(Z+E)-mercapto-para-menthan-3-one
cis- and trans-L-mercapto-p-menthan-3-one

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  Endeavour Specialty Chemicals Ltd

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  Endeavour Speciality Chemicals offers high-impact aroma chemicals, at small to medium scale.
  Speciality Chemical has more than 25 years experience of manufacturing high-impact aroma chemicals. With our core expertise in sulfur and heterocyclic chemistries, Endeavours products have applications in a range of industry sectors including flavours and fragrances, pharmaceutical research and material sciences. Endeavour also offer custom synthesis and contract manufacturing services at their UK manufacturing site.
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  TH0660 Mercapto-p-menthan-3-one

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  Robinson Brothers Limited

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  Based in the UK, Robinson Brothers is an award-winning chemical manufacturer of chemical intermediates and high-impact aroma chemicals. Robinson Brothers serve many industry sectors across the globe, include: flavour/fragrance, pharmaceutical, agrochemical and material sciences. Our team of Chemists are experts in custom synthesis, contract manufacture and process optimisation.
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  TH0660 Mercapto-p-menthan-3-one

Name: (Z+E)-laevo-mercapto-para-menthan-3-one CAS Number: 29725-66-4 3D/inchi % from: 89.00% to 91.00% FDA UNII: A451PTS4VT XlogP: 2.66 (est) Molecular Weight: 186.31766000 Formula: C10 H18 O S NMR Predictor: Predict (works with chrome, Edge or firefox) Also(can) Contains: piperitone 8.00% to 9.00%   alpha-terpineol 1.00% to 2.00% EFSA/JECFA Comments: Minimum assay (89%) (EFFA, 2006u). Secondary components are piperitone (8-9 %) and alpha-terpineol (1-2 %) (California Department of Pest. Regulation, 1987 ). Category:flavoring agents   US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: Google Scholar: Search Google Books: Search Google Scholar: with word "volatile" Search Google Scholar: with word "flavor" Search Google Scholar: with word "odor" Search Perfumer and Flavorist: Search Google Patents: Search US Patents: Search EU Patents: Search PubMed: Search NCBI: Search JECFA Food Flavoring: 1673 cis- and trans-mercapto-p-menthan-3-one DG SANTE Food Flavourings: 12.259 1-mercapto-p-menthane-3-one FEMA Number: 4300 cis- and trans-L-mercapto-p-menthan-3-one FDA: No longer provide for the use of these seven synthetic flavoring substances FDA Mainterm (SATF): 29725-66-4 ; CIS- AND TRANS-L-MERCAPTO-P-MENTHAN-3-ONE   Physical Properties: Appearance: colorless to pale yellow clear liquid (est) Assay: 89.00 to 100.00 Food Chemicals Codex Listed: No Specific Gravity: 0.98900 to 0.99900 @ 25.00 °C. Pounds per Gallon - (est).: 8.229 to 8.313 Refractive Index: 1.48700 to 1.49700 @ 20.00 °C. Boiling Point: 119.00 to 123.00 °C. @ 10.00 mm Hg Boiling Point: 261.00 to 262.00 °C. @ 760.00 mm Hg (est) Vapor Pressure: 0.012000 mmHg @ 25.00 °C. (est) Flash Point: 233.00 °F. TCC ( 111.90 °C. ) (est) logP (o/w): 2.474 (est) Soluble in:   alcohol   water, 218.4 mg/L @ 25 °C (est) Insoluble in:   water   Organoleptic Properties: Odor Description:at 0.10 % in propylene glycol. citrus Odor and/or flavor descriptions from others (if found).   