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CAS Number: 125643-61-0

SMILES : O=C(CCc1cc(c(c(c1)C(C)(C)C)O)C(C)(C)C)OCC(CC)CCC

CHEM : Benzenepropanoic acid, 3,5-bis(1,1-dimethylethyl)-4-hydroxy-, C7-9-br

anched alkyl esters

MOL FOR: C24 H40 O3

MOL WT : 376.58

------------------------------ EPI SUMMARY (v4.10) --------------------------

Henry LC (atm-m3/mole) : ------

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Water Solubility (mg/L): ------

Physical Property Inputs:

Vapor Pressure (mm Hg) : ------

Melting Point (deg C) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 7.93

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 426.18 (Adapted Stein & Brown method)

Melting Pt (deg C): 164.63 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 1.3E-008 (Modified Grain method)

VP (Pa, 25 deg C) : 1.73E-006 (Modified Grain method)

Subcooled liquid VP: 3.55E-007 mm Hg (25 deg C, Mod-Grain method)

: 4.73E-005 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 0.002721

log Kow used: 7.93 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 0.0056438 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Esters

Phenols

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 7.14E-008 atm-m3/mole (7.23E-003 Pa-m3/mole)

Group Method: 1.86E-008 atm-m3/mole (1.88E-003 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 2.367E-006 atm-m3/mole (2.399E-001 Pa-m3/mole)

VP: 1.3E-008 mm Hg (source: MPBPVP)

WS: 0.00272 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 7.93 (KowWin est)

Log Kaw used: -5.535 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 13.465

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.5451

Biowin2 (Non-Linear Model) : 0.4452

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.0645 (months )

Biowin4 (Primary Survey Model) : 3.1977 (weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.2954

Biowin6 (MITI Non-Linear Model): 0.0916

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.5649

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 4.73E-005 Pa (3.55E-007 mm Hg)

Log Koa (Koawin est ): 13.465

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.0634

Octanol/air (Koa) model: 7.16

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.696

Mackay model : 0.835

Octanol/air (Koa) model: 0.998

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 28.3318 E-12 cm3/molecule-sec

Half-Life = 0.378 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 4.530 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Reaction With Nitrate Radicals May Be Important!

Fraction sorbed to airborne particulates (phi):

0.766 (Junge-Pankow, Mackay avg)

0.998 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 4.655E+005 L/kg (MCI method)

Log Koc: 5.668 (MCI method)

Koc : 2.586E+005 L/kg (Kow method)

Log Koc: 5.413 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Total Kb for pH > 8 at 25 deg C : 4.384E-002 L/mol-sec

Kb Half-Life at pH 8: 182.971 days

Kb Half-Life at pH 7: 5.009 years

(Total Kb applies only to esters, carbmates, alkyl halides)

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 3.444 (BCF = 2782 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.0573 days (HL = 0.8763 days)

Log BCF Arnot-Gobas method (upper trophic) = 1.302 (BCF = 20.07)

Log BAF Arnot-Gobas method (upper trophic) = 1.620 (BAF = 41.71)

log Kow used: 7.93 (estimated)

Volatilization from Water:

Henry LC: 1.86E-008 atm-m3/mole (estimated by Group SAR Method)

Half-Life from Model River: 6.109E+004 hours (2545 days)

Half-Life from Model Lake : 6.666E+005 hours (2.777E+004 days)

Removal In Wastewater Treatment:

Total removal: 94.01 percent

Total biodegradation: 0.78 percent

Total sludge adsorption: 93.23 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.073 9.06 1000

Water 5.62 1.44e+003 1000

Soil 59.1 2.88e+003 1000

Sediment 35.2 1.3e+004 0

Persistence Time: 3.18e+003 hr

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