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Physical Properties:
| Appearance: | colorless clear liquid (est) |
| Assay: | 97.00 to 100.00 % sum of isomers
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| Food Chemicals Codex Listed: | No |
| Specific Gravity: | 0.88800 to 0.89200 @ 25.00 °C.
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| Pounds per Gallon - (est).: | 7.389 to 7.422
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| Refractive Index: | 1.42800 to 1.43100 @ 20.00 °C.
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| Boiling Point: | 180.00 to 182.00 °C. @ 760.00 mm Hg
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| Boiling Point: | 83.00 to 84.00 °C. @ 17.00 mm Hg
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| Vapor Pressure: | 0.404000 mm/Hg @ 25.00 °C. (est) |
| Vapor Density: | 5.3 ( Air = 1 ) |
| Flash Point: | 140.00 °F. TCC ( 60.00 °C. )
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| logP (o/w): | 2.909 (est) |
Organoleptic Properties:
| Odor Type: | green |
| Odor Strength: | medium , recommend smelling in a 10.00 % solution or less |
Odor Description: at 10.00 % in dipropylene glycol. | green pear apple fresh fruity waxy leafy Luebke, William tgsc, (1991) |
| Odor sample from: | Bedoukian Research, Inc. |
Odor Description:
| Green, fruity, apple and pear with a sweet, leafy nuance Mosciano, Gerard P&F 21, No. 1, 33, (1996) |
Taste Description: at 5.00 ppm. | Green, apple and pear with an oily, waxy, slightly citrus note Mosciano, Gerard P&F 21, No. 1, 33, (1996) |
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Cosmetic Information:
Suppliers:
| A.C.S. International |
| cis-3-Hexenyl Propionate
|
| Advanced Biotech |
| cis-3-HEXENYL PROPIONATE NATURAL
98% min. (mixed isomers) |
| Alfrebro |
| cis-3-HEXENYL PROPIONATE NATURAL
Odor: Fruity, Tropical, Pineapple |
| Apiscent Labs |
| C3 HEXENYL PROPIONATE
Odor: Intensely green vegetable-like, fatty odor & taste |
| Apple Flavor & Fragrance |
| cis-3-Hexenyl propionate
|
| Aurochemicals |
| cis-3-HEXENYL PROPIONATE, Natural
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| Bedoukian Research |
| cis-3-HEXENYL PROPIONATE
≥97.0% (cis), Kosher Odor: Sweet, powerful, intensely green odor that is vegetable-like and fatty Use: Lends a citrus note to fragrances or can be used as a modifier for the acetate. Flavor: green Can be used in vegetable, spice and fruit flavors. |
| Beijing Lys Chemicals |
| cis-3-Hexenyl propionate
|
| Berjé |
| cis-3-Hexenyl Propionate
|
| CG Herbals |
| cis-3-Hexenyl Propionate
|
| Ernesto Ventós |
| CIS-3-HEXENYL PROPIONATE
Odor: GREEN, VEGETABLE-LIKE, FATTY |
| Flowersynth |
| CIS-3-HEXENYL PROPIONATE
Odor: GREEN PEAR FRESH APPLE |
| Frutarom |
| cis-3-HEXENYL PROPIONATE
≥98.00% (sum of isomers), NI, Kosher Odor: Fresh, Fruity, Green, Pear, Waxy Use: Suggested Uses: Apple, Apricot, Citrus Fruits, Hard Fruits, Kiwi, Plum, Soft Fruits, Tea |
| Grau Aromatics |
| HEXENYL-cis-3-PROPIONATE
NI, Kosher |
| Indukern F&F |
| CIS-3-HEXENYL PROPIONATE
Odor: SWEET, GREEN, VEGETABLE |
| Inoue Perfumery |
| CIS-3-HEXENYL PROPIONATE
|
| Lluch Essence |
| cis-3-HEXENYL PROPIONATE
|
| Moellhausen |
| PROPANOATO CIS-3-ESENILE
Nature-identical |
| Penta International |
| cis-3-HEXENYL PROPIONATE, Kosher
| | Penta International |
| cis-3-HEXENYL PROPIONATE, NATURAL, Kosher
| | Reincke & Fichtner |
| cis-3-Hexenyl Propionate
|
| Robertet |
| HEXENYL CIS-3 PROPIONATE
Pure & Nat (EU) |
| Crops calendar |
| SAFC Global |
| cis-3-Hexenyl propionate
>97%, Kosher |
| SRS Aromatics |
| HEXENYL CIS 3 PROPIONATE
|
| Taytonn |
| Cis-3-Hexenyl Propionate
Odor: Fresh, Fruity, Green, Waxy |
| The Lermond Company |
| cis-3-Hexenyl Propionate
|
| Treatt |
| cis-3-Hexenyl Propionate
|
| Vigon International |
| Hexenyl cis-3 Propionate Natural
|
| ZEON Chemicals |
| cis-3-Hexenyl propionate
|
Safety Information:
| European information : |
| Most important hazard(s): | | None - None found. |
| |
S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes.
