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CAS Number: 36338-96-2

SMILES : c1cc(ccc1C=CC(=O)C2=C(C(=CC3=C(C(=C(C=Cc4ccc(cc4)O)O)C(=O)C(C3(=O))(C

5C(C(C(C(O5)CO)O)O)O)O)O)C(=O)C(C2(=O))(C6C(C(C(C(O6)CO)O)O)O)O)O)O

CHEM : carthamus red

MOL FOR: C43 H42 O22

MOL WT : 910.80

------------------------------ EPI SUMMARY (v4.00) --------------------------

Henry LC (atm-m3/mole) : ------

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Water Solubility (mg/L): ------

Physical Property Inputs:

Vapor Pressure (mm Hg) : ------

Melting Point (deg C) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = -0.55

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 1420.42 (Adapted Stein & Brown method)

Melting Pt (deg C): 349.84 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0 (Modified Grain method)

VP (Pa, 25 deg C) : 0 (Modified Grain method)

Subcooled liquid VP: 5.61E-045 mm Hg (25 deg C, Mod-Grain method)

: 7.47E-043 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 15.05

log Kow used: -0.55 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 1e+006 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Vinyl/Allyl Ketones

Vinyl/Allyl Alcohols

a-,b-Ketone alcohol

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : Incomplete

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

not available

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Can Not Estimate (can not calculate HenryLC)

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 1.2632

Biowin2 (Non-Linear Model) : 0.0002

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.5049 (weeks-months)

Biowin4 (Primary Survey Model) : 3.5995 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.9503

Biowin6 (MITI Non-Linear Model): 0.0018

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -1.3691

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 7.47E-043 Pa (5.61E-045 mm Hg)

Log Koa (): not available

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 4.02E+036

Octanol/air (Koa) model: not available

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 1

Mackay model : 1

Octanol/air (Koa) model: not available

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 624.9724 E-12 cm3/molecule-sec [Cis-isomer]

OVERALL OH Rate Constant = 634.0923 E-12 cm3/molecule-sec [Trans-isomer]

Half-Life = 12.322 Min (12-hr day; 1.5E6 OH/cm3) [Cis-isomer]

Half-Life = 12.145 Min (12-hr day; 1.5E6 OH/cm3) [Trans-isomer]

Ozone Reaction:

OVERALL Ozone Rate Constant = 3.720000 E-17 cm3/molecule-sec [Cis-]

OVERALL Ozone Rate Constant = 5.820000 E-17 cm3/molecule-sec [Trans-]

Half-Life = 443.612 Min (at 7E11 mol/cm3) [Cis-isomer]

Half-Life = 283.546 Min (at 7E11 mol/cm3) [Trans-isomer]

Reaction With Nitrate Radicals May Be Important!

Fraction sorbed to airborne particulates (phi):

1 (Junge-Pankow, Mackay avg)

not available (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 1E+010 L/kg (MCI method)

Log Koc: 10.993 (MCI method)

Koc : 7.084 L/kg (Kow method)

Log Koc: 0.850 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 0.500 (BCF = 3.162 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -5.2648 days (HL = 5.434e-006 days)

Log BCF Arnot-Gobas method (upper trophic) = -0.047 (BCF = 0.8984)

Log BAF Arnot-Gobas method (upper trophic) = -0.047 (BAF = 0.8984)

log Kow used: -0.55 (estimated)

Volatilization from Water:

Henry LC: 7.96E-017 atm-m3/mole (calculated from VP/WS)

Half-Life from Model River: 2.219E+013 hours (9.246E+011 days)

Half-Life from Model Lake : 2.421E+014 hours (1.009E+013 days)

Removal In Wastewater Treatment:

Total removal: 1.85 percent

Total biodegradation: 0.09 percent

Total sludge adsorption: 1.76 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.000141 0.389 1000

Water 1.49 900 1000

Soil 39.3 1.8e+003 1000

Sediment 59.2 8.1e+003 0

Persistence Time: 4.12e+003 hr

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