rhubarb oxirane
rhubofix (Firmenich)

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  41816-03-9 3,7'-Dimethyl-3,4,4a,5,8,8a-hexahydrospiro-(1,4-methanonaphthalene- 2(1H),2'-oxirane)

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  978880 RHUBOFIX® for fragrance
  RHUBOFIX® has the ability to fill out a fragrance. It blends very well with woody, spicy, rose, bergamot and lavender notes. With salicylates, interesting spicy effects can be obtained particularly if sweetened by heliotropin or similar materials. Its delicate green-woody nuance also harmonizes effectively with citrus notes, in particular lemon and grapefruit.

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  Indukern, S.A. F&F Ingredients Division

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  RHUBARD OXIRANE

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  502835 Rhubofix

Fragrance Demo Formulas CAS Number: 41816-03-9 3D/inchi Other(deleted CASRN): 177771-99-2 ECHA EINECS - REACH Pre-Reg: 255-560-0 FDA UNII: Search Nikkaji Web: J248.398J XlogP3-AA: 2.50 (est) Molecular Weight: 204.31260000 Formula: C14 H20 O NMR Predictor: Predict (works with chrome, Edge or firefox) Category:fragrance agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search   Physical Properties: Appearance: colorless clear liquid (est) Assay: 96.00 to 100.00 Food Chemicals Codex Listed: No Specific Gravity: 1.02300 to 1.03300 @ 20.00 °C. Pounds per Gallon - (est).: 8.522 to 8.606 Refractive Index: 1.50200 to 1.50800 @ 20.00 °C. Boiling Point: 203.00 °C. @ 760.00 mm Hg Acid Value: 1.00 max. KOH/g Vapor Pressure: 0.003000 mmHg @ 25.00 °C. (est) Flash Point: > 212.00 °F. TCC ( > 100.00 °C. ) logP (o/w): 3.790 (est) Soluble in:   alcohol   water, 21.56 mg/L @ 25 °C (est) Stability:   APC: traces - 0.2%   candle: traces - 0.5%   detergent: traces - 0.2%   fine fragrances: traces - 0.5%   shampoo: traces - 0.2%   shower gel: traces - 0.2%   soap: traces - 0.2%   softener: traces - 0.2%   Organoleptic Properties: Odor Type: woody Odor Strength:medium , recommend smelling in a 10.00 % solution or less Substantivity:96 hour(s) at 100.00 % fresh woody spicy floral fruity rhubarb zesty Odor Description:at 10.00 % in dipropylene glycol. fresh woody spicy floral fruity rhubarb zesty Luebke, William tgsc, (1987) Odor sample from: Firmenich Inc. Odor and/or flavor descriptions from others (if found). Firmenich RHUBOFIX® for fragrance Odor Description:Complex woody, spicy, floral and fruity note. It has a zesty freshness and unique green rhubarb effect RHUBOFIX® has the ability to fill out a fragrance. It blends very well with woody, spicy, rose, bergamot and lavender notes. With salicylates, interesting spicy effects can be obtained particularly if sweetened by heliotropin or similar materials. Its delicate green-woody nuance also harmonizes effectively with citrus notes, in particular lemon and grapefruit. Moellhausen RHUBOFIX Odor Description:Complex woody, spicy, floral and fruity note. It has a zesty freshness and unique green rhubarb effect   Cosmetic Information: CosIng: cosmetic data Cosmetic Uses: perfuming agents   Suppliers: Azelis UK RHUBOFIX BOC Sciences For