cresyl acetate FL/FR cuminyl acetate FL/FR cyclohexyl benzoate FL/FR 8,9- dehydrotheaspirone FL diethyl malate FL/FR 2,4- difurfuryl furan FL dihydrocitronellyl acetate FL/FR 2',4'- dimethyl acetophenone FL/FR (E+Z)-4,8- dimethyl-3,7-nonadien-2-one FL/FR (R)-gamma- dodecalactone FL/FR ethyl ethyl anthranilate FL/FR trans-1- ethyl-2-methyl propyl 2-butenoate FL/FR heptyl isovalerate FL/FR ilex paraguariensis oleoresin FL/FR ionone mixed isomers FL/FR linaloe wood oil mexico FL/FR (Z)- linalool oxide (furanoid) FL/FR linalool oxide acetates FL/FR magnolia flower oil CO2 extract FL/FR marigold pot flower oil FL/FR laevo- menthyl propionate FL/FR methyl benzyl acetate (mixed ortho-,meta-,para-) FL/FR (E)- methyl geranate FL/FR beta-iso methyl ionone FL/FR (E)-beta- methyl ionone FL/FR (E)-alpha- methyl ionone (50-60%) FL/FR methyl ortho-anisate FL/FR myrtle oil morocco FL/FR 2- nonanone propylene glycol acetal FL/FR alpha- ocimene FL/FR 3- octanon-1-ol FL/FR 1- phenyl propyl butyrate FL/FR 2- phenyl propyl isobutyrate FL/FR iso propyl benzoate FL/FR white sassafras oil FL/FR (R)- styralyl acetate FL/FR styralyl formate FL/FR terpinyl isobutyrate FL/FR zdravetz oil FL/FR iso amyl 3-(2-furan) propionate FL/FR benzyl acetoacetate FL/FR iso butyl furyl propionate FL/FR beta- damascone FL/FR acidic acidic (E)-2- hexenoic acid FL amber iso butyl benzyl carbinol FL/FR aromatic amyl salicylate FL/FR balsamic benzyl benzoate FL/FR benzyl salicylate FL/FR iso bornyl propionate FL/FR berry raspberry ketone methyl ether FL/FR camphoreous laevo- borneol FL/FR (-)-alpha- fenchol FL/FR geranic oxide FL/FR rosemary oil tunisia FL/FR citrus bergamot oil bergaptene reduced italy FL/FR beta- bisabolol FL/FR freesia heptanol FL/FR laevo- linalool FL/FR myrcenyl acetate FL/FR petitgrain cedrat oil FL/FR petitgrain lemon oil FL/FR petitgrain mandarin oil FL/FR styralyl propionate FL/FR dairy methyl (Z)-5-octenoate FL/FR estery octyl propionate FL/FR ethereal methyl isobutyrate FL/FR fatty heptyl formate FL/FR methyl decanoate FL/FR (E)-7- methyl-3-octen-2-one FL/FR floral bois de rose oil peru FL/FR citronellal FL/FR (S)- citronellyl acetate FL/FR citronellyl hexanoate FL/FR dimethyl benzyl carbinyl acetate FL/FR geraniol FL/FR geranyl isobutyrate FL/FR geranyl tiglate FL/FR beta- ionol FL/FR alpha- ionone FL/FR lepidine FL/FR linalyl butyrate FL/FR alpha-iso methyl ionone (50% min.) FL/FR (E)-alpha- methyl ionone (74-80%) FL/FR alpha-iso methyl ionone (90% min.) FL/FR muguet shiseol FL/FR orris rhizome concrete butter (iris pallida) FL/FR rhodinyl butyrate FL/FR tropical ionone FL/FR fruity apricot essence FL/FR benzaldehyde propylene glycol acetal FL/FR benzyl acetate FL/FR benzyl formate FL/FR benzyl isobutyrate FL/FR benzyl propionate FL/FR boronia absolute FL/FR buchu mercaptan acetate FL/FR citronellyl butyrate FL/FR citronellyl isobutyrate FL/FR (E)-beta- damascone