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CAS Number: 84-99-1

SMILES : O=C1C=Cc2c(OC)c3C=CC(C)(C)Oc3cc2O1

CHEM : Xanthoxyletin

MOL FOR: C15 H14 O4

MOL WT : 258.28

------------------------------ EPI SUMMARY (v4.10) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 3.26

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 392.97 (Adapted Stein & Brown method)

Melting Pt (deg C): 141.55 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 1.02E-006 (Modified Grain method)

VP (Pa, 25 deg C) : 0.000135 (Modified Grain method)

MP (exp database): 133 deg C

Subcooled liquid VP: 1.23E-005 mm Hg (25 deg C, Mod-Grain method)

: 0.00164 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 35.21

log Kow used: 3.26 (estimated)

no-melting pt equation used

Water Sol (Exper. database match) = 40 mg/L ( deg C)

Exper. Ref: MERCK INDEX (1996); cold water

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 3.9608 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Acrylates

Vinyl/Allyl Ethers

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 1.14E-008 atm-m3/mole (1.16E-003 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 9.845E-009 atm-m3/mole (9.975E-004 Pa-m3/mole)

VP: 1.02E-006 mm Hg (source: MPBPVP)

WS: 35.2 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 3.26 (KowWin est)

Log Kaw used: -6.332 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 9.592

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.8787

Biowin2 (Non-Linear Model) : 0.9980

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.4403 (weeks-months)

Biowin4 (Primary Survey Model) : 3.7049 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.7798

Biowin6 (MITI Non-Linear Model): 0.7011

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.4015

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.00164 Pa (1.23E-005 mm Hg)

Log Koa (Koawin est ): 9.592

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.00183

Octanol/air (Koa) model: 0.000959

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.062

Mackay model : 0.128

Octanol/air (Koa) model: 0.0713

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 269.4616 E-12 cm3/molecule-sec

Half-Life = 0.040 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 28.580 Min

Ozone Reaction:

OVERALL Ozone Rate Constant = 4.200000 E-17 cm3/molecule-sec

Half-Life = 0.273 Days (at 7E11 mol/cm3)

Half-Life = 6.549 Hrs

Fraction sorbed to airborne particulates (phi):

0.0948 (Junge-Pankow, Mackay avg)

0.0713 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 432.4 L/kg (MCI method)

Log Koc: 2.636 (MCI method)

Koc : 595 L/kg (Kow method)

Log Koc: 2.775 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 1.816 (BCF = 65.43 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.9293 days (HL = 0.1177 days)

Log BCF Arnot-Gobas method (upper trophic) = 1.592 (BCF = 39.1)

Log BAF Arnot-Gobas method (upper trophic) = 1.592 (BAF = 39.1)

log Kow used: 3.26 (estimated)

Volatilization from Water:

Henry LC: 1.14E-008 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 8.254E+004 hours (3439 days)

Half-Life from Model Lake : 9.006E+005 hours (3.752E+004 days)

Removal In Wastewater Treatment:

Total removal: 8.62 percent

Total biodegradation: 0.15 percent

Total sludge adsorption: 8.47 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.0272 0.832 1000

Water 17.5 900 1000

Soil 82.1 1.8e+003 1000

Sediment 0.419 8.1e+003 0

Persistence Time: 1.17e+003 hr

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