Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Appearance: | colorless clear liquid (est) |
Assay: | 95.00 to 100.00
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 0.88900 to 0.89400 @ 25.00 °C.
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Pounds per Gallon - (est).: | 7.397 to 7.439
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Refractive Index: | 1.43700 to 1.44200 @ 20.00 °C.
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Boiling Point: | 202.00 to 209.00 °C. @ 760.00 mm Hg
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Vapor Pressure: | 0.206000 mmHg @ 25.00 °C. (est) |
Flash Point: | 176.00 °F. TCC ( 80.00 °C. )
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logP (o/w): | 3.597 (est) |
Soluble in: |
| alcohol | | water, 53.9 mg/L @ 25 °C (est) |
Insoluble in: |
| water |
Similar Items:note |
amyl angelate |
Organoleptic Properties:
Odor Type: floral |
floral fruity chamomile |
Odor Description:at 100.00 %. floral fruity chamomile |
Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
Preferred SDS: View |
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: |
Not determined
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Dermal Toxicity: |
Not determined
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Inhalation Toxicity: |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
RIFM Fragrance Material Safety Assessment: Search |
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
Recommendation for isoamyl angelate usage levels up to: | | 3.0000 % in the fragrance concentrate.
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Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.012 (μg/capita/day) |
Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 3900 (μg/person/day) |
Threshold of Concern: | 1800 (μg/person/day) |
Structure Class: | I |
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Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). |
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. |
| average usage mg/kg | maximum usage mg/kg |
Dairy products, excluding products of category 02.0 (01.0): | 7.00000 | 35.00000 |
Fats and oils, and fat emulsions (type water-in-oil) (02.0): | 5.00000 | 25.00000 |
Edible ices, including sherbet and sorbet (03.0): | 10.00000 | 50.00000 |
Processed fruit (04.1): | 7.00000 | 35.00000 |
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | - | - |
Confectionery (05.0): | 10.00000 | 50.00000 |
Chewing gum (05.3): | - | - |
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 5.00000 | 25.00000 |
Bakery wares (07.0): | 10.00000 | 50.00000 |
Meat and meat products, including poultry and game (08.0): | 2.00000 | 10.00000 |
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | 2.00000 | 10.00000 |
Eggs and egg products (10.0): | - | - |
Sweeteners, including honey (11.0): | - | - |
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 5.00000 | 25.00000 |
Foodstuffs intended for particular nutritional uses (13.0): | 10.00000 | 50.00000 |
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | 5.00000 | 25.00000 |
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 10.00000 | 50.00000 |
Ready-to-eat savouries (15.0): | 20.00000 | 100.00000 |
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | 5.00000 | 25.00000 |
Safety References:
European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
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European Food Safety Authority (EFSA) reference(s):
