ammonium glycyrrhizate, 53956-04-0

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CODE102675 CODE102675
Product(s):
53956-04-0 Glycyrrhizic acid ammonium salt

Charkit Chemical Corporation

The Specialty Chemical Specialists
Explore this website to discover the products and services that Charkit provides for your industry and please contact us directly to find out how we can be of service to you.
about: Since 1982, Charkit has been committed to expanding the markets we serve as our roster of products and services continues to grow with us. Our substantial portfolio of personal care ingredients now include a wide array of luxury and exotic components to compliment the key products we have always offered. We have expanded our offerings to the nutraceutical, industrial, and resin markets with a growing roster of versatile and unique ingredients. We continue to lead the way in our traditional markets such as Metal and Water Treatment, Imaging, Flavor & Fragrance, Aroma and Food. Our Pharmaceutical offerings continue to expand, still anchored by the Boronic Derivatives that meet the demands of Suzuki coupling reactions. Please contact us to learn how we can help you reach your goals.
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CODE102675 CODE102675
Product(s):
MONO AMMONIUM GLYCYRRHIZINATE MAG

Glentham Life Sciences Ltd

The Chemical, Biochemical & Research Essentials Supplier
Glentham Life Sciences is a supplier of fine chemicals and raw materials with warehousing, laboratories and packaging facilities in the UK.
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CODE102675 CODE102675
Product(s):
GK2256 Glycyrrhizic acid ammonium salt

FRUTAROM USA INC,

Flavor & Specialty Ingredients
Your preferred partner for flavour and fragrance success.
Our broad and diverse product portfolio is designed to provide and cater for every flavor and taste profile required by our customer base and incorporates historic, and iconic, market leading products.
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CODE102675 CODE102675
Product(s):
3324453501 GLYCYRRHIZIN AMMONIATED KOSHER

M&U International LLC

Steady supply & demand
Meeting customers increasing demands at home as well as abroad.
M&U dedicates itself to the development and production of new products as well as continuously promoting those new products. We’ve maintained a steady supply&demand relationship with a large number of manufacturers at home and abroad. We’ve developed an extensive network and because of our relationships with these manufacturers, we’re able to provide a stable supply of great quality materials. We’re located in China’s largest communications hub, Shanghai and in the U.S. near one of the largest sea ports on the East Coast. The strategic locations of our facilities ensure convenient, prompt and secure delivery of our products to our customers.
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N0160 NAT.AMMONIUM GLYCYRRHIZATE

O'Laughlin Industries Inc.

Manufacturer of chemicals and ingredients used in flavors, fragrances, food, beverages and cosmetics
Leading the Flavor and Fragrance Industry since 1980.
O'Laughlin was established in 1980 by its owner and chief executive Michael O'Laughlin, when he moved to Beijing, China and established a small office. Since then it has grown to be a world class producer of chemicals, with significant production facilities in China, and distribution and sales in all major world markets.
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774-2304 MAGOLIN, Ammonium glycyrrhizinate 18%

Penta International Corporation

Chemistry innovation
At Penta, our products and services help businesses do business better.
For over 30 years, Penta Manufacturing Company has played a growing role in worldwide chemistry innovations and applications. As an industry leader, Penta continues to pioneer chemistry-based solutions for practically every area of commerce. Our products and expertise have helped fuel technical advances in dozens of commercial applications including flavoring, coloring, fragrances and chemical processes.
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Product(s):
01-27500 AMMONIATED GLYCYRRHIZIN
01-27501 AMMONIATED GLYCYRRHIZIN NATURAL

TCI AMERICA

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CODE102675 CODE102675
Product(s):
G0151 Monoammonium Glycyrrhizinate Hydrate >75.0%(LC)
SDS

Name:	(2S,3S,4S,5R,6R)-6-[(2S,3R,4S,5S,6S)-2-[[(3S,4aR,6aR,6bS,8aS,11S,12aR,14aR,14bS)-11-carboxy-4,4,6a,6b,8a,11,14b-heptamethyl-14-oxo-2,3,4a,5,6,7,8,9,10,12,12a,14
CAS Number:	53956-04-0	3D/inchi
Other(deleted CASRN):	1407-03-0
ECHA EINECS - REACH Pre-Reg:	258-887-7
FDA UNII:	3VRD35U26C
Beilstein Number:	3897076
MDL:	MFCD00167400
CoE Number:	2221
Molecular Weight:	839.97425000
Formula:	C42 H65 N O16
NMR Predictor:	Predict (works with chrome, Edge or firefox)

