| Name: | (2E,6Z)-1,1-diethoxynona-2,6-diene |
| CAS Number: | 67674-36-6 |  3D/inchi
|
| % from: | 85.00% to 99.90% |
| ECHA EINECS - REACH Pre-Reg: | 266-874-2 |
| FDA UNII: | V5C72V7U8P |
| CoE Number: | 660 |
| XlogP3-AA: | 3.30 (est) |
| Molecular Weight: | 212.33268000 |
| Formula: | C13 H24 O2 |
| NMR Predictor: | Predict (works with chrome, Edge or firefox) |
| Name: | (2E,6E)-1,1-diethoxynona-2,6-diene |
| CAS Number: | 67674-36-6 (EE) |  3D/inchi
|
| % from: | 0.10% to 15.00% |
| FDA UNII: | Search |
| Nikkaji Web: | J798.303D |
| XlogP3-AA: | 3.30 (est) |
| Molecular Weight: | 212.33268000 |
| Formula: | C13 H24 O2 |
| NMR Predictor: | Predict (works with chrome, Edge or firefox) |
| EFSA/JECFA Comments: |
| CASrn refers to (2Z,6Z)-isomer.
The chemical name should be changed to 1,1-Diethoxynona-(2E,6Z)-diene, to refect the stereochemical confguration of the favouring substance. The purity requirement for the named compound [FL-no: 06.025] in the UL should be updated according to the specifcations provided.(Documentation provided to EFSA n. 2)
90% sum of isomers (82% (2E,6Z)-isomer and 8% other geometric isomers: 2–6% (2E,6E), 1–4% (2Z,6E) and 1–2% (2Z,6Z) SC: 8% 2-nonenal diethyl acetal |
Category:flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
Organoleptic Properties:
| Odor Type: green |
| Odor Strength:medium |
| Substantivity:92 hour(s) at 100.00 % |
| green cucumber fresh oily painty |
Odor Description:at 100.00 %. green cucumber fresh oily painty
Luebke, William tgsc, (1996) |
| Odor sample from: Bedoukian Research, Inc. |
| Flavor Type: green |
| green oily cucumber fatty melon seedy lard |
Taste Description: green oily cucumber fatty melon seedy lard
Luebke, William tgsc, (1996) |
| Odor and/or flavor descriptions from others (if found). |
| Bedoukian Research |
| e,z-2,6-NONADIEN-1-AL DIETHYL ACETAL ≥85.0% (e,z), Kosher |
Odor Description:smooth violet, melon
Used in galbanum and Oakmoss blends. |
Taste Description:Strong cucumber, melon
Very good for melon, cucumber, and strawberry. |
| FCI SAS |
| TRANS-2-CIS-6-NONADIENAL DIETHYL ACETAL |
| Odor Description:Smooth violet-melon |
| Taste Description:green cucumber melon |
Cosmetic Information:
Suppliers:
| Bedoukian Research |
| e,z-2,6-NONADIEN-1-AL DIETHYL ACETAL
≥85.0% (e,z), Kosher Odor: smooth violet, melon Use: Used in galbanum and Oakmoss blends. Flavor: Strong cucumber, melon Very good for melon, cucumber, and strawberry. |
| BOC Sciences |
| For experimental / research use only. |
| 2,6-Nonadiene,1,1-diethoxy-, (2E,6Z)- 95.0% (sum of isomers)
|
| EGNO Chimie |
| TRANS 2 CIS 6 NONADIENAL DEA
|
| FCI SAS |
| TRANS-2-CIS-6-NONADIENAL DIETHYL ACETAL
Odor: Smooth violet-melon |
| Parchem |
| (E,Z)-2,6-nonadien-1-al diethyl acetal
|
| Penta International |
| 2,6-NONADIENAL DIETHYL ACETAL
|
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | None - None found. |
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 36 - Wear suitable protective clothing.
|
| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
|
Not determined
|
| Dermal Toxicity: |
|
Not determined
|
| Inhalation Toxicity: |
|
Not determined
|
Safety in Use Information:
| Category: | | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| Recommendation for (E,Z)-2,6-nonadienal diethyl acetal usage levels up to: | | | 0.5000 % in the fragrance concentrate.