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Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) on a request from the Commission related to Flavouring Group Evaluation 5: Esters of 23 branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and 24 branched- and straight-chain unsaturated carboxylic acids from chemical groups 1, 2, and 5 View page or View pdf
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Flavouring Group Evaluation 5, Revision 1 (FGE.05Rev1):Esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids from chemical groups 1, 2, and 5 (Commission Regulation (EC) No 1565/2000 of 18 July 2000) [1] - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) View page or View pdf
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Flavouring Group Evaluation 62 (FGE.62) Consideration of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05 (2005) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06 (2004) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) View page or View pdf
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Scientific Opinion on Flavouring Group Evaluation 71: Consideration of aliphatic, linear, alpha,beta-unsaturated carboxylic acids and related esters View page or View pdf
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Flavouring Group Evaluation 72 (FGE.72): Consideration of aliphatic, branched-chain saturated and unsaturated alcohols, aldehydes, acids, and related esters evaluated by the JECFA (61st meeting) structurally related to branched- and straight-chain unsaturated carboxylic acids. Esters of these and straight-chain aliphatic saturated alcohols evaluated by EFSA in FGE.05Rev2 (2010) View page or View pdf
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Flavouring Group Evaluation 5, Revision 2 (FGE.05Rev2): Branched- and straight-chain unsaturated carboxylic acids and esters of these with aliphatic saturated alcohols from chemical groups 1, 2, 3 and 5 View page or View pdf
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Scientific Opinion on Flavouring Group Evaluation 95 (FGE.95): Consideration of aliphatic, linear or branched-chain saturated and unsaturated alcohols, aldehydes, acids and related esters evaluated by JECFA (69th meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05Rev1 (2008) View page or View pdf
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Scientific Opinion on Flavouring Group Evaluation 5, Revision 3 (FGE.05Rev3): Branched- and straight-chain unsaturated aldehydes, dienals, unsaturated and saturated carboxylic acids and related esters with saturated and unsaturated aliphatic alcohols and a phenylacetic acid related ester from chemical groups 1, 2, 3, 5 and 15 View page or View pdf
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EPI System: View |
AIDS Citations:Search |
Cancer Citations:Search |
Toxicology Citations:Search |
EPA Substance Registry Services (TSCA):10482-55-0 |
EPA ACToR:Toxicology Data |
EPA Substance Registry Services (SRS):Registry |
Laboratory Chemical Safety Summary :5366155 |
National Institute of Allergy and Infectious Diseases:Data |
WISER:UN 3272 |
3-methylbutyl (Z)-2-methylbut-2-enoate |
Chemidplus:0010482550 |
References:
Other Information:
Potential Blenders and core components note
For Odor |
No odor group found for these |
(E+Z)-4,8- dimethyl-3,7-nonadien-2-one FL/FR |
aldehydic |
aldehydic |
3- methyl-4-hexyl oxybutyraldehyde FR |
anisic |
amyl furoate FL/FR |
balsamic |
benzyl cinnamate FL/FR |
cinnamyl formate FL/FR |
citrus |
(R)- citronellyl nitrile FR |
citronitrile (Symrise) FR |
2- heptanol FL/FR |
ethereal |
ethyl 4-pentenoate FL/FR |
fatty |
butyl undecylenate FL/FR |
4- ethyl octanoic acid FL/FR |
fermented |
methyl decanoate FL/FR |
floral |
acetal 318 FR |
alpha- amyl cinnamaldehyde FL/FR |
