BT

Typical G.C. analysis

asarum canadense root oil
#%LeftshiftComponents
210.20  aristolene
290.90  aristolone
150.40(E)-beta- bergamotene
410.10  borneol
91.50  bornyl acetate
240.20delta- cadinene
160.30  camphene
170.301,8- cineole
360.10  copaene
180.30para- cymene
81.70  elemicin
300.90(E)-iso elemicin
340.60  eugenol
230.20(E)-beta- farnesene
111.30  geraniol
53.90  geranyl acetate
200.30gamma- guaiene
370.10beta- gurjunene
101.40  junenol
280.90  limonene
214.90  linalool
44.00  linalyl acetate
390.10  methyl chavicol
141.80  methyl eugenol
190.30(E)- methyl isoeugenol
42trace  methyl thymol
400.10alpha- muurolene
71.70  myrcene
121.20  nerol
62.40  neryl acetate
140.40(E)-ocimene
320.60(Z)- ocimene
130.90alpha- pinene
270.90beta- pinene
250.10  sabinene
220.20  seychellene
330.60  terpinen-4-ol
260.10alpha- terpinene
310.80gamma- terpinene
35.90alpha- terpineol
350.40  terpinolene
380.10 vetiselinene

B. M. Lawrence, unpublished information.

P&F 11, No. 6, 39, (1986)

