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Category:flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | colorless to pale yellow clear liquid (est) |
| Assay: | 98.00 to 100.00
|
| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.90400 to 0.91400 @ 25.00 °C.
|
| Pounds per Gallon - (est).: | 7.522 to 7.605
|
| Refractive Index: | 1.41800 to 1.42600 @ 20.00 °C.
|
| Boiling Point: | 151.00 to 152.00 °C. @ 760.00 mm Hg
|
| Acid Value: | 1.00 max. KOH/g
|
| Vapor Pressure: | 4.459000 mmHg @ 25.00 °C. (est) |
| Flash Point: | 134.00 °F. TCC ( 56.67 °C. )
|
| logP (o/w): | 1.800 (est) |
| Soluble in: |
| | alcohol | | | water, 1104 mg/L @ 25 °C (est) |
| Insoluble in: |
| | water |
Organoleptic Properties:
| Odor Description:at 100.00 %. fruity |
| Odor and/or flavor descriptions from others (if found). |
Cosmetic Information:
Suppliers:
Safety Information:
| Preferred SDS: View |
| European information : |
| Most important hazard(s): | | Xi - Irritant |
R 10 - Flammable.
R 36/38 - Irritating to skin and eyes.
S 02 - Keep out of the reach of children.
S 16 - Keep away from sources of ignition - No Smoking.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 - Wear suitable gloves and eye/face protection.
|
| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
|
Not determined
|
| Dermal Toxicity: |
|
Not determined
|
| Inhalation Toxicity: |
|
Not determined
|
Safety in Use Information:
| Category: | | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| Recommendation for isoprenyl acetate usage levels up to: | | | 1.0000 % in the fragrance concentrate.
|
| |
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 7.30 (μg/capita/day) |
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 11.00 (μg/capita/day) |
| Modified Theoretical Added Maximum Daily Intake (mTAMDI): | 3900 (μg/person/day) |
| Threshold of Concern: | 1800 (μg/person/day) |
| Structure Class: | I |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 20 |
| Click here to view publication 20 |
| | average usual ppm | average maximum ppm |
| baked goods: | 10.00000 | 100.00000 |
| beverages(nonalcoholic): | 0.30000 | 3.00000 |
| beverages(alcoholic): | 1.50000 | 15.00000 |
| breakfast cereal: | 0.30000 | 1.50000 |
| cheese: | - | - |
| chewing gum: | 15.00000 | 100.00000 |
| condiments / relishes: | - | - |
| confectionery froastings: | 1.50000 | 10.00000 |
| egg products: | 1.50000 | 10.00000 |
| fats / oils: | 1.50000 | 10.00000 |
| fish products: | - | - |
| frozen dairy: | 6.00000 | 60.00000 |
| fruit ices: | 3.00000 | 30.00000 |
| gelatins / puddings: | 3.00000 | 30.00000 |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | 5.00000 | 50.00000 |
| imitation dairy: | - | - |
| instant coffee / tea: | 0.60000 | 6.00000 |
| jams / jellies: | 3.00000 | 30.00000 |
| meat products: | - | - |
| milk products: | 0.60000 | 60.00000 |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | 1.50000 | 15.00000 |
| snack foods: | - | - |
| soft candy: | 3.00000 | 30.00000 |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
| |
| Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i). |
| Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm. |
| | average usage mg/kg | maximum usage mg/kg |
| Dairy products, excluding products of category 02.0 (01.0): | 7.00000 | 35.00000 |
| Fats and oils, and fat emulsions (type water-in-oil) (02.0): | 5.00000 | 10.00000 |
| Edible ices, including sherbet and sorbet (03.0): | 10.00000 | 50.00000 |
| Processed fruit (04.1): | 7.00000 | 35.00000 |
| Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2): | - | - |
| Confectionery (05.0): | 10.00000 | 50.00000 |
| Chewing gum (05.3): | - | - |
| Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0): | 5.00000 | 25.00000 |
| Bakery wares (07.0): | 10.00000 | 50.00000 |
| Meat and meat products, including poultry and game (08.0): | 2.00000 | 10.00000 |
| Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0): | 2.00000 | 10.00000 |
| Eggs and egg products (10.0): | - | - |
| Sweeteners, including honey (11.0): | - | - |
| Salts, spices, soups, sauces, salads, protein products, etc. (12.0): | 5.00000 | 25.00000 |
