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Category: flavor and fragrance agents
US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:
Physical Properties:
| Appearance: | pale yellow to yellow clear liquid (est) |
| Assay: | 88.00 to 100.00 sum of isomers
|
| Food Chemicals Codex Listed: | No |
| Boiling Point: | 102.00 °C. @ 2.60 mm Hg
|
| Boiling Point: | 238.00 to 242.00 °C. @ 760.00 mm Hg
|
| Vapor Pressure: | 0.001000 mmHg @ 25.00 °C. (est) |
| Flash Point: | > 200.00 °F. TCC ( > 93.33 °C. )
|
| logP (o/w): | 4.099 (est) |
| Soluble in: |
| | alcohol | | | water, 2.579 mg/L @ 25 °C (est) |
Organoleptic Properties:
| Odor Type: orris |
Odor Strength:medium ,
recommend smelling in a 10.00 % solution or less |
| Substantivity:328 hour(s) at 100.00 % |
| orris woody powdery floral violet tropical tobacco creamy |
Odor Description:at 10.00 % in dipropylene glycol. orris woody powdery floral violet tropical tobacco creamy
Luebke, William tgsc, (2017) |
| Odor sample from: International Flavors & Fragrances Inc. |
| Flavor Type: floral |
| floral orris woody tobacco powdery berry violet creamy |
Taste Description: sweet floral orris woody tobacco powdery berry violet creamy
Luebke, William tgsc, (2017) |
| Odor and/or flavor descriptions from others (if found). |
| IFF |
| Meth Ionone Beta Coeur |
| Odor Description:Precious woody, orris tobacco note with violet nuances |
Cosmetic Information:
Suppliers:
| Azelis UK |
| Meth Ionone Beta Coeur
|
| Berjé |
| Methyl Ionone Beta
|
| Media |
| Ernesto Ventós |
| METHYL IONONE BETA COEUR IFF
|
| IFF |
| Meth Ionone Beta Coeur
Odor: Precious woody, orris tobacco note with violet nuances |
| Kun Shan P&A |
| Methyl Ionone Beta Coeur
|
| Lluch Essence |
| BETA-METHYLIONONE COEUR
|
| Penta International |
| BETA METHYL IONONE
|
| Perfumer Supply House |
| Methyl Beta Ionone Coeur
Odor: A delicate, floral, violet note |
| Perfumery Laboratory |
| METHYL ION BETA IFF (METHYL IONONE BETA COEUR IFF)
Odor: Soft, woody, sweet, iris, powdery, floral |
| Perfumery Laboratory |
| METHYL ION BETA IFF (METHYL IONONE BETA COEUR IFF)
Odor: Soft, woody, sweet, iris, powdery, floral |
| The John D. Walsh Company |
| Methyl Ionone Beta Coeur
|
Safety Information:
| European information : |
| Most important hazard(s): | | Xn - Harmful. |
R 20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R 36/37/38 - Irritating to eyes, respiratory system, and skin.
S 23 - Do not breath fumes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 - Wear suitable clothing, gloves and eye/face protection.
