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CAS Number: 6001-97-4

SMILES : CCCCC(C)OC(=O)C(S(=O)(=O)O([Na]))CC(=O)OC(CCCC)C

CHEM : Butanedioic acid, sulfo-, 1,4-bis(1-methylpentyl) ester, sodium salt

MOL FOR: C16 H29 O7 S1 Na1

MOL WT : 388.46

------------------------------ EPI SUMMARY (v4.11) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 1.98

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 637.48 (Adapted Stein & Brown method)

Melting Pt (deg C): 276.82 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 1.28E-014 (Modified Grain method)

VP (Pa, 25 deg C) : 1.7E-012 (Modified Grain method)

Subcooled liquid VP: 7.67E-012 mm Hg (25 deg C, Mod-Grain method)

: 1.02E-009 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 6.486

log Kow used: 1.98 (estimated)

no-melting pt equation used

Water Sol (Exper. database match) = 3.43e+005 mg/L (25 deg C)

Exper. Ref: MERCK INDEX (1996)

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 2.2923 mg/L

ECOSAR Class Program (ECOSAR v1.11):

Class(es) found:

Esters-acid

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 1.62E-012 atm-m3/mole (1.64E-007 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.009E-015 atm-m3/mole (1.022E-010 Pa-m3/mole)

VP: 1.28E-014 mm Hg (source: MPBPVP)

WS: 6.49 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 1.98 (KowWin est)

Log Kaw used: -10.179 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 12.159

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 1.2467

Biowin2 (Non-Linear Model) : 1.0000

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 3.4590 (days-weeks )

Biowin4 (Primary Survey Model) : 4.4922 (hours-days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.5049

Biowin6 (MITI Non-Linear Model): 0.4069

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.0896

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 1.02E-009 Pa (7.67E-012 mm Hg)

Log Koa (Koawin est ): 12.159

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 2.93E+003

Octanol/air (Koa) model: 0.354

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 1

Mackay model : 1

Octanol/air (Koa) model: 0.966

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 17.3507 E-12 cm3/molecule-sec

Half-Life = 0.616 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 7.398 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Fraction sorbed to airborne particulates (phi):

1 (Junge-Pankow, Mackay avg)

0.966 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 62.86 L/kg (MCI method)

Log Koc: 1.798 (MCI method)

Koc : 77.47 L/kg (Kow method)

Log Koc: 1.889 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Total Kb for pH > 8 at 25 deg C : 3.009E-002 L/mol-sec

Kb Half-Life at pH 8: 266.614 days

Kb Half-Life at pH 7: 7.299 years

(Total Kb applies only to esters, carbmates, alkyl halides)

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 0.500 (BCF = 3.162 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -2.0839 days (HL = 0.008243 days)

Log BCF Arnot-Gobas method (upper trophic) = 1.098 (BCF = 12.54)

Log BAF Arnot-Gobas method (upper trophic) = 1.098 (BAF = 12.54)

log Kow used: 4.13 (estimated)

Volatilization from Water:

Henry LC: 1.62E-012 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 7.123E+008 hours (2.968E+007 days)

Half-Life from Model Lake : 7.771E+009 hours (3.238E+008 days)

Removal In Wastewater Treatment:

Total removal: 2.23 percent

Total biodegradation: 0.10 percent

Total sludge adsorption: 2.13 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 1.04 14.8 1000

Water 25.7 208 1000

Soil 73.1 416 1000

Sediment 0.101 1.87e+003 0

Persistence Time: 342 hr

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