methyl furfuryl thiol
5-methylfurfurylmercaptan

Supplier Sponsors

• 
  Penta International Corporation

  Chemistry innovation
  At Penta, our products and services help businesses do business better.
  For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes.
  US Email:	Technical Services
  US Email:	Sales
  US Voice: (973) 740-2300
  US Fax: (973) 740-1839
  CODE155221 CODE155221
  Product(s):
  13-45500 5-METHYLFURFURYL MERCAPTAN

• 
  R C Treatt and Co Ltd

  Innovative ingredient solutions
  World-leading innovative ingredient solutions provider for the flavour, fragrance and FMCG industries.
  We offer innovative and trend-setting product concepts for our customers, collaborating with them to create true value for their products.
  Email:	Enquiries
  US Email:	Enquiries
  Voice: +44 (0) 1284 702500
  Fax: +44 (0) 1284 703809
  US Voice: +1 863 668 9500
  US Fax: +1 863 668 3388
  Twitter
  Linkedin
  Youtube
  News
  CODE155221 CODE155221
  Product(s):
  5-Methylfurfuryl mercaptan 1% in TEC Kosher

Name: (5-methylfuran-2-yl)methanethiol CAS Number: 59303-05-8 3D/inchi FDA UNII: 1NB0MP3CK9 Nikkaji Web: J827.773G XlogP3-AA: 1.50 (est) Molecular Weight: 128.19396000 Formula: C6 H8 O S NMR Predictor: Predict (works with chrome, Edge or firefox) Category:flavoring agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search Pubchem Patents: Search PubMed: Search NCBI: Search JECFA Food Flavoring: 2090 5-methylfurfurylmercaptan DG SANTE Food Flavourings: 13.149 5-methyl-2-furanmethanethiol FEMA Number: 4697 5-methylfurfurylmercaptan FDA: No longer provide for the use of these seven synthetic flavoring substances FDA Mainterm (SATF): 59303-05-8 ; 5-METHYLFURFURYLMERCAPTAN   Physical Properties: Appearance: colorless to yellow clear liquid (est) Assay: 95.00 to 100.00 Food Chemicals Codex Listed: No Specific Gravity: 1.04700 to 1.05700 @ 25.00 °C. Pounds per Gallon - (est).: 8.712 to 8.795 Refractive Index: 1.52300 to 1.52900 @ 20.00 °C. Boiling Point: 177.00 to 179.00 °C. @ 760.00 mm Hg Vapor Pressure: 1.259000 mmHg @ 25.00 °C. (est) Flash Point: 144.00 °F. TCC ( 62.22 °C. ) logP (o/w): 1.766 (est) Soluble in:   alcohol   water, slightly   water, 832.1 mg/L @ 25 °C (est) Insoluble in:   water   Organoleptic Properties: Odor Type: sulfurous sulfurous coffee roasted coffee coffee Odor Description:at 0.10 % in dipropylene glycol. sulfurous roasted coffee Flavor Type: coffee mustard garlic burnt meaty Taste Description: strong mustard garlic burnt meaty Odor and/or flavor descriptions from others (if found).   Cosmetic Information: None found   Suppliers: DeLong Chemicals America 5-Methylfurfurylmercaptan, Kosher Penta International 5-METHYLFURFURYL MERCAPTAN R C Treatt & Co Ltd 5-Methylfurfuryl mercaptan 1% in TEC Kosher   Safety Information:   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: Not determined Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: flavoring agents Recommendation for methyl furfuryl thiol usage levels up to:   not for fragrance use.   Maximised Survey-derived Daily Intakes (MSDI-EU): 0.37 (μg/capita/day) Modified Theoretical Added Maximum Daily Intake (mTAMDI): 160 (μg/person/day) Adequate NOAEL exists: Yes Threshold of Concern: 90 (μg/person/day) Structure Class: III Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library publication number: 25 Click here to view publication 25   average usual ppm average maximum ppm baked goods: - - beverages(nonalcoholic): 0.00500 0.05000 beverages(alcoholic): - - breakfast cereal: - - cheese: - - chewing gum: - - condiments / relishes: - - confectionery froastings: - - egg products: - - fats / oils: - - fish products: - - frozen dairy: - - fruit ices: - - gelatins / puddings: - - granulated sugar: - - gravies: - - hard candy: - - imitation dairy: - - instant coffee / tea: 0.00500 0.05000 jams / jellies: - - meat products: - - milk products: - - nut products: - - other grains: - - poultry: - - processed fruits: - - processed vegetables: - - reconstituted vegetables: - - seasonings / flavors: - - snack foods: - - soft candy: - - soups: - - sugar substitutes: - - sweet sauces: - -   Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.   