Category: flavor and fragrance agents
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JECFA Food Flavoring: | 1900 mixture of 2,4-, 3,5- and 3,6-dimethyl-3-cyclohexenylcarbaldehyde |
FEMA Number: | 4505 mixture of 2,4-, 3,5- and 3,6-dimethyl-3-cyclohexenylcarbaldehyde |
FDA: | No longer provide for the use of these seven synthetic flavoring substances |
FDA Mainterm (SATF): | 27939-60-2 ; (2,4)- AND (3,5)- AND (3,6)-DIMETHYL-3-CYCLOHEXENYLCARBALDEHYDE |
Physical Properties:
Appearance: | colorless to pale yellow clear liquid (est) |
Assay: | 95.00 to 100.00 sum of isomers
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 0.92800 to 0.93500 @ 25.00 °C.
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Pounds per Gallon - (est).: | 7.722 to 7.780
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Refractive Index: | 1.46700 to 1.47000 @ 20.00 °C.
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Boiling Point: | 176.00 to 179.00 °C. @ 760.00 mm Hg
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Boiling Point: | 99.00 to 101.00 °C. @ 30.00 mm Hg
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Vapor Pressure: | 0.953000 mmHg @ 25.00 °C. (est) |
Flash Point: | 148.00 °F. TCC ( 64.44 °C. )
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logP (o/w): | 2.621 (est) |
Soluble in: |
| alcohol | | water, 311.5 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Organoleptic Properties:
Odor Type: green |
Odor Strength:medium , recommend smelling in a 10.00 % solution or less |
Substantivity: < 3 hour(s) at 100.00 % |
green aldehydic weedy herbal cortex privet soapy |
Odor Description:at 10.00 % in dipropylene glycol. green aldehydic weedy herbal cortex privet soapy Luebke, William tgsc, (2009) |
Odor sample from: International Flavors & Fragrances Inc. |
Flavor Type: green |
green weedy aldehydic herbal privet cortex grassy alfalfa |
Taste Description: green weedy aldehydic herbal privet cortex grassy alfalfa Luebke, William tgsc, (2009) |
Odor and/or flavor descriptions from others (if found). |
Pell Wall Perfumes |
Triplal Extra |
Odor Description:green-herbal, citrus-aldehydic, soapy Widely used, versatile green note, particularly good in combination with citrus. Near-identical odour to conventional Triplal but some perfumers would argue it is finer. |
Cosmetic Information:
Suppliers:
Safety Information:
Preferred SDS: View |
European information : |
Most important hazard(s): | Xn - Harmful. |
R 22 - Harmful if swallowed. R 36/38 - Irritating to skin and eyes. S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 - Wear suitable gloves and eye/face protection.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
oral-rat LD50 3100 mg/kg Widely used, versatile green note, particularly good in combination with citrus. Near-identical odour to conventional Triplal but some perfumers would argue it is finer.
oral-rat LD50 3600 mg/kg Food and Chemical Toxicology. Vol. 30, Pg. 29S, 1992.
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Dermal Toxicity: |
skin-rabbit LD50 5000 mg/kg Food and Chemical Toxicology. Vol. 30, Pg. 29S, 1992.
skin-rabbit LD50 5000 mg/kg Food and Chemical Toxicology. Vol. 30, Pg. 29S, 1992.
