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CAS Number: 81496-82-4

SMILES : O1C(O)C(C4CCC(C)C3C42OOC(OC12)(C)CC3)C

CHEM : dihydroartemisinin

MOL FOR: C15 H24 O5

MOL WT : 284.36

------------------------------ EPI SUMMARY (v4.10) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 1.86

Log Kow (Exper. database match) = 2.19

Exper. Ref: SANGSTER (1994)

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 361.50 (Adapted Stein & Brown method)

Melting Pt (deg C): 133.38 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 1.99E-007 (Modified Grain method)

VP (Pa, 25 deg C) : 2.66E-005 (Modified Grain method)

Subcooled liquid VP: 2.44E-006 mm Hg (25 deg C, Mod-Grain method)

: 0.000325 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 659.9

log Kow used: 2.19 (expkow database)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 104.87 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Peroxy Acids

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 5.89E-012 atm-m3/mole (5.97E-007 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.128E-010 atm-m3/mole (1.143E-005 Pa-m3/mole)

VP: 1.99E-007 mm Hg (source: MPBPVP)

WS: 660 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 2.19 (exp database)

Log Kaw used: -9.618 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 11.808

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : -0.2917

Biowin2 (Non-Linear Model) : 0.0000

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.2892 (weeks-months)

Biowin4 (Primary Survey Model) : 3.2406 (weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.3203

Biowin6 (MITI Non-Linear Model): 0.0205

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.6962

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.000325 Pa (2.44E-006 mm Hg)

Log Koa (Koawin est ): 11.808

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.00922

Octanol/air (Koa) model: 0.158

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.25

Mackay model : 0.425

Octanol/air (Koa) model: 0.927

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 81.9796 E-12 cm3/molecule-sec

Half-Life = 0.130 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 1.566 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Fraction sorbed to airborne particulates (phi):

0.337 (Junge-Pankow, Mackay avg)

0.927 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 295.9 L/kg (MCI method)

Log Koc: 2.471 (MCI method)

Koc : 34.98 L/kg (Kow method)

Log Koc: 1.544 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 1.112 (BCF = 12.94 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.2393 days (HL = 0.5763 days)

Log BCF Arnot-Gobas method (upper trophic) = 1.199 (BCF = 15.8)

Log BAF Arnot-Gobas method (upper trophic) = 1.199 (BAF = 15.8)

log Kow used: 2.19 (expkow database)

Volatilization from Water:

Henry LC: 5.89E-012 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 1.676E+008 hours (6.984E+006 days)

Half-Life from Model Lake : 1.829E+009 hours (7.619E+007 days)

Removal In Wastewater Treatment:

Total removal: 2.46 percent

Total biodegradation: 0.10 percent

Total sludge adsorption: 2.37 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 6.34e-005 3.13 1000

Water 13.5 900 1000

Soil 86.3 1.8e+003 1000

Sediment 0.225 8.1e+003 0

Persistence Time: 1.75e+003 hr

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