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CAS Number: 23103-98-2

SMILES : CN(C)C(=O)Oc1nc(nc(C)c1C)N(C)C

CHEM : Pirimicarb

MOL FOR: C11 H18 N4 O2

MOL WT : 238.29

------------------------------ EPI SUMMARY (v4.10) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 1.40

Log Kow (Exper. database match) = 1.70

Exper. Ref: TOMLIN,C (1994)

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 326.21 (Adapted Stein & Brown method)

Melting Pt (deg C): 112.43 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.000112 (Modified Grain method)

VP (Pa, 25 deg C) : 0.015 (Modified Grain method)

MP (exp database): 90.5 deg C

VP (exp database): 7.28E-06 mm Hg (9.71E-004 Pa) at 25 deg C

Subcooled liquid VP: 3.24E-005 mm Hg (25 deg C, exp database VP )

: 0.00431 Pa (25 deg C, exp database VP )

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 969.5

log Kow used: 1.70 (expkow database)

no-melting pt equation used

Water Sol (Exper. database match) = 2700 mg/L (25 deg C)

Exper. Ref: YALKOWSKY,SH & DANNENFELSER,RM (1992)

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 14409 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Carbamate Esters

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 2.62E-009 atm-m3/mole (2.66E-004 Pa-m3/mole)

Group Method: Incomplete

Exper Database: 8.45E-10 atm-m3/mole (8.56E-005 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 3.622E-008 atm-m3/mole (3.670E-003 Pa-m3/mole)

VP: 0.000112 mm Hg (source: MPBPVP)

WS: 970 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 1.70 (exp database)

Log Kaw used: -7.462 (exp database)

Log Koa (KOAWIN v1.10 estimate): 9.162

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.6177

Biowin2 (Non-Linear Model) : 0.3931

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.2214 (months )

Biowin4 (Primary Survey Model) : 3.2725 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : -0.0405

Biowin6 (MITI Non-Linear Model): 0.0166

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -1.3006

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.00432 Pa (3.24E-005 mm Hg)

Log Koa (Koawin est ): 9.162

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.000694

Octanol/air (Koa) model: 0.000356

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.0245

Mackay model : 0.0526

Octanol/air (Koa) model: 0.0277

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 151.5235 E-12 cm3/molecule-sec

Half-Life = 0.071 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 0.847 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Fraction sorbed to airborne particulates (phi):

0.0386 (Junge-Pankow, Mackay avg)

0.0277 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 56.06 L/kg (MCI method)

Log Koc: 1.749 (MCI method)

Koc : 118.2 L/kg (Kow method)

Log Koc: 2.073 (Kow method)

Experimental Log Koc: 1.9 (database)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Total Kb for pH > 8 at 25 deg C : 3.061E-005 L/mol-sec

Kb Half-Life at pH 8: 717.616 years

Kb Half-Life at pH 7: 7176.159 years

(Total Kb applies only to esters, carbmates, alkyl halides)

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 0.789 (BCF = 6.147 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -2.0230 days (HL = 0.009485 days)

Log BCF Arnot-Gobas method (upper trophic) = 0.296 (BCF = 1.975)

Log BAF Arnot-Gobas method (upper trophic) = 0.296 (BAF = 1.975)

log Kow used: 1.70 (expkow database)

Volatilization from Water:

Henry LC: 8.45E-010 atm-m3/mole (Henry experimental database)

Half-Life from Model River: 1.07E+006 hours (4.457E+004 days)

Half-Life from Model Lake : 1.167E+007 hours (4.862E+005 days)

Removal In Wastewater Treatment:

Total removal: 2.05 percent

Total biodegradation: 0.09 percent

Total sludge adsorption: 1.95 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.00526 1.69 1000

Water 20.9 1.44e+003 1000

Soil 79 2.88e+003 1000

Sediment 0.0983 1.3e+004 0

Persistence Time: 1.92e+003 hr

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