Cosmetic Information: None found   Suppliers: Endeavour Specialty Chemicals Mercapto-p-menthan-3-one Speciality Chemical Product Groups Parchem (Z+E)-laevo-mercapto-para-menthan-3-one Robinson Brothers Mercapto-p-menthan-3-one https://www.robinsonbrothers.uk/chemistry-competences Chemical Sources Association Need This Item for Flavor/Food?: You can contact the Chemical Sources Association   Safety Information:   Hazards identification   Classification of the substance or mixture GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) None found. GHS Label elements, including precautionary statements   Pictogram   Hazard statement(s) None found. Precautionary statement(s) None found. Oral/Parenteral Toxicity: Not determined Dermal Toxicity: Not determined Inhalation Toxicity: Not determined   Safety in Use Information: Category: flavoring agents Recommendation for (Z+E)-mercapto-para-menthan-3-one usage levels up to:   not for fragrance use.   Maximised Survey-derived Daily Intakes (MSDI-EU): 1.60 (μg/capita/day) Maximised Survey-derived Daily Intakes (MSDI-USA): ND (μg/capita/day) Modified Theoretical Added Maximum Daily Intake (mTAMDI): 7 (μg/person/day) NOEL (No Observed Effect Level): 0.7 (mg/kg bw per day) Threshold of Concern: 540 (μg/person/day) Structure Class: II Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library publication number: 23 Click here to view publication 23   average usual ppm average maximum ppm baked goods: 0.10000 0.50000 beverages(nonalcoholic): 1.00000 5.00000 beverages(alcoholic): 1.00000 5.00000 breakfast cereal: - - cheese: 0.01000 0.05000 chewing gum: - - condiments / relishes: 0.01000 0.05000 confectionery froastings: 1.00000 5.00000 egg products: - - fats / oils: 0.01000 0.05000 fish products: 0.01000 0.05000 frozen dairy: 0.01000 0.05000 fruit ices: 0.10000 0.50000 gelatins / puddings: 0.01000 0.05000 granulated sugar: - - gravies: 0.01000 0.05000 hard candy: - - imitation dairy: 0.01000 0.05000 instant coffee / tea: - - jams / jellies: - - meat products: 0.01000 0.05000 milk products: 0.01000 0.05000 nut products: - - other grains: - - poultry: 0.01000 0.05000 processed fruits: 0.01000 0.05000 processed vegetables: 0.01000 0.05000 reconstituted vegetables: - - seasonings / flavors: 0.01000 0.05000 snack foods: - - soft candy: - - soups: 0.01000 0.05000 sugar substitutes: - - sweet sauces: 0.01000 0.05000   Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.   average usage mg/kg maximum usage mg/kg Dairy products, excluding products of category 02.0 (01.0): 0.00100 0.01000 Fats and oils, and fat emulsions (type water-in-oil) (02.0): - - Edible ices, including sherbet and sorbet (03.0): 0.02000 0.05000 Processed fruit (04.1): - - Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): 0.01000 0.03000 Confectionery (05.0): 0.02000 0.05000 Chewing gum (05.3): 0.02000 0.10000 Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): 0.00100 0.01000 Bakery wares (07.0): 0.00100 0.01000 Meat and meat products, including poultry and game (08.0): 0.02000 0.05000 Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): 0.00100 0.01000 Eggs and egg products (10.0): - - Sweeteners, including honey (11.0): - - Salts, spices, soups, sauces, salads, protein products, etc. (12.0): 0.02000 0.03000 Foodstuffs intended for particular nutritional uses (13.0): - - Non-alcoholic ("soft") beverages, excl. dairy products (14.1): 0.01000 0.02000 Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): 0.01000 0.03000 Ready-to-eat savouries (15.0): - - Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): - -   Safety References: European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... European Food Safety Authority (EFSA) reference(s): Flavouring Group Evaluation 91 (FGE.91): Consideration of simple aliphatic and aromatic sulphides and thiols evaluated by JECFA (53rd and 68th meetings) structurally related to aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups evaluated by EFSA in FGE.08Rev1 (2009) View page or View pdf Scientific Opinion on Flavouring Group Evaluation 91, Revision 1 (FGE.91Rev1): Consideration of simple aliphatic and aromatic sulphides and thiols evaluated by JECFA (53rd and 68th meetings) structurally related to aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups evaluated by EFSA in FGE.08Rev3 (2011) View page or View pdf Statement on List of Representative Substances for Testing. The current Statement lays down a list of substances in sub-groups with representative substances for which additional data are required prior to their evaluation through the Procedure (Regulation (EC) No 1565/2000). View page or View pdf Scientific Opinion on Flavouring Group Evaluation 91, Revision 2 (FGE.91Rev2): Consideration of simple aliphatic and aromatic sulphides and thiols evaluated by the JECFA (53rd and 68th meetings) structurally related to aliphatic and alicyclic mono-, di-, tri-, and polysulphides with or without additional oxygenated functional groups evaluated by EFSA in FGE.08Rev5 (2012) View page or View pdf Scientific Opinion on Flavouring Group Evaluation 91, Revision 3 (FGE.91Rev3): consideration of aliphatic, aromatic and a,ß-unsaturated sulfides and thiols evaluated by JECFA (53rd, 61st, 68th and 76th meetings), structurally related to substances in FGE.08Rev5 View page or View pdf EPI System: View AIDS Citations:Search Cancer Citations:Search Toxicology Citations:Search EPA ACToR:Toxicology Data EPA Substance Registry Services (SRS):Registry National Institute of Allergy and Infectious Diseases:Data (Z+E)-laevo-mercapto-para-menthan-3-one Chemidplus:0029725664   References:   (Z+E)-laevo-mercapto-para-menthan-3-one NIST Chemistry WebBook: Search Inchi Pubchem (sid): 135323547   Other Information: (IUPAC): Atomic Weights of the Elements 2011 (pdf) Videos: The Periodic Table of Videos tgsc: Atomic Weights use for this web site (IUPAC): Periodic Table of the Elements FDA Substances Added to Food (formerly EAFUS): View HMDB (The Human Metabolome Database): HMDB32205 FooDB: FDB009186 VCF-Online: VCF Volatile Compounds in Food ChemSpider: View   Potential Blenders and core components note For Odor No odor group found for these (E)-5- nonen-2-one FL/FR (E)- tiglaldehyde FL/FR aldehydic aldehydic iso valeraldehyde FL/FR animal para- cresyl