amber carane
spirambrene (Givaudan)

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  500932 Spirambrene

Fragrance Demo Formulas Name: (1'S,4'R,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane] CAS Number: 121251-68-1 3D/inchi FDA UNII: Search XlogP3-AA: 3.70 (est) Molecular Weight: 238.37062000 Formula: C15 H26 O2 NMR Predictor: Predict (works with chrome, Edge or firefox) Name: (1'S,4'S,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane] CAS Number: 121251-67-0 3D/inchi FDA UNII: Search XlogP3-AA: 3.70 (est) Molecular Weight: 238.37062000 Formula: C15 H26 O2 NMR Predictor: Predict (works with chrome, Edge or firefox) Category:fragrance agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search   Physical Properties: Appearance: colorless to pale yellow clear liquid (est) Assay: 97.00 to 100.00 Food Chemicals Codex Listed: No Specific Gravity: 0.97920 to 0.90000 @ 25.00 °C. Pounds per Gallon - (est).: 8.148 to 7.489 Refractive Index: 1.49400 to 1.50000 @ 20.00 °C. Boiling Point: 251.00 to 252.00 °C. @ 760.00 mm Hg Vapor Pressure: 0.003900 mmHg @ 20.00 °C. Flash Point: 255.00 °F. TCC ( 123.89 °C. ) logP (o/w): 4.900 Soluble in:   alcohol   water, 50 mg/L @ 20 °C (exp) Stability:   alcoholic - good   antiperspirant spray - moderate   APC (pH = 10) - good   candles - good   damp fabric - good   dry fabric - poor   liquid bleach - poor   pH = 2 - moderate   powder detergent - good   powder detergent + activator - moderate   soap - good   toiletries - good   Organoleptic Properties: Odor Type: amber Odor Strength:medium Substantivity:96 hour(s) at 100.00 % amber woody spicy aldehydic green seaweed Odor Description:at 100.00 %. amber woody spicy aldehydic green seaweed Odor and/or flavor descriptions from others (if found). Givaudan Spirambrene Odor Description:Woody, Ambery, Spicy, Aldehydic, Powerful Spirambrene blends well with sparkling, green, spicy and aldehydic top notes. It is an interesting complement in woody accords for providing a diffusive ambery effect. Due to its high impact, it produces unique and original effects when combined with other woody elements   Cosmetic Information: CosIng: cosmetic data Cosmetic Uses: perfuming agents   Suppliers: Augustus Oils Spirambrene Services BOC Sciences For experimental / research use only. Spirambrene Ernesto Ventós SPIRAMBRENE Odor: WOODY-AMBERY,SPICY,ALDEHYDIC,POTENT Givaudan Spirambrene Odor: Woody, Ambery, Spicy, Aldehydic, Powerful Use: Spirambrene blends well with sparkling, green, spicy and aldehydic top notes. It is an interesting complement in woody accords for providing a diffusive ambery effect. Due to its high impact, it produces unique and original effects when combined with other woody elements Indukern F&F SPIRAMBRENE Odor: WOODY, AMBER, ALDEHYDIC, SPICY Lluch Essence SPIRAMBRENE Moellhausen SPIRAMBRENE Odor: powerful amber-like, woody and aldehydic note Vigon International Spirambrene Odor: Woody, Ambery, Spicy, Aldehydic, Powerful   Safety Information: European information : Most important hazard(s): Xi - Irritant, Dangerous for the environment. R 38 - Irritating to skin. R 51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S 02 - Keep out of the reach of children. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36 - Wear suitable protective clothing. S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet.   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: oral-rat LD50 5000 mg/kg Spirambrene blends well with sparkling, green, spicy and aldehydic top notes. It is an interesting complement in woody accords for providing a diffusive ambery effect. Due to its high impact, it produces unique and original effects when combined with other woody elements Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: fragrance agents RIFM Fragrance Material Safety Assessment: Search IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice Recommendation for amber carane usage levels up to:   3.0000 % in the fragrance concentrate.   