Category:licorice and licorice derivatives

US / EU / FDA / JECFA / FEMA / FLAVIS / Scholar / Patent Information:

Google Scholar:	Search
Google Books:	Search
Google Scholar: with word "volatile"	Search
Google Scholar: with word "flavor"	Search
Google Scholar: with word "odor"	Search
Perfumer and Flavorist:	Search
Google Patents:	Search
US Patents:	Search
EU Patents:	Search
Pubchem Patents:	Search
PubMed:	Search
NCBI:	Search
	FDA/DG SANTE Petitions, Reviews, Notices:
184.1408	Ammoniated Glycyrrhizin View - review
184.1408	Licorice, Glycyrrhiza, and Ammoniated Glycyrrhizin View - review
DG SANTE Food Flavourings:	16.060 glycyrrhizic acid ammoniated
FEMA Number:	2528 glycyrrhizic acid ammoniated
FDA:	No longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF):	53956-04-0 ; GLYCYRRHIZIN, AMMONIATED (GLYCYRRHIZA SPP.)
FDA Regulation:
FDA PART 184 -- DIRECT FOOD SUBSTANCES AFFIRMED AS GENERALLY RECOGNIZED AS SAFE Subpart B--Listing of Specific Substances Affirmed as GRAS Sec. 184.1408 Licorice and licorice derivatives.

Physical Properties:

Appearance:	pale yellow to amber brown solid (est)
Assay:	75.00 to 100.00
Food Chemicals Codex Listed:	No
Melting Point:	209.00 to 215.00 °C. @ 760.00 mm Hg
Boiling Point:	971.00 to 972.00 °C. @ 760.00 mm Hg
Flash Point:	550.00 °F. TCC ( 287.78 °C. )
logP (o/w):	4.637 (est)
Shelf Life:	12.00 month(s) or longer if stored properly.
Storage:	refrigerate in tightly sealed containers.
Soluble in:
	water, 5.355 mg/L @ 25 °C (est)
Similar Items:note
glycyrrhizin
glycyrrhizic acid

Organoleptic Properties:

Odor Strength:none

Odor Description:at 100.00 %. bland

Odor and/or flavor descriptions from others (if found).

Cosmetic Information:

CosIng:	cosmetic data
Cosmetic Uses:	fragrance skin conditioning

Suppliers:

Alfa Biotechnology

For experimental / research use only.

Glycyrrhizic Acid Monoammonium Salt 98%

Aromiens International

Ammonium Glycyrrhizate

BOC Sciences

For experimental / research use only.

Glycyrrhizic acid ammonium salt

Charkit Chemical

MONO AMMONIUM GLYCYRRHIZINATE MAG

Coompo

For experimental / research use only.

Glycyrrhizic Acid Ammonium Salt from Plants ≥96%

Odor: characteristic

Use: Glycyrrhizic acid ammonium salt is active against viruses. It inhibits growth and cytopathology of several unrelated DNA and RNA viruses, while not affecting cell activity and ability to replicate. In addition, glycyrrhizic acid inactivates herpes simplex virus particles irreversibly.

ExtraSynthese

For experimental / research use only.

Glycyrrhizin ammoniacal

Frutarom

GLYCYRRHIZIN AMMONIATED

KOSHER

Flavor: Artifical sweetness, medicinal, slight burnt notes

CBD Offering

Glentham Life Sciences

Glycyrrhizic acid ammonium salt

IFF

GLYCYRRHIZIN AMMONIATED

KOSHER

Flavor: Artifical sweetness, medicinal, slight burnt notes

M&U International

NAT.AMMONIUM GLYCYRRHIZATE

Nacalai USA

For experimental / research use only.

Glycyrrhizic Acid Monoammonium Salt n-Hydrate

O'Laughlin Industries

MAGOLIN, Ammonium glycyrrhizinate 18%

Penta International

AMMONIATED GLYCYRRHIZIN NATURAL

Penta International

AMMONIATED GLYCYRRHIZIN

Sabinsa Corporation

MonoAmmonium Glycyrrhizinate

TCI AMERICA

For experimental / research use only.

