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CAS Number: 4192-90-9

SMILES : C1C(C(C(C(O1)CC(=O)O)OC(=O)C2=Cc3cc(c(cc3C(C2C(=O)O)c4cc(c(cc4)O)O)O)

O)O)O

CHEM : trilobatin

MOL FOR: C25 H24 O13

MOL WT : 532.46

------------------------------ EPI SUMMARY (v4.00) --------------------------

Henry LC (atm-m3/mole) : ------

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Water Solubility (mg/L): ------

Physical Property Inputs:

Vapor Pressure (mm Hg) : ------

Melting Point (deg C) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = -1.35

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 818.10 (Adapted Stein & Brown method)

Melting Pt (deg C): 349.84 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 3.19E-025 (Modified Grain method)

VP (Pa, 25 deg C) : 4.25E-023 (Modified Grain method)

Subcooled liquid VP: 1.63E-021 mm Hg (25 deg C, Mod-Grain method)

: 2.18E-019 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 5.885e+004

log Kow used: -1.35 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 60972 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Acrylates-acid

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 4.46E-042 atm-m3/mole (4.52E-037 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 3.798E-030 atm-m3/mole (3.848E-025 Pa-m3/mole)

VP: 3.19E-025 mm Hg (source: MPBPVP)

WS: 5.89E+004 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: -1.35 (KowWin est)

Log Kaw used: -39.739 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 38.389

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 1.3016

Biowin2 (Non-Linear Model) : 0.9788

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 3.3539 (days-weeks )

Biowin4 (Primary Survey Model) : 4.4190 (hours-days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.5837

Biowin6 (MITI Non-Linear Model): 0.0334

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 1.1838

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 2.17E-019 Pa (1.63E-021 mm Hg)

Log Koa (Koawin est ): 38.389

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 1.38E+013

Octanol/air (Koa) model: 6.01E+025

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 1

Mackay model : 1

Octanol/air (Koa) model: 1

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 193.0931 E-12 cm3/molecule-sec

Half-Life = 0.055 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 0.665 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 13.650000 E-17 cm3/molecule-sec

Half-Life = 0.084 Days (at 7E11 mol/cm3)

Half-Life = 2.015 Hrs

Reaction With Nitrate Radicals May Be Important!

Fraction sorbed to airborne particulates (phi):

1 (Junge-Pankow, Mackay avg)

1 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 1278 L/kg (MCI method)

Log Koc: 3.106 (MCI method)

Koc : 0.1251 L/kg (Kow method)

Log Koc: -0.903 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Total Kb for pH > 8 at 25 deg C : 1.469E-003 L/mol-sec

Kb Half-Life at pH 8: 14.952 years

Kb Half-Life at pH 7: 149.517 years

(Total Kb applies only to esters, carbmates, alkyl halides)

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 0.500 (BCF = 3.162 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -4.3817 days (HL = 4.152e-005 days)

Log BCF Arnot-Gobas method (upper trophic) = -0.049 (BCF = 0.8939)

Log BAF Arnot-Gobas method (upper trophic) = -0.049 (BAF = 0.8939)

log Kow used: -1.35 (estimated)

Volatilization from Water:

Henry LC: 4.46E-042 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 3.029E+038 hours (1.262E+037 days)

Half-Life from Model Lake : 3.305E+039 hours (1.377E+038 days)

Removal In Wastewater Treatment:

Total removal: 1.85 percent

Total biodegradation: 0.09 percent

Total sludge adsorption: 1.75 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 2.26e-019 0.801 1000

Water 18.3 208 1000

Soil 81.2 416 1000

Sediment 0.545 1.87e+003 0

Persistence Time: 466 hr

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