isobutyrate FL/FR balsamic iso amyl benzoate FL/FR fir carboxylate FR caramellic maltyl isobutyrate FL/FR citrus bergamot acetoacetate FR 2- heptanol FL/FR ocimene quintoxide FL/FR coconut delta- decalactone FL/FR delta- undecalactone FL/FR ethereal 2- methyl valeraldehyde FL/FR propyl formate FL/FR iso valeraldehyde propylene glycol acetal FL/FR fatty 3- decen-2-one FL/FR hexyl pivalate FR methyl (E)-2-hexenoate FL/FR methyl 2-hexenoate FL/FR fermented 3- methyl-1-pentanol FL/FR valeraldehyde FL/FR floral alpha- amyl cinnamaldehyde diethyl acetal FR boronia absolute FL/FR citronellyl propionate FL/FR cyclohexyl propanol FR gamma- damascone FR 6,8- dimethyl-2-nonanol FR (E)- geranyl acetone FL/FR beta- ionone FL/FR lily propanol FR papaya isobutyrate FL/FR phenethyl acetate FL/FR rose carboxylate FR fruity acetaldehyde dihexyl acetal FL/FR allyl 2-ethyl butyrate FL/FR allyl amyl glycolate FR allyl butyrate FL/FR iso amyl butyrate FL/FR amyl hexanoate FL/FR iso amyl isovalerate FL/FR iso amyl octanoate FL/FR 3- benzyl-4-heptanone FL/FR berry hexanoate FR berry pentadienoate FL/FR butyl 2-decenoate FL/FR butyl 2-methyl butyrate FL/FR butyl hexanoate FL/FR butyl isobutyrate FL/FR iso butyl propionate FL/FR cherry pentenoate FL/FR cyclohexyl cinnamate FL/FR 2- cyclopentyl cyclopentanone FL/FR decen-1-yl cyclopentanone FL/FR diethyl malonate FL/FR dimethyl succinate FL/FR epsilon- dodecalactone FL/FR ethyl 2-cyclohexyl propionate FR ethyl 2-hydroxy-3-methyl valerate FL/FR ethyl 2-octenoate FL/FR ethyl 3-acetoxyhexanoate FL/FR ethyl 3,5,5-trimethyl hexanoate FR ethyl acetoacetate FL/FR ethyl methyl-para-tolyl glycidate FL/FR fleuramone (IFF) FR fruity butanate FR fruity cyclopentanone FR geranyl isovalerate FL/FR heliotropyl isobutyrate FL/FR heptanal cyclic ethylene acetal FR heptyl isobutyrate FL/FR hexanal propylene glycol acetal FL/FR 2- hexen-1-ol FL/FR (Z)-3- hexen-1-yl 2-methyl-2-pentenoate FR (E)-3- hexen-1-yl acetate FL/FR (Z)-3- hexen-1-yl isobutyrate FL/FR hexyl (E)-tiglate FL/FR hexyl acetate FL/FR hexyl isovalerate FL/FR hexyl propionate FL/FR beta- ionone epoxide FL/FR linalyl hexanoate FL/FR methyl 2-methyl valerate FL/FR methyl 3-nonenoate FL/FR 2- methyl butyl 2-methyl butyrate FL/FR methyl heptanoate FL/FR methyl valerate FL/FR nerolidyl isobutyrate FR 3- nonen-2-one FL/FR octen-1-yl cyclopentanone FL/FR octyl butyrate FL/FR osmanthus flower absolute FL/FR peach cyclopentanone FR peach pivalate FR 2- pentyl furan FL/FR 4- phenyl-2-butyl acetate FL/FR pineapple pentenoate FL/FR prenyl ethyl ether FL/FR prenyl hexanoate FL/FR iso propenyl acetate FL/FR iso propyl 2-methyl butyrate FL/FR propyl isobutyrate FL/FR rhubarb undecane FR styralyl butyrate FL/FR tetrahydrofurfuryl butyrate FL/FR tropical indene FR tropical thiazole FL/FR gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR vanilla carboxylate FL/FR green acetaldehyde benzyl 2-methoxyethyl acetal FL/FR acetaldehyde methyl hexyl acetal FR iso amyl formate FL/FR cognac heptanone FL/FR alpha- decalactone FL/FR ethyl (E,Z)-2,4-decadienoate FL/FR ethyl (E)-2-hexenoate FL/FR ethyl (E)-4-decenoate FL/FR green dioxolane FR heptanal dimethyl acetal FL/FR (Z)-3- hexen-1-yl (E)-2-hexenoate FL/FR (Z)-3- hexen-1-yl 