Monoammonium Glycyrrhizinate Hydrate >75.0%(LC)

sds

Safety Information:

Preferred SDS: View
European information :
Most important hazard(s):
None - None found.
S 02 - Keep out of the reach of children. S 24/25 - Avoid contact with skin and eyes.

Hazards identification

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
None found.
GHS Label elements, including precautionary statements

Pictogram

Hazard statement(s)
None found.
Precautionary statement(s)
None found.
Oral/Parenteral Toxicity:
oral-rat LD50 > 10000 mg/kg Yaoxue Tongbao. Bulletin of Pharmacology. Vol. 22, Pg. 449, 1987. intraperitoneal-rat LD50 > 300 mg/kg Yaoxue Tongbao. Bulletin of Pharmacology. Vol. 22, Pg. 449, 1987. oral-mouse LD50 9818 mg/kg Yaoxue Tongbao. Bulletin of Pharmacology. Vol. 22, Pg. 449, 1987. intravenous-mouse LD50 540 mg/kg Yaoxue Tongbao. Bulletin of Pharmacology. Vol. 22, Pg. 449, 1987. intraperitoneal-mouse LDLo 1000 mg/kg Yaoxue Tongbao. Bulletin of Pharmacology. Vol. 22, Pg. 449, 1987.
Dermal Toxicity:
Not determined
Inhalation Toxicity:
Not determined

Safety in Use Information:

Category:
licorice and licorice derivatives
RIFM Fragrance Material Safety Assessment: Search
IFRA Code of Practice Notification of the 49th Amendment to the IFRA Code of Practice

Maximised Survey-derived Daily Intakes (MSDI-EU):	130.00 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA):	90 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI):	210000 (μg/person/day)
Structure Class:	III
Use levels for FEMA GRAS flavoring substances on which the FEMA Expert Panel based its judgments that the substances are generally recognized as safe (GRAS).
The Expert Panel also publishes separate extensive reviews of scientific information on all FEMA GRAS flavoring substances and can be found at FEMA Flavor Ingredient Library
publication number: 3
Click here to view publication 3
	average usual ppm	average maximum ppm
baked goods:	-	5.00000
beverages(nonalcoholic):	-	51.00000
beverages(alcoholic):	-	-
breakfast cereal:	-	-
cheese:	-	-
chewing gum:	-	-
condiments / relishes:	-	-
confectionery froastings:	-	-
egg products:	-	-
fats / oils:	-	-
fish products:	-	-
frozen dairy:	-	-
fruit ices:	-	-
gelatins / puddings:	-	-
granulated sugar:	-	-
gravies:	-	-
hard candy:	5.00000	62.00000
imitation dairy:	-	-
instant coffee / tea:	-	-
jams / jellies:	-	-
meat products:	-	-
milk products:	-	-
nut products:	-	-
other grains:	-	-
poultry:	-	-
processed fruits:	-	-
processed vegetables:	-	-
reconstituted vegetables:	-	-
seasonings / flavors:	-	-
snack foods:	-	-
soft candy:	-	-
soups:	-	-
sugar substitutes:	-	-
sweet sauces:	-	-

Food categories according to Commission Regulation EC No. 1565/2000 (EC, 2000) in FGE.06 (EFSA, 2002a). According to the Industry the "normal" use is defined as the average of reported usages and "maximum use" is defined as the 95th percentile of reported usages (EFSA, 2002i).
Note: mg/kg = 0.001/1000 = 0.000001 = 1/1000000 = ppm.
	average usage mg/kg	maximum usage mg/kg
Dairy products, excluding products of category 02.0 (01.0):	-	40.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0):	-	-
Edible ices, including sherbet and sorbet (03.0):	-	91.00000
Processed fruit (04.1):	-	-
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2):	-	-
Confectionery (05.0):	-	1512.00000
Chewing gum (05.3):	-	-
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0):	-	45.00000
Bakery wares (07.0):	-	61.00000
Meat and meat products, including poultry and game (08.0):	-	-
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0):	-	300.00000
Eggs and egg products (10.0):	-	-
Sweeteners, including honey (11.0):	-	100.00000
Salts, spices, soups, sauces, salads, protein products, etc. (12.0):	-	50.00000
Foodstuffs intended for particular nutritional uses (13.0):	-	60.00000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1):	-	200.00000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2):	-	200.00000
Ready-to-eat savouries (15.0):	-	150.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0):	-	79.00000

Safety References:

European Food Safety Athority(EFSA):Flavor usage levels; Subacute, Subchronic, Chronic and Carcinogenicity Studies; Developmental / Reproductive Toxicity Studies; Genotoxicity Studies...

