EU/US Properties Organoleptics Cosmetics Suppliers Safety Safety in use Safety references References Other Blenders Uses Occurrence Synonyms Articles Notes
 

geranyl tiglate
geranyl 2-methylcrotonate

Supplier Sponsors

Fragrance Demo Formulas
Name:[(2E)-3,7-dimethylocta-2,6-dienyl] (E)-2-methylbut-2-enoate
CAS Number: 7785-33-3Picture of molecule3D/inchi
ECHA EINECS - REACH Pre-Reg:232-078-9
FDA UNII: CUP7SL28J8
Nikkaji Web:J15.693K
MDL:MFCD00016622
CoE Number:11829
XlogP3-AA:4.70 (est)
Molecular Weight:236.35468000
Formula:C15 H24 O2
NMR Predictor:Predict (works with chrome, Edge or firefox)
EFSA/JECFA Comments:
CASrn refers to (E,E) isomer. Register name to be changed accordingly.
Category: flavor and fragrance agents
 
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Google Scholar:Search
Google Books:Search
Google Scholar: with word "volatile"Search
Google Scholar: with word "flavor"Search
Google Scholar: with word "odor"Search
Perfumer and Flavorist:Search
Google Patents:Search
US Patents:Search
EU Patents:Search
Pubchem Patents:Search
PubMed:Search
NCBI:Search
JECFA Food Flavoring:1822 (E)-geranyl tiglate
DG SANTE Food Flavourings:09.383 geranyl 2-methylcrotonate
FEMA Number:4044 geranyl tiglate
FDA:No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):7785-33-3 ; GERANYL TIGLATE
 
Physical Properties:
Appearance:colorless to pale yellow clear oily liquid (est)
Assay: 95.00 to 100.00
Food Chemicals Codex Listed: No
Specific Gravity:0.91600 to 0.92600 @ 25.00 °C.
Pounds per Gallon - (est).: 7.622 to 7.705
Refractive Index:1.47800 to 1.48500 @ 20.00 °C.
Boiling Point: 149.00 to 151.00 °C. @ 7.00 mm Hg
Boiling Point: 271.00 to 272.00 °C. @ 760.00 mm Hg
Acid Value: 1.00 max. KOH/g
Vapor Pressure:0.000332 mmHg @ 25.00 °C. (est)
Flash Point:> 212.00 °F. TCC ( > 100.00 °C. )
logP (o/w): 5.731 (est)
Soluble in:
 alcohol
 water, 0.3194 mg/L @ 25 °C (est)
Stability:
 AP roll-on 15% (good)
 bleach (poor)
 body lotion (very good)
 cleaner APC liquid (good)
 cleaner liquid citric acid (poor)
 detergent powder conc. (good)
 shampoo/shower gel (good)
 soap (good)
Similar Items:note
allyl tiglate
amyl tiglate
isoamyl tiglate
benzyl methyl tiglate
benzyl tiglate
butyl tiglate
isobutyl tiglate
cinnamyl tiglate
(E)-citronellyl tiglate
(E)-ethyl tiglate
geranyl methyl tiglate
(Z)-3-hexen-1-yl tiglate
hexyl tiglate
methyl tiglate
3-octyl tiglate
phenethyl tiglate
propyl tiglate
isopropyl tiglate
 
Organoleptic Properties:
Odor Type: floral
Odor Strength:medium ,
recommend smelling in a 10.00 % solution or less
Substantivity: > 8 hour(s) at 100.00 %
geranium fruity sweet herbal
Odor Description:at 10.00 % in dipropylene glycol. geranium fruity sweet herbal
Flavor Type: floral
geranium melon herbal citrus
Taste Description: at 5.00 - 10.00 ppm. geranium melon herbal citrus
Odor and/or flavor descriptions from others (if found).
Bedoukian Research
GERANYL TIGLATE ≥96.0%, Kosher
Odor Description:Somewhat fruity, geranium-like
Imparts pleasant geranium notes. Natural and refreshing, jam-like sweet. Useful in geranium, rose, lavender and oriental types.
Taste Description:Typical geranyl character, rosy, lemon
Rosy, geraniol notes for citrus fruits especially lemon; floral notes for lychee and other fruits.
Symrise
Geranyl tiglate
Odor Description:sweet-herbaceous, geranium-like, with a light fruity undertone
Stable in: body lotion (very good), shampoo (good), soap (good), ap roll-on (good), powder (good), cleaner citric (poor), cleaner apc (good), bleach (poor).
Moellhausen
GERANYL TIGLATE
Odor Description:fruity, floreal, geranium like
 