2-methyl butyrate FL/FR (E)-2- hexen-1-yl acetate FL/FR (Z)-3- hexen-1-yl acetate FL/FR (E)-2- hexen-1-yl formate FL/FR (E)-2- hexen-1-yl hexanoate FL/FR (Z)-3- hexen-1-yl hexanoate FL/FR (Z)-3- hexen-1-yl isovalerate FL/FR (E)-2- hexen-1-yl propionate FL/FR (Z)-3- hexen-1-yl valerate FL/FR (E)-2- hexen-1-yl valerate FL/FR 2- hexenyl acetate FL/FR hexyl butyrate FL/FR hexyl isobutyrate FL/FR hexyl octanoate FL/FR manzanate (Givaudan) FL/FR (E)-2- pentenal FL/FR phenoxyethyl isobutyrate FL/FR alpha-iso propyl phenyl acetaldehyde FL/FR propylene acetal FL/FR sorbyl isobutyrate FL/FR thiogeraniol FL/FR violet dienyne FR herbal benzyl octanoate FL/FR buchu oxime FR tricyclodecyl acetate FR viridiflorol FL/FR licorice sweet basil oleoresin FL/FR mentholic menthyl acetate racemic FL/FR minty diosphenol FL/FR ethyl salicylate FL/FR methyl salicylate FL/FR iso propyl tiglate FL/FR (R)-(+)- pulegone FR iso pulegyl formate FL/FR soapy ambrettolide FL/FR sulfurous blackberry thiophenone FL/FR buchu mercaptan FL/FR cassis pentanone FL/FR mango thiol FL/FR passiflora acetate FL/FR tropical beta- cyclocitral FL/FR glyceryl 5-hydroxydecanoate FL/FR glyceryl 5-hydroxydodecanoate FL/FR waxy 9- decenoic acid FL/FR (E)- methyl geranate FL/FR (E)-2- octen-1-yl butyrate FL/FR octyl 2-methyl butyrate FL/FR woody verdoxan FR woody acetate FR For Flavor No flavor group found for these acetaldehyde benzyl 2-methoxyethyl acetal FL/FR allyl cyclohexyl valerate FL allyl tiglate FL benzyl octanoate FL/FR blackberry thiophenone FL/FR 2- cyclopentyl cyclopentanone FL/FR alpha- decalactone FL/FR epsilon- dodecalactone FL/FR ethyl 2-hydroxy-3-methyl valerate FL/FR ethyl 3-acetoxyhexanoate FL/FR (E,E)-2,4- heptadien-1-ol FL 2- hexenal FL 2- hexenal diethyl acetal FL 2- hexenyl acetate FL/FR hexyl (E)-2-hexenoate FL hexyl propionate FL/FR beta- ionone epoxide FL/FR linalyl hexanoate FL/FR menthyl acetate racemic FL/FR methyl (E)-2-hexenoate FL/FR methyl 2-hexenoate FL/FR methyl 4-pentenoate FL (E)- methyl geranate FL/FR 2- methyl-2-octenal FL (E)-2- methyl-2-octenal FL 3- methyl-3-pentanol FL (E)-5- nonen-2-one FL/FR (E,E)-3,5- octadien-2-one FL (E)-2- octen-1-yl butyrate FL/FR (E)-2- octen-4-ol FL 4- phenyl-2-butyl acetate FL/FR prenyl ethyl ether FL/FR prenyl hexanoate FL/FR alpha-iso propyl phenyl acetaldehyde FL/FR propylene acetal FL/FR iso pulegyl formate FL/FR (E)- tiglaldehyde FL/FR viridiflorol FL/FR sorbyl isobutyrate FL/FR alliaceous alliaceous tropical thiazole FL/FR aromatic para- cresyl isobutyrate FL/FR berry heptyl isobutyrate FL/FR citrus cognac heptanone FL/FR coconut delta- decalactone FL/FR coffee 2-iso propyl pyrazine FL cooling manzanate (Givaudan) FL/FR creamy glyceryl 5-hydroxydecanoate FL/FR glyceryl 5-hydroxydodecanoate FL/FR massoia lactone FL delta- undecalactone FL/FR gamma- undecalactone (aldehyde C-14 (so-called)) FL/FR earthy 1- hexen-3-yl acetate FL estery ethyl acetoacetate FL/FR ethereal allyl 2-ethyl butyrate FL/FR iso propenyl acetate FL/FR fatty ethyl (E)-4-decenoate FL/FR floral citronellyl propionate FL/FR (E)- geranyl acetone FL/FR fruity iso amyl benzoate FL/FR amyl hexanoate FL/FR iso amyl octanoate FL/FR 3- benzyl-4-heptanone FL/FR berry pentadienoate FL/FR boronia