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CAS Num: 071078-31-4

SMILES : O(C(C(=CCC1C)C)(C=C2)C1C)C2C

CHEM : 1-Oxaspiro[4.5]deca-3,6-diene, 2,6,9,10-tetramethyl-

MOL FOR: C13 H20 O1

MOL WT : 192.30

------------------------------ EPI SUMMARY (v4.00) --------------------------

Physical Property Inputs:

Water Solubility (mg/L): ------

Vapor Pressure (mm Hg) : ------

Henry LC (atm-m3/mole) : ------

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = 4.54

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1.43):

Boiling Pt (deg C): 244.03 (Adapted Stein & Brown method)

Melting Pt (deg C): 34.88 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.0471 (Modified Grain method)

VP (Pa, 25 deg C) : 6.28 (Modified Grain method)

Subcooled liquid VP: 0.0578 mm Hg (25 deg C, Mod-Grain method)

: 7.7 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 6.365

log Kow used: 4.54 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 37.201 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Vinyl/Allyl Ethers

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 3.45E-003 atm-m3/mole (3.50E+002 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.872E-003 atm-m3/mole (1.897E+002 Pa-m3/mole)

VP: 0.0471 mm Hg (source: MPBPVP)

WS: 6.37 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 4.54 (KowWin est)

Log Kaw used: -0.851 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 5.391

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.1247

Biowin2 (Non-Linear Model) : 0.0076

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.5534 (weeks-months)

Biowin4 (Primary Survey Model) : 3.4071 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.2864

Biowin6 (MITI Non-Linear Model): 0.0616

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.2959

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 7.71 Pa (0.0578 mm Hg)

Log Koa (Koawin est ): 5.391

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 3.89E-007

Octanol/air (Koa) model: 6.04E-008

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 1.41E-005

Mackay model : 3.11E-005

Octanol/air (Koa) model: 4.83E-006

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 163.9471 E-12 cm3/molecule-sec

Half-Life = 0.065 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 0.783 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 8.531250 E-17 cm3/molecule-sec

Half-Life = 0.134 Days (at 7E11 mol/cm3)

Half-Life = 3.224 Hrs

Fraction sorbed to airborne particulates (phi):

2.26E-005 (Junge-Pankow, Mackay avg)

4.83E-006 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 1406 L/kg (MCI method)

Log Koc: 3.148 (MCI method)

Koc : 2217 L/kg (Kow method)

Log Koc: 3.346 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 2.662 (BCF = 459 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 1.1018 days (HL = 12.64 days)

Log BCF Arnot-Gobas method (upper trophic) = 3.310 (BCF = 2042)

Log BAF Arnot-Gobas method (upper trophic) = 3.387 (BAF = 2436)

log Kow used: 4.54 (estimated)

Volatilization from Water:

Henry LC: 0.00345 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 1.65 hours

Half-Life from Model Lake : 134.3 hours (5.595 days)

Removal In Wastewater Treatment:

Total removal: 76.49 percent

Total biodegradation: 0.35 percent

Total sludge adsorption: 47.46 percent

Total to Air: 28.68 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.207 1.05 1000

Water 16.3 900 1000

Soil 82.2 1.8e+003 1000

Sediment 1.28 8.1e+003 0

Persistence Time: 503 hr

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