cinnamyl tiglate
cinnamyl 2-methylcrotonate

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  CODE101552 CODE101552
  Product(s):
  61792-12-9 Cinnamyl 2-methylcrotonate

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  Penta International Corporation

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  Product(s):
  03-28000 CINNAMYL TIGLATE

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  Synerzine, Inc.

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  CODE101552 CODE101552
  Product(s):
  W0345 Cinnamyl Tiglate

Name: [(E)-3-phenylprop-2-enyl] (E)-2-methylbut-2-enoate CAS Number: 61792-12-9 3D/inchi ECHA EINECS - REACH Pre-Reg: 263-215-0 FDA UNII: Search Nikkaji Web: J372.615K XlogP3-AA: 3.50 (est) Molecular Weight: 216.27992000 Formula: C14 H16 O2 NMR Predictor: Predict (works with chrome, Edge or firefox) Name: [(E)-3-phenylprop-2-enyl] (Z)-2-methylbut-2-enoate CAS Number: 84254-87-5 3D/inchi FDA UNII: Search Nikkaji Web: J297.576I XlogP3-AA: 3.50 (est) Molecular Weight: 216.27992000 Formula: C14 H16 O2 NMR Predictor: Predict (works with chrome, Edge or firefox) EFSA/JECFA Comments: (Z)- or (E)- isomer not specified by CASrn in Register. Mixture of (2E)-2-methylbut-2-enoate ester of (E/Z )-cinnamic acid (EFFA, 2010a). Composition of stereoisomeric mixture to be specified. Category:fragrance agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search DG SANTE Food Flavourings: 09.339 cinnamyl 2-methylcrotonate   Physical Properties: Appearance: colorless clear oily liquid (est) Assay: 95.00 to 100.00 Food Chemicals Codex Listed: No Specific Gravity: 0.99500 to 1.00100 @ 25.00 °C. Pounds per Gallon - (est).: 8.279 to 8.329 Refractive Index: 1.52100 to 1.52700 @ 20.00 °C. Melting Point: 18.00 °C. @ 760.00 mm Hg Boiling Point: 340.00 °C. @ 760.00 mm Hg Vapor Pressure: 0.001320 mmHg @ 25.00 °C. Flash Point: 388.00 °F. TCC ( 197.78 °C. ) logP (o/w): 4.010 (est) Soluble in:   alcohol   water, 10.04 mg/L @ 25 °C (est) Insoluble in:   water Similar Items:note allyl tiglate amyl tiglate isoamyl tiglate benzyl methyl tiglate benzyl tiglate butyl tiglate isobutyl tiglate (E)-citronellyl tiglate (E)-ethyl tiglate geranyl methyl tiglate geranyl tiglate (Z)-3-hexen-1-yl tiglate hexyl tiglate methyl tiglate 3-octyl tiglate phenethyl tiglate propyl tiglate isopropyl tiglate   Organoleptic Properties: Odor Type: woody woody cinnamyl green herbal Odor Description:at 100.00 %. woody cinnamyl green herbal Odor and/or flavor descriptions from others (if found).   Cosmetic Information: CosIng: cosmetic data Cosmetic Uses: perfuming agents   Suppliers: BOC Sciences For experimental / research use only. Cinnamyl 2-methylcrotonate Inoue Perfumery CINNAMYL TIGLATE Penta International CINNAMYL TIGLATE Synerzine Cinnamyl Tiglate   Safety Information:   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Human Experience: 4 % solution: no irritation or sensitization. Oral/Parenteral Toxicity: oral-rat LD50 > 5000 mg/kg RIFM (1975b) Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: fragrance agents RIFM Fragrance Material Safety Assessment: Search IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice maximum skin levels for fine fragrances:   0.0020 % and are based on the assumption that the fragrance mixture is used at 20% in a consumer product (IFRA Use Level Survey). (IFRA, 2001) Recommendation for cinnamyl tiglate usage levels up to:   2.0000 % in the fragrance concentrate. use level in formulae for use in cosmetics:   0.0100 % Dermal Systemic Exposure in Cosmetic Products:   0.0003 mg/kg/day (IFRA, 2001)   Maximised Survey-derived Daily Intakes (MSDI-EU): 0.012 (μg/capita/day) Modified Theoretical Added Maximum Daily Intake (mTAMDI): 3900 (μg/person/day) Threshold of Concern: 1800 (μg/person/day) Structure Class: I   Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.   