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| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
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| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: | | |
oral-rat LD50 > 5000 mg/kg (Moreno, 1976f)
oral-rat LD50 > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 17, Pg. 805, 1979.
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| Dermal Toxicity: | | |
skin-rabbit LD50 > 5000 mg/kg Food and Cosmetics Toxicology. Vol. 17, Pg. 805, 1979.
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| Inhalation Toxicity: | | |
Not determined
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Safety in Use Information:
| Category: | flavor and fragrance agents |
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 12.00 (μg/capita/day) |
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 18.00 (μg/capita/day) |
| Modified Theoretical Added Maximum Daily Intake (mTAMDI): | ND (μg/person/day) |
| Threshold of Concern: | 1800 (μg/person/day) |
| Structure Class: | I |
| Recommendation for (Z)-3-hexen-1-yl propionate usage levels up to: | | | 8.0000 % in the fragrance concentrate.
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| Recommendation for (Z)-3-hexen-1-yl propionate flavor usage levels up to: | | | 5.0000 ppm in the finished product.
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Safety References:
| European Food Safety Athority(efsa): | Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies... |
| European Food Safety Authority (EFSA) reference(s): |
Flavouring Group Evaluation 62 (FGE.62) Consideration of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st meeting) structurally related to esters of branched- and straight-chain aliphatic saturated primary alcohols and of one secondary alcohol, and branched- and straight-chain unsaturated carboxylic acids evaluated by EFSA in FGE.05 (2005) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06 (2004) (Commission Regulation (EC) No 1565/2000 of 18 July 2000) page or pdf |
Flavouring Group Evaluation 62 Rev1 (FGE.62 Rev1): Consideration of of linear and branched-chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st and 68th meeting) structurally related to branched- and straight-chain unsaturated carboxylic acids and esters of these with aliphatic saturated alcohols evaluated by EFSA in FGE.05Rev2 (2010) and to straight- and branched-chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06Rev1 (2008) page or pdf |
| EPI System: | View |
| Chemicalize.org: | Calculate predicted properties |
| EPA Substance Registry Services (TSCA): | 33467-74-2 |
| EPA ACToR: | Toxicology Data |
| National Institute of Allergy and Infectious Diseases: | Data |
| WGK Germany: | 2 |
| | [(Z)-hex-3-enyl] propanoate |
| Chemidplus: | 0033467742 |
References:
Other Information:
Potential Blenders and core components note
Potential Uses:
Natural Occurrence in: note
Synonyms:
| (3Z)- | hex-3-en-1-yl propanoate | | (3Z)- | hex-3-en-1-yl propionate | | (Z)- | hex-3-enyl propionate | | cis- | hex-3-enyl propionate | | [(Z)- | hex-3-enyl] propanoate | | | hex-3(cis)-enyl propionate | | (Z)-3- | hexen-1-ol propanoate | | (Z)-3- | hexen-1-ol propionate | | 3- | hexen-1-ol, propanoate, (3Z)- | | 3- | hexen-1-ol, propanoate, (Z)- | | 3- | hexen-1-ol, propionate, (Z)- | | beta,gamma- | hexen-1-yl propanoate | | (Z)-3- | hexen-1-yl propionate | | cis-3- | hexen-1-yl propionate | | cis-beta- | hexen-1-yl propionate | | | hexenyl cis-3 propionate | | | hexenyl cis-3 propionate natural | | cis-3- | hexenyl propanoate | | 3- | hexenyl propanoate, cis- | | (Z)-3- | hexenyl propionate | | C3 | hexenyl propionate | | cis-3- | hexenyl propionate | | cis-3- | hexenyl propionate natural | | 3- | hexenyl propionate, cis- | | | hexenyl-cis-3-propionate | | | propanoato cis-3-esenile | | | propionic acid cis-hex-3-en-1-yl ester |
Articles:
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