BT

Typical G.C. analysis

agathosma betulina leaf oil
#%LeftshiftComponents
330.23(E)-2-acetoxyisomenthone
340.21(E)-2-acetoxymenthone
26trace  carvone
84.431,8- cineole
110.16para- cymene
200.12(E)- dihydrocarvone
190.21(Z)- dihydrocarvone
3022.30  diosphenol
2718.584-diosphenol
350.671-hydroxy-4-diosphenol
360.404-hydroxydiosphenol
240.46(E)-2-hydroxymenthone
290.37(Z)-2-hydroxymenthone
280.128-hydroxymenthone
611.64  limonene
150.50  linalool
139.82  menthone
1419.91iso menthone
310.53(E)-8- mercapto-para-menthan-3-one ((E)-3-oxo-para-menthan-8-thiol)
322.33(Z)-8- mercapto-para-menthan-3-one ((Z)-3-oxo-para-menthan-8-thiol)
40.61  myrcene
100.25(E)-beta- ocimene
70.08beta- phellandrene
10.37alpha- pinene
20.29beta- pinene
250.06  piperitone
210.94  pulegone
160.54(E)-iso pulegone
170.40(Z)-iso pulegone
30.15  sabinene
180.90  terpinen-4-ol
50.13alpha- terpinene
90.34gamma- terpinene
230.28alpha- terpineol
220.23delta- terpineol
120.09  terpinolene
M. A. Posthumus, T. A. van Beek, N. F. Collins and E. H. Graven, Chemical composition of the essential oils of Agathosma betulina, A. crenulata and an A. betulina x crenulata hybrid (buchu), J. Essent, Oil Res., 8, 223-228 (1996). P&F 23, No. 4, 37, (1998)
agathosma crenulata oil
#%LeftshiftComponents
 6.83(E)-8-acetyl thio-para-menthan-3-one ((E)-3-oxo-para-menthan-8-thiol acetate)
 0.37(Z)-8-acetyl thio-para-menthan-3-one ((Z)-3-oxo-para-menthan-8-thiol acetate)
 0.22  carvone
 1.191,8- cineole
 0.41para- cymene
 0.18(E)- dihydrocarvone
 0.21(Z)- dihydrocarvone
 1.038-hydroxy-para-menth-4-en-3-one
 trace(Z)-2-hydroxyisomenthone
 4.678-hydroxymenthone
 11.70  limonene
 0.76  linalool
 trace  menthofuran
 2.91  menthone
 3.58iso menthone
 1.01  myrcene
 0.06(E)-beta- ocimene
 0.07beta- phellandrene
 0.73alpha- pinene
 0.44beta- pinene
 trace  piperitone
 53.75  pulegone
 2.77(E)-iso pulegone
 2.78(Z)-iso pulegone
 trace  sabinene
 0.77  terpinen-4-ol
 0.05alpha- terpinene
 0.09gamma- terpinene
 0.43alpha- terpineol
 0.08delta- terpineol

M. A. Posthumus, T. A. van Beek, N. F. Collins and E. H. Graven, Chemical composition of the essential oils of Agathosma betulina, A. crenulata and an A. betulina x crenulata hybrid (buchu), J. Essent, Oil Res., 8, 223-228 (1996).

P&F 23, No. 4, 37, (1998)

cymbopogon citratus leaf oil morocco
#%LeftshiftComponents
310.10(E)-alpha- bergamotene
240.40trans- carveol
320.20  caryophyllene oxide
51.001,8- cineole
210.50  citronellol
300.10ar- curcumene
14trace(Z)- dihydrocarvone
330.1010-epi-gamma- eudesmol
280.10alpha- fenchol
1839.80  geranial
261.40  geranic acid
253.30  geraniol
200.70  geranyl acetate
230.20  geranyl isobutyrate
40.20  limonene
101.30  linalool
80.10(E)- linalool oxide furanoid
70.20(Z)- linalool oxide furanoid
120.20  menthone
170.60  methyl geranate
62.206- methyl-5-hepten-2-one
20.80  myrcene
130.30  myrtenyl acetate
1632.00  neral
270.10  neric acid
190.50  neryl acetate
11trace  octanal
9trace3- octanol
10.40alpha- pinene
290.30iso pulegol
150.90  pulegone
30.10alpha- terpinene
220.402- undecanone

A. Il. Idrissi, J. Bellakhbar, S. Canigueral, J. Iglesias and R. Vila, Composition de L'huile essentielle de la citronelle (Cymbopogon citratus (DC) Stapf.) acclimatee et Maroc. Plant. Medicin Phytother., 26, 274-277 (1993).