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
IFRA Critical Effect: | Dermal sensitization |
| View the IFRA Standard |
View IFRA Standards Library for complete information. |
Please review Amendment 49 IFRA documentation for complete information. |
IFRA RESTRICTION LIMITS IN THE FINISHED PRODUCT (%): |
Category 1: Products applied to the lips |
0.45 % |
Category 2: Products applied to the axillae |
0.14 % |
Category 3: Products applied to the face/body using fingertips |
2.70 % |
Category 4: Products related to fine fragrance |
2.50 % |
| Category 5: Products applied to the face and body using the hands (palms), primarily leave-on |
Category 5A: Body lotion products applied to the body using the hands (palms), primarily leave-on |
0.64 % |
Category 5B: Face moisturizer products applied to the face using the hands (palms), primarily leave-on |
0.64 % |
Category 5C: Hand cream products applied to the hands using the hands (palms), primarily leave-on |
0.64 % |
Category 5D: Baby Creams, baby Oils and baby talc |
0.64 % |
Category 6: Products with oral and lip exposure |
1.50 % |
| Category 7: Products applied to the hair with some hand contact |
Category 7A: Rinse-off products applied to the hair with some hand contact |
5.20 % |
Category 7B: Leave-on products applied to the hair with some hand contact |
5.20 % |
Category 8: Products with significant anogenital exposure |
0.27 % |
Category 9: Products with body and hand exposure, primarily rinse off |
4.90 % |
| Category 10: Household care products with mostly hand contact |
Category 10A: Household care excluding aerosol products (excluding aerosol/spray products) |
18.00 % |
Category 10B: Household aerosol/spray products |
18.00 % |
| Category 11: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate |
Category 11A: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure |
9.80 % |
Category 11B: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure |
9.80 % |
Category 12: Products not intended for direct skin contact, minimal or insignificant transfer to skin |
No Restriction |
| Notes: |
IFRA FLAVOR REQUIREMENTS: |
Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards. |
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Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
publication number: 24 |
Click here to view publication 24 |
| average usual ppm | average maximum ppm |
baked goods: | 0.20000 | 4.00000 |
beverages(nonalcoholic): | 0.50000 | 5.00000 |
beverages(alcoholic): | - | - |
breakfast cereal: | - | - |
cheese: | - | - |
chewing gum: | 5.00000 | 50.00000 |
condiments / relishes: | - | - |
confectionery froastings: | - | - |
egg products: | - | - |
fats / oils: | 0.50000 | 4.00000 |
fish products: | - | - |
frozen dairy: | 0.50000 | 10.00000 |
fruit ices: | 0.50000 | 10.00000 |
gelatins / puddings: | - | - |
granulated sugar: | - | - |
gravies: | - | - |
hard candy: | 0.20000 | 5.00000 |
imitation dairy: | - | - |
instant coffee / tea: | - | - |
jams / jellies: | - | - |
meat products: | - | - |
milk products: | - | - |
nut products: | - | - |
other grains: | - | - |
poultry: | - | - |
processed fruits: | - | - |
processed vegetables: | - | - |