experimental / research use only. 3,7'-Dimethyl-3,4,4a,5,8,8a-hexahydrospiro-(1,4-methanonaphthalene- 2(1H),2'-oxirane) Ernesto Ventós RHUBOFIX FIRMENICH 978880 Odor: WOODY,FLORAL,SPICY,FRUITY,RHUBARB Firmenich RHUBOFIX® for fragrance Odor: Complex woody, spicy, floral and fruity note. It has a zesty freshness and unique green rhubarb effect Use: RHUBOFIX® has the ability to fill out a fragrance. It blends very well with woody, spicy, rose, bergamot and lavender notes. With salicylates, interesting spicy effects can be obtained particularly if sweetened by heliotropin or similar materials. Its delicate green-woody nuance also harmonizes effectively with citrus notes, in particular lemon and grapefruit. Indukern F&F RHUBARD OXIRANE Odor: WOODY, SPICY, FLORAL, FRUITY Lluch Essence RHUBAFIX Moellhausen RHUBOFIX Penta International RHUBOFIX Perfumery Laboratory RUBOFIKS® Firmenich (Rhubofix® Firmenich) Odor: Spicy, floral, fruity with a note of zesty freshness and a unique effect of green rhubarb Santa Cruz Biotechnology For experimental / research use only. Rhubofix Vigon International Rhubofix Odor: Complex woody, spicy, floral and fruity note. It has a zesty freshness and unique green rhubarb effect   Safety Information:   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: Not determined Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: fragrance agents RIFM Fragrance Material Safety Assessment: Search IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice Recommendation for rhubarb oxirane usage levels up to:   0.5000 % in the fragrance concentrate.   Recommendation for rhubarb oxirane flavor usage levels up to:   not for flavor use.   Safety References: EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA Substance Registry Services (TSCA):41816-03-9 EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :94522 National Institute of Allergy and Infectious Diseases:Data WGK Germany:2 Chemidplus:0041816039   References: NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 41816-03-9 Pubchem (cid): 94522 Pubchem (sid): 135049897   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements HMDB (The Human Metabolome Database): Search ChemSpider: View   Potential Blenders and core components note For Odor aldehydic 3- methyl-4-hexyl oxybutyraldehyde FR amber amber carane FR animal musk indenofuran FR anise estragon absolute FR balsamic benzyl cinnamate FL/FR alpha- bisabolene FL/FR cinnamyl formate FL/FR croton glabellus bark extract FL/FR guaiacyl phenyl acetate FL/FR guaiyl acetate FL/FR khella oil FR alpha- methyl cinnamyl alcohol FR myrrh resinoid FR opoponax absolute (balsamodendron kafal) FL/FR valeriana wallichii root oil FR citrus (R)- citronellyl nitrile FR citronitrile (Symrise) FR 2- heptanol FL/FR fatty butyl undecylenate FL/FR fermented methyl decanoate FL/FR floral acetal 318 FR iso amyl angelate FL/FR benzyl acetate FL/FR benzyl acetoacetate FL/FR benzyl isobutyrate FL/FR blue lagoon fragrance FR iso butyl salicylate FL/FR cardamom absolute FL/FR carnation concrete FR cassis specialty FR cestrum nocturnum flower oil FR (S)- citronellyl acetate FL/FR citronellyl butyrate FL/FR citronellyl hexanoate