|
| |
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 0.01 (μg/capita/day) |
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 0.01 (μg/capita/day) |
| Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 1700 (μg/person/day) |
| Threshold of Concern: | 1800 (μg/person/day) |
| Structure Class: | I |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 6 |
| Click here to view publication 6 |
| | average usual ppm | average maximum ppm |
| baked goods: | - | - |
| beverages(nonalcoholic): | - | - |
| beverages(alcoholic): | - | - |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | - | - |
| condiments / relishes: | - | 0.10000 |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | - | 0.10000 |
| fruit ices: | - | 0.10000 |
| gelatins / puddings: | - | - |
| granulated sugar: | - | - |
| gravies: | - | 0.10000 |
| hard candy: | - | 0.10000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | 0.10000 |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | 0.10000 |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
| |
| Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). |
| Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. |
| | average usage mg/kg | maximum usage mg/kg |
| Dairy products, excluding products of category 02.0 (01.0): | 5.70000 | 12.00000 |
| Fats and oils, and fat emulsions (type water-in-oil) (02.0): | 1.50000 | 14.25000 |
| Edible ices, including sherbet and sorbet (03.0): | - | - |
| Processed fruit (04.1): | - | - |
| Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | 5.00000 | 5.03000 |
| Confectionery (05.0): | 5.50000 | 14.46000 |
| Chewing gum (05.3): | 6.02000 | 20.87000 |
| Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 4.80000 | 11.55000 |
| Bakery wares (07.0): | 6.00000 | 17.00000 |
| Meat and meat products, including poultry and game (08.0): | 0.90000 | 2.98000 |
| Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | - | - |
| Eggs and egg products (10.0): | - | - |
| Sweeteners, including honey (11.0): | - | - |
| Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 2.00000 | 5.00000 |
| Foodstuffs intended for particular nutritional uses (13.0): | - | - |
| Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | 2.00000 | 4.43000 |
| Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 1.00000 | 2.00000 |
| Ready-to-eat savouries (15.0): | 2.50000 | 4.50000 |
| Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | - | - |
Safety References:
European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
|
European Food Safety Authority (EFSA) reference(s):
|
Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 3 (FGE.03); Acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated aldehydes, and a orthoester of formic acid, from chemical groups 1 and 2 (Commission Regulation (EC) No 1565/2000 of 18 July 2000)
View page or View pdf
|
Flavouring Group Evaluation 3, Revision 1 (FGE.03Rev1): Acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated or unsaturated aldehydes, an ester of a hemiacetal and an orthoester of formic acid, from chemical groups 1, 2 & 4 Commission Regulation (EC) No 1565/2000 of 18 July 2000) [1] - Scientific Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)on a request from the Commission
View page or View pdf
|
Scientific Opinion on Flavouring Group Evaluation 3, Revision 2 (FGE.03Rev2): Acetals of branched- and straight-chain aliphatic saturated primary alcohols and branched- and straight-chain saturated or unsaturated aldehydes, an ester of a hemiacetal and an orthoester of formic acid, from chemical groups 1, 2 and 4
View page or View pdf
|
EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF)
View page or View pdf
|
Scientific Opinion on Flavouring Group Evaluation 200, Revision 1 (FGE.200 Rev.1): 74 a,ß-unsaturated aliphatic aldehydes and precursors from chemical subgroup 1.1.1 of FGE.19
View page or View pdf
|
Scientific Opinion on Flavouring Group Evaluation 61 Revision 2 (FGE.61Rev2): consideration of aliphatic acetals evaluated by JECFA (57th, 63rd and 68th meetings) structurally related to acetals evaluated by EFSA in FGE.03Rev2
