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CAS Number: 124166-25-2

SMILES : COc1ccc(cc1)C=C2COc3c(C2(=O))ccc(c3O)OC

CHEM : (3E)-8-hydroxy-7-methoxy-3-[(4-methoxyphenyl)methylidene]chromen-4-on

e

MOL FOR: C18 H16 O5

MOL WT : 312.32

------------------------------ EPI SUMMARY (v4.00) --------------------------

Henry LC (atm-m3/mole) : ------

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Water Solubility (mg/L): ------

Physical Property Inputs:

Vapor Pressure (mm Hg) : ------

Melting Point (deg C) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = 3.42

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 454.62 (Adapted Stein & Brown method)

Melting Pt (deg C): 191.40 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 1.1E-009 (Modified Grain method)

VP (Pa, 25 deg C) : 1.47E-007 (Modified Grain method)

Subcooled liquid VP: 6.12E-008 mm Hg (25 deg C, Mod-Grain method)

: 8.16E-006 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 12.36

log Kow used: 3.42 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 13.627 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Phenols

Vinyl/Allyl Ketones

Vinyl/Allyl Ethers

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 2.60E-015 atm-m3/mole (2.63E-010 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 3.657E-011 atm-m3/mole (3.706E-006 Pa-m3/mole)

VP: 1.1E-009 mm Hg (source: MPBPVP)

WS: 12.4 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 3.42 (KowWin est)

Log Kaw used: -12.973 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 16.393

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 1.1172

Biowin2 (Non-Linear Model) : 0.9969

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.3685 (weeks-months)

Biowin4 (Primary Survey Model) : 3.6460 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.6267

Biowin6 (MITI Non-Linear Model): 0.4561

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.1337

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 8.16E-006 Pa (6.12E-008 mm Hg)

Log Koa (Koawin est ): 16.393

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.368

Octanol/air (Koa) model: 6.07E+003

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.93

Mackay model : 0.967

Octanol/air (Koa) model: 1

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 206.9620 E-12 cm3/molecule-sec

Half-Life = 0.052 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 0.620 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 13.650000 E-17 cm3/molecule-sec

Half-Life = 0.084 Days (at 7E11 mol/cm3)

Half-Life = 2.015 Hrs

Reaction With Nitrate Radicals May Be Important!

Fraction sorbed to airborne particulates (phi):

0.949 (Junge-Pankow, Mackay avg)

1 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 6614 L/kg (MCI method)

Log Koc: 3.820 (MCI method)

Koc : 1955 L/kg (Kow method)

Log Koc: 3.291 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 1.342 (BCF = 21.96 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.2207 days (HL = 0.6016 days)

Log BCF Arnot-Gobas method (upper trophic) = 2.123 (BCF = 132.8)

Log BAF Arnot-Gobas method (upper trophic) = 2.123 (BAF = 132.8)

log Kow used: 3.42 (estimated)

Volatilization from Water:

Henry LC: 2.6E-015 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 3.98E+011 hours (1.658E+010 days)

Half-Life from Model Lake : 4.341E+012 hours (1.809E+011 days)

Removal In Wastewater Treatment:

Total removal: 11.34 percent

Total biodegradation: 0.17 percent

Total sludge adsorption: 11.17 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 3.6e-007 0.768 1000

Water 10.6 900 1000

Soil 85.3 1.8e+003 1000

Sediment 4.07 8.1e+003 0

Persistence Time: 1.92e+003 hr

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