average usage mg/kg maximum usage mg/kg Dairy products, excluding products of category 02.0 (01.0): 0.40000 2.00000 Fats and oils, and fat emulsions (type water-in-oil) (02.0): 0.20000 1.00000 Edible ices, including sherbet and sorbet (03.0): 0.40000 2.00000 Processed fruit (04.1): 0.30000 1.50000 Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): - - Confectionery (05.0): 0.40000 2.00000 Chewing gum (05.3): - - Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 0.20000 1.00000 Bakery wares (07.0): 0.40000 2.00000 Meat and meat products, including poultry and game (08.0): 0.10000 0.40000 Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): 0.10000 0.40000 Eggs and egg products (10.0): - - Sweeteners, including honey (11.0): - - Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 0.20000 1.00000 Foodstuffs intended for particular nutritional uses (13.0): 0.40000 2.00000 Non-alcoholic ("soft") beverages, excl. dairy products (14.1): 0.20000 1.00000 Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 0.40000 2.00000 Ready-to-eat savouries (15.0): 1.00000 5.00000 Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): 0.20000 1.00000   Safety References: European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... European Food Safety Authority (EFSA) reference(s): Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 13 (FGE.13); Furfuryl and furan derivatives with and without additional side-chain substituents and heteroatoms from chemical group 14 (Commission Regulation (EC) No 1565/2000 of 18 View page or View pdf Scientific Opinion on Flavouring Group Evaluation 13Rev1: Furfuryl and furan derivatives with and without additional side-chain substituents and heteroatoms from chemical group 14 View page or View pdf Consideration of sulfur-substituted furan derivatives used as flavouring agents evaluated by JECFA (59th meeting) structurally related to a subgroup of substances within the group of “Furfuryl and furan derivatives with and without additional side-chain substituents and heteroatoms from chemical group 14” evaluated by EFSA in FGE.13Rev1 (2009) View page or View pdf Flavouring Group Evaluation 67 (FGE.67): Consideration of 40 furan-substituted aliphatic hydrocarbons, alcohols, aldehydes, ketones, carboxylic acids and related esters, sulfides, disulfides and ethers evaluated by JECFA at the 65th meeting (JECFA, 2006b) and re-evaluated at the 69th meeting (JECFA, 2009c) View page or View pdf Scientific Opinion on Flavouring Group Evaluation 13, Revision 2 (FGE.13Rev2): Furfuryl and furan derivatives with and without additional side-chain substituents and heteroatoms from chemical group 14 View page or View pdf Scientific Opinion on Flavouring Group Evaluation 67, Revision 1 (FGE.67Rev.1): Consideration of 40 furan-substituted aliphatic hydrocarbons, alcohols, aldehydes, ketones, carboxylic acids and related esters, sulfides, disulfides and ethers evaluated by JECFA at the 65th meeting (JECFA, 2006b) and re-evaluated at the 69th meeting (JECFA, 2009c) View page or View pdf Scientific Opinion on Flavouring Group Evaluation 13 Revision 3 (FGE.13Rev3): furfuryl and furan derivatives with and without additional side-chain substituents and heteroatoms from chemical group 14 View page or View pdf EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry Laboratory