benzyl acetate FL/FR |
benzyl acetoacetate FL/FR |
benzyl formate FL/FR |
benzyl isobutyrate FL/FR |
benzyl pivalate FL/FR |
blue lagoon fragrance FR |
cassis cyclohexene FR |
(S)- citronellyl acetate FL/FR |
citronellyl butyrate FL/FR |
citronellyl hexanoate FL/FR |
citronellyl isovalerate FL/FR |
citronellyl propionate FL/FR |
(E)- citronellyl tiglate FL/FR |
3- cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester FR |
cymbopogon validus leaf oil FR |
dihydrojasmone FL/FR |
dimethyl benzyl carbinyl acetate FL/FR |
dimethyl benzyl carbinyl butyrate FL/FR |
3,6- dimethyl-3-octyl acetate FR |
ethyl anthranilate FL/FR |
ethyl ethyl anthranilate FL/FR |
eucalyptus macarthurii oil FR |
geraniol FL/FR |
geranyl isobutyrate FL/FR |
hibiscus fragrance FR |
ionone mixed isomers FL/FR |
jasmin absolute egypt (from concrete) FL/FR |
jasmin cyclopentanone FR |
iso jasmone FL/FR |
linalyl butyrate FL/FR |
magnolia flower oil CO2 extract FL/FR |
magnolia specialty FR |
menthadienyl formate FR |
ortho- methoxybenzyl ethyl ether FR |
methoxymelonal FL/FR |
1-(2- methyl allyl oxy)-3-methoxy-3-methyl-1-butane FR |
para- methyl benzyl acetate FL/FR |
methyl benzyl acetate (mixed ortho-,meta-,para-) FL/FR |
alpha-iso methyl ionone (90% min.) FL/FR |
methyl ionyl acetate FL/FR |
pink nelumbo nucifera flower absolute FR |
white nelumbo nucifera flower absolute FR |
white nelumbo nucifera flower concrete FR |
nonan-3-yl acetate FL/FR |
3- nonanon-1-yl acetate FL/FR |
orris rhizome concrete butter (iris pallida) FL/FR |
osmanthus absolute replacer FR |
osmanthus concrete FL/FR |
petitgrain mandarin oil FL/FR |
phenethyl isobutyrate FL/FR |
phenethyl isovalerate FL/FR |
1- phenyl propyl butyrate FL/FR |
2- phenyl propyl isobutyrate FL/FR |
4- phenyl-3-buten-2-ol FL/FR |
iso propyl benzoate FL/FR |
rhodinyl butyrate FL/FR |
rose undecene FR |
souroubea specialty FR |
star fruit oil cuba FL/FR |
styralyl propionate FL/FR |
terpinyl valerate FL/FR |
tetrahydroionyl acetate FR |
fruity |
allyl benzoate FR |
allyl phenoxyacetate FL/FR |
para- anisyl propionate FL/FR |
apricot essence FL/FR |
balsam specialty FR |
benzaldehyde / methyl anthranilate schiff's base FR |
benzyl propionate FL/FR |
benzyl valerate FL/FR |
berry hexanoate FR |
butyl 2-naphthyl ether FL/FR |
iso butyl anthranilate FL/FR |
iso butyl furyl propionate FL/FR |
citronellyl isobutyrate FL/FR |
beta- damascone FL/FR |
(Z)-beta- damascone FL/FR |
(E)-beta- damascone FL/FR |
(R)-gamma- dodecalactone FL/FR |
eriocephalus punctulatus flower oil FR |
ethyl levulinate FL/FR |
ginsene FR |
heptyl butyrate FL/FR |
heptyl isobutyrate FL/FR |
linalool oxide acetates FL/FR |
3- mercaptohexyl acetate FL/FR |
methyl (Z)-3-hexenoate FL/FR |
methyl bicycloheptenyl methyloxirane carboxylate FR |
2- methyl butyl isovalerate FL/FR |
methyl isobutyrate FL/FR |
(E)-7- methyl-3-octen-2-one FL/FR |
(±)-3- methyl-gamma-decalactone FL/FR |
myrascone FR |
2- nonanone propylene glycol acetal FL/FR |
alpha- ocimene FL/FR |
peach nitrile FR |
plum damascone (high alpha) FR |
rhubarb pyran FR |
sambucus canadensis fruit absolute FL/FR |
strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR |
(R)- styralyl acetate FL/FR |
4-(para- tolyl)-2-butanone FL/FR |
tropical ionone FL/FR |
cis- woody acetate FR |
green |
iso amyl 3-(2-furan) propionate FL/FR |
iso butyl heptanoate FL/FR |
butyl heptanoate FL/FR |
iso butyl methyl ketone FL/FR |
dicyclopentadiene propionate FR |
herbal cyclohexane FR |
(Z)-3- hexen-1-yl isovalerate FL/FR |
hexoxyacetaldehyde dimethyl acetal FR |
hexyl tiglate FL/FR |
1-[(3aS,7aR)-3a,4,7,7a- tetrahydro-1H-inden-6-yl]ethanone FR |
herbal |
