Articles:
| None found yet. Try the PubMed Search. |
-
Alfrebro LLC Let's get reacquainted Building great taste with aroma chemicals, extracts, and distillates The Alfrebro brand was established in the early 1900s by Alex Fries & Brothers, a Cincinnati Flavor Company. In 1980, the brand was re-launched as an aroma chemical manufacturer. Since its inception, Alfrebro’s primary focus has been to provide quality natural and high value synthetic chemicals. Email: Sarah Forbis Email: Sales Voice: 513-539-3021 Fax: 513-539-7372 US Voice: 513-539-7373 Product(s): cis-3-HEXENYL VALERATE NATURAL
-
-
Bedoukian Research, Inc. Constantly Improving Working closely with our customers to meet their requirements. Paul Bedoukian founded the company to fill a niche as a supplier of high quality specialty aroma and flavor ingredients. In 1975 the company began manufacturing insect pheromones which are chemically similar to flavor and fragrance ingredients. Today, Bedoukian Research offers more than 450 Aroma Chemicals and 50 Insect Pheromones, while also providing custom manufacturing services to the pharmaceutical, agrochemical, and specialty chemical industries. US Email: Customer Service US Voice: 1-203-830-4000 US Fax: 1-203-830-4010 Products List: View Product(s): 118 cis-3-HEXENYL VALERATE ≥97.5% (cis), Kosher MSDS Can be used for green, peppery notes in delicate fragrances.
Can be used in butter and fruit flavors.
-
-
Beijing Lys Chemicals Co, LTD. From Grams to Tons Fine chemical high-tech company which contains R&D, production, and sales. BEIJING LYS CHEMICALS CO, LTD, established in 2004, is a fine chemical high-tech company which contains R&D, production, and sales. We mainly engaged in export and technology development of flavor and fragrance materials and pharmaceutical intermediates. We have nearly 500 kinds of products, from grams to tons, exported to USA, Europe, South Asia and etc. And we custom manufacture new products according to customers’ needs, and serve good quality products and service. Our goal is to become a fine chemical enterprise which could provide special products and services. Email: Mr. Jia Email: Mr. Guo Voice: 86-10-68418738 Fax: 86-10-68418739 Mr. Guo 86-10-68483445 Mr. Guo 86-10-68418739 Product(s): 10274 Cis-3-Hexenyl valerate
-
-
Penta International Corporation Chemistry innovation At Penta, our products and services help businesses do business better. For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes. US Email: Technical Services US Email: Sales US Voice: (973) 740-2300 US Fax: (973) 740-1839 Product(s): 08-36600 cis-3-HEXENYL VALERATE, Kosher 08-36602 cis-3-HEXENYL VALERATE NATURAL, Kosher
-
-
SAFC Complete Supply Chain The perfect blend of products and services that bring your creativity to life. Sigma-Aldrich is a leading Life Science and High Technology company dedicated to providing high-quality, safe and certified flavor ingredients with transparent and easily accessible documentation to customers around the globe. Sigma-Aldrich also provides a suite of analytical tools that allow food analysts to simplify sample preparation, cleanup and analysis steps, while increasing sensitivity to trace ingredients and harmful substances to meet regulations and quality standards. Email: Information US Email: Sales US Voice: 800-244-1173 US Fax: 800-368-4661 Product(s): W393600 cis-3-Hexenyl valerate mixture of isomers, natural (US), ≥97%, Kosher MSDS
-
-