reconstituted vegetables: | - | - |
seasonings / flavors: | - | - |
snack foods: | - | - |
soft candy: | - | - |
soups: | - | - |
sugar substitutes: | - | - |
sweet sauces: | - | - |
Safety References:
References:
Other Information:
Potential Blenders and core components note
For Odor |
aldehydic |
adoxal (Givaudan) FL/FR |
citrus carbaldehyde FR |
decanal (aldehyde C-10) FL/FR |
6,7,8- decen-1-ol FR |
9- decenal FL/FR |
fresh carbaldehyde FR |
2- methyl undecanal (aldehyde C-12 mna) FL/FR |
nonanal (aldehyde C-9) FL/FR |
octanal (aldehyde C-8) FL/FR |
10- undecenal (aldehyde C-11 undecylenic) FL/FR |
amber |
amber carane FR |
angelica root oil FL/FR |
balsamic |
2- acetyl furan FL/FR |
iso amyl benzoate FL/FR |
benzyl benzoate FL/FR |
benzyl salicylate FL/FR |
laevo- bornyl acetate FL/FR |
iso bornyl acetate FL/FR |
cinnamyl alcohol FL/FR |
clover nitrile FR |
ethyl cinnamate FL/FR |
fir needle oil siberia FL/FR |
citrus |
bergamot oil bergaptene reduced italy FL/FR |
citral FL/FR |
citrus specialty FR |
grapefruit oil c.p. california FL/FR |
grapefruit pentanol FR |
lemon oil c.p. california FL/FR |
lemongrass oil FL/FR |
lime oil distilled mexico FL/FR |
lime pyran FR |
limonene aldehyde FR |
litsea cubeba fruit oil FL/FR |
methyl heptenone FL/FR |
blood orange oil italy FL/FR |
sweet orange peel oil c.p. brazil FL/FR |
tetrahydrocitral FL/FR |
tetrahydromyrcenol FR |
earthy |
methyl undecylenate FL/FR |
fatty |
(E,Z)-2,6- dodecadienal FL/FR |
floral |
alpha- amyl cinnamaldehyde diethyl acetal FR |
iso amyl salicylate FL/FR |
benzyl acetate FL/FR |
benzyl alcohol FL/FR |
benzyl isobutyrate FL/FR |
bois de rose oil brazil FL/FR |
iso butyl salicylate FL/FR |
citronellyl acetate FL/FR |
coriander seed oil FL/FR |
cyclamen aldehyde FL/FR |
cyclamen propanal FR |
cyclohexyl ethyl alcohol FL/FR |
dimethyl benzyl carbinol FL/FR |
floral pyranol FR |
gardenia oxide FR |
geraniol FL/FR |
geranium oil africa FL/FR |
geranyl acetate FL/FR |
heliotropyl diethyl acetal FR |
(Z)-3- hexen-1-yl salicylate FL/FR |
alpha- hexyl cinnamaldehyde FL/FR |
ho leaf oil FR |
hyacinth ether FR |
leerall FR |
lily of the valley fragrance FR |
lily of the valley specialty FR |
linalool FL/FR |
laevo- linalool FL/FR |
linalool oxide FL/FR |
methyl dihydrojasmonate FL/FR |
mimosa absolute france FL/FR |
muguet carboxaldehyde FR |
muguet octadienol FR |
nerol FL/FR |
nerolidol FL/FR |
neryl acetate FL/FR |
ocean propanal FL/FR |
octahydro-4,7-methano-1H-indene-5-acetaldehyde + 6-methyl-octahydro-4,7-methano-indene-5-carbaldehyd FR |
orris pyridine 25% IPM FR |
peony alcohol FR |
clementine petitgrain oil FL/FR |
petitgrain oil paraguay FL/FR |
phenethyl acetate FL/FR |
phenethyl alcohol FL/FR |
propyl anthranilate FL/FR |
rhodinol FL/FR |
rose butanoate FL/FR |
tetrahydrolinalool FL/FR |
violet methyl carbonate FR |
fruity |
allyl amyl glycolate FR |
allyl cyclohexyl propionate FL/FR |
allyl hexanoate FL/FR |
bitter almond oil FL/FR |
iso amyl acetate FL/FR |
benzaldehyde FL/FR |
benzyl propionate FL/FR |
diethyl malonate FL/FR |
green acetate FR |
hexyl acetate FL/FR |
methyl 2-methyl valerate FL/FR |
strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR |
gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR |
green |
acetaldehyde dipropyl acetal FL/FR |
acetaldehyde ethyl phenethyl acetal FL/FR |
acetaldehyde methyl hexyl acetal FR |
iso cyclocitral (IFF) FL/FR |
fern fragrance FR |
galbanum oil FL/FR |
green carbaldehyde FR |
(Z)-3- hexen-1-ol FL/FR |
(Z)-3- hexen-1-yl acetate FL/FR |
(Z)-3- hexen-1-yl benzoate FL/FR |
(Z)-3- hexen-1-yl formate FL/FR |
(Z)-3- hexen-1-yl tiglate FL/FR |
hexyl 2-methyl butyrate FL/FR |
hexyl tiglate FL/FR |
2,4- ivy carbaldehyde FL/FR |
3,6- ivy carbaldehyde FL/FR |
3,5- ivy carbaldehyde FL/FR |
ivy carbaldehyde / methyl anthranilate schiff's base FR |
2,4- ivy carbaldehyde / methyl anthranilate schiff's base FR |
english ivy leaf absolute FR |
(Z)- leaf acetal FL/FR |
melon nonenoate FL/FR |
nerol oxide FL/FR |
(E,Z)-2,6- nonadien-1-ol FL/FR |
(E,Z)-2,6- nonadienal FL/FR |
(E)-2- octen-1-yl acetate FL/FR |
olive oil absolute FL/FR |
phenyl acetaldehyde FL/FR |
3- phenyl propionaldehyde FL/FR |
styralyl acetate FL/FR |
violet leaf absolute FL/FR |
herbal |
anthemis nobilis flower oil roman FL/FR |
clary acetate FR |
clary sage oil france FL/FR |
daucus carota fruit oil FL/FR |
dihexyl (E)-fumarate FR |
eucalyptus globulus oil FL/FR |
herbal undecanone FR |
lavender absolute bulgaria FL/FR |
linalyl acetate FL/FR |
nopyl acetate FR |
2- pentyl acetate FL/FR |
alpha- terpinyl acetate FL/FR |
marine |
marine pyridine FR |
melon |
melon heptenal FL/FR |
watermelon ketone FR |
phenolic |
methyl benzoate FL/FR |
powdery |
para- anisyl acetate FL/FR |
spicy |
iso butyl angelate FL/FR |
terpenic |
frankincense oil FL/FR |
juniperus communis fruit oil FL/FR |
alpha- terpineol FL/FR |
waxy |
decanal diethyl acetal FL/FR |
ethyl laurate FL/FR |
woody |
amber carbinol FR |
patchouli ethanone FR |
spruce needle oil canada FL/FR |
thuja occidentalis leaf oil FL/FR |
vetiver oil haiti FL/FR |
woody acetate FR |
(Z)- woody amylene FR |
woody propanol FR |
For Flavor |
No flavor group found for these |
9- decenal FL/FR |
epoxy-2-decenal FL |
3,5- ivy carbaldehyde FL/FR |
propyl anthranilate FL/FR |
tetrahydrocitral FL/FR |
aldehydic |
aldehydic |
nonanal (aldehyde C-9) FL/FR |
octanal (aldehyde C-8) FL/FR |
apple |
(E,Z)-2,6- nonadien-1-ol FL/FR |
balsamic |
benzyl benzoate FL/FR |
benzyl salicylate FL/FR |
laevo- bornyl acetate FL/FR |
ethyl cinnamate FL/FR |
fir needle oil siberia FL/FR |
citrus |
bergamot oil bergaptene reduced italy FL/FR |
citral FL/FR |
grapefruit oil c.p. california FL/FR |
lemon oil c.p. california FL/FR |
lemongrass oil FL/FR |
lime oil distilled mexico FL/FR |
linalool FL/FR |
laevo- linalool FL/FR |
litsea cubeba fruit oil FL/FR |
nerol FL/FR |
blood orange oil italy FL/FR |
sweet orange peel oil c.p. brazil FL/FR |
clementine petitgrain oil FL/FR |
alpha- terpineol FL/FR |
cooling |
iso butyl salicylate FL/FR |
creamy |
gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR |
dairy |
2- pentyl acetate FL/FR |
fatty |
(Z)-3- hexen-1-yl benzoate FL/FR |
10- undecenal (aldehyde C-11 undecylenic) FL/FR |
floral |
bois de rose oil brazil FL/FR |
citronellyl acetate FL/FR |
geraniol FL/FR |
geranium oil africa FL/FR |