Cosmetic Information:
CosIng:cosmetic data
Cosmetic Uses: perfuming agents
 
Suppliers:
Apple Flavor & Fragrance
Geranyl tiglate
Associate Allied Chemicals
Geranyl Tiglate
About
Augustus Oils
Geranyl Tiglate
Services
Bedoukian Research
GERANYL TIGLATE
≥96.0%, Kosher
Odor: Somewhat fruity, geranium-like
Use: Imparts pleasant geranium notes. Natural and refreshing, jam-like sweet. Useful in geranium, rose, lavender and oriental types.
Flavor: Typical geranyl character, rosy, lemon
Rosy, geraniol notes for citrus fruits especially lemon; floral notes for lychee and other fruits.
Berjé
Geranyl Tiglate
Media
BOC Sciences
For experimental / research use only.
Geranyl Tiglate
Ernesto Ventós
GERANYL TIGLATE
Odor: SWEET,HERBAL,GERANIUM,FRUITY
Global Essence
Geranyl Tiglate
Indukern F&F
GERANYL TIGLATE
Odor: SWEET, HERBAL, GERANIUM, FRUITY
Inoue Perfumery
GERANYL TIGLATE S
Lluch Essence
GERANYL TIGLATE
Miltitz Aromatics
GERANYL TIGLATE
min. 94,5 % (main peak)
Odor: Pleasant herbal and fruity impression of profound sweetness. Especially the middle and basis notes make one think of natural geranium
Use: In addition to the imitation of geranium, GERANYL TIGLATE is widely used in oriental and floral (roses) lines. Furthermore this ester supplements herbal-spicy bases with freshness and naturalness.
Moellhausen
GERANYL TIGLATE
Odor: fruity, floreal, geranium like
Organica Aromatics
GERANYL TIGLATE
Min 95% (sum of isomers)
Penta International
GERANYL TIGLATE
Reincke & Fichtner
Geranyl Tiglate
Seqens
Geranyl Tiglate
Shanghai Vigen Fine Chemical
Gernayl tiglate (C.M.)
SRS Aromatics
GERANYL TIGLATE
Symrise
Geranyl tiglate
Odor: sweet-herbaceous, geranium-like, with a light fruity undertone
Use: Stable in: body lotion (very good), shampoo (good), soap (good), ap roll-on (good), powder (good), cleaner citric (poor), cleaner apc (good), bleach (poor).
Synerzine
Geranyl Tiglate
TCI AMERICA
For experimental / research use only.
GERANYL TIGLATE >98.0%(GC)
Vigon International
Geranyl Tiglate
Odor: Sweet-herbaceaous, geranium-like, fruity
 
Safety Information:
Preferred SDS: View
European information :
Most important hazard(s):
Xi - Irritant
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36 - Wear suitable protective clothing.
 
Hazards identification
 
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements
 
Pictogram
 
Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Human Experience:
6 % solution: no irritation or sensitization.
Oral/Parenteral Toxicity:
oral-rat LD50 > 5000 mg/kg
Food and Cosmetics Toxicology. Vol. 12, Pg. 899, 1974.

Dermal Toxicity:
skin-rabbit LD50 > 5000 mg/kg
Food and Cosmetics Toxicology. Vol. 12, Pg. 899, 1974.

Inhalation Toxicity:
Not determined
 
Safety in Use Information:
Category:
flavor and fragrance agents
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice
Recommendation for geranyl tiglate usage levels up to:
  6.0000 % in the fragrance concentrate.
 
Maximised Survey-derived Daily Intakes (MSDI-EU): 1.90 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA): 0.08 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI): 2300 (μg/person/day)
Threshold of Concern:1800 (μg/person/day)
Structure Class: I
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 21
Click here to view publication 21
 average usual ppmaverage maximum ppm
baked goods: --
beverages(nonalcoholic): 20.0000020.00000
beverages(alcoholic): 20.0000020.00000
breakfast cereal: --
cheese: --
chewing gum: --
condiments / relishes: --
confectionery froastings: 100.00000100.00000
egg products: --
fats / oils: --
fish products: --
frozen dairy: 50.0000050.00000
fruit ices: 50.0000050.00000
gelatins / puddings: --
granulated sugar: --
gravies: --
hard candy: 100.00000100.00000
imitation dairy: 50.0000050.00000
instant coffee / tea: --
jams / jellies: --
meat products: --
milk products: 50.0000050.00000
nut products: --
other grains: --
poultry: --
processed fruits: --
processed vegetables: --
reconstituted vegetables: --
seasonings / flavors: --
snack foods: --
soft candy: 100.00000100.00000
soups: --
sugar substitutes: --
sweet sauces: --
 
Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i).
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.
 average usage mg/kgmaximum usage mg/kg
Dairy products, excluding products of category 02.0 (01.0): 7.0000035.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0): 5.0000025.00000
Edible ices, including sherbet and sorbet (03.0): 10.0000050.00000
Processed fruit (04.1): 7.0000035.00000
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): --
Confectionery (05.0): 10.0000050.00000
Chewing gum (05.3): --
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 5.0000025.00000
Bakery wares (07.0): 10.0000050.00000
Meat and meat products, including poultry and game (08.0): 2.0000010.00000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): 2.0000010.00000
Eggs and egg products (10.0): --
Sweeteners, including honey (11.0): --
Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 5.0000025.00000
Foodstuffs intended for particular nutritional uses (13.0): 10.0000050.00000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1): --
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 10.0000050.00000
Ready-to-eat savouries (15.0): 20.00000100.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): 5.0000025.00000
 
Safety References:
European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Flavouring Group Evaluation 202: 3-Alkylated aliphatic acyclic alpha,beta-unsaturated aldehydes and precursors with or without additional double bonds from chemical subgroup 1.1.3 of FGE.19[1]
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 95 (FGE.95): Consideration of aliphatic, linear or branched-chain saturated and unsaturated alcohols, aldehydes, acids and related esters evaluated by JECFA (69th meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05Rev1 (2008)
View page or View pdf

EPI System: View
AIDS Citations:Search
Cancer Citations:Search
Toxicology Citations:Search
EPA Substance Registry Services (TSCA):7785-33-3
EPA ACToR:Toxicology Data
EPA Substance Registry Services (SRS):Registry
Laboratory Chemical Safety Summary :5367785
National Institute of Allergy and Infectious Diseases:Data
WGK Germany:2
[(2E)-3,7-dimethylocta-2,6-dienyl] (E)-2-methylbut-2-enoate
Chemidplus:0007785333
RTECS:RG5927900 for cas# 7785-33-3
 
References:
 [(2E)-3,7-dimethylocta-2,6-dienyl] (E)-2-methylbut-2-enoate
NIST Chemistry WebBook:Search Inchi
Canada Domestic Sub. List:7785-33-3
Pubchem (cid):5367785
Pubchem (sid):134991236
Pherobase:View
 
Other Information:
(IUPAC):Atomic Weights of the Elements 2011 (pdf)
Videos:The Periodic Table of Videos
tgsc:Atomic Weights use for this web site
(IUPAC):Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):View
CHEMBL:View
HMDB (The Human Metabolome Database):HMDB32292
FooDB:FDB009483
Export Tariff Code:2916.19.5000
Typical G.C.
VCF-Online:VCF Volatile Compounds in Food
ChemSpider:View
 