chenopodium ambrosioides oil
#%LeftshiftComponents
154.1 aristolenol
20.2  camphene
174.2  carvacrol
122.0para- cymen-8-ol
618.0para- cymene
114.0 dihydropinocarvone
76.0  limonene
90.6  linalool
142.8  methyl thymol
50.7  myrcene
110.0alpha- pinene
40.3beta- pinene
103.9  pinocarveol
30.2  sabinene
80.1gamma- terpinene
131.9alpha- terpineol
162.0  thymol
crithmum maritimum oil
#%LeftshiftComponents
53<0.10(E)-alpha- bergamotol
26<0.10  bornyl formate
5<0.10delta-3- carene
540.10  carvacrol
45<0.10trans- carveol
57<0.10 caryophylla-2(12),6(13)-dien-5a-ol
46<0.10para- cymen-8-ol
125.30para- cymene
44<0.10beta- damascenone
320.10(E)-2- decenal
41<0.10neo dihydrocarveol
58<0.10  dillapiole
16<0.10alpha-para- dimethyl styrene
550.10  elemicin
400.10(Z)-1,2-epoxyterpinen-4-ol
19<0.104,8- epoxyterpinolene
36<0.10  limonen-4-ol
824.20  limonene
17<0.10(Z)-1,2- limonene epoxide
21<0.10  linalool
240.70(E)-para- menth-2-en-1-ol
310.40(Z)-para- menth-2-en-1-ol
50<0.10(Z)-para-menth-3-en-1,2-diol
48<0.10para- mentha-1,4-dien-7-ol
33<0.10(E)-para- mentha-2,8-dien-1-ol
520.20para- methoxypropiophenone
29<0.10  methyl carvacrol
343.40  methyl chavicol
47<0.10  methyl eugenol
250.30  methyl isothymol
270.30  methyl thymol
30<0.102- methyl-6-methylene-3,7-octadien-2-ol
61.60  myrcene
56<0.10  myristicin
370.10  myrtenyl acetate
15<0.10  nonanal
200.10(E)-2- nonenal
100.30(Z)-beta- ocimene
14<0.10  octanal
23<0.10  octanol
90.30beta- phellandrene
59<0.10  phytol
10.70alpha- pinene
30.20beta- pinene
350.20(E)- piperitol
430.40(Z)- piperitol
42<0.10  piperitone
426.90  sabinene
180.90(E)- sabinene hydrate
220.60(Z)- sabinene hydrate
490.30  spathulenol
289.00  terpinen-4-ol
71.40alpha- terpinene
1119.30gamma- terpinene
380.40alpha- terpineol
130.70  terpinolene
39<0.10alpha- terpinyl acetate
20.30alpha- thujene
51<0.10  thymol
J. of Ess. Oil Res. 12, No. 4, 424, (2000)
croton eluteria bark oil
#%LeftshiftComponents
800.01  amyl benzoate
330.28allo- aromadendrene
129tracealpha- bisabolol
126tracebeta- bisabolol
1010.94  borneol
550.22  cadalene
460.42delta- cadinene
440.17gamma- cadinene
1231.00T- cadinol
470.96alpha- calacorene
490.24beta- calacorene
450.11  calamenene
40.40  camphene
630.02  camphor
100.21delta-2- carene
1130.02  carvacrol
110trace  carvenone
1080.08trans- carveol
670.03  carvone
680.21  carvotan acetone
320.25beta- caryophyllene
870.67 caryophyllene oxide + dihydro-ar-bisabolol
860.32 cascarilla epoxide
890.08 cascarilla furan
1331.34 cascarilla hydroxyketone
920.01 cascarilla hydroxyketone
930.02 cascarilla lactone
274.62  cascarilladiene
901.28 cascarilladienone
1370.74  cascarillone
1211.78beta-cedren-10-ol
281.11beta-cedrene isomer
1180.07  cedrol
430.20alpha- chamigrene
360.11beta- chamigrene
600.281,8- cineole
480.09 compound k
500.23 compound l
510.07 compound m
520.14 compound n
530.01 compound o
540.07 compound p
740.02 compound q
770.73 compound r
1270.38 compound t
1280.18 compound u
1350.06 compound v
1384.30 compound w
250.39alpha- copaene
230.04alpha- cubebene
370.21beta- cubebene
660.05  cuminaldehyde
422.45 cuparene + alpha-muurolene
1341.88 cuparophenol
350.39ar- curcumene
240.53  cyclosativene
1020.28para- cymen-8-ol
119.91para- cymene
650.062- decanone
1310.86 dictyopterol 1A
1320.43 dictyopterol 1B
1300.513,4-dihydro-6-methyl-4-isopropyl-1(2H)-naphthalenone
79trace2,5-dimethoxy-meta-cymene
200.012,5- dimethoxytoluene (fennelone)
160.16alpha-para- dimethyl styrene
1191.286,7-dimethyl undeca-5,9-dien-2-ol
340.731,11-oxido calamenene
261.63beta- elemene
410.31gamma- elemene
1140.56  elemicin
1150.51beta- elemol
1243.03beta- eudesmol
310.07(E)-beta- farnesene
970.01alpha- fenchyl alcohol
1360.35 geran-9-yl-alpha-terpineol
812.18  geranyl acetone
290.07  germacrene D
120trace  guaiol
57trace2- heptanol
560.012- heptanone
1trace2,4- hexadien-1-al
880.28 humulene epoxide isomer
1250.71  intermedeol
120.94 limonene + 1,8-cineole
965.12  linalool
940.09  linalool oxide
690.02  linalyl acetate
390.01beta- maaliene
980.04para-menth-2-en-1-ol
111tracepara- mentha-1,3-dien-7-al
640.02para- methyl acetophenone
80.02ortho- methyl anisole
820.053- methyl but-2-enyl benzoate
220.02  methyl carvacrol
760.05 methyl cascarillate
190.01  methyl chavicol
780.22  methyl eugenol
580.036- methyl heptan-2-one
210.02  methyl thymol
590.026- methyl-5-hepten-2-one
180.095-methyl-5-hexyl furan
70.64  myrcene
1050.17  myrtenol
1160.05  nerolidol
950.022- nonanol
610.182- nonanone
140.01(E)-beta- ocimene
130.01(Z)-beta- ocimene
700.05  phellandral
90.13alpha- phellandrene
32.59alpha- pinene
60.35beta- pinene
990.17  pinocarveol
1070.10  piperitol
840.03  prenyl benzoate
910.094-iso propyl-6-methyl tetral-1-one
50.09  sabinene
109trace  sabinol
380.58beta- selinene
1170.70  spathulenol
1031.70  terpinen-4-ol
73trace  terpinen-4-yl acetate
150.60gamma- terpinene
1041.10alpha- terpineol
100tracebeta- terpineol
170.07  terpinolene
750.16alpha- terpinyl acetate
22.11alpha- thujene
620.14alpha- thujone
300.23  thujopsene
112trace  thymol
1220.77  torilenol
85trace2- tridecanone
830.15(Z)-5-tridecen-2-one
710.295,8-undecadien-2-one + (Z)-5-undecen-2-one
720.312- undecanone
400.18  valencene
1060.11  verbenone