Recommendation for amber carane flavor usage levels up to:   not for flavor use.   Safety References: EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA Substance Registry Services (TSCA):121251-68-1 EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :44154128 National Institute of Allergy and Infectious Diseases:Data WISER:UN 3082 WGK Germany:2 (1'S,4'R,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane] Chemidplus:0121251681 (1'S,4'S,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane] Chemidplus:0121251670   References:   (1'S,4'R,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane] NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 121251-68-1 Pubchem (cid): 44154128 Pubchem (sid): 135203302   (1'S,4'S,6'R)-2,2,4',7',7'-pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane] NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 121251-67-0 Pubchem (cid): 44152459 Pubchem (sid): 135203301   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements HMDB (The Human Metabolome Database): Search Wikipedia: View   Potential Blenders and core components note For Odor aldehydic agrumen nitrile FR citrus carbaldehyde FR 6,7,8- decen-1-ol FR dodecanal (aldehyde C-12 lauric) FL/FR fresh carbaldehyde FR oriental aldehydic fragrance FR amber (Z)- abienol FL/FR acetoxymethyl isolongifolene FR amber acetate FR amber butanol FR amber cyclohexanol FR amber specialty FR ambermax 50 (Givaudan) FR ambroxan FL/FR angelica root oil FL/FR cistus ladaniferus resinoid FL/FR formoxymethyl isolongifolene FR hydroxymethyl isolongifolene 50% in dpg FR labdanum absolute FL/FR animal animal carbolactone FR iso butyl quinoline FR costus valerolactone FR para- cresyl caprylate FL/FR indole FL/FR musk indenofuran FR anise estragon absolute FR anisic para- anisaldehyde FL/FR balsamic iso amyl benzoate FL/FR amyris wood oil FL/FR benzyl cinnamate FL/FR benzyl salicylate FL/FR laevo- bornyl acetate FL/FR iso butyl cinnamate FL/FR cinnamyl alcohol FL/FR clover nitrile FR croton glabellus bark extract FL/FR fir balsam absolute FR fir carboxylate FR guaiyl acetate FL/FR khella oil FR mastic gum resin FR methyl (E)-cinnamate FL/FR methyl hydrogenated rosinate FR myrrh resinoid FR opoponax absolute (balsamodendron kafal) FL/FR opoponax resin (commiphora erythraea var. glabrescens engler) FL/FR opoponax resinoid replacer FR oriental specialty FR 3- phenyl propyl alcohol FL/FR sclareol FL/FR styrax resin (liquidambar styraciflua) FL/FR styrax resinoid (liquidambar styraciflua) FL/FR valeriana wallichii root oil FR berry raspberry ketone methyl ether FL/FR citrus bergamot oil bergaptene reduced italy FL/FR citral FL/FR citrus specialty FR lime pyran FR limonene aldehyde FR tetrahydrocitral FL/FR dusty woody furan FR fatty (E,Z)-2,6- dodecadienal FL/FR floral alpha- amyl cinnamaldehyde FL/FR alpha- amyl cinnamaldehyde diethyl acetal FR iso amyl salicylate FL/FR benzyl acetate FL/FR benzyl alcohol FL/FR benzyl isobutyrate FL/FR bois de rose oil brazil FL/FR iso butyl salicylate FL/FR cassis specialty FR citronellol FL/FR citronellyl acetate FL/FR coriander seed oil FL/FR cyclamen aldehyde FL/FR cyclamen propanal FR cyclohexyl ethyl alcohol FL/FR 9- decen-1-ol FL/FR dihydrojasmone FL/FR dimethyl anthranilate FL/FR dimethyl benzyl carbinol FL/FR ethyl phenyl acetate FL/FR floral pyranol FR gardenia oxide FR geraniol FL/FR geranyl acetate FL/FR heliotropyl acetone FL/FR heliotropyl diethyl acetal FR (Z)-3- hexen-1-yl salicylate FL/FR alpha- hexyl cinnamaldehyde FL/FR hyacinth