average usage mg/kg maximum usage mg/kg Dairy products, excluding products of category 02.0 (01.0): 7.00000 35.00000 Fats and oils, and fat emulsions (type water-in-oil) (02.0): 5.00000 25.00000 Edible ices, including sherbet and sorbet (03.0): 10.00000 50.00000 Processed fruit (04.1): 7.00000 35.00000 Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): - - Confectionery (05.0): 10.00000 50.00000 Chewing gum (05.3): - - Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 5.00000 25.00000 Bakery wares (07.0): 10.00000 50.00000 Meat and meat products, including poultry and game (08.0): 2.00000 10.00000 Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): 2.00000 10.00000 Eggs and egg products (10.0): - - Sweeteners, including honey (11.0): - - Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 5.00000 25.00000 Foodstuffs intended for particular nutritional uses (13.0): 10.00000 50.00000 Non-alcoholic ("soft") beverages, excl. dairy products (14.1): 5.00000 25.00000 Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 10.00000 50.00000 Ready-to-eat savouries (15.0): 20.00000 100.00000 Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): 5.00000 25.00000   Safety References: European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... European Food Safety Authority (EFSA) reference(s): Flavouring Group Evaluation 214: alpha,beta-Unsaturated aldehydes and precursors from chemical subgroup 3.1 of FGE.19: Cinnamyl derivatives[1] View page or View pdf Flavouring Group Evaluation 15, Revision 2 (FGE.15Rev2): Aryl-substituted saturated and unsaturated primary alcohol/aldehyde/acid/ester derivatives from chemical group 22 View page or View pdf EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA Substance Registry Services (TSCA):61792-12-9 EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :5367766 National Institute of Allergy and Infectious Diseases:Data WGK Germany:2 [(E)-3-phenylprop-2-enyl] (E)-2-methylbut-2-enoate Chemidplus:0061792129 [(E)-3-phenylprop-2-enyl] (Z)-2-methylbut-2-enoate Chemidplus:084254875   References:   [(E)-3-phenylprop-2-enyl] (E)-2-methylbut-2-enoate NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 61792-12-9 Pubchem (cid): 5367766 Pubchem (sid): 135071096   [(E)-3-phenylprop-2-enyl] (Z)-2-methylbut-2-enoate NIST Chemistry WebBook: Search Inchi Canada Domestic Sub. List: 84254-87-5 Pubchem (cid): 6432955 Pubchem (sid): 43026715   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements HMDB (The Human Metabolome Database): Search Typical G.C. VCF-Online: VCF Volatile Compounds in Food ChemSpider: View   Potential Blenders and core components note For Odor No odor group found for these cinnamyl valerate FL/FR octanal propylene glycol acetal FL/FR aldehydic aldehydic agrumen nitrile FR animal iso butyl quinoline FR anisic estragole FL/FR ocimum basilicum leaf oil america FL/FR balsamic betula pubescens bud oil FL/FR iso butyl cinnamate FL/FR cinnamyl alcohol FL/FR cinnamyl benzoate FL/FR cinnamyl butyrate FL/FR cinnamyl cinnamate FL/FR cinnamyl formate FL/FR ethyl cinnamate FL/FR fir balsam absolute FR (Z)-3- hexen-1-yl cinnamate FR hexyl cinnamate FR linalyl cinnamate FL/FR octyl cinnamate FR peru balsam oil FL/FR peru balsam resinoid FL/FR 2- phenoxyethyl formate FR christmas pine fragrance FR spruce needle absolute FL/FR tetrahydrofurfuryl cinnamate FL/FR tolu balsam absolute FL/FR tolu balsam resinoid FL/FR valerian rhizome absolute FL/FR caramellic 2-iso butyl-3-methyl pyrazine FL/FR chocolate iso amyl phenyl acetate FL/FR citrus iso decyl acetate FR alpha- methylene citronellal FR neroli ketone FR ocimene quintoxide FL/FR earthy geosmin FL/FR 2- octanone FL/FR (S)-1- octen-3-ol FL/FR ethereal ethyl 4-pentenoate FL/FR fatty (E)-2- octenal FL/FR 2- octenal FL/FR floral amyl salicylate FL/FR anise indene FR cassis oxime 10% FR cilantro herb oil egypt FL/FR cinnamyl phenyl acetate FL/FR citronellyl valerate FL/FR cymbopogon validus leaf oil FR dictamnus hispanicus oil FR dihydrocitronellyl ethyl ether FR dihydrorose oxide FR dimethyl benzyl carbinyl butyrate FL/FR 2,4- dimethyl-3-cyclohexene-1-methanol FR geranium oil africa FL/FR geranium oil egypt FL/FR (Z)- jasmone FL/FR karo karounde absolute FR linalool FL/FR linden flower absolute FR melaleuca ericifolia leaf oil FR para- methyl benzyl acetate FL/FR neryl formate FL/FR 3- nonanone FL/FR beta- ocimene FL/FR orange leaf absolute FL/FR 2- pentyl cyclopentanone FR petitgrain bigarade oil FL/FR iso phytol FL/FR prenyl salicylate FL/FR reseda absolute FR rose pyran FR 5- tricyclodecenyl acetate FR fruity apple ketal FL/FR 3- benzyl-4-heptanone FL/FR 3- butyl bicyclo[3.2.1]-6-octen-2-one FR cinnamyl hexanoate FL/FR cinnamyl isobutyrate FL/FR ethyl 2-ethyl acetoacetate FL/FR green acetate FR osmanthus flower absolute FL/FR tropical indene FR green agrumen aldehyde FR bergoxane FR birch leaf specialty FR iso butyl heptanoate FL/FR iso butyl methyl ketone FL/FR 2-sec- butyl thiazole FL/FR S-sec- butyl thioisovalerate FL/FR carrot leaf oil (daucus carota ssp.maximus) FR chrysanthemum carbaldehyde FR iso cyclocitral (IFF) FL/FR alpha- elemol FL/FR fresh nitrile FR galbanum oil FL/FR galbanum oleoresin FL/FR galbanum resinoid FL/FR heptanal (aldehyde C-7) FL/FR 1- heptanol FL/FR heptyl benzoate FL/FR (Z)-4- hexen-1-ol FL/FR (E)-2- hexen-1-yl salicylate FR 3- hexenyl 2-methyl butyrate FL/FR hexyl hexanoate FL/FR english ivy leaf absolute FR marigold pot absolute FL/FR para- methyl hydratropaldehyde FL/FR 6- methyl-3-hepten-2-one FL/FR 3- propyl bicyclo(3.2.1)-6-octen-2-one FR rosa damascena leaf absolute FR seaweed absolute (fucus vesiculosus et serratus) FL/FR terpinyl propionate FL/FR triplal / ethyl anthranilate schiff's base FR valerian rhizome oil CO2 extract china FL/FR herbal 6- acetoxydihydrotheaspirane FL/FR alpha- amyl cinnamyl formate FL/FR anethum graveolens herb oil FL/FR anethum graveolens herb tincture FL/FR anthemis nobilis flower extract FL/FR anthemis nobilis flower oil roman FL/FR apium graveolens seed oil FL/FR apium graveolens seed oil india FL/FR artemisia alba oil FR artemisyl ketone FL/FR sweet basil absolute FL/FR bornyl salicylate FR (+)-alpha- campholenic aldehyde FL/FR canarium luzonicum oil FL/FR chrysanthemum ketone FR coriander oleoresin FL/FR iso dihydrolavandulal FL/FR dill weed oil cuba FL/FR dill weed oil reunion FL/FR dimethyl benzyl carbinyl formate FL/FR dimethyl cyclormol (IFF) FR 2-(2,4- dimethyl-3-cyclohexene-1-yl)-4,4-dimethyl-1,3-oxathiane FR american elder flower absolute FR cis- herbal cyclohexane FR herbal dioxane FR herbal heptane FR