iso amyl heptanoate FL/FR |
anthemis nobilis flower extract FL/FR |
anthemis nobilis flower oil england FL/FR |
anthemis nobilis flower oil roman FL/FR |
anthemis nobilis flower water FR |
anthemis nobilis oil FL/FR |
arnica flower absolute FR |
artemisia ludoviciana oil FR |
buchu mercaptan acetate FL/FR |
butyl levulinate FL/FR |
chamomile absolute FL/FR |
chamomile concrete FR |
chamomile distillates FL/FR |
chamomile extract FL/FR |
chamomile fragrance FR |
chamomile isobutyrate FR |
chamomile octenone FR |
chamomile oil morocco FR |
chamomile oil replacer FR |
chamomile propionate FR |
chamomile specialty FR |
chamomile valerate FR |
clary propyl acetate FR |
dimethyl benzyl carbinyl crotonate FL/FR |
geranium cyclohexane FR |
herbal acetal FR |
levisticum officinale root absolute FL/FR |
linalyl formate FL/FR |
matricaria chamomilla flower oil FL/FR |
1-para- menthen-9-yl acetate FL/FR |
methyl cyclogeranate (Firmenich) FR |
myrtle oil FL/FR |
3- octanon-1-ol FL/FR |
ormenis multicaulis flower oil morocco FR |
rue oil FL/FR |
rue oil cuba FL/FR |
tagete oil CO2 extract FL/FR |
tagete oil egypt FL/FR |
tagete oil madagascar FL/FR |
tagete oil turkey FL/FR |
tagete oil zambia FL/FR |
tricyclodecenyl isobutyrate FR |
tricyclodecenyl propionate FR |
medicinal |
ortho- cresyl acetate FL/FR |
orris |
orris capronate FL/FR |
powdery |
alpha- methyl ionone FL/FR |
(E)-alpha- methyl ionone (74-80%) FL/FR |
spicy |
para- anisyl formate FL/FR |
honey extract CS |
levisticum officinale root oil FL/FR |
spicy acetoacetate FL/FR |
tropical |
triflaige A (ZEON) FR |
waxy |
dihydrocitronellyl acetate FL/FR |
(E)- methyl geranate FL/FR |
phytyl acetate FL/FR |
woody |
cistus twig/leaf oil FL/FR |
2- decalinyl acetate FR |
melozol acetate FR |
3- methyl pentyl angelate FR |
patchouli absolute FR |
rhubarb oxirane FR |
For Flavor |
No flavor group found for these |
1- acetyl cyclohexyl acetate FL |
amyl angelate FL |
amyl furoate FL/FR |
para- anisyl propionate FL/FR |
benzyl methyl tiglate FL |
benzyl pivalate FL/FR |
benzyl valerate FL/FR |
butyl 2-naphthyl ether FL/FR |
iso butyl heptanoate FL/FR |
2- butyl thiophene FL |
citronellyl isovalerate FL/FR |
ortho- cresyl acetate FL/FR |
2,4- difurfuryl furan FL |
dihydrocitronellyl acetate FL/FR |
(±)-(cis+trans)-1,2- dihydroperillaldehyde FL |
dimethyl benzyl carbinyl crotonate FL/FR |
S-(2,5- dimethyl-3-furyl) ethane thioate FL |
(E+Z)-4,8- dimethyl-3,7-nonadien-2-one FL/FR |
(R)-gamma- dodecalactone FL/FR |
ethyl 3-hydroxyoctanoate FL |
ethyl 4-pentenoate FL/FR |
ethyl ethyl anthranilate FL/FR |
4- hydroxyphenethyl alcohol FL |
ionone mixed isomers FL/FR |
linalool oxide acetates FL/FR |
magnolia flower oil CO2 extract FL/FR |
methyl benzyl acetate (mixed ortho-,meta-,para-) FL/FR |
(E)- methyl geranate FL/FR |
nonan-3-yl acetate FL/FR |
2- nonanone propylene glycol acetal FL/FR |
alpha- ocimene FL/FR |
3- octanon-1-ol FL/FR |
1- phenyl propyl butyrate FL/FR |
2- phenyl propyl isobutyrate FL/FR |
iso propyl benzoate FL/FR |
(R)- styralyl acetate FL/FR |
vitispirane FL |
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althaea officinalis root tincture FL |
iso amyl 3-(2-furan) propionate FL/FR |
benzyl acetoacetate FL/FR |
iso butyl furyl propionate FL/FR |
berry |
berry |
heptyl isobutyrate FL/FR |
burnt |
ethyl 2-furoate FL |
citrus |
petitgrain mandarin oil FL/FR |
styralyl propionate FL/FR |
creamy |
althaea officinalis root extract FL |
ethereal |
methyl isobutyrate FL/FR |
fatty |
4- ethyl octanoic acid FL/FR |
methyl decanoate FL/FR |
(E)-7- methyl-3-octen-2-one FL/FR |
floral |
(S)- citronellyl acetate FL/FR |
citronellyl hexanoate FL/FR |