P&F 23, No. 4, 37, (1998)

mentha arvensis leaf oil india
#%LeftshiftComponents
10.02  acetic acid
400.05  carvone
490.29  caryophyllene oxide
160.251,8- cineole
350.10  citronellol
290.03para- cymen-8-ol
140.02para- cymene
420.03  decanol
40.03(Z)-3- hexen-1-ol
360.28(Z)-3- hexen-1-yl 3-methyl butyrate
110.04(Z)-3- hexen-1-yl acetate
370.03  hexyl 3-methyl butyrate
150.39  limonene
200.03  linalool
460.03para- menth-8-ene-1,2-diol
2774.51  menthol
280.05iso menthol
300.12neo menthol
248.30  menthone
264.59iso menthone
446.11  menthyl acetate
380.23iso menthyl acetate
450.12neo menthyl acetate
430.16neoiso menthyl acetate
20.083- methyl butanol
210.033- methyl butyl 3-methyl butyrate
6trace3- methyl cyclohexanol
7trace3- methyl cyclohexanone
130.02  methyl octyl ether
30.023- methyl-2-cyclopenten-1-one
330.04 myrtenal + myrtenol
480.02  nerolidol
250.09  nonanol
190.043- nonanol
170.06  octanol
100.963- octanol
320.11  octyl acetate
220.043- octyl acetate
120.02alpha- phellandrene
50.15alpha- pinene
90.24beta-pinene + 3-octanone
410.45  piperitone
390.13  pulegone
80.06  sabinene
180.02  sabinene hydrate
470.06 terpin hydrate
310.07alpha- terpineol
230.01beta- terpineol
340.03  verbenone

M. H. Boelens, Chemical characterization of cornmint oil, Perf. & Flav., 18(5), 27-32 (1993).

P&F 19, No. 6, 57, (1994)

mentha pulegium herb oil
#%LeftshiftComponents
13tracebeta- bourbonene
190.60beta- caryophyllene
260.20 germacrene D + alpha-terpineol
7trace(E)-2- hexenal
241.10alpha- humulene
61.00  limonene
15trace  linalool
25traceiso menthol
200.40neo menthol
22traceneoiso menthol
112.30  menthone
120.80iso menthone
14traceneo menthyl acetate
80.505- methyl-3-heptanone
5trace  myrcene
100.703- octanol
9trace  octyl acetate
10.40alpha- pinene
30.30beta- pinene
291.80  piperitenone
28traceiso piperitenone
27trace piperitone + delta-cadinene
16traceiso pulegol
2386.70  pulegone
171.20(E)-iso pulegone
180.60(Z)-iso pulegone
4trace  sabinene
21trace  terpinen-4-ol
2tracealpha- thujene

M. Stengale, Beitrage Rolle glykosidisch gebundenerfluchtiger Komponenten in atherisches Ole furhrenden Pflanzen. Unterschungen an augewahlten Arten der Gattung Mentha L. PhD thesis Univ. Hamburg (1994).

P&F 23, No. 3, 63, (1998)

mentha pulegium oil cuba
#%LeftshiftComponents
270.10beta- bourbonene
300.18delta- cadinene
250.09alpha- calacorene
282.49beta- caryophyllene
311.04  caryophyllene oxide
60.08para- cymene
260.39beta- damascenone
336.78  hexadecanoic acid
290.27alpha- humulene
71.13  limonene
90.77  linalool
150.16  menthol
160.30iso menthol
131.86neo menthol
1420.68neoiso menthol
106.29  menthone
119.73iso menthone
200.14iso menthyl acetate
230.28neo menthyl acetate
226.24neoiso menthyl acetate
50.06  myrcene
80.11(Z)-beta- ocimene
40.413- octanol
10.35alpha- pinene
30.38beta- pinene
242.39  piperitenone
191.02  piperitone
1825.14  pulegone
20.11  sabinene
170.29alpha- terpineol
320.56  tetradecanoic acid
213.03  thymol
120.74  umbellulone

J. Pino, A. R.sado and V. Fluentes, Chemical composition of the essential oil of Mentha puiegium L. from Cuba. J. Essent. Oil. Res., 8, 295-296 (1996).