M. L. Hagedorn and S. M. Brown, The constituents of Cascarilla oil (Croton eluteria Bennett) Flav. Fragr. J., 6, 193-204 (1991).

P&F 18, No. 6, 53, (1993)

croton flavens l. (welensali) leaf oil curacao
#%LeftshiftComponents
470.30allo- aromadendrene
241.20  borneol
320.20  bornyl acetate
280.50  bornyl formate
390.30beta- bourbonene
511.20delta- cadinene
41.70  camphene
220.30  camphene hydrate
19tracealpha- campholenal
20trace  camphor
449.30iso caryophyllene
110.101,8- cineole
380.60alpha- copaene
360.20alpha- cubebene
487.90ar- curcumene
101.70para- cymene
420.50  cyperene
270.102- decanone
430.202,6- dimethoxy-para-cymene
40trace2- dodecanone
410.80beta- elemene
350.30delta- elemene
490.30  germacrene D
450.80alpha- gurjunene
461.50alpha- humulene
121.30  limonene
180.40  linalool
16trace(E)- linalool oxide furanoid
15trace(Z)- linalool oxide furanoid
370.20  longicyclene
8trace4- methyl anisole
300.10  methyl carvacrol
29trace  methyl thymol
70.60  myrcene
520.40(E)- nerolidol
130.20(Z)-beta- ocimene
91.50alpha- phellandrene
316.00alpha- pinene
60.70beta- pinene
21.020trans- pinocarveol
230.10  pinocarvone
50.20  sabinene
534.50  spathulenol
250.10  terpinen-4-ol
140.20gamma- terpinene
260.10alpha- terpineol
17trace  terpinolene
20.30alpha- thujene
34trace  thymol
10.20  tricyclene
500.302- tridecanone
330.502- undecanone
310.60trans- verbenyl acetate
J. of Ess. Oil Res. 12, No. 6, 667, (2000)
lavandula angustifolia herb oil france
#%LeftshiftComponents
50trace(E)-alpha- bergamotene
292.76 borneol + linalool oxide pyranoid
380.06  bornyl acetate
70.18  butyl isobutyrate
59trace  cadalene
530.56gamma- cadinene
580.99T- cadinol
40.13  camphene
260.59  camphor
10tracedelta-3- carene
491.08beta- caryophyllene
563.74  caryophyllene oxide
480.05alpha- cedrene
123.321,8- cineole
430.22  citronellyl acetate
46tracealpha- copaene
110.33para- cymene
19tracepara- cymenene
42tracedelta- elemene
510.97(Z)-beta- farnesene
60trace(Z,E)- farnesol
36trace  geraniol
451.95  geranyl acetate
520.14  germacrene D
570.10  hexadecane
91.96  hexyl acetate
320.25  hexyl butyrate
280.12 hexyl isobutyrate + pinocarvone
405.46  lavandulyl acetate
130.59  limonene
2220.98  linalool
201.98(E)- linalool oxide furanoid
182.44(Z)- linalool oxide furanoid
3726.54  linalyl acetate
410.12  linalyl propionate
35trace  methyl thymol
81.08  myrcene
341.02 nerol + citronellol + carvone
550.08(E)- nerolidol
54trace(Z)- nerolidol
441.02  neryl acetate
151.15(E)-beta- ocimene
140.86(Z)-beta- ocimene
61trace  octadecane
250.093- octen-1-yl acetate
231.341- octen-3-yl acetate
330.12  octyl acetate
30.14alpha- pinene
60.51beta-pinene + 6-methyl-5-hepten-2-one
240.07cis- pinene hydrate
270.16trans- pinocarveol
50.05  sabinene
170.11(E)- sabinene hydrate
301.52  terpinen-4-ol
160.07gamma- terpinene
314.34alpha- terpineol
210.29  terpinolene
47trace  tetradecane
2tracealpha- thujene
39trace  thymol
1trace  tricyclene