citronellyl propionate FL/FR |
dihydrojasmone FL/FR |
dimethyl benzyl carbinyl acetate FL/FR |
dimethyl benzyl carbinyl butyrate FL/FR |
geraniol FL/FR |
geranyl isobutyrate FL/FR |
jasmin absolute egypt (from concrete) FL/FR |
linalyl butyrate FL/FR |
2- methyl butyl 3-methyl butenoate FL |
(E)-alpha- methyl ionone (74-80%) FL/FR |
alpha-iso methyl ionone (90% min.) FL/FR |
orris rhizome concrete butter (iris pallida) FL/FR |
rhodinyl butyrate FL/FR |
tropical ionone FL/FR |
fruity |
allyl phenoxyacetate FL/FR |
apricot essence FL/FR |
benzyl acetate FL/FR |
benzyl formate FL/FR |
benzyl isobutyrate FL/FR |
benzyl propionate FL/FR |
buchu mercaptan acetate FL/FR |
iso butyl anthranilate FL/FR |
butyl heptanoate FL/FR |
citronellyl butyrate FL/FR |
citronellyl isobutyrate FL/FR |
beta- damascone FL/FR |
(E)-beta- damascone FL/FR |
(Z)-beta- damascone FL/FR |
ethyl anthranilate FL/FR |
ethyl levulinate FL/FR |
2- heptanol FL/FR |
2- hexyl-4-acetoxytetrahydrofuran FL |
1-para- menthen-9-yl acetate FL/FR |
methoxymelonal FL/FR |
methyl (Z)-3-hexenoate FL/FR |
methyl 4-phenyl butyrate FL |
para- methyl benzyl acetate FL/FR |
2- methyl butyl isovalerate FL/FR |
alpha- methyl ionone FL/FR |
3- nonanon-1-yl acetate FL/FR |
osmanthus concrete FL/FR |
phenethyl isovalerate FL/FR |
2- phenyl-4-pentenal FL |
sambucus canadensis fruit absolute FL/FR |
star fruit oil cuba FL/FR |
strawberry glycidate 1 (aldehyde C-16 (so-called)) FL/FR |
tagete oil CO2 extract FL/FR |
tagete oil madagascar FL/FR |
tagete oil turkey FL/FR |
tagete oil zambia FL/FR |
terpinyl valerate FL/FR |
4-(para- tolyl)-2-butanone FL/FR |
green |
iso butyl methyl ketone FL/FR |
(E)- citronellyl tiglate FL/FR |
heptyl butyrate FL/FR |
(Z)-3- hexen-1-yl isovalerate FL/FR |
hexyl tiglate FL/FR |
iso jasmone FL/FR |
herbal |
iso amyl heptanoate FL/FR |
anthemis nobilis flower extract FL/FR |
anthemis nobilis flower oil england FL/FR |
anthemis nobilis flower oil roman FL/FR |
anthemis nobilis oil FL/FR |
butyl levulinate FL/FR |
chamomile absolute FL/FR |
chamomile distillates FL/FR |
chamomile extract FL/FR |
linalyl formate FL/FR |
matricaria chamomilla flower oil FL/FR |
rue oil FL/FR |
rue oil cuba FL/FR |
tagete oil egypt FL/FR |
honey |
phenethyl isobutyrate FL/FR |
nutty |
phytyl acetate FL/FR |
orris |
orris capronate FL/FR |
spicy |
para- anisyl formate FL/FR |
benzyl cinnamate FL/FR |
cinnamyl formate FL/FR |
levisticum officinale root absolute FL/FR |
levisticum officinale root oil FL/FR |
myrtle oil FL/FR |
spicy acetoacetate FL/FR |
tropical |
alpha- amyl cinnamaldehyde FL/FR |
3- mercaptohexyl acetate FL/FR |
waxy |
butyl undecylenate FL/FR |
(±)-3- methyl-gamma-decalactone FL/FR |
4- phenyl-3-buten-2-ol FL/FR |
woody |
cistus twig/leaf oil FL/FR |
methyl ionyl acetate FL/FR |
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
(Z)-iso | amyl angelate | iso | amyl angelate 70 | | angelate-530 | | angelic acid isoamyl ester | 2- | butenoic acid, 2-methyl-, 3-methylbutyl ester, (2Z)- | 2- | butenoic acid, 2-methyl-, 3-methylbutyl ester, (Z)- | 3- | methyl butyl (Z)-2-methyl but-2-enoate | 3- | methyl butyl 2-methyl but-2(cis)-enoate | 3- | methyl butyl angelate | (Z)-2- | methyl-2-butenoic acid 3-methyl butyl ester | 3- | methylbutyl (2Z)-2-methylbut-2-enoate | 3- | methylbutyl (Z)-2-methylbut-2-enoate | 3- | methylbutyl 2-methylbut-2(cis)-enoate | 3- | methylbutyl angelate | iso | pentyl (2Z)-2-methyl-2-butenoate | (Z)-iso | pentyl 2-methyl crotonate | iso | pentyl 2-methyl crotonate | iso | pentyl 2-methylcrotonate (Z)- | iso | pentyl-(Z)-but-2-enoate |
Articles:
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