P&F 23, No. 3, 63, (1998)

mentha pulegium oil uruguay
#%LeftshiftComponents
130.20-2.20  carvone
100.90-1.40beta- caryophyllene
5trace-0.101,8- cineole
40.20  limonene
110.50-3.60  menthol
91.60-4.20neo menthol
74.20-5.60  menthone
835.60-40.60iso menthone
60.20-1.503- octanol
3tracealpha- phellandrene
1trace-0.40alpha- pinene
2tracebeta- pinene
1226.8-41.10  pulegone

M. B. de Grosso and P. Moyna. Cmposicion quimica de las esencias de Mentha del Uruguayrmias de Ment. An. Real. Acad. Farm., 51, 333-338 (1985).

P&F 23, No. 3, 63, (1998)

mentha x piperita herb oil idaho
Kubeczka (1993) compared the chemical compositions of peppermint oil produced from two different regions in the United States with the composition of an oil noted as Mitcham oil (origin unknown). His results are shown in Table VI. Note: Only the Peppermint Oil from Michigan analysis will be shown here:
#%LeftshiftComponents
20.01  camphene
222.24beta- caryophyllene
87.021,8-cineole + beta-phellandrene
120.24para- cymene
271.27  germacrene D
72.44  limonene
190.31  linalool
172.48  menthofuran
2438.01  menthol
213.25neo menthol
1623.14  menthone
183.08iso menthone
203.69  menthyl acetate
50.33  myrcene
90.41(Z)-beta- ocimene
110.11(Z)-beta- ocimene
140.303- octanol
11.34alpha- pinene
31.65beta- pinene
280.46  piperitone
230.78iso(iso) pulegol
251.38  pulegone
40.77  sabinene
151.14(E)- sabinene hydrate
60.43alpha- terpinene
100.68gamma- terpinene
260.15alpha- terpineol
130.18  terpinolene
290.15  viridiflorol

K. H. Kubeczka, Moglichkeiten und grenzen der qualitatsbeurteilung arzneilich verwendeter atherischer Ole. In: Atherische Ole-anspruch und wirklichkeit. Edit., R. Carle, pp. 85-102, Wissenschaft, Verlag. mbh Stuttgart (1993).

P&F 22, No. 4, 57, (1997)

mentha x piperita oil CO2 extract
Reverchon et al. (1994) compared the composition of a supercritical CO2 extract (SFE) of peppermint under two separate sets of conditions with a sample of peppermint oil produced by hydrodistillation. The results of the GC/MS analyses of the volatile concentrates of peppermint oil and peppermint produced by SFE can be seen in Table VIII. Note: Only the SFE-2 (T:40C, P:120 bar) will be shown as follows:
#%LeftshiftComponents
180.20  bornyl acetate
220.70beta- bourbonene
295.00gamma- cadinene
330.60T- cadinol
310.40(E)- calamenene
244.30beta- caryophyllene
320.20  caryophyllene oxide
63.601,8- cineole
21tracealpha- cubebene
50.10  decane
130.20  dihydrocarveol
230.90beta- elemene
300.40gamma- elemene
270.60beta- farnesene
250.20beta- gurjunene
26tracealpha- humulene
160.60  linalyl acetate
80.40para-menth-2-en-1-ol
1123.80  menthol
120.20iso menthol
936.10  menthone
107.50iso menthone
1911.70  menthyl acetate
200.20iso menthyl acetate
170.20neo menthyl acetate
28tracegamma- muurolene
30.20  myrcene
70.20(Z)-beta- ocimene
40.103- octanol
10.20alpha- pinene
20.50beta- pinene
150.60  piperitone
140.30  pulegone

E. Reverchon, A. Ambruosi and F. Senatore, Isolation of peppermint oil using ssupercritical CO2 extraction. Flav. Fragr. J., 9, 19-23 (1994).

