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CAS Number: 6635-22-9

SMILES : CC=Cc1cc(c(c(c1)OC)O)OC

CHEM : 2,6-dimethoxy-4-prop-1-enylphenol

MOL FOR: C11 H14 O3

MOL WT : 194.23

------------------------------ EPI SUMMARY (v4.00) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = 2.48

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 302.15 (Adapted Stein & Brown method)

Melting Pt (deg C): 82.85 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.000162 (Modified Grain method)

VP (Pa, 25 deg C) : 0.0216 (Modified Grain method)

Subcooled liquid VP: 0.000578 mm Hg (25 deg C, Mod-Grain method)

: 0.0771 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 358.8

log Kow used: 2.48 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 1166.1 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Phenols

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 1.58E-009 atm-m3/mole (1.60E-004 Pa-m3/mole)

Group Method: 2.23E-007 atm-m3/mole (2.26E-002 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.154E-007 atm-m3/mole (1.169E-002 Pa-m3/mole)

VP: 0.000162 mm Hg (source: MPBPVP)

WS: 359 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 2.48 (KowWin est)

Log Kaw used: -7.190 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 9.670

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 1.0347

Biowin2 (Non-Linear Model) : 0.9965

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.7101 (weeks-months)

Biowin4 (Primary Survey Model) : 3.7614 (days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.6190

Biowin6 (MITI Non-Linear Model): 0.6006

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.6962

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.0771 Pa (0.000578 mm Hg)

Log Koa (Koawin est ): 9.670

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 3.89E-005

Octanol/air (Koa) model: 0.00115

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.0014

Mackay model : 0.0031

Octanol/air (Koa) model: 0.0841

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 211.8322 E-12 cm3/molecule-sec [Cis-isomer]

OVERALL OH Rate Constant = 219.4322 E-12 cm3/molecule-sec [Trans-isomer]

Half-Life = 0.606 Hrs (12-hr day; 1.5E6 OH/cm3) [Cis-isomer]

Half-Life = 0.585 Hrs (12-hr day; 1.5E6 OH/cm3) [Trans-isomer]

Ozone Reaction:

OVERALL Ozone Rate Constant = 6.825000 E-17 cm3/molecule-sec [Cis-]

OVERALL Ozone Rate Constant = 13.650000 E-17 cm3/molecule-sec [Trans-]

Half-Life = 4.030 Hrs (at 7E11 mol/cm3) [Cis-isomer]

Half-Life = 2.015 Hrs (at 7E11 mol/cm3) [Trans-isomer]

Reaction With Nitrate Radicals May Be Important!

Fraction sorbed to airborne particulates (phi):

0.00225 (Junge-Pankow, Mackay avg)

0.0841 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 446.4 L/kg (MCI method)

Log Koc: 2.650 (MCI method)

Koc : 376.3 L/kg (Kow method)

Log Koc: 2.576 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 1.301 (BCF = 20.02 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.8473 days (HL = 0.1421 days)

Log BCF Arnot-Gobas method (upper trophic) = 1.295 (BCF = 19.72)

Log BAF Arnot-Gobas method (upper trophic) = 1.295 (BAF = 19.72)

log Kow used: 2.48 (estimated)

Volatilization from Water:

Henry LC: 2.23E-007 atm-m3/mole (estimated by Group SAR Method)

Half-Life from Model River: 3660 hours (152.5 days)

Half-Life from Model Lake : 4.005E+004 hours (1669 days)

Removal In Wastewater Treatment:

Total removal: 3.05 percent

Total biodegradation: 0.10 percent

Total sludge adsorption: 2.94 percent

Total to Air: 0.01 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.0429 0.932 1000

Water 19.4 900 1000

Soil 80.1 1.8e+003 1000

Sediment 0.479 8.1e+003 0

Persistence Time: 1.03e+003 hr

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