hop absolute FL/FR hop oil FL/FR 6- hydroxydihydrotheaspirane (mixture of isomers) FL/FR lantana camara flower oil FR linalyl formate FL/FR linalyl octanoate FL/FR marigold oil mexico FL/FR melaleuca leucadendron var. cajuputi leaf oil FL/FR 1-(2- methyl allyl oxy) heptane FR (E)-6- methyl-3-hepten-2-one FL/FR monarda fistulosa oil FR nonisyl formate FR 1- octen-3-yl acetate FL/FR 3- octyl acetate FL/FR oregano specialty FR origanum oil FL/FR origanum oil greece FL/FR perilla leaf oil FL/FR perillaldehyde FL/FR petroselinum crispum seed oil CO2 extract FL/FR phenyl acetaldehyde diisoamyl acetal FR prenyl senecioate FL/FR rosmarinus officinalis extract FL/FR rosmarinus officinalis tincture FL/FR tagete oil CO2 extract FL/FR tagete oil south africa FL/FR theaspirane FL/FR thyme absolute FL/FR tricyclo(5.2.1.02,6)dec-3-enyl acetate FR tricyclodecyl acetate FR valerian rhizome oil FL/FR valerian rhizome oil china FL/FR viridiflorol FL/FR wormwood oil america FL/FR wormwood oil italy FL/FR wormwood oil poland FL/FR honey butyl phenyl acetate FL/FR melon (Z)-6- nonenal FL/FR minty (-)- menthone FL/FR (-)-iso pulegol FL/FR mossy oakmoss absolute FL/FR treemoss absolute FR orris iso eugenyl formate FL/FR phenolic 2'- hydroxyacetophenone FL/FR soapy methyl anthranilate / hexyl cinnamaldehyde schiff's base FR spicy alpha- amyl cinnamyl alcohol FL/FR iso butyl angelate FL/FR carnation absolute FR cinnamon acrolein FL/FR cinnamyl acetate FL/FR cinnamyl isovalerate FL/FR cinnamyl propionate FL/FR (-)- cubenol FL/FR cuminaldehyde FL/FR iso cyclogeraniol (IFF) FR 2- octanol FL/FR origanum majorana oil FL/FR outdoors specialty FR 4-iso propyl-2-cyclohexenone FL/FR spicy carbonate FR thujonic woody ketone FL/FR woody camphene FL/FR cistus twig/leaf oil FL/FR dalbergia sissoo leaf oil FR alpha- farnesene FL/FR alpha- farnesene isomer FL/FR marine formate FR polylimonene FL/FR spruce needle oil canada FL/FR verdoxan FR For Flavor No flavor group found for these 6- acetoxydihydrotheaspirane FL/FR 4- acetyl-2-isopropenyl pyridine FL alpha- amyl cinnamyl formate FL/FR artemisyl ketone FL/FR betula pubescens bud oil FL/FR iso butyl heptanoate FL/FR 4- butyl thiazole FL 2-sec- butyl thiazole FL/FR S-sec- butyl thioisovalerate FL/FR cinnamyl benzoate FL/FR cinnamyl hexanoate FL/FR cinnamyl phenyl acetate FL/FR cinnamyl valerate FL/FR citronellyl valerate FL/FR dimethyl benzyl carbinyl formate FL/FR alpha- elemol FL/FR ethyl 4-pentenoate FL/FR iso eugenyl formate FL/FR fig leaf absolute FL heptyl benzoate FL/FR (E,E)-2,4- hexadien-1-ol FL melaleuca leucadendron var. cajuputi leaf oil FL/FR methyl furfuracrylate FL 1- methyl pyrrole FL (E)-6- methyl-3-hepten-2-one FL/FR 6- methyl-3-hepten-2-one FL/FR octanal propylene glycol acetal FL/FR (S)-1- octen-3-ol FL/FR 2- octenal FL/FR 3- octyl butyrate FL perilla leaf oil FL/FR polylimonene FL/FR prenyl senecioate FL/FR 2- propyl thiazole FL 4-iso propyl-2-cyclohexenone FL/FR seaweed absolute (fucus vesiculosus et serratus) FL/FR tetrahydrofurfuryl cinnamate FL/FR ortho- vinyl anisole FL viridiflorol FL/FR woody ketone FL/FR aromatic aromatic amyl salicylate FL/FR balsamic iso butyl cinnamate FL/FR ethyl cinnamate FL/FR peru balsam oil FL/FR peru balsam resinoid FL/FR spruce needle absolute FL/FR tolu balsam absolute FL/FR tolu balsam resinoid FL/FR camphoreous camphene FL/FR 6- hydroxydihydrotheaspirane (mixture of isomers) FL/FR citrus linalool FL/FR petitgrain bigarade oil FL/FR cooling theaspirane