Physical Properties:
Appearance: | colorless clear liquid (est) |
Assay: | 97.00 to 100.00 % sum of isomers
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Food Chemicals Codex Listed: | No |
Specific Gravity: | 0.88800 to 0.89200 @ 25.00 °C.
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Pounds per Gallon - (est).: | 7.389 to 7.422
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Refractive Index: | 1.42800 to 1.43100 @ 20.00 °C.
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Boiling Point: | 180.00 to 182.00 °C. @ 760.00 mm Hg
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Boiling Point: | 83.00 to 84.00 °C. @ 17.00 mm Hg
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Vapor Pressure: | 0.404000 mm/Hg @ 25.00 °C. (est) |
Vapor Density: | 5.3 ( Air = 1 ) |
Flash Point: | 140.00 °F. TCC ( 60.00 °C. )
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logP (o/w): | 2.909 (est) |
Organoleptic Properties:
Odor Type: | green |
Odor Strength: | medium , recommend smelling in a 10.00 % solution or less |
Odor Description: at 10.00 % in dipropylene glycol. | green pear apple fresh fruity waxy leafy Luebke, William tgsc, (1991) |
Odor sample from: | Bedoukian Research, Inc. |
Odor Description:
| Green, fruity, apple and pear with a sweet, leafy nuance Mosciano, Gerard P&F 21, No. 1, 33, (1996) |
Taste Description: at 5.00 ppm. | Green, apple and pear with an oily, waxy, slightly citrus note Mosciano, Gerard P&F 21, No. 1, 33, (1996) |
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Cosmetic Information:
Suppliers:
A.C.S. International |
cis-3-Hexenyl Propionate
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Advanced Biotech |
cis-3-HEXENYL PROPIONATE NATURAL
98% min. (mixed isomers) |
Alfrebro |
cis-3-HEXENYL PROPIONATE NATURAL
Odor: Fruity, Tropical, Pineapple |
Apiscent Labs |
C3 HEXENYL PROPIONATE
Odor: Intensely green vegetable-like, fatty odor & taste |
Apple Flavor & Fragrance |
cis-3-Hexenyl propionate
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Aurochemicals |
cis-3-HEXENYL PROPIONATE, Natural
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Bedoukian Research |
cis-3-HEXENYL PROPIONATE
≥97.0% (cis), Kosher Odor: Sweet, powerful, intensely green odor that is vegetable-like and fatty Use: Lends a citrus note to fragrances or can be used as a modifier for the acetate. Flavor: green Can be used in vegetable, spice and fruit flavors. |
Beijing Lys Chemicals |
cis-3-Hexenyl propionate
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Berjé |
cis-3-Hexenyl Propionate
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CG Herbals |
cis-3-Hexenyl Propionate
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Ernesto Ventós |
CIS-3-HEXENYL PROPIONATE
Odor: GREEN, VEGETABLE-LIKE, FATTY |
Flowersynth |
CIS-3-HEXENYL PROPIONATE
Odor: GREEN PEAR FRESH APPLE |
Frutarom |
cis-3-HEXENYL PROPIONATE
≥98.00% (sum of isomers), NI, Kosher Odor: Fresh, Fruity, Green, Pear, Waxy Use: Suggested Uses: Apple, Apricot, Citrus Fruits, Hard Fruits, Kiwi, Plum, Soft Fruits, Tea |
Grau Aromatics |
HEXENYL-cis-3-PROPIONATE
NI, Kosher |
Indukern F&F |
CIS-3-HEXENYL PROPIONATE
Odor: SWEET, GREEN, VEGETABLE |
Inoue Perfumery |
CIS-3-HEXENYL PROPIONATE
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Lluch Essence |
cis-3-HEXENYL PROPIONATE
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Moellhausen |
PROPANOATO CIS-3-ESENILE
Nature-identical |
Penta International |
cis-3-HEXENYL PROPIONATE, Kosher
| Penta International |
cis-3-HEXENYL PROPIONATE, NATURAL, Kosher
| Reincke & Fichtner |
cis-3-Hexenyl Propionate
|
Robertet |
HEXENYL CIS-3 PROPIONATE
Pure & Nat (EU) |
Crops calendar |
SAFC Global |
cis-3-Hexenyl propionate
>97%, Kosher |
SRS Aromatics |
HEXENYL CIS 3 PROPIONATE
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Taytonn |
Cis-3-Hexenyl Propionate
Odor: Fresh, Fruity, Green, Waxy |
The Lermond Company |
cis-3-Hexenyl Propionate
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Treatt |
cis-3-Hexenyl Propionate
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Vigon International |
Hexenyl cis-3 Propionate Natural
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ZEON Chemicals |
cis-3-Hexenyl propionate
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Safety Information:
European information : |
Most important hazard(s): | None - None found. |
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S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes.