FL/FR (E)- citronellyl tiglate FL/FR coffee flower absolute FR 3- cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester FR cymbopogon validus leaf oil FR daffodil fragrance FR dimethyl benzyl carbinyl acetate FL/FR 3,6- dimethyl-3-octyl acetate FR ethyl anthranilate FL/FR ethyl ethyl anthranilate FL/FR eucalyptus macarthurii oil FR iso eugenyl ethyl acetal FR geraniol FL/FR geranium oil bourbon FL/FR geranyl isobutyrate FL/FR ginger lily fragrance FR hawthorn specialty FR hibiscus fragrance FR ionone mixed isomers FL/FR jasmin absolute italy (from concrete) FL/FR jasmin cyclopentanone FR iso jasmone FL/FR jonquil absolute replacer FR linalyl butyrate FL/FR magnolia flower oil CO2 extract FL/FR magnolia specialty FR menthadienyl formate FR ortho- methoxybenzyl ethyl ether FR methoxymelonal FL/FR 1-(2- methyl allyl oxy)-3-methoxy-3-methyl-1-butane FR para- methyl benzyl acetate FL/FR methyl benzyl acetate (mixed ortho-,meta-,para-) FL/FR alpha-iso methyl ionone (90% min.) FL/FR methyl ionyl acetate FL/FR mimosa absolute FL/FR mimosa absolute france FL/FR mimosa absolute india FL/FR pink nelumbo nucifera flower absolute FR white nelumbo nucifera flower absolute FR white nelumbo nucifera flower concrete FR 3- nonanon-1-yl acetate FL/FR orris rhizome concrete butter (iris pallida) FL/FR osmanthus absolute replacer FR osmanthus concrete FL/FR petitgrain mandarin oil FL/FR phenethyl isobutyrate FL/FR phenethyl isovalerate FL/FR 1- phenyl propyl butyrate FL/FR 2- phenyl propyl isobutyrate FL/FR 4- phenyl-3-buten-2-ol FL/FR iso propyl benzoate FL/FR rhodinol FL/FR rhodinyl butyrate FL/FR rose absolute (rosa centifolia) FL/FR rose absolute (rosa centifolia) morocco FL/FR rose concrete (rosa centifolia) FR rose oil (rosa centifolia) egypt FL/FR rose oil (rosa damascena) bulgaria FL/FR rose oil (rosa damascena) iran FL/FR rose oil (rosa damascena) turkey FL/FR rose oil replacer FR rose undecene FR souroubea specialty FR star fruit oil cuba FL/FR styralyl propionate FL/FR terpinyl valerate FL/FR tetrahydroionyl acetate FR tuberose absolute chassis FL/FR tuberose absolute replacer FR ylang ylang flower absolute FL/FR fruity allyl benzoate FR apricot essence FL/FR benzaldehyde / methyl anthranilate schiff's base FR benzyl propionate FL/FR benzyl valerate FL/FR berry hexanoate FR butyl 2-naphthyl ether FL/FR iso butyl furyl propionate FL/FR citronellyl isobutyrate FL/FR (Z)-beta- damascone FL/FR beta- damascone FL/FR (E)-beta- damascone FL/FR (R)-gamma- dodecalactone FL/FR eriocephalus punctulatus flower oil FR ginsene FR linalool oxide acetates FL/FR marigold absolute (tagetes glandulifera) FR 3- mercaptohexyl acetate FL/FR methyl bicycloheptenyl methyloxirane carboxylate FR methyl isobutyrate FL/FR (E)-7- methyl-3-octen-2-one FL/FR (±)-3- methyl-gamma-decalactone FL/FR myrascone FR 2- nonanone propylene glycol acetal FL/FR alpha- ocimene FL/FR peach nitrile FR plum damascone (high alpha) FR rhubarb pyran FR sambucus canadensis fruit absolute FL/FR strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR (R)- styralyl acetate FL/FR 4-(para- tolyl)-2-butanone FL/FR cis- woody acetate FR green iso amyl 3-(2-furan) propionate FL/FR