P&F 22, No. 4, 57, (1997)

mentha x piperita oil mongolia
#%LeftshiftComponents
290.05  borneol
160.31beta-bourbonene + benzaldehyde
330.16delta- cadinene
170.42  camphor
320.16  carvone
32.471,8- cineole
40.22para- cymene
340.05  geraniol
300.05  germacrene D
130.06(Z)-3- hexen-1-yl isovalerate
270.18alpha- humulene
350.04(Z)- jasmone
20.38  limonene
180.28  linalool
10trace(Z)- linalool oxide furanoid
140.07  menthofuran
2535.07  menthol
213.74neo menthol
240.39neoiso menthol
1132.22  menthone
155.43iso menthone
209.39  menthyl acetate
50.072- methyl butyl 2-methyl butyrate
60.082- methyl butyl isovalerate
360.06(Z)- nerolidol
80.213- octanol
90.301- octen-3-ol
70.073- octyl acetate
10.04beta- pinene
311.32  piperitone
260.22  pulegone
230.05  rosefuran oxide
12trace(E)- sabinene hydrate
190.24(Z)- sabinene hydrate
220.07  terpinen-4-ol
280.06alpha- terpineol
370.09  viridiflorol

D. Karasawa, S. Shatar, A. Erdenechimeg, Y. Okamoto, H. Tateha and S, Shimizu, A study on Mongolian mints. A new chemotype from Mentha asiatia Borriss and constituents of M. arvensis L. and M. piperita L. J. Essent. Oil. Res., 7, 255-260 (1995).

P&F 22, No. 4, 57, (1997)

mentha x piperita oil russia
#%LeftshiftComponents
40.171,8- cineole
30.68  limonene
1044.46  menthol
92.00neo menthol
616.77  menthone
723.45iso menthone
83.75  menthyl acetate
10.80alpha- pinene
20.69beta- pinene
121.08 piperitone + piperitenone
110.99  pulegone
52.29(E)- sabinene hydrate

E. B. Kirichenko, L-D. Ky and V. A. Mel’nikov, Essential oil composition of some Vietnanese mint varieties. Byull. GI, Bot. sada, 154, 56-69 (1989).

P&F 22, No. 4, 57, (1997)

ruta graveolens oil cuba
#%LeftshiftComponents
260.61(E)- amyl cinnamic alcohol
170.77(Z)-gamma- bisabolene
180.07delta- cadinene
60.37  camphor
140.22beta- caryophyllene
298.18  curcuphenol
20.01para- cymene
90.722- decanone
132.432- dodecanone
191.44  elemol
250.42alpha- eudesmol
240.56beta- eudesmol
230.33gamma- eudesmol
71.64  geijerene
315.68  hexadecanoic acid
300.362- hexadecanone
150.03alpha- humulene
30.16  limonene
10.01  myrcene
200.26(E)- nerolidol
50.622- nonanone
40.02(E)-beta- ocimene
322.38iso phytol
110.52 pregeijerene
100.10  pulegone
80.08  terpinen-4-ol
280.29  tetradecanoic acid
270.06  tetradecanol
210.202- tetradecanone
220.07  tridecanoic acid
163.722- tridecanone
1248.672- undecanone

J. A. Pino, A. Rosado and V. Fuentes, Leaf oils of Ruta graveolens L. grown in Cuba. J. Essent. Oil Res., 9, 365-366 (1997).

P&F 23, No. 6, 53, (1998)

salvia officinalis oil cuba
Sage oil produced from S. officinalis grown in Cuba was analyzed by CC/MS. The constituents characterized in this oil by Pino et al. (1997) were as follows:
#%LeftshiftComponents
213.81  borneol
22.48  camphene
1510.36  camphor
220.21  carvone
185.51beta- caryophyllene
230.96  caryophyllene oxide
71.811,8- cineole
100.35para- cymene
172.24alpha- fenchyl acetate
209.72alpha- humulene
242.21  humulene oxide I
61.69  limonene
160.26  linalool
2814.74  manool
140.11  menthone
270.06  methyl (Z)-9-hexadecenoate
260.26  methyl palmitate
290.11  methyl stearate
80.19(Z)-beta- ocimene
41.16alpha- phellandrene
10.81alpha- pinene
30.96beta- pinene
190.86  pulegone
50.12alpha- terpinene
90.29gamma- terpinene
110.22  terpinolene
1212.95alpha- thujone
1310.89beta- thujone
2513.46  viridiflorol

J. A. Pino, M. Estarron and V. Fuentes, Essential oil of sage (salvia officinalis L.) grown in Cuba. J. Essent. Oil Res., 9, 221-222 (1997).

