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CAS Number: 129673-85-4

SMILES : CC1=CCC(=C(C)C(=O))C(=O)CC(=CCC1)C

CHEM :

MOL FOR: C15 H20 O2

MOL WT : 232.33

------------------------------ EPI SUMMARY (v4.11) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 4.95

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 350.77 (Adapted Stein & Brown method)

Melting Pt (deg C): 103.76 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 2.15E-005 (Modified Grain method)

VP (Pa, 25 deg C) : 0.00287 (Modified Grain method)

Subcooled liquid VP: 0.000127 mm Hg (25 deg C, Mod-Grain method)

: 0.0169 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 1.758

log Kow used: 4.95 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 227.6 mg/L

ECOSAR Class Program (ECOSAR v1.11):

Class(es) found:

Vinyl/Allyl Ketones

Vinyl/Allyl Aldehydes

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 1.71E-007 atm-m3/mole (1.73E-002 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 3.739E-006 atm-m3/mole (3.788E-001 Pa-m3/mole)

VP: 2.15E-005 mm Hg (source: MPBPVP)

WS: 1.76 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 4.95 (KowWin est)

Log Kaw used: -5.155 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 10.105

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.9284

Biowin2 (Non-Linear Model) : 0.9984

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.6856 (weeks-months)

Biowin4 (Primary Survey Model) : 3.6870 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.6426

Biowin6 (MITI Non-Linear Model): 0.6123

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.2991

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.0169 Pa (0.000127 mm Hg)

Log Koa (Koawin est ): 10.105

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.000177

Octanol/air (Koa) model: 0.00313

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.00636

Mackay model : 0.014

Octanol/air (Koa) model: 0.2

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 228.6781 E-12 cm3/molecule-sec

Half-Life = 0.047 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 0.561 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 87.182999 E-17 cm3/molecule-sec

Half-Life = 0.013 Days (at 7E11 mol/cm3)

Half-Life = 18.928 Min

Reaction With Nitrate Radicals May Be Important!

Fraction sorbed to airborne particulates (phi):

0.0102 (Junge-Pankow, Mackay avg)

0.2 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 114.2 L/kg (MCI method)

Log Koc: 2.058 (MCI method)

Koc : 4260 L/kg (Kow method)

Log Koc: 3.629 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 2.932 (BCF = 854.7 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 0.7724 days (HL = 5.921 days)

Log BCF Arnot-Gobas method (upper trophic) = 3.267 (BCF = 1849)

Log BAF Arnot-Gobas method (upper trophic) = 3.323 (BAF = 2102)

log Kow used: 4.95 (estimated)

Volatilization from Water:

Henry LC: 1.71E-007 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 5220 hours (217.5 days)

Half-Life from Model Lake : 5.708E+004 hours (2378 days)

Removal In Wastewater Treatment:

Total removal: 76.06 percent

Total biodegradation: 0.67 percent

Total sludge adsorption: 75.39 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.0131 0.246 1000

Water 24 900 1000

Soil 75.8 1.8e+003 1000

Sediment 0.177 8.1e+003 0

Persistence Time: 920 hr

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