ether FR leerall FR linalool FL/FR laevo- linalool FL/FR linalool oxide FL/FR methyl dihydrojasmonate FL/FR mimosa absolute FL/FR mimosa absolute france FL/FR mimosa absolute india FL/FR muguet carboxaldehyde FR nerol FL/FR nerolidol FL/FR neryl acetate FL/FR ocean propanal FL/FR octahydro-4,7-methano-1H-indene-5-acetaldehyde + 6-methyl-octahydro-4,7-methano-indene-5-carbaldehyd FR orris pyridine 25% IPM FR peony alcohol FR clementine petitgrain oil FL/FR phenethyl acetate FL/FR phenethyl alcohol FL/FR phenethyl isobutyrate FL/FR phenethyl propionate FL/FR rhodinol FL/FR rose butanoate FL/FR rose concrete (rosa centifolia) FR violet methyl carbonate FR fruity artemisia pallens herb oil FL/FR balsam specialty FR benzyl propionate FL/FR (E)-alpha- damascone FL/FR (E)-beta- damascone FL/FR dimethyl benzyl carbinyl isobutyrate FR green acetate FR methyl anthranilate FL/FR strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR green iso cyclocitral (IFF) FL/FR green carbaldehyde FR (Z)-3- hexen-1-ol FL/FR (Z)-3- hexen-1-yl acetate FL/FR (Z)-3- hexen-1-yl tiglate FL/FR 2,4- ivy carbaldehyde FL/FR 3,5- ivy carbaldehyde FL/FR ivy carbaldehyde FL/FR 2,4- ivy carbaldehyde / methyl anthranilate schiff's base FR melon nonenoate FL/FR octanal diethyl acetal FL/FR (E)-2- octen-1-yl acetate FL/FR olive oil absolute FL/FR 3- phenyl propionaldehyde FL/FR styralyl acetate FL/FR violet leaf absolute FL/FR herbal acorus calamus rhizome oil FR sweet basil absolute FL/FR calamintha clinopodium oil FR (+)-alpha- campholenic aldehyde FL/FR canarium luzonicum oil FL/FR carum carvi fruit oil FL/FR clary sage oil france FL/FR daucus carota fruit oil FL/FR dill seed oil FL/FR dill seed oil CO2 extract FL/FR linalyl acetate FL/FR nonisyl acetate FR curled parsley seed oil FL/FR petroselinum crispum seed oil CO2 extract FL/FR romanal FR common tansy flower oil FR common tansy flower oil dutch FR alpha- terpinyl acetate FL/FR melon watermelon ketone FR mossy moss specialty FR oakmoss absolute FL/FR veramoss (IFF) FR musk musk indanone FR oily mcp acetate FR orris eugenyl formate FL/FR para-iso propyl acetophenone FL/FR peppery asarum europaeum oil FR phenolic 4- methyl-2,6-dimethoxyphenol FL/FR powdery para- anisyl alcohol FL/FR midnight passion fragrance FR saffron saffron stigmates absolute FR spicy allspice berry absolute FL/FR angelica seed absolute FL/FR anona squamosa leaf oil FR artemisia dracunculus herb oil FL/FR ayou wood oil FR caryophyllene FL/FR beta- caryophyllene FL/FR alpha- caryophyllene alcohol FL/FR cascarilla oil replacer FL/FR cassia bark oil china FL/FR cassia leaf oil FL/FR cinnamon bark oil FL/FR cinnamon bark oil (cinnamomum zeylanicum) india FL/FR cinnamon bark oil ceylon FL/FR cinnamon leaf oil ceylon FL/FR cinnamon oleoresin ceylon FL/FR clove bud absolute FL/FR clove bud oil FL/FR clove bud oil CO2 extract FL/FR black currant bud absolute FL/FR eugenyl acetate FL/FR iso eugenyl acetate FL/FR galangal root oil FL/FR ginger oleoresin africa FL/FR ginger root oil brazil FL/FR grains of paradise oil FL/FR green oxane FR mace absolute FL/FR mace oil FL/FR machilus kusanoi leaf oil FR machilus kusanoi wood oil FR maja fragrance FR myristica fragrans fruit extract FL/FR myristica fragrans seed tincture FL/FR nutmeg oil FL/FR black pepper absolute FL/FR pepper hexanone FR black pepper oil CO2 extract FL/FR pepper tree berry absolute FL/FR pepper tree berry oil FL/FR piper longum fruit oil FL/FR piper longum fruit oil CO2 extract FL/FR spicy carbonate FR sugandha kokila berry oil FR (E)- tiglic acid FL/FR turmeric root absolute FL/FR zingiber officinale root extract FL/FR zingiber officinale root tincture FL/FR terpenic angelica seed oil FL/FR para- cymene FL/FR frankincense oil FL/FR juniper branch oil