P&F 26, No. 3, 66, (2001)

salvia officinalis oil cuba
#%LeftshiftComponents
290.11  methyl (E)-9-octadecenoate
213.81  borneol
22.48  camphene
1510.36  camphor
220.21  carvone
185.51beta- caryophyllene
230.96  caryophyllene oxide
71.811,8- cineole
100.35para- cymene
172.24alpha- fenchyl acetate
209.72alpha- humulene
242.21  humulene oxide I
61.69  limonene
160.26  linalool
2814.74  manool
140.11  menthone
270.06  methyl (Z)-9-hexadecenoate
260.26  methyl hexadecanoate
80.19(Z)-beta- ocimene
41.16alpha- phellandrene
10.81alpha- pinene
30.96beta- pinene
190.86  pulegone
50.12alpha- terpinene
90.29gamma- terpinene
110.22  terpinolene
1212.95alpha- thujone
1310.89beta- thujone
2513.46  viridiflorol
satureja calamintha (l.) scheele oil greece
#%LeftshiftComponents
21tracebeta- bourbonene
22traceiso caryophyllene
23trace  germacrene D
73.40  limonene
144.30iso menthone
1332.00  menthone
40.30  myrcene
8trace(Z)-beta- ocimene
11trace  octanol
50.703- octanol
10.70alpha- pinene
30.60beta- pinene
197.00  piperitenone
201.00  piperitenone oxide
187.30  piperitone
1741.00  pulegone
150.70iso pulegone
20.20  sabinene
10trace(Z)- sabinene hydrate
160.50  terpinen-4-ol
6tracealpha- terpinene
9tracegamma- terpinene
12trace  terpinolene
J. of Ess. Oil Res. 13, No. 1, 11, (2001)
satureja viminea oil costa rica
#%LeftshiftComponents
30tracebeta- bourbonene
360.60delta- cadinene
350.20gamma- cadinene
420.10alpha- cadinol
40traceT- cadinol
5trace  camphene
323.60beta- caryophyllene
130.101,8- cineole
290.30alpha- copaene
11tracepara- cymene
17tracepara- cymenene
31tracealpha- gurjunene
1trace(E)-2- hexenal
20.10(Z)-3- hexen-1-ol
331.30alpha- humulene
121.00  limonene
180.50  linalool
1940.00para- menth-3-en-8-ol
155.20para- mentha-3,8-diene
200.10  menthofuran
340.60gamma- muurolene
410.10T- muurolol
8trace  myrcene
230.20  myrtenal
270.10  neral
370.20(E)- nerolidol
28trace  neryl acetate
9tracealpha- phellandrene
40.40alpha- pinene
70.50beta- pinene
260.70  piperitenone
2535.30  pulegone
210.60iso pulegone
60.20  sabinene
380.50  spathulenol
220.10  terpinen-4-ol
10tracealpha- terpinene
14tracegamma- terpinene
240.10alpha- terpineol
160.90  terpinolene
30.10alpha- thujene
39trace  viridiflorol
J. of Ess. Oil Res. 12, No. 3, 279, (2000)
thymus serpyllum oil pakistan
#%LeftshiftComponents
243.13  borneol
30.20  camphene
163.54  camphor
60.96delta-3- carene
288.15  carvacrol
182.19beta- caryophyllene
100.161,8- cineole
150.17  citronellal
129.54para- cymene
20.14 fenchene
190.91alpha- fenchol
250.35  geranial
260.35  geraniol
90.85  limonene
170.50  linalool
210.10  neral
140.17  nonanal
130.11  octanal
70.88alpha- phellandrene
10.27alpha- pinene
40.51beta- pinene
200.21  pulegone
50.56  sabinene
232.90  terpinen-4-ol
80.67alpha- terpinene
111.66gamma- terpinene
2742.63  thymol
220.23  undecanal

A. Sattar, M. Shafiq Malik and S. A. Khan, Essential oils of the species of Labiatae. part IV. Composition of the essential oil of Thymus serpyllum. Pak. J. Sci. Ind. Res., 34(4), 119-120 (1991).

P&F 23, No. 3, 63, (1998)

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