FL/FR dairy 2- octanone FL/FR earthy geosmin FL/FR fatty (E)-2- octenal FL/FR floral iso amyl phenyl acetate FL/FR cinnamyl propionate FL/FR dimethyl benzyl carbinyl butyrate FL/FR geranium oil africa FL/FR geranium oil egypt FL/FR orange leaf absolute FL/FR fruity apple ketal FL/FR 3- benzyl-4-heptanone FL/FR cinnamyl isobutyrate FL/FR cinnamyl isovalerate FL/FR ethyl 2-ethyl acetoacetate FL/FR hexyl hexanoate FL/FR linalyl cinnamate FL/FR linalyl octanoate FL/FR para- methyl benzyl acetate FL/FR neryl formate FL/FR osmanthus flower absolute FL/FR tagete oil CO2 extract FL/FR tagete oil south africa FL/FR valerian rhizome absolute FL/FR valerian rhizome oil FL/FR valerian rhizome oil china FL/FR valerian rhizome oil CO2 extract china FL/FR green anethum graveolens herb tincture FL/FR iso butyl angelate FL/FR iso butyl methyl ketone FL/FR 2-iso butyl-3-methyl pyrazine FL/FR (+)-alpha- campholenic aldehyde FL/FR canarium luzonicum oil FL/FR celery distillates FL cinnamyl alcohol FL/FR iso cyclocitral (IFF) FL/FR alpha- farnesene FL/FR alpha- farnesene isomer FL/FR galbanum oil FL/FR galbanum oleoresin FL/FR galbanum resinoid FL/FR heptanal (aldehyde C-7) FL/FR (Z)-4- hexen-1-ol FL/FR 3- hexenyl 2-methyl butyrate FL/FR marigold pot absolute FL/FR para- methyl hydratropaldehyde FL/FR 3- nonanone FL/FR (Z)-6- nonenal FL/FR oakmoss absolute FL/FR beta- ocimene FL/FR ocimene quintoxide FL/FR 1- octen-3-yl acetate FL/FR 3- octyl acetate FL/FR terpinyl propionate FL/FR herbal anethum graveolens herb oil FL/FR anthemis nobilis flower extract FL/FR anthemis nobilis flower oil roman FL/FR apium graveolens seed oil FL/FR apium graveolens seed oil india FL/FR sweet basil absolute FL/FR celery seed oleoresin FL cilantro herb oil egypt FL/FR coriander oleoresin FL/FR iso dihydrolavandulal FL/FR dill weed oil cuba FL/FR dill weed oil reunion FL/FR hop absolute FL/FR hop oil FL/FR linalyl formate FL/FR marigold oil mexico FL/FR ocimum basilicum leaf oil america FL/FR origanum majorana oil FL/FR origanum oil FL/FR origanum oil greece FL/FR petroselinum crispum seed oil CO2 extract FL/FR prenyl salicylate FL/FR rosmarinus officinalis extract FL/FR rosmarinus officinalis tincture FL/FR thyme absolute FL/FR wormwood oil america FL/FR wormwood oil italy FL/FR wormwood oil poland FL/FR honey butyl phenyl acetate FL/FR licorice estragole FL/FR minty (-)- menthone FL/FR (-)-iso pulegol FL/FR naphthyl 2'- hydroxyacetophenone FL/FR nutty peanut oxazole FL oily iso phytol FL/FR solvent 1- heptanol FL/FR spicy alpha- amyl cinnamyl alcohol FL/FR cinnamon acrolein FL/FR cinnamyl acetate FL/FR cinnamyl cinnamate FL/FR cinnamyl formate FL/FR (-)- cubenol FL/FR cuminaldehyde FL/FR 2- octanol FL/FR perillaldehyde FL/FR winey cinnamyl butyrate FL/FR woody cistus twig/leaf oil FL/FR (Z)- jasmone FL/FR spruce needle oil canada FL/FR   Potential Uses: FR leather russian leather FR woody   Occurrence (nature, food, other):note   champaca concrete @ 0.05% Data GC Search Trop Picture   Synonyms: 2- butenoic acid, 2-methyl-, (2E)-3-phenyl-2-propen-1-yl ester, (2E)- 2- butenoic acid, 2-methyl-, 3-phenyl-2-propenyl ester, (2E)-   cinnamyl 2-methyl crotonate   cinnamyl 2-methylcrotonate 3- phenyl allyl 2-methyl crotonate 3- phenyl-2-propenyl (E)-2-methyl-2-butenoate (2E)-3- phenylprop-2-en-1-yl (2E)-2-methylbut-2-enoate [(E)-3- phenylprop-2-enyl] (E)-2-methylbut-2-enoate   tiglic acid cinnamyl ester   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Notes: None found