FR pine needle oil dwarf FL/FR alpha- terpineol FL/FR thujonic common tansy oil canada FR tonka tonka bean absolute FR vanilla ethyl vanillin FL/FR vanilla cresol FR waxy decanal diethyl acetal FL/FR 1- dodecanol FL/FR ethyl laurate FL/FR woody acetyl cedrene FR amber carbinol FR amber dioxane FR amber formate FR amber pentadecane FR caryophyllene alcohol acetate FR caryophyllene formate FL/FR beta- caryophyllene oxide FL/FR cedarwood oil texas fractions FR alpha- cedrene epoxide FR cedryl formate FR curcuma zedoaria bark extract FL/FR dacrydium franklinii wood oil FR dragons blood fragrance FR frankincense resinoid replacer FR georgywood FR guaiacwood oil FL/FR guaiacwood oil 20% in gurjun balsam oil FR guaiacyl acetate FL/FR hedychium spicatum root oil FR hydroxyambran FR jatamansi root oil FR juniper berry oleoresin FL/FR 2- methoxy-4-vinyl phenol FL/FR methyl cedryl ketone FL/FR methyl methylene tricyclodecanol FR (4aR,5R,7aS,9R)- octahydro-2,2,5,8,8,9a-hexamethyl-4h-4a,9-methanoazuleno(5,6-d)-1,3-dioxole FR patchouli absolute FR patchouli ethanone FR patchouli woody amber fragrance FR 4-iso propyl phenol FL/FR rhubarb oxirane FR sabinene FL/FR santal penten-2-ol FR santall FR spikenard oil FL/FR spikenard oil CO2 extract FL/FR tetramethyl-4-methylene-2-heptanol FR tobacarol (IFF) FR vetiver oil haiti FL/FR vetiver specialty FR woody acetate FR (Z)- woody amylene FR woody dioxolane FR woody nonane (ethoxy) FR woody propanol FR zedoary bark oil FL/FR zedoary root oil FL/FR zedoary root oil CO2 extract FL/FR For Flavor No flavor group found for these alpha- caryophyllene alcohol FL/FR caryophyllene formate FL/FR cistus ladaniferus resinoid FL/FR croton glabellus bark extract FL/FR eugenyl formate FL/FR grains of paradise oil FL/FR guaiyl acetate FL/FR ivy carbaldehyde FL/FR 3,5- ivy carbaldehyde FL/FR methyl (E)-cinnamate FL/FR spikenard oil FL/FR spikenard oil CO2 extract FL/FR tetrahydrocitral FL/FR amber amber angelica seed oil FL/FR labdanum absolute FL/FR animal para- cresyl caprylate FL/FR indole FL/FR balsamic benzyl salicylate FL/FR laevo- bornyl acetate FL/FR iso butyl cinnamate FL/FR opoponax absolute (balsamodendron kafal) FL/FR opoponax resin (commiphora erythraea var. glabrescens engler) FL/FR styrax resin (liquidambar styraciflua) FL/FR styrax resinoid (liquidambar styraciflua) FL/FR berry heliotropyl acetone FL/FR raspberry ketone methyl ether FL/FR brown (E)- tiglic acid FL/FR burnt 4-iso propyl phenol FL/FR citrus bergamot oil bergaptene reduced italy FL/FR citral FL/FR laevo- linalool FL/FR linalool FL/FR nerol FL/FR clementine petitgrain oil FL/FR alpha- terpineol FL/FR cooling iso butyl salicylate FL/FR creamy para- anisaldehyde FL/FR gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR floral bois de rose oil brazil FL/FR citronellol FL/FR citronellyl acetate FL/FR dihydrojasmone FL/FR geraniol FL/FR linalyl acetate FL/FR methyl dihydrojasmonate FL/FR neryl acetate FL/FR ocean propanal FL/FR phenethyl alcohol FL/FR phenethyl propionate FL/FR rhodinol FL/FR fruity iso amyl benzoate FL/FR para- anisyl alcohol FL/FR artemisia pallens herb oil FL/FR benzyl acetate FL/FR benzyl alcohol FL/FR benzyl isobutyrate FL/FR benzyl propionate FL/FR (E)-alpha- damascone FL/FR (E)-beta- damascone FL/FR dimethyl anthranilate FL/FR methyl anthranilate FL/FR piper longum fruit oil CO2 extract FL/FR rose butanoate FL/FR strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR styralyl acetate FL/FR green iso amyl salicylate FL/FR angelica root oil FL/FR (+)-alpha- campholenic aldehyde FL/FR canarium luzonicum oil FL/FR cinnamyl alcohol FL/FR cyclamen aldehyde FL/FR iso cyclocitral (IFF) FL/FR cyclohexyl ethyl alcohol FL/FR (E,Z)-2,6- dodecadienal FL/FR geranyl acetate FL/FR (Z)-3- hexen-1-ol