P. R. Venskutonis, A. Dapkevicies and M. Baranauskiene, Composition of the essential oil of lavender (Lavandula angustifolia Mill.) from Lithuania. J. Essent. Oil Res., 9, 107-110 (1997).

P&F 26, No. 4, 55, (2000)

lippia aff. gracillis h.b.k. leaf oil brazil
#%LeftshiftComponents
170.50  aromadendrene
201.60  bicyclogermacrene
100.50  borneol
210.10delta- cadinene
1438.40  carvacrol
165.00beta- caryophyllene
230.80  caryophyllene oxide
62.101,8- cineole
514.50para- cymene
180.50alpha- humulene
191.403-hydroxymethyl carvacrol
70.40  limonene
91.20  linalool
126.00  methyl thymol
32.30  myrcene
20.60alpha- pinene
220.80  spathulenol
110.80  terpinen-4-ol
41.90alpha- terpinene
810.60gamma- terpinene
11.30alpha- thujene
138.00  thymol
150.40  thymyl acetate
J. of Ess. Oil Res. 12, No. 3, 295, (2000)
thymus richardii pers. subsp. nitidus (guss.) jalas oil italy
#%LeftshiftComponents
270.70allo- aromadendrene
3032.30beta- bisabolene
14trace  borneol
250.60beta- bourbonene
311.00delta- cadinene
344.00T- cadinol
13trace  camphor
2213.10  carvacrol
24trace  carvacryl acetate
180.50trans- carveol
200.70  carvone
263.40beta- caryophyllene
333.10  caryophyllene oxide
80.751,8- cineole
52.10para- cymene
161.00(Z)- dihydrocarvone
175.00(E)- dihydrocarvone
291.90  germacrene D
61.00  limonene
121.60  linalool
1912.40  methyl thymol
280.40gamma- muurolene
4trace  myrcene
70.50beta- phellandrene
320.70beta-sesqui phellandrene
10.70alpha- pinene
3tracebeta- pinene
2trace  sabinene
101.50(Z)- sabinene hydrate
150.60  terpinen-4-ol
9tracegamma- terpinene
11tracebeta- thujone
211.30  thymol
23trace  thymyl acetate
J. of Ess. Oil Res. 13, No. 1, 8, (2001)
thymus vulgaris oil CO2 extract
Oszagyan et al. (1996) analyzed the composition od supercritical fluid CO2 extract of thyme (ex. T. vulgaris) and compared it to a steam-distilled oil. The quantitative data was obtained in a GD-FID, whereas the identity od each component was determined by GC/MS. A comparison between the two analyses is shown in Table VII. Note, only the CO2 extract will be shown here.
#%LeftshiftComponents
160.02  borneol
220.37  bornyl acetate
300.24gamma- cadinene
30.04  camphene
243.17  carvacrol
271.64beta- caryophyllene
100.161,8- cineole
260.22alpha- copaene
82.55para- cymene
210.04  geraniol
320.27  heptadecane
340.16  heptadecanoic acid
310.10  hexadecane
280.09alpha- humulene
90.09  limonene
131.63  linalool
200.54  methyl carvacrol
190.32  methyl thymol
50.17  myrcene
335.98  palmitic acid
60.09alpha- phellandrene
20.01alpha- pinene
40.35beta- pinene
140.02  pinocarveol
358.30  stearic acid
171.04  terpinen-4-ol
70.07alpha- terpinene
110.67gamma- terpinene
180.20alpha- terpineol
150.22beta- terpineol
120.09  terpinolene
10.03alpha- thujene
2336.59  thymol
290.01  valencene
25tracealpha- ylangene

H. J. Bestmann, J. Ederand O. Vostrowky, Extraktion von Thymian mit flusigem CO2 in Labormasstab. Zeit. Lebersmitt. Unters Forsch., 180, 491-493 (1985).

