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CAS Number: 2746-19-2

SMILES : O=C(OC(=O)C1C(C=CC23)C2)C13

CHEM : 4,7-Methanoisobenzofuran-1,3-dione, 3a,4,7,7a-tetrahydro-, (3a.alpha.

,4.beta.,7.beta.,7a.alpha.)-

MOL FOR: C9 H8 O3

MOL WT : 164.16

------------------------------ EPI SUMMARY (v4.10) --------------------------

Henry LC (atm-m3/mole) : ------

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Water Solubility (mg/L): ------

Physical Property Inputs:

Vapor Pressure (mm Hg) : ------

Melting Point (deg C) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 1.85

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 248.34 (Adapted Stein & Brown method)

Melting Pt (deg C): 18.91 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.00106 (Modified Grain method)

VP (Pa, 25 deg C) : 0.142 (Modified Grain method)

MP (exp database): 164.5 deg C

Subcooled liquid VP: 0.029 mm Hg (25 deg C, Mod-Grain method)

: 3.86 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 1731

log Kow used: 1.85 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 2766.1 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Neutral Organics

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 1.11E-005 atm-m3/mole (1.12E+000 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.323E-007 atm-m3/mole (1.340E-002 Pa-m3/mole)

VP: 0.00106 mm Hg (source: MPBPVP)

WS: 1.73E+003 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 1.85 (KowWin est)

Log Kaw used: -3.343 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 5.193

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.6694

Biowin2 (Non-Linear Model) : 0.6632

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.8364 (weeks )

Biowin4 (Primary Survey Model) : 3.6109 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.3056

Biowin6 (MITI Non-Linear Model): 0.0803

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.7268

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 3.87 Pa (0.029 mm Hg)

Log Koa (Koawin est ): 5.193

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 7.76E-007

Octanol/air (Koa) model: 3.83E-008

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 2.8E-005

Mackay model : 6.21E-005

Octanol/air (Koa) model: 3.06E-006

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 60.1285 E-12 cm3/molecule-sec

Half-Life = 0.178 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 2.135 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 20.000000 E-17 cm3/molecule-sec

Half-Life = 0.057 Days (at 7E11 mol/cm3)

Half-Life = 1.375 Hrs

Fraction sorbed to airborne particulates (phi):

4.5E-005 (Junge-Pankow, Mackay avg)

3.06E-006 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 10 L/kg (MCI method)

Log Koc: 1.000 (MCI method)

Koc : 30.89 L/kg (Kow method)

Log Koc: 1.490 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 0.886 (BCF = 7.693 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -0.3981 days (HL = 0.3998 days)

Log BCF Arnot-Gobas method (upper trophic) = 0.886 (BCF = 7.699)

Log BAF Arnot-Gobas method (upper trophic) = 0.886 (BAF = 7.699)

log Kow used: 1.85 (estimated)

Volatilization from Water:

Henry LC: 1.11E-005 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 68.89 hours (2.87 days)

Half-Life from Model Lake : 858.9 hours (35.79 days)

Removal In Wastewater Treatment:

Total removal: 2.74 percent

Total biodegradation: 0.09 percent

Total sludge adsorption: 2.02 percent

Total to Air: 0.62 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.162 1.04 1000

Water 40.4 360 1000

Soil 59.4 720 1000

Sediment 0.0909 3.24e+003 0

Persistence Time: 351 hr

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