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CAS Number: 116-31-4

SMILES : O=CC=C(C=CC=C(C=CC(=C(CCC1)C)C1(C)C)C)C

CHEM : Retinal

MOL FOR: C20 H28 O1

MOL WT : 284.45

------------------------------ EPI SUMMARY (v4.11) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 7.60

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 370.37 (Adapted Stein & Brown method)

Melting Pt (deg C): 97.72 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 1.91E-005 (Modified Grain method)

VP (Pa, 25 deg C) : 0.00254 (Modified Grain method)

MP (exp database): 63 deg C

Subcooled liquid VP: 4.31E-005 mm Hg (25 deg C, Mod-Grain method)

: 0.00575 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 0.004883

log Kow used: 7.60 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 0.97111 mg/L

ECOSAR Class Program (ECOSAR v1.11):

Class(es) found:

Vinyl/Allyl Aldehydes

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 1.18E-003 atm-m3/mole (1.19E+002 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.464E-003 atm-m3/mole (1.483E+002 Pa-m3/mole)

VP: 1.91E-005 mm Hg (source: MPBPVP)

WS: 0.00488 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 7.60 (KowWin est)

Log Kaw used: -1.317 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 8.917

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.7128

Biowin2 (Non-Linear Model) : 0.9882

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.3808 (weeks-months)

Biowin4 (Primary Survey Model) : 3.4806 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.4433

Biowin6 (MITI Non-Linear Model): 0.1729

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.5746

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.00575 Pa (4.31E-005 mm Hg)

Log Koa (Koawin est ): 8.917

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.000522

Octanol/air (Koa) model: 0.000203

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.0185

Mackay model : 0.0401

Octanol/air (Koa) model: 0.016

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 307.2805 E-12 cm3/molecule-sec

Half-Life = 0.035 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 25.062 Min

Ozone Reaction:

OVERALL Ozone Rate Constant = 13.501150 E-17 cm3/molecule-sec

Half-Life = 0.085 Days (at 7E11 mol/cm3)

Half-Life = 2.037 Hrs

Fraction sorbed to airborne particulates (phi):

0.0293 (Junge-Pankow, Mackay avg)

0.016 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 1.372E+004 L/kg (MCI method)

Log Koc: 4.137 (MCI method)

Koc : 7.936E+004 L/kg (Kow method)

Log Koc: 4.900 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 3.830 (BCF = 6759 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 2.1248 days (HL = 133.3 days)

Log BCF Arnot-Gobas method (upper trophic) = 3.464 (BCF = 2912)

Log BAF Arnot-Gobas method (upper trophic) = 6.603 (BAF = 4.007e+006)

log Kow used: 7.60 (estimated)

Volatilization from Water:

Henry LC: 0.00118 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 2.558 hours

Half-Life from Model Lake : 169.3 hours (7.055 days)

Removal In Wastewater Treatment:

Total removal: 93.99 percent

Total biodegradation: 0.78 percent

Total sludge adsorption: 93.19 percent

Total to Air: 0.02 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.037 0.592 1000

Water 13.4 900 1000

Soil 83 1.8e+003 1000

Sediment 3.61 8.1e+003 0

Persistence Time: 1e+003 hr

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