View page or View pdf
|
| EPI System: View |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA Substance Registry Services (TSCA):67674-36-6 |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :6364671 |
| National Institute of Allergy and Infectious Diseases:Data |
| WGK Germany:2 |
| (2E,6Z)-1,1-diethoxynona-2,6-diene |
| Chemidplus:0067674366 |
| (2E,6E)-1,1-diethoxynona-2,6-diene |
References:
Other Information:
Potential Blenders and core components note
| For Odor |
| aldehydic |
nonanal (aldehyde C-9)
FL/FR |
| creamy |
waxy lactone
FL/FR |
| earthy |
1- octen-3-ol
FL/FR |
| fatty |
2- nonen-1-ol
FL/FR |
(E)-2- nonenal
FL/FR |
(E)-2- octenal
FL/FR |
| floral |
cyclohexyl ethyl alcohol
FL/FR |
(Z)- methyl epi-jasmonate
FL/FR |
methyl jasmonate
FL/FR |
| fruity |
octyl formate
FL/FR |
propyl 2,4-decadienoate
FL/FR |
| green |
(Z)-4- heptenal diethyl acetal
FL/FR |
(Z)-3- hexen-1-yl butyrate
FL/FR |
(E)-2- hexen-1-yl butyrate
FL/FR |
(E)-2- hexen-1-yl propionate
FL/FR |
(Z)-3- hexen-1-yl pyruvate
FL/FR |
leafy acetal
FL/FR |
manzanate (Givaudan)
FL/FR |
melon nonenoate
FL/FR |
methyl octine carbonate
FL/FR |
methyl octine carbonate replacer
FR |
(E,Z)-2,6- nonadien-1-ol
FL/FR |
3,6- nonadien-1-ol
FL/FR |
(E,Z)-3,6- nonadien-1-ol
FL/FR |
(Z,Z)-3,6- nonadien-1-ol
FL/FR |
2,6- nonadien-1-ol
FL/FR |
3,6- nonadien-1-yl acetate
FL/FR |
(E,Z)-2,6- nonadien-1-yl acetate
FL/FR |
(E,Z)-3,6- nonadien-1-yl acetate
FL/FR |
2,6- nonadienal
FL/FR |
(E,Z)-2,6- nonadienal
FL/FR |
(E)-2- nonen-1-ol
FL/FR |
(Z)-2- nonen-1-ol
FL/FR |
olive oil absolute
FL/FR |
violet leaf absolute egypt
FL/FR |
| herbal |
3- octyl acetate
FL/FR |
sabinene hydrate
FL/FR |
| marine |
green algae absolute
FL/FR |
| melon |
melon carboxaldehyde
FR |
(Z)-6- nonenal
FL/FR |
watermelon ketone
FR |
| terpenic |
gamma- terpinene
FL/FR |
| waxy |
2,4- nonadien-1-ol
FL/FR |
(Z)-3- nonen-1-ol
FL/FR |
| For Flavor |
| No flavor group found for these |
green algae absolute
FL/FR |
(Z)-6- decenal
FL |
2,6- nonadienal
FL/FR |
2,4,6- nonatrienal
FL |
3,5- undecadien-2-one
FL |
| aldehydic |
| aldehydic |
nonanal (aldehyde C-9)
FL/FR |
| apple |
(E,Z)-2,6- nonadien-1-ol
FL/FR |
| aromatic |
leafy acetal
FL/FR |
| cooling |
manzanate (Givaudan)
FL/FR |
sabinene hydrate
FL/FR |
| creamy |
waxy lactone
FL/FR |
| cucumber |
2- ethyl octine carbonate
FL |
| fatty |
(E,E)-2,4- decadienal
FL |
(E,E)-2,4- heptadienal
FL |
2,4- nonadien-1-ol
FL/FR |
(E,E)-2,4- nonadienal
FL |
2,4- nonadienal
FL |
(Z)-2- nonen-1-ol
FL/FR |
2- nonen-1-ol
FL/FR |
(E)-2- octenal
FL/FR |
| floral |
(Z)- methyl epi-jasmonate
FL/FR |
methyl jasmonate
FL/FR |
| green |
cucumber distillates
FL |
cyclohexyl ethyl alcohol
FL/FR |
(Z)-4- heptenal diethyl acetal
FL/FR |
(E)-2- hexen-1-yl butyrate
FL/FR |
(Z)-3- hexen-1-yl butyrate
FL/FR |
(E)-2- hexen-1-yl propionate
FL/FR |
(Z)-3- hexen-1-yl pyruvate
FL/FR |
melon nonenoate
FL/FR |
methyl octine carbonate
FL/FR |
(E,Z)-3,6- nonadien-1-ol
FL/FR |
3,6- nonadien-1-ol
FL/FR |
2,6- nonadien-1-ol
FL/FR |
(E,Z)-3,6- nonadien-1-yl acetate
FL/FR |
3,6- nonadien-1-yl acetate
FL/FR |
(E,Z)-2,6- nonadien-1-yl acetate
FL/FR |
(E,E)-2,6- nonadienal
FL |
(E,Z)-2,6- nonadienal
FL/FR |
(E)-2- nonen-1-ol
FL/FR |
(E)-2- nonenal
FL/FR |
(Z)-6- nonenal
FL/FR |
3- octyl acetate
FL/FR |
octyl formate
FL/FR |
violet leaf absolute egypt
FL/FR |
| melon |
propyl 2,4-decadienoate
FL/FR |
| mushroom |
1- octen-3-ol
FL/FR |
| oily |
olive oil absolute
FL/FR |
tetrahydrofurfuryl propionate
FL |
| terpenic |
gamma- terpinene
FL/FR |
| waxy |
(Z,Z)-3,6- nonadien-1-ol
FL/FR |
(Z)-3- nonen-1-ol
FL/FR |
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| (2E,6Z)-1,1- | diethoxy-2,6-nonadiene | | (2E,6Z)-1,1- | diethoxynona-2,6-diene | | (6Z,2E)-1,1- | diethoxynona-2,6-diene | | (E,Z)-2,6- | nonadien-1-al diethyl acetal | | (E)-2,(Z)-6- | nonadien-1-al diethyl acetal | | 2-trans-6-cis- | nonadien-1-al diethyl acetal | | trans,cis-2,6- | nonadien-1-al diethyl acetal | | (E,Z)-2,6- | nonadienal diethyl acetal | | trans,cis-2,6- | nonadienal diethyl acetal | | 2,6- | nonadiene, 1,1-diethoxy-, (2E,6Z)- |
Articles:
|