SRS Aromatics Ltd For over 25 years Bringing flavour and fragrance into your world. As suppliers / distributors of ingredients to the fragrance and flavour industries, our goal is to provide high quality materials at competitive prices with an exceptional level of service. Established in 1984, SRS Aromatics Ltd is an independent family owned business which has become very well-respected within the fragrance and flavour industry as a reliable and trustworthy partner. Over the years this has allowed the company to develop strong relationships with many global manufacturers; several of whom we represent in the UK. A core aim of our business is to work extremely closely with both our suppliers and customers to maximise service levels with minimum disruption to supply. Email: Info Email: Sales Voice: +44 (0) 1284 704076 Fax: +44 (0) 1284 760819 Product(s): HEXENYL CIS 3 VALERATE
-
-
Treatt PLC Full Range of Naturals World-leading, independent ingredients supplier to the flavour and fragrance industries. We are proud of our heritage in trading essential oils. Our founder Richard Court Treatt's charismatic and personable approach still embodies the spirit of Treatt today. Email: Enquiries US Email: Enquiries Voice: +44 (0) 1284 702500 Fax: +44 (0) 1284 703809 US Voice: +1 863 668 9500 US Fax: +1 863 668 3388 Product(s): cis-3-Hexenyl Valerate
-
-
Ernesto Ventós S.A. Continued Customer Satisfaction We employ our five senses to do our job well. Ventós has specialized in the distribution of raw materials for the flavour and fragrance industry. With more than 1700 references permanently available from stock, we offer a just-in-time response to our customer needs, being able to deliver from 1kg to several tonnes all over the world. Email: Information Email: Gemma Parramon (Europe) US Email: Jordi Sort (Northern Europe and US) Email: Olivia Gautier (Asia, Africa and Oceania ) Email: Ramon Rubau (Latin America) Voice: +34 934706210 Fax: +34 934733010 Product(s): CIS-3-HEXENYL VALERATE
-
| [(Z)-hex-3-enyl] pentanoate (Click)
IUPAC Name: [(Z)-hex-3-enyl] pentanoate
Std.InChI: InChI=1S/C11H20O2/c1-3-5-7-8-10-13-11(12)9-6-4-2/h5,7H,3-4,6,8-10H2,1-2H3/b7-5+
InChI: InChI=1/C11H20O2/c1-3-5-7-8-10-13-11(12)9-6-4-2/h5,7H,3-4,6,8-10H2,1-2H3/b7-5+
Std.InChIKey: XPFTVTFOOTVHIA-FNORWQNLSA-N
InChIKey: XPFTVTFOOTVHIA-FNORWQNLBR
SMILES: CCCCC(=O)OCC/C=C/CC
| |
| CAS Number: | 35852-46-1 |
| % from: | 97.50% to 99.90% |
| ECHA EC Number: | 252-761-5 |
| FDA UNII: | FLC67L4NLM |
| MDL: | MFCD00036549 |
| FEMA Number: | 3936 |
| CoE Number: | 10686 |
| XlogP3-AA: | 3.30 (est) |
| Molecular Weight: | 184.27880000 |
| Formula: | C11 H20 O2 |
| NMR Predictor: | Predict |
| Also(can) Contains: | (E)-3-hexen-1-yl valerate 0.10% to 2.50% |
| EFSA/JECFA Comments: | CASrn in Register refers to (Z)-isomer. Register name to be changed to Hex-(3Z)-enyl valerate. |
| Category: | flavor and fragrance agents |
| US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information: | |
| Google Scholar: | Search |
| Google Books: | Search |
| Google Scholar: with word "volatile" | Search |
| Google Scholar: with word "flavor" | Search |
| Google Scholar: with word "odor" | Search |
| Perfumer and Flavorist: | Search |
| Google Patents: | Search |
| US Patents: | Search |
| EU Patents: | Search |
| Pubchem Patents: | Search |
| JECFA Food Flavoring: | 1278 cis-3-hexenyl valerate |
| Flavis Number: | 09.571 (Old) |
| EU SANCO Food Flavourings: | 09.571 (3Z)-hexenyl valerate |
| FEMA Number: | 3936 (Z)-3-hexenyl valerate |
| FDA Mainterm: | (Z)-3-HEXENYL VALERATE |
Physical Properties:
| Appearance: | colorless clear liquid (est) |
| Assay: | 97.00 to 100.00 % sum of isomers |
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.87900 to 0.88500 @ 25.00 °C. |