absolute FL/FR butyl 2-decenoate FL/FR butyl 2-methyl butyrate FL/FR butyl hexanoate FL/FR butyl isobutyrate FL/FR iso butyl propionate FL/FR cherry pentenoate FL/FR cyclohexyl cinnamate FL/FR decen-1-yl cyclopentanone FL/FR diethyl malonate FL/FR dimethyl succinate FL/FR ethyl (E)-2-hexenoate FL/FR ethyl (E)-2-octenoate FL ethyl 2-octenoate FL/FR ethyl 3-oxohexanoate FL ethyl methyl-para-tolyl glycidate FL/FR furfuryl propionate FL heliotropyl isobutyrate FL/FR 2- heptanol FL/FR hexanal propylene glycol acetal FL/FR 2- hexen-1-ol FL/FR (Z)-3- hexen-1-yl (E)-2-hexenoate FL/FR (E)-3- hexen-1-yl acetate FL/FR (Z)-3- hexen-1-yl isobutyrate FL/FR hexyl acetate FL/FR methyl (E)-3-nonenoate FL methyl 2-methyl valerate FL/FR methyl 3-nonenoate FL/FR 2- methyl butyl 2-methyl butyrate FL/FR methyl heptanoate FL/FR methyl valerate FL/FR octen-1-yl cyclopentanone FL/FR osmanthus flower absolute FL/FR pineapple pentenoate FL/FR iso propyl 2-methyl butyrate FL/FR propyl formate FL/FR propyl isobutyrate FL/FR styralyl butyrate FL/FR tetrahydrofurfuryl butyrate FL/FR iso valeraldehyde FL/FR iso valeraldehyde propylene glycol acetal FL/FR vanilla carboxylate FL/FR green acetaldehyde dihexyl acetal FL/FR allyl butyrate FL/FR iso amyl formate FL/FR iso amyl isovalerate FL/FR cassis pentanone FL/FR 3- decen-2-one FL/FR ethyl (E,Z)-2,4-decadienoate FL/FR geranyl isovalerate FL/FR heptanal dimethyl acetal FL/FR (Z)-3- hexen-1-yl 2-methyl butyrate FL/FR (Z)-3- hexen-1-yl acetate FL/FR (E)-2- hexen-1-yl acetate FL/FR (Z)-3- hexen-1-yl hexanoate FL/FR (E)-2- hexen-1-yl hexanoate FL/FR (Z)-3- hexen-1-yl isovalerate FL/FR (E)-2- hexen-1-yl propionate FL/FR (E)-2- hexen-1-yl valerate FL/FR (Z)-3- hexen-1-yl valerate FL/FR (E)-2- hexenal diethyl acetal FL hexyl (E)-tiglate FL/FR hexyl butyrate FL/FR hexyl isobutyrate FL/FR hexyl isovalerate FL/FR hexyl octanoate FL/FR methyl 2-undecynoate FL ocimene quintoxide FL/FR papaya isobutyrate FL/FR (E)-2- pentenal FL/FR 2- pentyl furan FL/FR phenoxyethyl isobutyrate FL/FR iso propyl tiglate FL/FR thiogeraniol FL/FR honey phenethyl acetate FL/FR jammy maltyl isobutyrate FL/FR licorice sweet basil oleoresin FL/FR minty diosphenol FL/FR ethyl salicylate FL/FR methyl salicylate FL/FR oily 3- nonen-2-one FL/FR rummy (E)-2- hexen-1-yl formate FL/FR soapy ambrettolide FL/FR sour 3- methyl valeric acid FL sulfurous buchu mercaptan FL/FR mango thiol FL/FR methyl 2-(methyl thio) butyrate FL methyl thiomethyl butyrate FL tropical beta- cyclocitral FL/FR passiflora acetate FL/FR vegetable 2- methyl valeraldehyde FL/FR potato butyraldehyde FL waxy iso amyl butyrate FL/FR 9- decenoic acid FL/FR octyl 2-methyl butyrate FL/FR octyl butyrate FL/FR whiskey 3- methyl-1-pentanol FL/FR winey valeraldehyde FL/FR woody beta- ionone FL/FR   Potential Uses: FL citrus   Occurrence (nature, food, other):note   found in nature   Synonyms: (Z+E)- mercapto-p-menthan-3-one cis- and trans- mercapto-p-menthan-3-one cis- and trans-L- mercapto-p-menthan-3-one   mercapto-p-menthan-3-one, cis- and trans- 1- mercapto-p-menthane-3-one cis+trans- mercapto-para-menthan-3-one   Articles: PubMed:Odor similarity between stress-inducing odorants in wistar rats.

Notes: Used as a food additive [EAFUS]