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CAS Number:

SMILES : O=C(O)C=2CCC(CC1C=2CCC1C)C(=C)C

CHEM : guaia-1(10),11-dien-15-carboxylic acid

MOL FOR: C15 H22 O2

MOL WT : 234.34

------------------------------ EPI SUMMARY (v4.00) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = 6.68

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 345.61 (Adapted Stein & Brown method)

Melting Pt (deg C): 103.90 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 2.84E-005 (Modified Grain method)

VP (Pa, 25 deg C) : 0.00379 (Modified Grain method)

Subcooled liquid VP: 0.000168 mm Hg (25 deg C, Mod-Grain method)

: 0.0224 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 0.1418

log Kow used: 6.68 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 0.93499 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Neutral Organics

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : Incomplete

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 6.176E-005 atm-m3/mole (6.257E+000 Pa-m3/mole)

VP: 2.84E-005 mm Hg (source: MPBPVP)

WS: 0.142 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Can Not Estimate (can not calculate HenryLC)

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.7087

Biowin2 (Non-Linear Model) : 0.5803

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 3.0459 (weeks )

Biowin4 (Primary Survey Model) : 3.8952 (days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.3453

Biowin6 (MITI Non-Linear Model): 0.0984

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.2349

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.0224 Pa (0.000168 mm Hg)

Log Koa (): not available

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.000134

Octanol/air (Koa) model: not available

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.00481

Mackay model : 0.0106

Octanol/air (Koa) model: not available

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 65.3950 E-12 cm3/molecule-sec

Half-Life = 0.164 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 1.963 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 1.200000 E-17 cm3/molecule-sec

Half-Life = 0.955 Days (at 7E11 mol/cm3)

Half-Life = 22.920 Hrs

Fraction sorbed to airborne particulates (phi):

0.00771 (Junge-Pankow, Mackay avg)

not available (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 422.2 L/kg (MCI method)

Log Koc: 2.626 (MCI method)

Koc : 7090 L/kg (Kow method)

Log Koc: 3.851 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 1.750 (BCF = 56.23 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 2.1495 days (HL = 141.1 days)

Log BCF Arnot-Gobas method (upper trophic) = 4.025 (BCF = 1.059e+004)

Log BAF Arnot-Gobas method (upper trophic) = 6.507 (BAF = 3.213e+006)

log Kow used: 6.68 (estimated)

Volatilization from Water:

Henry LC: 6.18E-005 atm-m3/mole (calculated from VP/WS)

Half-Life from Model River: 16.08 hours

Half-Life from Model Lake : 303.7 hours (12.66 days)

Removal In Wastewater Treatment:

Total removal: 93.64 percent

Total biodegradation: 0.78 percent

Total sludge adsorption: 92.85 percent

Total to Air: 0.01 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.407 3.35 1000

Water 23.6 360 1000

Soil 75.7 720 1000

Sediment 0.326 3.24e+003 0

Persistence Time: 434 hr

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