P&F 20, No. 3, 67, (1995)

thymus vulgaris oil red spain
An oil of T. Vulgaris that was produced for two separate seasons in Casolavalsenio, Italy, was subjected to analysis by a combination of GC and GC/MS (Piccaglia and Marotti, 1993). The compounds that were characterized during this analysis were:
#%LeftshiftComponents
19trace  aromadendrene
340.44-0.45  borneol
400.04-0.07  bornyl acetate
16tracebeta- bourbonene
260.11-0.25delta- cadinene
250.06-0.15gamma- cadinene
29trace-0.05alpha- cadinol
28trace-0.09delta- cadinol
30.18-0.46  camphene
33trace-0.30  camphor
90.07-0.13delta-3- carene
420.61-1.72  carvacrol
172.38-4.28beta- caryophyllene
270.29-0.45  caryophyllene oxide
131.96-2.621,8- cineole
44tracealpha- copaene
43trace-0.08  cumin alcohol
36tracepara- cymen-8-ol
1118.60-25.34para- cymene
21trace-0.04(Z)-beta- farnesene
18trace-0.04beta- gurjunene
200.13-0.23alpha- humulene
120.17-0.30  limonene
302.42-2.82  linalool
381.43-1.52  methyl thymol
220.04-0.07alpha- muurolene
24trace-0.08gamma- muurolene
71.40-2.14  myrcene
60.41-0.671- octen-3-ol
80.15-0.19alpha- phellandrene
20.49-1.34alpha- pinene
50.17-0.41beta- pinene
4trace  sabinene
350.98-1.10  terpinen-4-ol
101.67-2.34alpha- terpinene
1412.06-12.27gamma- terpinene
370.17-0.26alpha- terpineol
150.18-0.19  terpinolene
10.87-2.10alpha- thujene
310.00-0.51alpha- thujone
320.00-0.15beta- thujone
4116.55-38.24  thymol
39trace  thymoquinone
23trace-0.10  viridiflorene

R. Piccaglia, M. Marotti, E. Giovanelli, S. G. Deans and E. Eaglesham, Antibacterial and antioxidant properties of Mediterranean aromatic plants. Inust. Crops Products, (2), 47-50 (1993).

R. Piccaglia, M. Marotti, Characterization of several aromatic plants grown in northern Italy. Flav. Fragr. J., 8, 115-122 (1993).

P&F 23, No. 1, 39, (1998)