European Food Safety Authority (EFSA) reference(s):

Flavouring Group Evaluation 29 (FGE29)[1] - Substance from the priority list: Vinylbenzene from chemical group 31 - Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food (AFC)
View page or View pdf

Flavouring Group Evaluation 36, (FGE.36) - Two triterpene glycosides from the priority list - Opinion of the Scientific Panel on Food Additives, Flavourings, Processing Aids and Materials in Contact with Food (AFC)
View page or View pdf

Scientific Opinion on the safety and efficacy of glycyrrhizic acid ammoniated (chemical group 30, miscellaneous substances) when used as a flavouring for all animal species
View page or View pdf

Scientific Opinion on Flavouring Group Evaluation 49, Revision 1 (FGE.49Rev1): xanthine alkaloids from the priority list
View page or View pdf

EPI System: View

Chemical Carcinogenesis Research Information System:Search

EPA Substance Registry Services (TSCA):53956-04-0

EPA ACToR:Toxicology Data

EPA Substance Registry Services (SRS):Registry

Laboratory Chemical Safety Summary :62074

National Institute of Allergy and Infectious Diseases:Data

WGK Germany:2

(2S,3S,4S,5R,6R)-6-[(2S,3R,4S,5S,6S)-2-[[(3S,4aR,6aR,6bS,8aS,11S,12aR,14aR,14bS)-11-carboxy-4,4,6a,6b,8a,11,14b-heptamethyl-14-oxo-2,3,4a,5,6,7,8,9,10,12,12a,14

Chemidplus:0053956040

RTECS:LZ6500000 for cas# 53956-04-0

References:

	(2S,3S,4S,5R,6R)-6-[(2S,3R,4S,5S,6S)-2-[[(3S,4aR,6aR,6bS,8aS,11S,12aR,14aR,14bS)-11-carboxy-4,4,6a,6b,8a,11,14b-heptamethyl-14-oxo-2,3,4a,5,6,7,8,9,10,12,12a,14
NIST Chemistry WebBook:	Search Inchi
Canada Domestic Sub. List:	53956-04-0
Pubchem (cid):	62074
Pubchem (sid):	135021079

Other Information:

(IUPAC):	Atomic Weights of the Elements 2011 (pdf)
Videos:	The Periodic Table of Videos
tgsc:	Atomic Weights use for this web site
(IUPAC):	Periodic Table of the Elements
FDA Substances Added to Food (formerly EAFUS):	View
CHEBI:	View
KEGG (GenomeNet):	C18610
HMDB (The Human Metabolome Database):	HMDB29844
FooDB:	FDB001061
FDA Listing of Food Additive Status:	View
ChemSpider:	View
Wikipedia:	View