Potential Blenders and core components note
For Odor
aldehydic
(Z)-4-
dodecenal
FL/FR
anisic
amyl furoate
FL/FR
caramellic
diethyl malate
FL/FR
citrus
(S)-(-)-
citronellal
FL/FR
citronitrile (Symrise)
FR
2-
dodecanone
FL/FR
(Z+E)-2-
methyl-2-(4-methyl-3-pentenyl) cyclopropane carbaldehyde
FL/FR
1-
methyl-4-methyl ethenyl cyclohexene sulfurized
FL/FR
ocimene quintoxide
FL/FR
tetrahydromyrcenyl acetate
FR
creamy
3-
heptyl dihydro-5-methyl-2(3H)-furanone
FL/FR
ethereal
ethyl 4-pentenoate
FL/FR
floral
alpha-
amyl cinnamaldehyde
FL/FR
benzyl acetone
FL/FR
bursera graveolens wood oil
FL/FR
butyl tiglate
FR
cassis cyclohexene
FR
cilantro herb oil egypt
FL/FR
citronellyl acetate
FL/FR
dihydrojasmone
FL/FR
dihydromyrcene
FR
dimethyl benzyl carbinyl butyrate
FL/FR
geranyl hexanoate
FL/FR
jasmin absolute egypt (from concrete)
FL/FR
menthadienyl formate
FR
methyl benzyl acetate (mixed ortho-,meta-,para-)
FL/FR
musk acetate
FR
neryl formate
FL/FR
nonan-3-yl acetate
FL/FR
3-
nonanone
FL/FR
(Z)-
rose oxide
FL/FR
rose undecene
FR
terpinyl formate
FL/FR
tetrahydrolinalool
FL/FR
(E)-2,5,9-
trimethyl-4,9-decadien-1-al
FR
fruity
iso
amyl 2-methyl butyrate
FL/FR
para-
anisyl propionate
FL/FR
iso
butyl 2-methyl butyrate
FL/FR
ethyl citronellate
FL/FR
geranyl isovalerate
FL/FR
para-
menth-1-ene-9-ol
FL/FR
methyl acetoacetate
FL/FR
2-
methyl butyl isovalerate
FL/FR
neryl propionate
FL/FR
ocimen-1-yl acetate
FR
tropical specialty
FR
green
agrumen aldehyde
FR
iso
butyl heptanoate
FL/FR
butyl heptanoate
FL/FR
iso
butyl methyl ketone
FL/FR
cilantro leaf oil
FL/FR
green carboxylate
FR
hexyl tiglate
FL/FR
3,6-
ivy carbaldehyde
FL/FR
dextro-
limonene oxide
FL/FR
(2-
methoxy-1-methyl butyl) benzene
FR
herbal
6-
acetoxydihydrotheaspirane
FL/FR
acorus calamus rhizome oil
FR
iso
amyl heptanoate
FL/FR
buchu mercaptan acetate
FL/FR
butyl levulinate
FL/FR
chamomile propionate
FR
(R)-(+)-
citronellal
FL/FR
citrus ocimenol acetate
FR
cuminyl acetate
FL/FR
2-
dodecenal
FL/FR
eucalyptus citriodora oil
FR
freesia heptanol
FL/FR
geranic oxide
FL/FR
jambu oleoresin
FL/FR
linalyl octanoate
FL/FR
1-para-
menthen-9-yl acetate
FL/FR
6-
methoxy-2,6-dimethyl octanal
FR
methyl hexyl ether
FL/FR
(1S,5R)-
myrtenyl acetate
FL/FR
3-
octanon-1-ol
FL/FR
petitgrain heptane
FR
rue oil
FL/FR
rue oil cuba
FL/FR
saffron pyranone
FR
tagete oil CO2 extract
FL/FR
tagete oil south africa
FL/FR
oswego
tea specialty
FR
tricyclodecenyl propionate
FR
viridiflorol
FL/FR
orris
orris capronate
FL/FR
pine
dipentene terpene hydrocarbon byproducts
FR
spicy
cubeb oil CO2 extract (piper cubeba)
FL/FR
ginger oleoresin africa
FL/FR
ginger root oil cochin
FL/FR
terpenic
gamma-
terpinene
FL/FR
waxy
3-
decanone
FL/FR
woody
polylimonene
FL/FR
For Flavor
No flavor group found for these
6-
acetoxydihydrotheaspirane
FL/FR
amyl furoate
FL/FR
para-
anisyl propionate
FL/FR
benzyl methyl tiglate
FL
bursera graveolens wood oil
FL/FR
iso
butyl heptanoate
FL/FR
(S)-(-)-
citronellal
FL/FR
(R)-(+)-
citronellal
FL/FR
beta-
cubebene
FL
cuminyl acetate
FL/FR
3-
decanone
FL/FR
diethyl malate
FL/FR
(Z)-4-
dodecenal
FL/FR
ethyl 4-pentenoate
FL/FR
2-
heptyl cyclopropane carboxylic acid
FL
3-
mercaptooctanal
FL
methyl acetoacetate
FL/FR
methyl benzyl acetate (mixed ortho-,meta-,para-)
FL/FR
(Z+E)-2-
methyl-2-(4-methyl-3-pentenyl) cyclopropane carbaldehyde
FL/FR
nonan-3-yl acetate
FL/FR
3-
octanon-1-ol
FL/FR
3-
octyl butyrate
FL
polylimonene
FL/FR
(E)-4-
undecenal
FL
viridiflorol
FL/FR
dextro-
limonene oxide
FL/FR
acidic
acidic
(E)-2-
hexenoic acid
FL
camphoreous
geranic oxide
FL/FR
citrus
cilantro leaf oil
FL/FR
dehydronootkatone
FL
freesia heptanol
FL/FR
1-
methyl-4-methyl ethenyl cyclohexene sulfurized
FL/FR
cooling
jambu oleoresin
FL/FR
dusty
ethyl citronellate
FL/FR
ethereal
methyl hexyl ether
FL/FR
fatty
2-
dodecanone
FL/FR
2-
dodecenal
FL/FR
floral
citronellyl acetate
FL/FR
dihydrojasmone
FL/FR
dimethyl benzyl carbinyl butyrate
FL/FR
jasmin absolute egypt (from concrete)
FL/FR
tetrahydrolinalool
FL/FR
fruity
iso
amyl 2-methyl butyrate
FL/FR
benzyl acetone
FL/FR
buchu mercaptan acetate
FL/FR
iso
butyl 2-methyl butyrate
FL/FR
butyl heptanoate
FL/FR
geranyl hexanoate
FL/FR
3-
heptyl dihydro-5-methyl-2(3H)-furanone
FL/FR
linalyl octanoate
FL/FR
1-para-
menthen-9-yl acetate
FL/FR
2-
methyl butyl isovalerate
FL/FR
neryl formate
FL/FR
tagete oil CO2 extract
FL/FR
tagete oil south africa
FL/FR
terpinyl formate
FL/FR
green
iso
butyl methyl ketone
FL/FR
geranyl isovalerate
FL/FR
(E)-2-
heptenal
FL
hexyl tiglate
FL/FR
3,6-
ivy carbaldehyde
FL/FR
neryl propionate
FL/FR
3-
nonanone
FL/FR
ocimene quintoxide
FL/FR
(Z)-
rose oxide
FL/FR
herbal
iso
amyl heptanoate
FL/FR
butyl levulinate
FL/FR
cilantro herb oil egypt
FL/FR
para-
menth-1-ene-9-ol
FL/FR
rue oil
FL/FR
rue oil cuba
FL/FR
orris
orris capronate
FL/FR
spicy
cubeb oil CO2 extract (piper cubeba)
FL/FR
ginger oleoresin africa
FL/FR
ginger root oil cochin
FL/FR
terpenic
gamma-
terpinene
FL/FR
tropical
alpha-
amyl cinnamaldehyde
FL/FR
woody
(1S,5R)-
myrtenyl acetate
FL/FR
 