| Pounds per Gallon - (est).: | 7.314 to 7.364 |
| Refractive Index: | 1.43200 to 1.43800 @ 20.00 °C. |
| Boiling Point: | 108.00 to 109.00 °C. @ 20.00 mm Hg |
| Acid Value: | 1.00 max. KOH/g |
| Vapor Pressure: | 0.046000 mm/Hg @ 25.00 °C. (est) |
| Vapor Density: | 6.3 ( Air = 1 ) |
| Flash Point: | 192.00 °F. TCC ( 88.89 °C. ) |
| logP (o/w): | 3.928 (est) |
Organoleptic Properties:
| Odor Type: | green |
| Odor Strength: | medium |
| Odor Description: at 100.00 %. | green fruity apple pear kiwi unripe banana tropical Luebke, William tgsc, (2009) |
| Odor sample from: | Bedoukian Research, Inc. |
| Odor Description: at 1.00 %. | Heavy green with an estry fresh fruity nuance of apple, pear, grape, banana and kiwi Mosciano, Gerard P&F 25, No. 5, 72, (2000) |
| Taste Description: at 1.00 - 10.00 ppm. | Green, with fresh to unripe juicy fruity notes reminiscent of apple, pear, kiwi, with tropical nuances Mosciano, Gerard P&F 25, No. 5, 72, (2000) |
| Substantivity: | 4 hour(s) at 100.00 % |
Cosmetic Information:
| CosIng: | cosmetic data |
| Cosmetic Uses: |
perfuming agents |
Suppliers:
Safety Information:
| European information : | |||
| Most important hazard(s): | |||
| None - None found. | |||
|
S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes. S 36 - Wear suitable protective clothing. | |||
| Hazards identification | |||
| Classification of the substance or mixture | |||
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) | |||
| None found. | |||
| GHS Label elements, including precautionary statements | |||
| Pictogram | |||
| Hazard statement(s) | |||
| None found. | |||
| Precautionary statement(s) | |||
| None found. | |||
| Oral/Parenteral Toxicity: | |||
|
oral-rat LD50 > 5000 mg/kg 1/10 rats died after a dose of 5000 mg/kg. (Moreno, 1978d) oral-rat LDLo 5000 mg/kg Food and Chemical Toxicology. Vol. 30, Pg. 47S, 1992. | |||
| Dermal Toxicity: | |||
|
skin-rabbit LDLo 5000 mg/kg Food and Chemical Toxicology. Vol. 30, Pg. 47S, 1992. | |||
| Inhalation Toxicity: | |||
| Not determined | |||
Safety in Use Information:
| Category: | flavor and fragrance agents | ||
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 6.10 (μg/capita/day) | ||
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 9.00 (μg/capita/day) | ||
| Modified Theoretical Added Maximum Daily Intake (mTAMDI): | ND (μg/person/day) | ||
| Threshold of Concern: | 1800 (μg/person/day) | ||
| Structure Class: | I | ||
| Recommendation for (Z)-3-hexen-1-yl valerate usage levels up to: | |||
| 10.0000 % in the fragrance concentrate. | |||
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). | |||
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA on the "Resources" link. | |||
| publication number: 19. Update in publication number(s): 20 | |||
| average usual ppm | average maximum ppm | ||
| baked goods: | 15.00000 | 30.00000 | |
| beverages(nonalcoholic): | 0.50000 | 3.00000 | |
| beverages(alcoholic): | 4.00000 | 8.00000 | |
| breakfast cereal: | - | - | |
| cheese: | - | - | |
| chewing gum: | 5.00000 | 30.00000 | |
| condiments / relishes: | - | - | |
| confectionery froastings: | - | - | |
| egg products: | - | - | |
| fats / oils: | - | - | |
| fish products: | - | - | |
| frozen dairy: | 7.00000 | 15.00000 | |
| fruit ices: | - | - | |
| gelatins / puddings: | - | - | |
| granulated sugar: | - | - | |
| gravies: | - | - | |
| hard candy: | 3.00000 | 18.00000 | |
| imitation dairy: | - | - | |
| instant coffee / tea: | - | - | |
| jams / jellies: | - | - | |
| meat products: | - | - | |