|
| |
| Hazards identification |
| |
| Classification of the substance or mixture |
| GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) |
| None found. |
| GHS Label elements, including precautionary statements |
| |
| Pictogram | |
| |
| Hazard statement(s) |
| None found. |
| Precautionary statement(s) |
| None found. |
| Oral/Parenteral Toxicity: |
|
Not determined
|
| Dermal Toxicity: |
|
Not determined
|
| Inhalation Toxicity: |
|
Not determined
|
Safety in Use Information:
| Category: | | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment: Search |
| IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice |
| IFRA Critical Effect: | | Dermal sensitization |
| IFRA Other Specification: | <= 2% Pseudomethylionone |
| | View the IFRA Standard |
| View IFRA Standards Library for complete information. |
| Please review Amendment 49 IFRA documentation for complete information. |
| IFRA RESTRICTION LIMITS IN THE FINISHED PRODUCT (%): |
| Category 1: Products applied to the lips |
| 5.40 % |
| Category 2: Products applied to the axillae |
| 1.60 % |
| Category 3: Products applied to the face/body using fingertips |
| 32.00 % |
| Category 4: Products related to fine fragrance |
| 30.00 % |
| | Category 5: Products applied to the face and body using the hands (palms), primarily leave-on |
| Category 5A: Body lotion products applied to the body using the hands (palms), primarily leave-on |
| 7.60 % |
| Category 5B: Face moisturizer products applied to the face using the hands (palms), primarily leave-on |
| 7.60 % |
| Category 5C: Hand cream products applied to the hands using the hands (palms), primarily leave-on |
| 7.60 % |
| Category 5D: Baby Creams, baby Oils and baby talc |
| 7.60 % |
| Category 6: Products with oral and lip exposure |
| 18.00 % |
| | Category 7: Products applied to the hair with some hand contact |
| Category 7A: Rinse-off products applied to the hair with some hand contact |
| 61.00 % |
| Category 7B: Leave-on products applied to the hair with some hand contact |
| 61.00 % |
| Category 8: Products with significant anogenital exposure |
| 3.20 % |
| Category 9: Products with body and hand exposure, primarily rinse off |
| 59.00 % |
| | Category 10: Household care products with mostly hand contact |
| Category 10A: Household care excluding aerosol products (excluding aerosol/spray products) |
| 100.00 % |
| Category 10B: Household aerosol/spray products |
| 100.00 % |
| | Category 11: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate |
| Category 11A: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate without UV exposure |
| 100.00 % |
| Category 11B: Products with intended skin contact but minimal transfer of fragrance to skin from inert substrate with potential UV exposure |
| 100.00 % |
| Category 12: Products not intended for direct skin contact, minimal or insignificant transfer to skin |
| No Restriction |
| | Notes: |
| IFRA FLAVOR REQUIREMENTS: |
Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards. |
| use level in formulae for use in cosmetics: | | | 0.1000 %
|
| Dermal Systemic Exposure in Cosmetic Products: | | | 0.0025 mg/kg/day (IFRA, 2001)
|
| |
| Maximised Survey-derived Daily Intakes (MSDI-EU): | 5.40 (μg/capita/day) |
| Maximised Survey-derived Daily Intakes (MSDI-USA): | 0.20 (μg/capita/day) |
| Structure Class: | I |
| Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS). |
| The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library |
| publication number: 3 |
| Click here to view publication 3 |
| | average usual ppm | average maximum ppm |
| baked goods: | - | 5.90000 |
| beverages(nonalcoholic): | - | 2.00000 |
| beverages(alcoholic): | - | - |
| breakfast cereal: | - | - |
| cheese: | - | - |
| chewing gum: | - | - |
| condiments / relishes: | - | - |
| confectionery froastings: | - | - |
| egg products: | - | - |
| fats / oils: | - | - |
| fish products: | - | - |
| frozen dairy: | - | 2.20000 |
| fruit ices: | - | 2.20000 |
| gelatins / puddings: | - | - |
| granulated sugar: | - | - |
| gravies: | - | - |
| hard candy: | - | 7.50000 |
| imitation dairy: | - | - |
| instant coffee / tea: | - | - |
| jams / jellies: | - | - |
| meat products: | - | - |
| milk products: | - | - |
| nut products: | - | - |
| other grains: | - | - |
| poultry: | - | - |
| processed fruits: | - | - |
| processed vegetables: | - | - |
| reconstituted vegetables: | - | - |
| seasonings / flavors: | - | - |
| snack foods: | - | - |
| soft candy: | - | - |
| soups: | - | - |
| sugar substitutes: | - | - |
| sweet sauces: | - | - |
Safety References:
European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...