valeriana officinalis rhizome oil
#%LeftshiftComponents
360.2-0.8beta- bisabolene
580.5-1.5epi-alpha-bisabolol
160.1-0.6  borneol
15trace-0.1iso borneol
252.3-33.5  bornyl acetate
430.5-1.2  bornyl isovalerate
460.1-0.3delta- cadinene
30.1-6.4  camphene
14trace-0.1  camphor
21trace-0.1trans- carveol
200.1-0.2cis- carveol
8trace-0.21,8- cineole
31trace-0.1  citronellyl acetate
510.2-2.1  citronellyl isovalerate
33trace-0.2alpha- copaene
570.4-3.9  cryptofauronol
70trace-2.9  cryptofauronyl acetate
22trace-0.1  cuminaldehyde
400.7-2.1ar- curcumene
70.1-1.5para- cymene
340.2-1.42,6- dimethoxy-para-cymene
620.1-0.4  drimenol
350.1-0.4beta- elemene
300.2-2.9delta- elemene
420.1-0.4gamma- elemene
75trace-0.6  ethyl palmitate
380.5-7.6  eudesma-2,6,8-triene
530.6-6.9beta- eudesmol
29trace-0.1  eugenol
610.1-0.4  eugenyl isovalerate
670.1-1.1iso eugenyl isovalerate
480.4-0.6  faurinone
410.2-1.4  germacrene D
44trace-1.0beta- gurjunene
370.1-0.9alpha- humulene
390.1-0.7beta- ionone
450.2-3.8  kessane
380.1-3.5  kessanyl acetate
730.1-0.7  kessoglycyl monoacetate
630.1-12.6alpha- kessyl acetate
520.5-2.1  ledol
100.1-1.2  limonene
13trace  linalool
500.1-1.6  maaliol
240.1-0.2  methyl carvacrol
710.1-0.9  methyl palmitate
23trace-0.4  methyl thymol
650.1-0.2  methyl valerenate
6trace-0.1  myrcene
190.1-4.0  myrtenol
28trace-9.1  myrtenyl acetate
560.1-0.2 myrtenyl hexanoate
491.6-10.5  myrtenyl isovalerate
26trace-0.8  nojigiku acetate
470.5-3.2  pacifigorgiol
720.1-1.9  palmitic acid
9trace-2.4beta- phellandrene
20.1-0.2alpha- pinene
5trace-0.9beta- pinene
4trace-0.1  sabinene
170.1-0.6  terpinen-4-ol
11trace-0.2gamma- terpinene
18trace-0.1alpha- terpineol
12trace-0.1  terpinolene
270.1  thymol
1trace-0.1  tricyclene
550.5-8.2  valeranone
660.1-1.5(E)-valeren-1-yl acetate
640.2-0.8(Z)-valeren-1-yl acetate
76trace-1.6(E)-valeren-1-yl isovalerate
74trace-0.7(Z)-valeren-1-yl isovalerate
590.4-12.4  valerenal
690.3-2.8  valerenic acid
600.3-1.2(Z+E)- valerenol
541.5-14.2  valerianol
320.1-0.4alpha- ylangene

R. Bos and H. J. Woerdenbag, Analytical aspects of the essential oil, valerenic acid derivatives and valepotriates in Valeriana officinalis roots and rhizomes. In: Proceedings, International Symposium on breeding research and medicinal and aromatic plants. Edits., F. Pank, p. 355-358, Beiträge zur Zuchtungsforschung, Quedlinburg, Germany (1996).

P&F 24, No. 3, 47, (1999)

valeriana officinalis rhizome oil china
#%LeftshiftComponents
101.31iso borneol
1246.22  bornyl acetate
130.61iso bornyl acetate
260.72  bornyl isovalerate
323.50  camphene
90.33  camphor
141.64  carvyl acetate
220.50beta- caryophyllene alcohol
50.40para- cymene
210.32  decahydro-1,1,4,7-tetramethyl cyclopropazulen-4-ol
200.44  decahydro-2,2,4,8-tetramethyl-4,8-methanazulen-9-ol
170.331,1- dimethoxy-3,7-dimethyl-2,6-octadiene
160.171,4-dimethoxytetramethyl benzene
71.377,7- dimethyl-2-methylene bicyclo(3.1.1)heptane
281.52(2Z)-3,7- dimethyl-2,6-octadien-1-ol isovalerate
230.602,6- dimethyl-6(4-methyl-3-pentenyl)-2-cyclohexene-1-carboxaldehyde
241.934-ethyl-2,2,4-trimethyl-3-(1-methyl ethenyl) cyclohexene methanol
270.61  geranyl isovalerate
180.38beta- gurjunene
250.53  ledol
60.77  limonene
80.353-methyl 2-norbornane carboxaldehyde
25.46alpha- pinene
43.50beta- pinene
110.282-iso propyl-5-methyl anisole
10.43alpha- thujene
190.984(2,6,6- trimethyl cyclohexa-1,3-dienyl)but-2-en-4-one
150.612,2,4-trimethyl-3-cyclohexene-1-methyl acetate

Y-D. Chen and C-H. Gu, Study on the chemical composition of essential oil from Valeriana officinalis. Lincnan Huaxue Yu Gongye, 9(1), 59-64 (1989).

P&F 24, No. 3, 47, (1999)

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