| Foodstuffs intended for particular nutritional uses (13.0): | 10.00000 | 50.00000 |
| Non-alcoholic ("soft") beverages, excl. dairy products (14.1): | 5.00000 | 25.00000 |
| Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2): | 10.00000 | 50.00000 |
| Ready-to-eat savouries (15.0): | 20.00000 | 100.00000 |
| Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0): | 5.00000 | 25.00000 |
Safety References:
European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
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European Food Safety Authority (EFSA) reference(s):
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Opinion of the Scientific Panel on food additives, flavourings, processing aids and materials in contact with food (AFC) related to Flavouring Group Evaluation 6 (FGE.06): Straight-and branched-chain aliphatic unsatured primary alcohols, aldehydes, carboxylic acids, and esters from chemical groups 1 and 4
View page or View pdf
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Flavouring Group Evaluation 6, Revision 1 (FGE.06Rev1) - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in contact with Food (AFC)
View page or View pdf
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Flavouring Group Evaluation 62 (FGE.62) Consideration of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05 (2005) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06 (2004) (Commission Regulation (EC) No 1565/2000 of 18 July 2000)
View page or View pdf
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Flavouring Group Evaluation 62 Rev1 (FGE.62 Rev1): Consideration of of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st and 68th meeting) structurally related to branched- and straight-chain unsaturated carboxylic acids and esters of these with aliphatic saturated alcohols evaluated by EFSA in FGE.05Rev2 (2010) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06Rev1 (2008)
View page or View pdf
|
| EPI System: View |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA Substance Registry Services (TSCA):5205-07-2 |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :78879 |
| National Institute of Allergy and Infectious Diseases:Data |
| WGK Germany:2 |
| 3-methylbut-3-enyl acetate |
| Chemidplus:0005205072 |
References:
Other Information:
Potential Blenders and core components note
| For Odor |
| No odor group found for these |
(E+Z)-4,8- dimethyl-3,7-nonadien-2-one
FL/FR |
(Z)-8- tetradecenal
FL/FR |
| aldehydic |
| aldehydic |
(Z)-4- dodecenal
FL/FR |
| balsamic |
benzyl cinnamate
FL/FR |
cinnamyl formate
FL/FR |
| citrus |
2- dodecanone
FL/FR |
2- heptanol
FL/FR |
| fatty |
butyl undecylenate
FL/FR |
4- ethyl octanoic acid
FL/FR |
| fermented |
methyl decanoate
FL/FR |
| floral |
iso amyl angelate
FL/FR |
alpha- amyl cinnamaldehyde
FL/FR |
benzyl acetate
FL/FR |
benzyl acetoacetate
FL/FR |
benzyl formate
FL/FR |
citronellyl acetate
FL/FR |
citronellyl butyrate
FL/FR |
citronellyl hexanoate
FL/FR |
citronellyl propionate
FL/FR |
(E)- citronellyl tiglate
FL/FR |
dihydrojasmone
FL/FR |
dimethyl benzyl carbinyl acetate
FL/FR |
geraniol
FL/FR |
menthadienyl formate
FR |
ortho- methoxybenzyl ethyl ether
FR |
methoxymelonal
FL/FR |
methyl benzyl acetate (mixed ortho-,meta-,para-)
FL/FR |
alpha-iso methyl ionone (90% min.)
FL/FR |
methyl ionyl acetate
FL/FR |
neryl isovalerate
FL/FR |
3- nonanon-1-yl acetate
FL/FR |
orris rhizome concrete butter (iris pallida)
FL/FR |
petitgrain lemon oil
FL/FR |
phenethyl isobutyrate
FL/FR |
phenethyl isovalerate
FL/FR |
1- phenyl propyl butyrate
FL/FR |
2- phenyl propyl isobutyrate
FL/FR |
4- phenyl-3-buten-2-ol
FL/FR |
iso propyl benzoate
FL/FR |
rose undecene
FR |
star fruit oil cuba
FL/FR |
terpinyl formate
FL/FR |
terpinyl valerate
FL/FR |
tetrahydroionyl acetate
FR |
(E)-2,5,9- trimethyl-4,9-decadien-1-al
FR |
| fruity |
iso amyl 2-methyl butyrate
FL/FR |
benzaldehyde / methyl anthranilate schiff's base
FR |
berry hexanoate
FR |
iso butyl anthranilate
FL/FR |
iso butyl furyl propionate
FL/FR |
citronellyl isobutyrate
FL/FR |
(Z)-beta- damascone
FL/FR |