linalyl acetate FL/FR |
methyl dihydrojasmonate FL/FR |
neryl acetate FL/FR |
ocean propanal FL/FR |
phenethyl alcohol FL/FR |
rhodinol FL/FR |
tetrahydrolinalool FL/FR |
fruity |
allyl cyclohexyl propionate FL/FR |
allyl hexanoate FL/FR |
bitter almond oil FL/FR |
iso amyl acetate FL/FR |
iso amyl benzoate FL/FR |
para- anisyl acetate FL/FR |
benzaldehyde FL/FR |
benzyl acetate FL/FR |
benzyl alcohol FL/FR |
benzyl isobutyrate FL/FR |
benzyl propionate FL/FR |
diethyl malonate FL/FR |
hexyl acetate FL/FR |
methyl 2-methyl valerate FL/FR |
rose butanoate FL/FR |
strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR |
styralyl acetate FL/FR |
green |
acetaldehyde dipropyl acetal FL/FR |
acetaldehyde ethyl phenethyl acetal FL/FR |
iso amyl salicylate FL/FR |
angelica root oil FL/FR |
iso butyl angelate FL/FR |
cinnamyl alcohol FL/FR |
cyclamen aldehyde FL/FR |
iso cyclocitral (IFF) FL/FR |
cyclohexyl ethyl alcohol FL/FR |
(E,Z)-2,6- dodecadienal FL/FR |
galbanum oil FL/FR |
geranyl acetate FL/FR |
2,4- hexadienal FL |
(Z)-3- hexen-1-ol FL/FR |
(Z)-3- hexen-1-yl acetate FL/FR |
(Z)-3- hexen-1-yl formate FL/FR |
(Z)-3- hexen-1-yl salicylate FL/FR |
(Z)-3- hexen-1-yl tiglate FL/FR |
hexyl 2-methyl butyrate FL/FR |
hexyl tiglate FL/FR |
2,4- ivy carbaldehyde FL/FR |
3,6- ivy carbaldehyde FL/FR |
(Z)- leaf acetal FL/FR |
linalool oxide FL/FR |
melon heptenal FL/FR |
melon nonenoate FL/FR |
methyl heptenone FL/FR |
nerol oxide FL/FR |
nerolidol FL/FR |
(E,Z)-2,6- nonadienal FL/FR |
(E)-2- octen-1-yl acetate FL/FR |
3- phenyl propionaldehyde FL/FR |
violet leaf absolute FL/FR |
herbal |
anthemis nobilis flower oil roman FL/FR |
celery seed oleoresin FL |
clary sage oil france FL/FR |
coriander seed oil FL/FR |
daucus carota fruit oil FL/FR |
eucalyptus globulus oil FL/FR |
lavender absolute bulgaria FL/FR |
petitgrain oil paraguay FL/FR |
honey |
phenethyl acetate FL/FR |
phenyl acetaldehyde FL/FR |
medicinal |
dimethyl benzyl carbinol FL/FR |
nutty |
2- acetyl furan FL/FR |
oily |
olive oil absolute FL/FR |
phenolic |
methyl benzoate FL/FR |
pungent |
acetaldehyde FL |
terpenic |
juniperus communis fruit oil FL/FR |
waxy |
adoxal (Givaudan) FL/FR |
decanal (aldehyde C-10) FL/FR |
decanal diethyl acetal FL/FR |
ethyl laurate FL/FR |
alpha- hexyl cinnamaldehyde FL/FR |
2- methyl undecanal (aldehyde C-12 mna) FL/FR |
methyl undecylenate FL/FR |
mimosa absolute france FL/FR |
woody |
iso bornyl acetate FL/FR |
frankincense oil FL/FR |
spruce needle oil canada FL/FR |
alpha- terpinyl acetate FL/FR |
thuja occidentalis leaf oil FL/FR |
vetiver oil haiti FL/FR |
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
3- | cyclohexene-1-carboxaldehyde, 1,2-dimethyl- | 3- | cyclohexene-1-carboxaldehyde, dimethyl- | 3- | cyclohexene-1-carboxaldehyde,dimethyl- | 1,2- | dimethyl cyclohex-3-ene-1-carbaldehyde | | dimethyl-3-cyclohexene-1-carboxaldehyde | mixture of 2,4-, 3,5- and 3,6- | dimethyl-3-cyclohexenylcarbaldehyde | | dimethylcyclohex-3-ene-1-carbaldehyde | 1,2- | dimethylcyclohex-3-ene-1-carbaldehyde | | ivy carbaldehyde | | triplal extra | | trivertal |
Articles:
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