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CAS Number: 82560-54-1

SMILES : c1ccc2CC(C)(C)Oc2c1OC(=O)N(C)SN(C(C)C)CCC(=O)OCC

CHEM : Benfuracarb

MOL FOR: C20 H30 N2 O5 S1

MOL WT : 410.53

------------------------------ EPI SUMMARY (v4.10) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 4.06

Log Kow (Exper. database match) = 4.30

Exper. Ref: TOMLIN,C (1994)

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 443.93 (Adapted Stein & Brown method)

Melting Pt (deg C): 163.99 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 6.95E-007 (Modified Grain method)

VP (Pa, 25 deg C) : 9.27E-005 (Modified Grain method)

MP (exp database): < 25 deg C

BP (exp database): 110 @ 0.173 mm Hg deg C

VP (exp database): 2.00E-07 mm Hg (2.67E-005 Pa) at 20 deg C

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 0.5604

log Kow used: 4.30 (expkow database)

no-melting pt equation used

Water Sol (Exper. database match) = 8 mg/L (20 deg C)

Exper. Ref: SHIU,WY ET AL. (1990)

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 16.213 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Aliphatic Amines

Carbamate Esters

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 3.02E-012 atm-m3/mole (3.06E-007 Pa-m3/mole)

Group Method: Incomplete

Exper Database: 1.35E-08 atm-m3/mole (1.37E-003 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 6.699E-007 atm-m3/mole (6.788E-002 Pa-m3/mole)

VP: 6.95E-007 mm Hg (source: MPBPVP)

WS: 0.56 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 4.30 (exp database)

Log Kaw used: -6.258 (exp database)

Log Koa (KOAWIN v1.10 estimate): 10.558

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.7289

Biowin2 (Non-Linear Model) : 0.9138

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.0871 (months )

Biowin4 (Primary Survey Model) : 3.3395 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.1664

Biowin6 (MITI Non-Linear Model): 0.0262

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.1217

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 2.67E-005 Pa (2E-007 mm Hg)

Log Koa (Koawin est ): 10.558

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.112

Octanol/air (Koa) model: 0.00887

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.803

Mackay model : 0.9

Octanol/air (Koa) model: 0.415

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 57.0859 E-12 cm3/molecule-sec

Half-Life = 0.187 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 2.248 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Fraction sorbed to airborne particulates (phi):

0.851 (Junge-Pankow, Mackay avg)

0.415 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 1515 L/kg (MCI method)

Log Koc: 3.180 (MCI method)

Koc : 1426 L/kg (Kow method)

Log Koc: 3.154 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Total Kb for pH > 8 at 25 deg C : 5.821E-002 L/mol-sec

Kb Half-Life at pH 8: 137.810 days

Kb Half-Life at pH 7: 3.773 years

(Total Kb applies only to esters, carbmates, alkyl halides)

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 2.504 (BCF = 319.3 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.3341 days (HL = 0.4633 days)

Log BCF Arnot-Gobas method (upper trophic) = 2.255 (BCF = 179.7)

Log BAF Arnot-Gobas method (upper trophic) = 2.255 (BAF = 179.8)

log Kow used: 4.30 (expkow database)

Volatilization from Water:

Henry LC: 1.35E-008 atm-m3/mole (Henry experimental database)

Half-Life from Model River: 8.787E+004 hours (3661 days)

Half-Life from Model Lake : 9.588E+005 hours (3.995E+004 days)

Removal In Wastewater Treatment:

Total removal: 45.27 percent

Total biodegradation: 0.44 percent

Total sludge adsorption: 44.83 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.0436 4.5 1000

Water 10.9 1.44e+003 1000

Soil 87.9 2.88e+003 1000

Sediment 1.11 1.3e+004 0

Persistence Time: 2.24e+003 hr

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