| milk products: | 0.50000 | 3.00000 | |
| nut products: | - | - | |
| other grains: | - | - | |
| poultry: | - | - | |
| processed fruits: | - | - | |
| processed vegetables: | - | - | |
| reconstituted vegetables: | - | - | |
| seasonings / flavors: | - | - | |
| snack foods: | - | - | |
| soft candy: | - | - | |
| soups: | - | - | |
| sugar substitutes: | - | - | |
| sweet sauces: | - | - | |
Safety References:
| European Food Safety Athority(efsa): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): | |
| Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 6 (FGE.06): Straight-and branched-chain aliphatic unsatured primary alcohols, aldehydes, carboxylic acids, and esters from chemical groups 1 and 4 page or pdf | |
| Flavouring Group Evaluation 6, Revision 1 (FGE.06Rev1) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC) page or pdf | |
| Flavouring Group Evaluation 62 (FGE.62) Consideration of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05 (2005) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06 (2004) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) page or pdf | |
| Flavouring Group Evaluation 62 Rev1 (FGE.62 Rev1): Consideration of of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st and 68th meeting) structurally related to branched- and straight-chain unsaturated carboxylic acids and esters of these with aliphatic saturated alcohols evaluated by EFSA in FGE.05Rev2 (2010) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06Rev1 (2008) page or pdf | |
| EPI System: | View |
| Chemicalize.org: | Calculate predicted properties |
| EPA Substance Registry Services (TSCA): | 35852-46-1 |
| EPA ACToR: | Toxicology Data |
| National Institute of Allergy and Infectious Diseases: | Data |
| WGK Germany: | 2 |
| [(Z)-hex-3-enyl] pentanoate | |
| Chemidplus: | 0035852461 |
| RTECS: | SA3698000 for cas# 35852-46-1 |
References:
| [(Z)-hex-3-enyl] pentanoate | |
| NIST Chemistry WebBook: | Search Inchi |
| Canada Domestic Sub. List: | 35852-46-1 |
| Pubchem (cid): | 5352976 |
| Pubchem (sid): | 135075565 |
Other Information:
| (IUPAC): | Atomic Weights of the Elements 2009 |
| (IUPAC): | Atomic Weights of the Elements 2009 (pdf) |
| Videos: | The Periodic Table of Videos |
| tgsc: | Atomic Weights use for this web site |
| (IUPAC): | Periodic Table of the Elements |
| FDA Everything Added to Food in the United States (EAFUS): | View |
| Export Tariff Code: | 2915.60.0000 |
| VCF-Online: | VCF Volatile Compounds in Food |
| ChemSpider: | View |
Potential Blenders and core components note
Potential Uses:
| apple | FR | |
| banana | FR | |
| butter | FR | |
| fruit | FR | |
| grape | FR | |
| green | FR | |
| kiwi | FR | |
| lychee | FR | |
| mango | FR | |
| melon | FR | |
| pear | FR | |
| tea black | FL |
Natural Occurrence in: note
| mango GRIN Trop Picture | |
| melon | |
| origanum | |
| pepper tabasco pepper | |
| tea black tea |
Synonyms:
| (Z)- | hex-3-enyl valerate | ||
| cis- | hex-3-enyl valerate | ||
| [(Z)- | hex-3-enyl] pentanoate | ||
| (Z)-3- | hexen-1-ol, pentanoate | ||
| (Z)-3- | hexen-1-yl pentanoate | ||
| cis-3- | hexen-1-yl pentanoate | ||
| (Z)-3- | hexen-1-yl valerate | ||
| cis-3- | hexen-1-yl valerate | ||
| cis-3- | hexenyl N-valerate | ||
| cis-3- | hexenyl pentanoate | ||
| (3Z)- | hexenyl valerate | ||
| (Z)-3- | hexenyl valerate | ||
| cis-3- | hexenyl valerate | ||
| hexenyl-cis-3-valerate | |||
| (Z)- | pentanoic acid 3-hexen-1-yl ester | ||
| pentanoic acid, 3-hexenyl ester, (Z)- | |||
| (Z)- | valeric acid 3-hexen-1-yl ester | ||
| valeric acid, 3-hexenyl ester, (Z)- |