marigold pot absolute FL/FR octanal diethyl acetal FL/FR 1-[(3aS,7aR)-3a,4,7,7a- tetrahydro-1H-inden-6-yl]ethanone FR herbal acorus calamus rhizome oil FR agate fragrance FR sweet basil absolute FL/FR calamintha clinopodium oil FR canarium luzonicum oil FL/FR chamomile isobutyrate FR chamomile propionate FR clary sage oil france FL/FR coriander seed absolute FL/FR dill seed oil FL/FR dill seed oil CO2 extract FL/FR american elder flower absolute FR geranium cyclohexane FR linalyl acetate FL/FR methyl cyclogeranate (Firmenich) FR nonisyl acetate FR curled parsley seed oil FL/FR petroselinum crispum seed oil CO2 extract FL/FR rose oil (rosa centifolia) morocco FL/FR tagete oil madagascar FL/FR common tansy flower oil FR common tansy flower oil dutch FR medicinal ortho- cresyl acetate FL/FR minty ethyl salicylate FL/FR musk musk indanone FR orris eugenyl formate FL/FR para-iso propyl acetophenone FL/FR peppery asarum europaeum oil FR phenolic 4- methyl-2,6-dimethoxyphenol FL/FR powdery alpha- methyl ionone FL/FR (E)-alpha- methyl ionone (74-80%) FL/FR saffron saffron stigmates absolute FR spicy acacia fragrance FR allspice berry absolute FL/FR homo anisaldehyde FL/FR anona squamosa leaf oil FR artemisia dracunculus herb oil FL/FR ayou wood oil FR cananga leaf oil FR carnation absolute replacer FR caryophyllene FL/FR beta- caryophyllene FL/FR alpha- caryophyllene alcohol FL/FR cascarilla oil replacer FL/FR cassia bark oil china FL/FR cassia leaf oil FL/FR cinnamaldehyde / methyl anthranilate schiff's base FR cinnamon bark oil FL/FR cinnamon bark oil (cinnamomum zeylanicum) india FL/FR cinnamon bark oil ceylon FL/FR cinnamon leaf oil ceylon FL/FR cinnamon oleoresin ceylon FL/FR (E)- cinnamyl acetate FL/FR (Z)- cinnamyl acetate FL/FR cinnamyl acetate FL/FR cinnamyl propionate FL/FR clove bud absolute FL/FR clove bud oil CO2 extract FL/FR eugenyl acetate FL/FR floral spice fragrance FR galangal root oil FL/FR ginger oleoresin africa FL/FR ginger root oil brazil FL/FR grains of paradise oil FL/FR green oxane FR mace absolute FL/FR mace oil FL/FR mace oleoresin FL/FR machilus kusanoi leaf oil FR machilus kusanoi wood oil FR maja fragrance FR para- methoxy-alpha-methyl cinnamaldehyde FL/FR (E)-para- methoxycinnamaldehyde FL/FR myristica fragrans fruit extract FL/FR myristica fragrans seed tincture FL/FR nutmeg oil FL/FR black pepper absolute FL/FR pepper hexanone FR black pepper oil CO2 extract FL/FR pepper tree berry absolute FL/FR pepper tree berry oil FL/FR piper longum fruit oil FL/FR piper longum fruit oil CO2 extract FL/FR spicy acetoacetate FL/FR spicy carbonate FR sugandha kokila berry oil FR (E)- tiglic acid FL/FR turmeric root absolute FL/FR zingiber officinale root extract FL/FR zingiber officinale root tincture FL/FR terpenic para- cymene FL/FR juniper branch oil FR pine needle oil dwarf FL/FR thujonic common tansy oil canada FR tropical triflaige A (ZEON) FR vanilla vanilla cresol FR waxy dihydrocitronellyl acetate FL/FR (E)- methyl geranate FL/FR phytyl acetate FL/FR woody caryophyllene alcohol acetate FR caryophyllene formate FL/FR beta- caryophyllene oxide FL/FR curcuma zedoaria bark extract FL/FR dacrydium franklinii wood