FL/FR (Z)-beta- damascone FL/FR ethyl anthranilate FL/FR 2- heptanol FL/FR 2- hexyl-4-acetoxytetrahydrofuran FL linalyl octanoate FL/FR 1-para- menthen-9-yl acetate FL/FR methoxymelonal FL/FR para- methyl benzyl acetate FL/FR alpha- methyl ionone FL/FR 3- nonanon-1-yl acetate FL/FR osmanthus concrete FL/FR 2- pentanone FL/FR phenethyl isovalerate FL/FR pineapple hydroxyhexanoate FL/FR sambucus canadensis fruit absolute FL/FR spicy pentanone FL/FR star fruit oil cuba FL/FR strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR tagete oil madagascar FL/FR terpinyl valerate FL/FR 4-(para- tolyl)-2-butanone FL/FR green acetaldehyde ethyl phenethyl acetal FL/FR iso amyl salicylate FL/FR (E)- citronellyl tiglate FL/FR cis- galbanum oxathiane FL/FR iso jasmone FL/FR iso jasmone FL/FR linalool oxide FL/FR marigold pot absolute FL/FR (Z)-beta- ocimene FL/FR perillyl acetate FL/FR herbal iso amyl heptanoate FL/FR butyl levulinate FL/FR coriander seed absolute FL/FR coriander seed oil FL/FR abrialis lavandin oil FL/FR lavandin oil FL/FR lavandula angustifolia flower oil FL/FR lavender absolute bulgaria FL/FR lavender concrete FL/FR lavender oil FL/FR lavender oil bulgaria FL/FR lavender oil france FL/FR lavender oil greece FL/FR lavender oil terpeneless FL/FR linalyl propionate FL/FR para- menth-1-ene-9-ol FL/FR origanum oil FL/FR origanum oil greece FL/FR prenyl salicylate FL/FR rosemary absolute FL/FR rosemary oil FL/FR rosemary oil africa FL/FR rosemary oil morocco FL/FR rosemary oil spain FL/FR honey phenethyl isobutyrate FL/FR mentholic peppermint cyclohexanone FL/FR musty geranyl acetoacetate FL/FR nutty phytyl acetate FL/FR oily iso phytol FL/FR orris orris capronate FL/FR spicy benzyl cinnamate FL/FR cinnamyl formate FL/FR myrtle oil FL/FR spicy acetoacetate FL/FR sweet orris rhizome absolute (iris pallida) FL/FR tropical alpha- amyl cinnamaldehyde FL/FR 3- mercaptohexyl acetate FL/FR waxy butyl undecylenate FL/FR (±)-3- methyl-gamma-decalactone FL/FR 4- phenyl-3-buten-2-ol FL/FR woody beta- ionone FL/FR (E)-beta- ionone FL/FR alpha- irone FL/FR (Z)- jasmone FL/FR methyl ionyl acetate FL/FR orris rhizome oil CO2 extract FL/FR   Potential Uses: FR basil oil replacer FR chamomile FR chypre FR flower shop FR fruit FR green FR herbal FR rosemary FR woody   Occurrence (nature, food, other):note   not found in nature   Synonyms: 2- cyclohexene-1-carboxylic acid 2,6,6,-trimethyl methyl ester 2- cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester   methyl 2,6,6-trimethyl cyclohex-2-ene carboxylate   methyl 2,6,6-trimethyl cyclohex-2-ene-1-carboxylate   methyl 2,6,6-trimethylcyclohex-2-ene-1-carboxylate   methyl cyclo geranate   methyl cyclogeranate (Firmenich)   methylcyclogeranate 2,6,6- trimethyl-2-cyclohexene-1-carboxylic acid, methyl ester   Articles:   None found yet. Try the PubMed Search.

Notes: Blends well with damascones. Gives good body.