|
European Food Safety Authority (EFSA) reference(s):
|
Flavouring Group Evaluation 213: alpha,beta-Unsaturated alicyclic ketones and precursors from chemical subgroup 2.7 of FGE.19
View page or View pdf
|
Scientific Opinion on Flavouring Group Evaluation 73, Revision 3 (FGE.73Rev3): Consideration of alicyclic alcohols, aldehydes, acids and related esters evaluated by JECFA (59th and 63rd meeting) structurally related to primary saturated or unsaturated alicyclic alcohols, aldehydes, acids and esters evaluated by EFSA in FGE.12Rev4 (2013)
View page or View pdf
|
Scientific Opinion on Flavouring Group Evaluation 9, Revision 5 (FGE.09Rev5): Secondary alicyclic saturated and unsaturated alcohols, ketones and esters containing secondary alicyclic alcohols from chemical group 8 and 30, and an ester of a phenol derivative from chemical group 25
View page or View pdf
|
Scientific Opinion on Flavouring Group Evaluation 87, Revision 2 (FGE.87Rev2): Consideration of bicyclic secondary alcohols, ketones and related esters evaluated by JECFA (63rd meeting) structurally related to bicyclic secondary alcohols, ketones and related esters evaluated by EFSA in FGE.47Rev1 (2008)
View page or View pdf
|
Scientific Opinion on Flavouring Group Evaluation 213, Revision 2 (FGE.213Rev2): Consideration of genotoxic potential for a,ß-unsaturated alicyclic ketones and precursors from chemical subgroup 2.7 of FGE.19
View page or View pdf
|
| EPI System: View |
| AIDS Citations:Search |
| Cancer Citations:Search |
| Toxicology Citations:Search |
| EPA Substance Registry Services (TSCA):127-43-5 |
| EPA ACToR:Toxicology Data |
| EPA Substance Registry Services (SRS):Registry |
| Laboratory Chemical Safety Summary :61072 |
| National Institute of Allergy and Infectious Diseases:Data |
| WGK Germany:2 |
| 1-(2,6,6-trimethyl-1-cyclohexenyl)pent-1-en-3-one |
| Chemidplus:0000127435 |
References:
Other Information:
Potential Blenders and core components note
| For Odor |
| amber |
amber naphthofuran
FL/FR |
amber oxepin
FR |
amber powdery floral fragrance
FR |
| anisic |
para- anisyl phenyl acetate
FL/FR |
| balsamic |
iso amyl cinnamate
FL/FR |
siam benzoin resin
FL/FR |
siam benzoin resinoid
FL/FR |
benzyl benzoate
FL/FR |
benzyl cinnamate
FL/FR |
guaiacyl phenyl acetate
FL/FR |
| berry |
raspberry ketone methyl ether
FL/FR |
| citrus |
bergamot vanilla specialty
FR |
| creamy |
veratraldehyde
FL/FR |
| floral |
cassie absolute
FL/FR |
cassie concrete
FR |
dimethyl alpha-ionone
FR |
dimethyl anthranilate
FL/FR |
beta- ionol
FL/FR |
alpha- ionol
FL/FR |
alpha- ionone
FL/FR |
(E)-beta- ionone
FL/FR |
alpha- ionyl acetate
FR |
alpha- irone
FL/FR |
beta- irone
FL/FR |
N- methyl ionone
FR |
alpha-iso methyl ionone (50% min.)
FL/FR |
alpha-iso methyl ionone (70% min.)
FL/FR |
alpha-iso methyl ionone (80% min.)
FL/FR |
alpha-iso methyl ionone (90% min.)
FL/FR |
mimosa absolute replacer
FR |
orris pyridine 25% IPM
FR |
orris rhizome resinoid (iris pallida)
FL/FR |
petitgrain mandarin oil terpeneless
FL/FR |
rhodinyl acetate
FL/FR |
tetrahydroionol
FR |
tobacco flower absolute
FR |
| fruity |
benzaldehyde
FL/FR |
tropical ionone
FL/FR |
| green |
(Z)-3- hexen-1-yl methyl carbonate
FL/FR |
hexen-1-yl oxypropane nitrile
FR |
violet dienyne
FR |
| herbal |
2- cyclohexyl cyclohexanone
FR |
| musk |
3- methyl-6-cyclohexadecen-1-one
FR |