oil FR 2- decalinyl acetate FR guaiacwood oil FL/FR guaiacwood oil 20% in gurjun balsam oil FR guaiacyl acetate FL/FR hedychium spicatum root oil FR jatamansi root oil FR juniper berry oleoresin FL/FR melozol acetate FR methyl methylene tricyclodecanol FR patchouli absolute FR 4-iso propyl phenol FL/FR sabinene FL/FR santal penten-2-ol FR spikenard oil FL/FR spikenard oil CO2 extract FL/FR zedoary bark oil FL/FR zedoary root oil FL/FR zedoary root oil CO2 extract FL/FR For Flavor No flavor group found for these iso amyl angelate FL/FR homo anisaldehyde FL/FR benzyl valerate FL/FR alpha- bisabolene FL/FR butyl 2-naphthyl ether FL/FR alpha- caryophyllene alcohol FL/FR caryophyllene formate FL/FR (Z)- cinnamyl acetate FL/FR (E)- cinnamyl acetate FL/FR ortho- cresyl acetate FL/FR croton glabellus bark extract FL/FR dihydrocitronellyl acetate FL/FR (R)-gamma- dodecalactone FL/FR ethyl ethyl anthranilate FL/FR eugenyl formate FL/FR grains of paradise oil FL/FR guaiyl acetate FL/FR ionone mixed isomers FL/FR linalool oxide acetates FL/FR magnolia flower oil CO2 extract FL/FR para- methoxy-alpha-methyl cinnamaldehyde FL/FR (E)-para- methoxycinnamaldehyde FL/FR methyl benzyl acetate (mixed ortho-,meta-,para-) FL/FR (E)- methyl geranate FL/FR 2- nonanone propylene glycol acetal FL/FR alpha- ocimene FL/FR 1- phenyl propyl butyrate FL/FR 2- phenyl propyl isobutyrate FL/FR iso propyl benzoate FL/FR spikenard oil FL/FR spikenard oil CO2 extract FL/FR (R)- styralyl acetate FL/FR iso amyl 3-(2-furan) propionate FL/FR benzyl acetoacetate FL/FR iso butyl furyl propionate FL/FR beta- damascone FL/FR balsamic balsamic opoponax absolute (balsamodendron kafal) FL/FR brown (E)- tiglic acid FL/FR burnt 4-iso propyl phenol FL/FR citrus petitgrain mandarin oil FL/FR styralyl propionate FL/FR cooling iso butyl salicylate FL/FR ethereal methyl isobutyrate FL/FR fatty methyl decanoate FL/FR (E)-7- methyl-3-octen-2-one FL/FR floral cardamom absolute FL/FR cinnamyl propionate FL/FR (S)- citronellyl acetate FL/FR citronellyl hexanoate FL/FR dimethyl benzyl carbinyl acetate FL/FR geraniol FL/FR geranium oil bourbon FL/FR geranyl isobutyrate FL/FR jasmin absolute italy (from concrete) FL/FR linalyl acetate FL/FR linalyl butyrate FL/FR (E)-alpha- methyl ionone (74-80%) FL/FR alpha-iso methyl ionone (90% min.) FL/FR orris rhizome concrete butter (iris pallida) FL/FR rhodinol FL/FR rhodinyl butyrate FL/FR rose absolute (rosa centifolia) FL/FR rose absolute (rosa centifolia) morocco FL/FR rose oil (rosa centifolia) egypt FL/FR rose oil (rosa damascena) bulgaria FL/FR rose oil (rosa damascena) iran FL/FR rose oil (rosa damascena) turkey FL/FR tuberose absolute chassis FL/FR ylang ylang flower absolute FL/FR fruity apricot essence FL/FR benzyl acetate FL/FR benzyl isobutyrate FL/FR benzyl propionate FL/FR citronellyl butyrate FL/FR citronellyl isobutyrate FL/FR (Z)-beta- damascone FL/FR (E)-beta- damascone FL/FR ethyl anthranilate FL/FR 2- heptanol FL/FR methoxymelonal FL/FR para- methyl benzyl acetate FL/FR alpha- methyl ionone FL/FR 3- nonanon-1-yl acetate FL/FR osmanthus concrete FL/FR phenethyl isovalerate FL/FR piper longum fruit oil CO2 extract FL/FR sambucus