FL/FR (Z)-3- hexen-1-yl acetate FL/FR (Z)-3- hexen-1-yl salicylate FL/FR (Z)-3- hexen-1-yl tiglate FL/FR 2,4- ivy carbaldehyde FL/FR linalool oxide FL/FR melon nonenoate FL/FR nerolidol FL/FR oakmoss absolute FL/FR octanal diethyl acetal FL/FR (E)-2- octen-1-yl acetate FL/FR 3- phenyl propionaldehyde FL/FR violet leaf absolute FL/FR herbal sweet basil absolute FL/FR carum carvi fruit oil FL/FR clary sage oil france FL/FR coriander seed oil FL/FR daucus carota fruit oil FL/FR dill seed oil FL/FR dill seed oil CO2 extract FL/FR curled parsley seed oil FL/FR petroselinum crispum seed oil CO2 extract FL/FR honey ethyl phenyl acetate FL/FR phenethyl acetate FL/FR phenethyl isobutyrate FL/FR medicinal dimethyl benzyl carbinol FL/FR oily olive oil absolute FL/FR phenolic 4- methyl-2,6-dimethoxyphenol FL/FR pine pine needle oil dwarf FL/FR smoky 2- methoxy-4-vinyl phenol FL/FR soapy dodecanal (aldehyde C-12 lauric) FL/FR 1- dodecanol FL/FR spicy allspice berry absolute FL/FR angelica seed absolute FL/FR artemisia dracunculus herb oil FL/FR benzyl cinnamate FL/FR beta- caryophyllene FL/FR caryophyllene FL/FR cascarilla oil replacer FL/FR cassia bark oil china FL/FR cassia leaf oil FL/FR cinnamon bark oil FL/FR cinnamon bark oil (cinnamomum zeylanicum) india FL/FR cinnamon bark oil ceylon FL/FR cinnamon leaf oil ceylon FL/FR cinnamon oleoresin ceylon FL/FR clove bud absolute FL/FR clove bud oil FL/FR clove bud oil CO2 extract FL/FR black currant bud absolute FL/FR iso eugenyl acetate FL/FR eugenyl acetate FL/FR galangal root oil FL/FR ginger oleoresin africa FL/FR ginger root oil brazil FL/FR mace absolute FL/FR mace oil FL/FR myristica fragrans fruit extract FL/FR myristica fragrans seed tincture FL/FR nutmeg oil FL/FR black pepper absolute FL/FR black pepper oil CO2 extract FL/FR pepper tree berry absolute FL/FR pepper tree berry oil FL/FR 3- phenyl propyl alcohol FL/FR piper longum fruit oil FL/FR para-iso propyl acetophenone FL/FR turmeric root absolute FL/FR zingiber officinale root extract FL/FR zingiber officinale root tincture FL/FR terpenic para- cymene FL/FR tropical alpha- amyl cinnamaldehyde FL/FR vanilla ethyl vanillin FL/FR waxy decanal diethyl acetal FL/FR 9- decen-1-ol FL/FR ethyl laurate FL/FR alpha- hexyl cinnamaldehyde FL/FR mimosa absolute FL/FR mimosa absolute france FL/FR mimosa absolute india FL/FR woody (Z)- abienol FL/FR ambroxan FL/FR amyris wood oil FL/FR beta- caryophyllene oxide FL/FR curcuma zedoaria bark extract FL/FR frankincense oil FL/FR guaiacwood oil FL/FR guaiacyl acetate FL/FR juniper berry oleoresin FL/FR methyl cedryl ketone FL/FR sabinene FL/FR sclareol FL/FR alpha- terpinyl acetate FL/FR vetiver oil haiti FL/FR zedoary bark oil FL/FR zedoary root oil FL/FR zedoary root oil CO2 extract FL/FR   Potential Uses: FR aldehydic FR amber FR green FR spice FR woody   Occurrence (nature, food, other):note   not found in nature   Synonyms:   amber carane 2,3,3,7,7- pentamethyl spiro(1,3-dioxane)-5,2-norcarane (1,3,6)-2',2',3,7,7- pentamethyl spiro(bicyclo(4.1.0)heptane-2,5'-(1,3)dioxane) (1alpha,3alpha, 6alpha)-2',2',3,7,7- pentamethyl spiro(bicyclo(4.1.0)heptane-2,5'-(1,3)dioxane)   pentamethyl spirobicycloheptane dioxane (1alpha,3alpha,6alpha)-2',2',3,7,7- pentamethylspiro(bicyclo(4.1.0)heptane-2,5'-(1,3)dioxane) (1'S,4'R,6'R)-2,2,4',7',7'- pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane] (1'S,4'S,6'R)-2,2,4',7',7'- pentamethylspiro[1,3-dioxane-5,5'-bicyclo[4.1.0]heptane]   spirambrene (Givaudan)   spiro(bicyclo(4.1.0)heptane-2,5'-(1,3)dioxane), 2',2',3,7,7-pentamethyl-, (1alpha,3alpha,6alpha)-   spiro(bicyclo(4.1.0)heptane-2,5'-(1,3)dioxane), 2',2',3,7,7-pentamethyl-, (1R,3S,6S)-rel-   Articles:   None found yet. Try the PubMed Search.

Notes: None found