(E)-beta- damascone
FL/FR |
beta- damascone
FL/FR |
ethyl isobutyrate
FL/FR |
ethyl levulinate
FL/FR |
heptanal cyclic ethylene acetal
FR |
heptyl isobutyrate
FL/FR |
3- mercaptohexyl acetate
FL/FR |
methyl (Z)-3-hexenoate
FL/FR |
methyl acetoacetate
FL/FR |
methyl isobutyrate
FL/FR |
(E)-7- methyl-3-octen-2-one
FL/FR |
iso propyl isobutyrate
FL/FR |
rhubarb pyran
FR |
4-(para- tolyl)-2-butanone
FL/FR |
tropical ionone
FL/FR |
(E)-2- undecenal
FL/FR |
| green |
iso amyl 3-(2-furan) propionate
FL/FR |
citrus carbaldehyde / methyl anthranilate schiff's base
FR |
green carboxylate
FR |
(Z)-3- hexen-1-yl isovalerate
FL/FR |
hexoxyacetaldehyde dimethyl acetal
FR |
| herbal |
chamomile isobutyrate
FR |
chamomile propionate
FR |
chamomile valerate
FR |
clary propyl acetate
FR |
methyl cyclogeranate (Firmenich)
FR |
(1S,5R)- myrtenyl acetate
FL/FR |
| powdery |
alpha- methyl ionone
FL/FR |
| spicy |
para- anisyl formate
FL/FR |
| waxy |
3- decanone
FL/FR |
| woody |
2- decalinyl acetate
FR |
| For Flavor |
| No flavor group found for these |
1- acetyl cyclohexyl acetate
FL |
amyl angelate
FL |
iso amyl angelate
FL/FR |
2- butyl thiophene
FL |
beta- cubebene
FL |
3- decanone
FL/FR |
2,4- difurfuryl furan
FL |
dihydronootkatone
FL |
S-(2,5- dimethyl-3-furyl) ethane thioate
FL |
(E+Z)-4,8- dimethyl-3,7-nonadien-2-one
FL/FR |
(Z)-4- dodecenal
FL/FR |
methyl acetoacetate
FL/FR |
methyl benzyl acetate (mixed ortho-,meta-,para-)
FL/FR |
3- octyl butyrate
FL |
1- phenyl propyl butyrate
FL/FR |
2- phenyl propyl isobutyrate
FL/FR |
iso propyl benzoate
FL/FR |
iso propyl isobutyrate
FL/FR |
(Z)-8- tetradecenal
FL/FR |
|
iso amyl 3-(2-furan) propionate
FL/FR |
benzyl acetoacetate
FL/FR |
iso butyl furyl propionate
FL/FR |
beta- damascone
FL/FR |
| berry |
| berry |
heptyl isobutyrate
FL/FR |
| burnt |
ethyl 2-furoate
FL |
| citrus |
dehydronootkatone
FL |
petitgrain lemon oil
FL/FR |
| ethereal |
ethyl isobutyrate
FL/FR |
methyl isobutyrate
FL/FR |
| fatty |
2- dodecanone
FL/FR |
4- ethyl octanoic acid
FL/FR |
methyl decanoate
FL/FR |
(E)-7- methyl-3-octen-2-one
FL/FR |
| floral |
citronellyl acetate
FL/FR |
citronellyl hexanoate
FL/FR |
citronellyl propionate
FL/FR |
dihydrojasmone
FL/FR |
dimethyl benzyl carbinyl acetate
FL/FR |
geraniol
FL/FR |
alpha-iso methyl ionone (90% min.)
FL/FR |
orris rhizome concrete butter (iris pallida)
FL/FR |
tropical ionone
FL/FR |
| fruity |
iso amyl 2-methyl butyrate
FL/FR |
benzyl acetate
FL/FR |
benzyl formate
FL/FR |
iso butyl anthranilate
FL/FR |
citronellyl butyrate
FL/FR |
citronellyl isobutyrate
FL/FR |
(E)-beta- damascone
FL/FR |
(Z)-beta- damascone
FL/FR |
ethyl levulinate
FL/FR |
2- heptanol
FL/FR |
2- hexyl-4-acetoxytetrahydrofuran
FL |
methoxymelonal
FL/FR |
methyl (Z)-3-hexenoate
FL/FR |
methyl 4-phenyl butyrate
FL |
alpha- methyl ionone
FL/FR |
neryl isovalerate
FL/FR |
3- nonanon-1-yl acetate
FL/FR |
phenethyl isovalerate
FL/FR |
2- phenyl-4-pentenal
FL |
star fruit oil cuba
FL/FR |
terpinyl formate
FL/FR |
terpinyl valerate
FL/FR |
4-(para- tolyl)-2-butanone
FL/FR |
| green |
(E)- citronellyl tiglate
FL/FR |
(Z)-3- hexen-1-yl isovalerate
FL/FR |
| honey |
phenethyl isobutyrate
FL/FR |
| spicy |
para- anisyl formate
FL/FR |
benzyl cinnamate
FL/FR |
cinnamyl formate
FL/FR |
| tropical |
alpha- amyl cinnamaldehyde
FL/FR |
3- mercaptohexyl acetate
FL/FR |
| waxy |
butyl undecylenate
FL/FR |
4- phenyl-3-buten-2-ol
FL/FR |
(E)-2- undecenal
FL/FR |
| woody |
methyl ionyl acetate
FL/FR |
(1S,5R)- myrtenyl acetate
FL/FR |
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| | acetic acid 3-methyl but-3-enyl ester | | | acetic acid, 3-methylbut-3-enyl ester | | 3- | buten-1-ol, 3-methyl-, acetate | | 3- | methyl but-3-enyl acetate | | 3- | methyl-3-buten-1-ol acetate | | 3- | methyl-3-buten-1-ol, acetate | | 3- | methyl-3-buten-1-yl acetate | | 3- | methyl-3-butenyl acetate | | 3- | methylbut-3-en-1-yl acetate | | 3- | methylbut-3-ene-1-ol acetate | | 3- | methylbut-3-enyl acetate | | 3-iso | pentenyl acetate | | iso | prenyl acetate | | iso | prenylacetate |
Articles:
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3D/inchi