Potential Blenders and core components note

For Odor

anise

anise oleoresin
FL/FR

anise seed oil
FL/FR

star

anise seed oil china
FL/FR

anise seed oil colombia
FL/FR

star

anise seed oil spain
FL/FR

star

anise seed oil terpeneless
FL/FR

sweet

fennel absolute
FL/FR

sweet

fennel oleoresin
FL/FR

anisic

dihydroanethol
FL/FR

estragole
FL/FR

ethyl para-anisate
FL/FR

ocimum basilicum herb oil egypt
FL/FR

ocimum basilicum leaf oil CO2 extract
FL/FR

caramellic

caramel pentadione
FL/FR

cyclotene
FL/FR

fruity

iso

butyl 2-butenoate
FL/FR

(E,E)-

ethyl sorbate
FL/FR

hexanal propylene glycol acetal
FL/FR

licorice

(E)-

anethol
FL/FR

glycyrrhiza glabra root extract
FL/FR

minty

carvone
FL/FR

musk

omega-

pentadecalactone
FL/FR

musty

acetyl pyrrole
FL/FR

powdery

para-

anisyl acetate
FL/FR

para-

anisyl alcohol
FL/FR

For Flavor

No flavor group found for these

carvone
FL/FR

fleabane oil (erigeron canadensis)
FL

anise

(E)-

anethol
FL/FR

anise oleoresin
FL/FR

anise seed oil
FL/FR

star

anise seed oil china
FL/FR

anise seed oil colombia
FL/FR

star

anise seed oil spain
FL/FR

star

anise seed oil terpeneless
FL/FR

ethyl para-anisate
FL/FR

sweet

fennel absolute
FL/FR

sweet

fennel oleoresin
FL/FR

anisic

ocimum basilicum herb oil egypt
FL/FR

caramellic

caramel pentadione
FL/FR

cyclotene
FL/FR

fruity

para-

anisyl acetate
FL/FR

para-

anisyl alcohol
FL/FR

ethyl 3-oxohexanoate
FL

(E,E)-

ethyl sorbate
FL/FR

furfuryl isovalerate
FL

hexanal propylene glycol acetal
FL/FR

(E,E)-

methyl sorbate
FL

green

iso

butyl 2-butenoate
FL/FR

herbal

dihydroanethol
FL/FR

ocimum basilicum leaf oil CO2 extract
FL/FR

licorice

butyl-3-methyl pyrazine
FL

estragole
FL/FR

glycyrrhiza glabra root extract
FL/FR

glycyrrhiza glabra root extract powder
FL

nutty

acetyl pyrrole
FL/FR

sweet

neo

hesperidin dihydrochalcone
FL

vanilla

omega-

pentadecalactone
FL/FR

Potential Uses:

	biological additives
	skin conditioning

Occurrence (nature, food, other):note

not found in nature

Synonyms:

	AMGZ
	ammoniated glycyrrhizin
	ammoniated glycyrrhizin FCC
	ammoniated glycyrrhizin FCC, natural
mono	ammonium glycyrrhizate
	ammonium glycyrrhizinate
mono	ammonium glycyrrhizinate
mono	ammonium glycyrrhizinate hydrate
	glycamil
	glycyrram
	glycyrrhizic acid ammoniated
	glycyrrhizic acid ammonium salt
	glycyrrhizic acid monoammonium salt
	glycyrrhizic acid, ammonium salt
	glycyrrhizic acid, monoammonium salt
	glycyrrhizin ammoniated
	glycyrrhizin, ammoniated
	glycyrrhizinate monoammonium
	glycyrrhizinic acid ammonium salt
	glycyrrhizinic acid, ammonium salt (1:1)
	olean-12-en-30-oic acid, 3-[(2-O-β-D-glucopyranuronosyl-a-D-glucopyranuronosyl)oxy]-11-oxo-, ammonium salt, (3β)-

Articles:

Google Patents:Sucrose-ammoniated glycyrrhizin sweetening agent

US Patents:8,007,849 - Unsaturated cyclic and acyclic carbamates exhibiting taste and flavor enhancement effect in flavor compositions

PubMed:[About flavouring substances and flavouring preparations regulation in the field of manufacturing of flavourings and foodstuffs].

PubMed:Final report on the safety assessment of Glycyrrhetinic Acid, Potassium Glycyrrhetinate, Disodium Succinoyl Glycyrrhetinate, Glyceryl Glycyrrhetinate, Glycyrrhetinyl Stearate, Stearyl Glycyrrhetinate, Glycyrrhizic Acid, Ammonium Glycyrrhizate, Dipotassium Glycyrrhizate, Disodium Glycyrrhizate, Trisodium Glycyrrhizate, Methyl Glycyrrhizate, and Potassium Glycyrrhizinate.

PubMed:Tests for mutagenic effects of ammoniated glycyrrhizin, butylated hydroxytoluene, and gum Arabic in rodent germ cells.

PubMed:Time required to achieve homogeneity in swine feed mixtures.

PubMed:Production of experimental hypertension and cardiovascularrenal lesions with licorice and ammoniated glycyrrhizin.

PubMed:Desoxycorticosterone-mimetic action of ammoniated glycyrrhizin in rats.

Notes:

Nonnutritive sweetener and flavour enhancer

ammonium glycyrrhizate glycyrrhizic acid ammoniated

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Articles:

ammonium glycyrrhizate
glycyrrhizic acid ammoniated