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CAS Number: 301-19-9

SMILES : c52OC(c6ccc(O)cc6)=C(OC3OC(COC4OC(C)C(O)C(O)C4O)C(O)C(O)C3O)C(=O)c5c(

O)cc(OC1OC(C)C(O)C(O)C1O)c2

CHEM : ROBININ

MOL FOR: C33 H40 O19

MOL WT : 740.67

------------------------------ EPI SUMMARY (v4.10) --------------------------

Henry LC (atm-m3/mole) : ------

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Water Solubility (mg/L): ------

Physical Property Inputs:

Vapor Pressure (mm Hg) : ------

Melting Point (deg C) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = -2.64

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 1050.23 (Adapted Stein & Brown method)

Melting Pt (deg C): 349.84 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 2.55E-033 (Modified Grain method)

VP (Pa, 25 deg C) : 3.4E-031 (Modified Grain method)

MP (exp database): 250 deg C

Subcooled liquid VP: 7.13E-031 mm Hg (25 deg C, Mod-Grain method)

: 9.51E-029 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 1.295e+004

log Kow used: -2.64 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 1e+006 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Vinyl/Allyl Ketones

Vinyl/Allyl Ethers

Phenols, Poly

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 6.81E-038 atm-m3/mole (6.90E-033 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 7.526E-035 atm-m3/mole (7.625E-030 Pa-m3/mole)

VP: 1E-030 mm Hg (source: MPBPVP)

WS: 1.3E+004 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: -2.64 (KowWin est)

Log Kaw used: -35.555 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 32.915

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.5890

Biowin2 (Non-Linear Model) : 0.0002

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.9328 (weeks )

Biowin4 (Primary Survey Model) : 4.1069 (days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.8891

Biowin6 (MITI Non-Linear Model): 0.0013

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.7563

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 9.51E-029 Pa (7.13E-031 mm Hg)

Log Koa (Koawin est ): 32.915

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 3.16E+022

Octanol/air (Koa) model: 2.02E+020

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 1

Mackay model : 1

Octanol/air (Koa) model: 1

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 424.6015 E-12 cm3/molecule-sec

Half-Life = 0.025 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 18.137 Min

Ozone Reaction:

OVERALL Ozone Rate Constant = 52.500000 E-17 cm3/molecule-sec

Half-Life = 0.022 Days (at 7E11 mol/cm3)

Half-Life = 31.433 Min

Reaction With Nitrate Radicals May Be Important!

Fraction sorbed to airborne particulates (phi):

1 (Junge-Pankow, Mackay avg)

1 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 5382 L/kg (MCI method)

Log Koc: 3.731 (MCI method)

Koc : 0.06762 L/kg (Kow method)

Log Koc: -1.170 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 0.500 (BCF = 3.162 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -4.1703 days (HL = 6.756e-005 days)

Log BCF Arnot-Gobas method (upper trophic) = -0.049 (BCF = 0.893)

Log BAF Arnot-Gobas method (upper trophic) = -0.049 (BAF = 0.893)

log Kow used: -2.64 (estimated)

Volatilization from Water:

Henry LC: 6.81E-038 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 2.34E+034 hours (9.749E+032 days)

Half-Life from Model Lake : 2.553E+035 hours (1.064E+034 days)

Removal In Wastewater Treatment:

Total removal: 1.85 percent

Total biodegradation: 0.09 percent

Total sludge adsorption: 1.75 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 2.51e-007 0.281 1000

Water 15.5 360 1000

Soil 81.9 720 1000

Sediment 2.56 3.24e+003 0

Persistence Time: 801 hr

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