musk amberol
FR |
musk ether
FR |
musk indanone
FR |
omega- pentadecalactone
FL/FR |
6,7,8,9- tetrahydro-7,7,8,9,9-pentamethyl-5H-cyclopenta[H]quinazoline
FR |
| orris |
2(1)- orris butanal
FL/FR |
| powdery |
dimethyl ionone
FR |
alpha- methyl ionone
FL/FR |
(E)-alpha- methyl ionone (44-50%)
FL/FR |
(E)-alpha- methyl ionone (50-60%)
FL/FR |
(E)-alpha- methyl ionone (74-80%)
FL/FR |
| smoky |
2,6- dimethoxyphenol
FL/FR |
| spicy |
nutmeg oil
FL/FR |
| tonka |
mint lactone
FL/FR |
| tropical |
patchwood
FR |
| vanilla |
heliotropyl alcohol
FL/FR |
| waxy |
orris rhizome oil CO2 extract
FL/FR |
| woody |
amber woody specialty
FR |
sandal pentenone
FR |
santalyl acetate
FL/FR |
timber propanol
FR |
4,6,11- trimethyl-5-oxatricyclo(6.2.2.0*4,9*)dodec-6-ene
FR |
vetiveryl acetate
FL/FR |
violet propanol
FR |
woody dioxolane
FR |
woody epoxide
FR |
woody nonane (ethoxy)
FR |
| For Flavor |
| No flavor group found for these |
alpha- campholene acetate
FL |
heliotropyl alcohol
FL/FR |
(E)-alpha- methyl ionone (44-50%)
FL/FR |
(E)-alpha- methyl ionone (50-60%)
FL/FR |
2(1)- orris butanal
FL/FR |
vetiveryl acetate
FL/FR |
| amber |
| amber |
amber naphthofuran
FL/FR |
| anisic |
para- anisyl phenyl acetate
FL/FR |
| balsamic |
siam benzoin resin
FL/FR |
siam benzoin resinoid
FL/FR |
benzyl benzoate
FL/FR |
peru balsam
FL |
| berry |
raspberry ketone methyl ether
FL/FR |
| coconut |
6- methyl coumarin
FL |
| creamy |
mint lactone
FL/FR |
veratraldehyde
FL/FR |
| floral |
iso amyl cinnamate
FL/FR |
beta- ionol
FL/FR |
alpha- ionone
FL/FR |
beta- irone
FL/FR |
alpha-iso methyl ionone (50% min.)
FL/FR |
alpha-iso methyl ionone (70% min.)
FL/FR |
(E)-alpha- methyl ionone (74-80%)
FL/FR |
alpha-iso methyl ionone (80% min.)
FL/FR |
alpha-iso methyl ionone (90% min.)
FL/FR |
orris rhizome resinoid (iris pallida)
FL/FR |
rhodinyl acetate
FL/FR |
tropical ionone
FL/FR |
| fruity |
benzaldehyde
FL/FR |
dimethyl anthranilate
FL/FR |
alpha- methyl ionone
FL/FR |
petitgrain mandarin oil terpeneless
FL/FR |
| green |
(Z)-3- hexen-1-yl methyl carbonate
FL/FR |
methyl 2-undecynoate
FL |
| medicinal |
2,6- dimethoxyphenol
FL/FR |
| phenolic |
guaiacyl phenyl acetate
FL/FR |
| spicy |
benzyl cinnamate
FL/FR |
cassie absolute
FL/FR |
nutmeg oil
FL/FR |
| vanilla |
omega- pentadecalactone
FL/FR |
| woody |
alpha- ionol
FL/FR |
(E)-beta- ionone
FL/FR |
alpha- irone
FL/FR |
orris rhizome oil CO2 extract
FL/FR |
santalyl acetate
FL/FR |
Potential Uses:
Occurrence (nature, food, other): note
Synonyms:
| beta- | cyclocitrylidene butanone | | | meth ionone beta coeur (IFF) | | | methyl beta-ionone | | b- | methyl ionone | | | methyl ionone beta coeur (IFF) | | 1- | penten-3-one, 1- (2,6, 6-trimethyl-1-cyclohexen-1-yl)- | | 1- | penten-3-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)- | | 1-(2,6,6- | trimethyl-1-cyclohexen-1-yl) pent-1-en-3-one | | 1-(2,6,6- | trimethyl-1-cyclohexen-1-yl)-1-penten-3-one | | 5-(2,6,6- | trimethyl-1-cyclohexen-1-yl)-4-penten-3-one | | 1-(2,6,6- | trimethyl-1-cyclohexen-1-yl)pent-1-en-3-one | | 5-2,6,6- | trimethyl-1-cyclohexen-1-yl-4-penten-3-one | | (E)-1-(2,6,6- | trimethyl-1-cyclohexenyl) pent-1-en-3-one | | 1-(2,6,6- | trimethyl-1-cyclohexenyl)pent-1-en-3-one | | 1-(2,6,6- | trimethylcyclohex-1-en-1-yl)pent-1-en-3-one |
Articles:
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3D/inchi