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Hazards identification |
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Classification of the substance or mixture |
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
None found. |
GHS Label elements, including precautionary statements |
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Pictogram | |
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Hazard statement(s) |
None found. |
Precautionary statement(s) |
None found. |
Oral/Parenteral Toxicity: | |
oral-rat LD50 > 5000 mg/kg (Moreno, 1976f)
oral-rat LD50 > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 17, Pg. 805, 1979.
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Dermal Toxicity: | |
skin-rabbit LD50 > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 17, Pg. 805, 1979.
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Inhalation Toxicity: | |
Not determined
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Safety in Use Information:
Category: | flavor and fragrance agents |
Maximised Survey-derived Daily Intakes (MSDI-EU): | 12.00 (μg/capita/day) |
Maximised Survey-derived Daily Intakes (MSDI-USA): | 18.00 (μg/capita/day) |
Modified Theoretical Added Maximum Daily Intake (mTAMDI): | ND (μg/person/day) |
Threshold of Concern: | 1800 (μg/person/day) |
Structure Class: | I |
Recommendation for (Z)-3-hexen-1-yl propionate usage levels up to: | | 8.0000 % in the fragrance concentrate.
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Recommendation for (Z)-3-hexen-1-yl propionate flavor usage levels up to: | | 5.0000 ppm in the finished product.
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Safety References:
European Food Safety Athority(efsa): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 62 (FGE.62) Consideration of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05 (2005) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06 (2004) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) page or pdf |
Flavouring Group Evaluation 62 Rev1 (FGE.62 Rev1): Consideration of of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st and 68th meeting) structurally related to branched- and straight-chain unsaturated carboxylic acids and esters of these with aliphatic saturated alcohols evaluated by EFSA in FGE.05Rev2 (2010) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06Rev1 (2008) page or pdf |
EPI System: | View |
Chemicalize.org: | Calculate predicted properties |
EPA Substance Registry Services (TSCA): | 33467-74-2 |
EPA ACToR: | Toxicology Data |
National Institute of Allergy and Infectious Diseases: | Data |
WGK Germany: | 2 |
| [(Z)-hex-3-enyl] propanoate |
Chemidplus: | 0033467742 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Natural Occurrence in: note
Synonyms:
(3Z)- | hex-3-en-1-yl propanoate | (3Z)- | hex-3-en-1-yl propionate | (Z)- | hex-3-enyl propionate | cis- | hex-3-enyl propionate | [(Z)- | hex-3-enyl] propanoate | | hex-3(cis)-enyl propionate | (Z)-3- | hexen-1-ol propanoate | (Z)-3- | hexen-1-ol propionate | 3- | hexen-1-ol, propanoate, (3Z)- | 3- | hexen-1-ol, propanoate, (Z)- | 3- | hexen-1-ol, propionate, (Z)- | beta,gamma- | hexen-1-yl propanoate | (Z)-3- | hexen-1-yl propionate | cis-3- | hexen-1-yl propionate | cis-beta- | hexen-1-yl propionate | | hexenyl cis-3 propionate | | hexenyl cis-3 propionate natural | cis-3- | hexenyl propanoate | 3- | hexenyl propanoate, cis- | (Z)-3- | hexenyl propionate | C3 | hexenyl propionate | cis-3- | hexenyl propionate | cis-3- | hexenyl propionate natural | 3- | hexenyl propionate, cis- | | hexenyl-cis-3-propionate | | propanoato cis-3-esenile | | propionic acid cis-hex-3-en-1-yl ester |
Articles:
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