Chemical Safety Summary :521873 National Institute of Allergy and Infectious Diseases:Data (5-methylfuran-2-yl)methanethiol Chemidplus:0059303058   References:   (5-methylfuran-2-yl)methanethiol NIST Chemistry WebBook: Search Inchi Pubchem (cid): 521873 Pubchem (sid): 10528708 Flavornet: 59303-05-8   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements FDA Substances Added to Food (formerly EAFUS): View HMDB (The Human Metabolome Database): HMDB39800 FooDB: FDB019450 YMDB (Yeast Metabolome Database): YMDB01503 VCF-Online: VCF Volatile Compounds in Food ChemSpider: View EFSA Update of results on the monitoring of furan levels in food: Read Report EFSA Previous report: Results on the monitoring of furan levels in food: Read Report EFSA Report of the CONTAM Panel on provisional findings on furan in food: Read Report   Potential Blenders and core components note For Odor alliaceous methyl furfuryl disulfide FL/FR balsamic 2- acetyl furan FL/FR burnt 2- ethyl-3,5(or 6)-dimethyl pyrazine FL/FR caramellic caramel furanone solution FL/FR coffee dione FL/FR cyclotene FL/FR fenugreek oleoresin FL/FR 5- methyl furfural FL/FR chocolate cocoa oleoresin FL/FR 2,6- dimethyl pyrazine FL/FR 2,4,5- trimethyl thiazole FL/FR cocoa 2- methyl butyraldehyde FL/FR coffee cichorium intybus root extract FL/FR cichorium intybus root solid extract FL/FR roasted coffea arabica seed extract FL/FR coffea arabica seed extract FL/FR coffea arabica seed oil FL/FR coffee absolute FL/FR arabica coffee bean butter FL/FR roasted arabica coffee bean essence FL/FR roasted coffee bean extract FL/FR roasted arabica coffee bean oil FL/FR roasted arabica coffee bean oil CO2 extract FL/FR coffee bean oil extract FL/FR coffee difuran FL/FR coffee resinoid FL/FR furfuryl mercaptan FL/FR 1- hydroxy-2-butanone FL/FR 2- methyl-3-,5 or 6-(furfuryl thio) pyrazine FL/FR earthy nutty pyrazine FL/FR fruity tropical thiazole FL/FR herbal wormwood oil america FL/FR wormwood oil italy FL/FR wormwood oil poland FL/FR medicinal 2,6- xylenol FL/FR moldy strawberry furanone methyl ether FL/FR musty menthofuran FL/FR nutty 3,6- cocoa pyrazine FL/FR 3,5- cocoa pyrazine FL/FR 2,3- dimethyl pyrazine FL/FR 4,5- dimethyl-2-ethyl-3-thiazoline FL/FR 2- ethyl pyrazine FL/FR 2- ethyl-4-methyl thiazole FL/FR filbert heptenone FL/FR filbert heptenone B FL/FR 5- methyl quinoxaline FL/FR sesame absolute FL/FR sesame absolute CO2 extract FL/FR 2,3,5,6- tetramethyl pyrazine FL/FR phenolic para-alpha- dimethyl styrene FL/FR popcorn 2- acetyl pyrazine FL/FR roasted fenugreek resinoid FL/FR trigonella foenum-graecum seed oil CO2 extract FL/FR sulfurous benzothiazole FL/FR cocoa essence FL/FR ethyl 3-mercaptobutyrate FL/FR furfuryl thioacetate FL/FR S- furfuryl thioformate FL/FR 2- methyl 5-(methyl thio) furan FL/FR 3- thiohexanol FL/FR sweet 2- hydroxy-3,4,5-trimethyl-2-cyclopenten-1-one FL/FR tobacco methyl benzoxole FL/FR vegetable 1- furfuryl pyrrole FL/FR woody juniper berry oleoresin FL/FR For Flavor No flavor group found for these 2- acetyl-6-methyl pyrazine FL 1,2- butane dithiol FL dimethyl dihydrocyclopentapyrazine FL (Z+E)-2,5- dimethyl-3-tetrahydrofuran thiol FL (Z+E)-2,5- dimethyl-3-thioacetoxytetrahydrofuran FL 2,5- dimethyl-3-thiofuroyl furan FL ethyl 3-mercaptobutyrate FL/FR 2- ethyl-3,5(or 6)-dimethyl pyrazine FL/FR 2- ethyl-5(or6)-methyl pyrazine FL 2- formyl pyrrole FL 2- hydroxy-3,4,5-trimethyl-2-cyclopenten-1-one FL/FR 3- mercapto-3-methyl butyl formate FL methyl dihydrofuran thiol FL methyl methane thiosulfonate FL methyl octyl sulfide FL 2- methyl-3-,5 or 6-(furfuryl thio) pyrazine FL/FR pyrazines mixture FL alliaceous alliaceous benzyl mercaptan FL 1,3- butane dithiol FL dicyclohexyl disulfide FL tropical thiazole FL/FR brown fenugreek oleoresin