canadensis fruit absolute FL/FR star fruit oil cuba FL/FR strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR tagete oil madagascar FL/FR terpinyl valerate FL/FR 4-(para- tolyl)-2-butanone FL/FR green canarium luzonicum oil FL/FR (E)- citronellyl tiglate FL/FR iso jasmone FL/FR marigold pot absolute FL/FR octanal diethyl acetal FL/FR herbal sweet basil absolute FL/FR clary sage oil france FL/FR coriander seed absolute FL/FR dill seed oil FL/FR dill seed oil CO2 extract FL/FR curled parsley seed oil FL/FR petroselinum crispum seed oil CO2 extract FL/FR rose oil (rosa centifolia) morocco FL/FR honey phenethyl isobutyrate FL/FR minty ethyl salicylate FL/FR nutty phytyl acetate FL/FR phenolic guaiacyl phenyl acetate FL/FR 4- methyl-2,6-dimethoxyphenol FL/FR pine pine needle oil dwarf FL/FR spicy allspice berry absolute FL/FR artemisia dracunculus herb oil FL/FR benzyl cinnamate FL/FR beta- caryophyllene FL/FR caryophyllene FL/FR cascarilla oil replacer FL/FR cassia bark oil china FL/FR cassia leaf oil FL/FR cinnamon bark oil FL/FR cinnamon bark oil (cinnamomum zeylanicum) india FL/FR cinnamon bark oil ceylon FL/FR cinnamon leaf oil ceylon FL/FR cinnamon oleoresin ceylon FL/FR cinnamyl acetate FL/FR cinnamyl formate FL/FR clove bud absolute FL/FR clove bud oil CO2 extract FL/FR eugenyl acetate FL/FR galangal root oil FL/FR ginger oleoresin africa FL/FR ginger root oil brazil FL/FR mace absolute FL/FR mace oil FL/FR mace oleoresin FL/FR myristica fragrans fruit extract FL/FR myristica fragrans seed tincture FL/FR nutmeg oil FL/FR black pepper absolute FL/FR black pepper oil CO2 extract FL/FR pepper tree berry absolute FL/FR pepper tree berry oil FL/FR piper longum fruit oil FL/FR para-iso propyl acetophenone FL/FR spicy acetoacetate FL/FR turmeric root absolute FL/FR zingiber officinale root extract FL/FR zingiber officinale root tincture FL/FR terpenic para- cymene FL/FR tropical 3- mercaptohexyl acetate FL/FR waxy butyl undecylenate FL/FR (±)-3- methyl-gamma-decalactone FL/FR mimosa absolute FL/FR mimosa absolute france FL/FR mimosa absolute india FL/FR 4- phenyl-3-buten-2-ol FL/FR woody beta- caryophyllene oxide FL/FR curcuma zedoaria bark extract FL/FR guaiacwood oil FL/FR guaiacyl acetate FL/FR juniper berry oleoresin FL/FR methyl ionyl acetate FL/FR sabinene FL/FR zedoary bark oil FL/FR zedoary root oil FL/FR zedoary root oil CO2 extract FL/FR   Potential Uses: FR bergamot FR grapefruit FR jasmin FR lavender FR rose FR spice FR vetiver FR woody   Occurrence (nature, food, other):note   not found in nature   Synonyms: 3,4,4a,5,8,8a- hexahydro-3',7 (or 6)-dimethylspiro(1,4-methanonaphthalene-2(1H),2'-oxirane) 3,4,4a,5,8,8a- hexahydro-3',7'-dimethyl spiro(1,4-methanonaphthalene-2(1H),2'-oxirane) 3,4,4a,5,8,8a- hexahydro-3',7'-dimethylspiro(1,4-methanonaphthalene-2(1H),2'-oxirane) 3,4,4a,5,8,8a- hexahydro-3',7'-dimethylspiro[1,4-methanonaphthalene-2(1H),2'-oxirane] 3',7'- hexahydrodimethyl spiromethanonaphthalene oxirane   rhubarb oxirane   rhubofix (Firmenich)   rubofin   spiro(1,4-methanonaphthalene-2(1H),2'-oxirane), 3,4,4a,5,8,8a-hexahydro-3',7-dimethyl-   Articles: Info:Rhubofix

Notes: Blends well with the salicylates.