Potential Uses:
FRgeranium
FRgreen
FRherbal
FRlavender
FRoriental
FRrose
 
Occurrence (nature, food, other):note
 geranium leaf oil india @ 1.61%
Data GC Search Trop Picture
 geranium oil
Search Trop Picture
 geranium oil africa @ 2.55%
Data GC Search Trop Picture
 geranium oil bourbon @ 1.25%
Data GC Search Trop Picture
 geranium oil bourbon @ 1.34%
Data GC Search Trop Picture
 geranium oil china @ 0.98%
Data GC Search Trop Picture
 geranium oil egypt @ 1.48%
Data GC Search Trop Picture
 geranium oil moroccan @ 2.24%
Data GC Search Trop Picture
 geranium oil rwanda @ 2.49%
Data GC Search Trop Picture
 geranium petiole oil india @ 4.05%
Data GC Search Trop Picture
 geranium stem oil india @ 1.84%
Data GC Search Trop Picture
 kumquat
Search Trop Picture
 
Synonyms:
2-butenoic acid, 2-methyl-, (2E)-3,7-dimethyl-2,6-octadien-1-yl ester, (2E)-
2-butenoic acid, 2-methyl-, (2E)-3,7-dimethyl-2,6-octadienyl ester,(2E)-
2-butenoic acid, 2-methyl-, 3,7-dimethyl-2,6-octadienyl ester, (E,E,E)-
2-butenoic acid, 2-methyl-, 3,7-dimethyl-2,6-octadienyl ester, (E,E)-
cis-alpha,beta-dimethyl acrylic acid geraniol ester
trans-3,7-dimethyl-2,6-octadien-1-yl cis-alpha,beta-dimethyl acrylate
 dimethyl-2,6-octadienyl 2-methyl crotonate
(E)-3,7-dimethyl-2,6-octadienyl 2-methyl crotonate
(E)-3,7-dimethyl-2,6-octadienyl 2-methylcrotonate
(2E)-3,7-dimethylocta-2,6-dien-1-yl (2E)-2-methylbut-2-enoate
[(2E)-3,7-dimethylocta-2,6-dienyl] (E)-2-methylbut-2-enoate
 geranyl 2-methyl crotonate
 geranyl 2-methylcrotonate
(E)-geranyl tiglate
 geranyl tiglate S
(E,E)-2-methyl butenoic acid 3,7-dimethyl-2,6-octadienyl ester
(E)-neryl tiglate
2,6-octadien-1-ol, 3,7-dimethyl-, 2-methyl-2-butenoate, (E,E,E)-
 tiglic acid 3,7-dimethyl-2,6-octadienyl ester
 tiglic acid geraniol ester
 tiglic acid geranyl ester
 tiglic acid, geraniol ester
 
 
Notes:
None found
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