FL/FR 1- hydroxy-2-butanone FL/FR 5- methyl furfural FL/FR burnt furfuryl alcohol FL 2- methyl quinoxaline FL 2,6- xylenol FL/FR caramellic caramel furanone FL caramel furanone solution FL/FR cyclotene FL/FR fenugreek resinoid FL/FR chocolate cocoa essence FL/FR cocoa oleoresin FL/FR coffee cichorium intybus root extract FL/FR cichorium intybus root solid extract FL/FR coffea arabica seed extract FL/FR roasted coffea arabica seed extract FL/FR coffea arabica seed oil FL/FR coffee absolute FL/FR arabica coffee bean butter FL/FR roasted arabica coffee bean essence FL/FR roasted coffee bean extract FL/FR roasted arabica coffee bean oil CO2 extract FL/FR coffee bean oil extract FL/FR coffee difuran FL/FR coffee dione FL/FR coffee distillates FL coffee pyrazine FL coffee resinoid FL/FR difurfuryl ether FL diisoamyl thiomalate FL 2,4- dimethyl thiazole FL 2- ethyl-4-methyl thiazole FL/FR furfuryl mercaptan FL/FR methyl furfuryl disulfide FL/FR 2- thiophene thiol FL earthy difurfuryl sulfide FL fruity furfuryl isobutyrate FL furfuryl isovalerate FL furfuryl propionate FL fusel 2- methyl butyraldehyde FL/FR green 2- methyl-5-isopropyl pyrazine FL herbal wormwood oil america FL/FR wormwood oil italy FL/FR wormwood oil poland FL/FR meaty benzothiazole FL/FR 2,6- dimethyl pyrazine FL/FR 3- mercapto-2-butanone FL (R,S)-2- mercapto-3-butanol FL 2- methyl 3-(methyl thio) furan FL bis(2- methyl-3-furyl) disulfide FL S-(2- methyl-3-furyl) ethane thioate FL 2- methyl-3-thioacetoxytetrahydrofuran FL milky dextro,laevo-3-( methyl thio) butanone FL molasses molasses blackstrap FL moldy strawberry furanone methyl ether FL/FR mustard furfuryl methyl ether FL musty 2- ethoxythiazole FL menthofuran FL/FR 2- methyl 5-(methyl thio) furan FL/FR nutty 2- acetyl furan FL/FR 3,5- cocoa pyrazine FL/FR 3,6- cocoa pyrazine FL/FR 2,3- dimethyl pyrazine FL/FR 4,5- dimethyl-2-ethyl-3-thiazoline FL/FR 2- ethyl pyrazine FL/FR 1- ethyl-2-acetyl pyrrole FL filbert heptenone FL/FR filbert heptenone B FL/FR methyl benzoxole FL/FR 5- methyl quinoxaline FL/FR nutty pyrazine FL/FR nutty thiazole FL sesame absolute FL/FR sesame absolute CO2 extract FL/FR 2,3,5,6- tetramethyl pyrazine FL/FR 2,4,5- trimethyl thiazole FL/FR onion furfuryl isopropyl sulfide FL phenolic 2- ethyl benzene thiol FL roasted 2- acetyl pyrazine FL/FR roasted arabica coffee bean oil FL/FR ethyl 3-(furfuryl thio) propionate FL furfuryl thioacetate FL/FR trigonella foenum-graecum seed oil CO2 extract FL/FR solvent 2- ethyl furan FL spicy para-alpha- dimethyl styrene FL/FR sulfurous 2,3- butane dithiol FL butyl mercaptan FL ethyl methyl sulfide FL S- ethyl thioacetate FL S- furfuryl thioformate FL/FR furfuryl thiopropionate FL 3- methyl-2-butane thiol FL potato butanone FL roasted butanol FL 2- thienyl mercaptan FL 3- thiohexanol FL/FR vegetable 1- furfuryl pyrrole FL/FR woody juniper berry oleoresin FL/FR   Potential Uses: FL cereal FL chocolate FL chocolate cocoa FL coffee   fruit juice FL meat FL milk FL tea FL vegetable   Occurrence (nature, food, other):note   coffee - up to 0.2 mg/kg Search PMC Picture   sesame roasted sesame Search Trop Picture   Synonyms: 2- furanmethanethiol, 5-methyl- 5- methyl furfuryl mercaptan (5- methyl furfuryl) mercaptan 5- methyl-2-furan methane thiol 5- methyl-2-furanmethanethiol 5- methyl-2-furfuryl thiol 5- methyl-2-furfurylthiol (5- methyl-2-furyl)methanethiol (5- methylfuran-2-yl)methanethiol   methylfurfuryl mercaptan 5- methylfurfurylmercaptan   methylfurfurylthiol   Articles: Google Patents:Flavour precursors US Patents:3,993,792 - Flavoring agent Leffingwell & Associates:Flavor Properties of FEMA GRAS List 25 flavor chemicals

Notes: Cysteine-derived Maillard product. Constit. of coffee, roasted sesame and yeast-extract volatiles