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CAS Number: 125109-84-4

SMILES : O=CCC(c1cccc(c1)C(=C)C)C

CHEM : Benzenepropanal, .beta.-methyl-3-(1-methylethenyl)-

MOL FOR: C13 H16 O1

MOL WT : 188.27

------------------------------ EPI SUMMARY (v4.10) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 3.90

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 274.44 (Adapted Stein & Brown method)

Melting Pt (deg C): 29.96 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.00677 (Modified Grain method)

VP (Pa, 25 deg C) : 0.903 (Modified Grain method)

Subcooled liquid VP: 0.0075 mm Hg (25 deg C, Mod-Grain method)

: 1 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 23.42

log Kow used: 3.90 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 45.223 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Aldehydes (Mono)

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 7.76E-006 atm-m3/mole (7.86E-001 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 7.161E-005 atm-m3/mole (7.256E+000 Pa-m3/mole)

VP: 0.00677 mm Hg (source: MPBPVP)

WS: 23.4 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 3.90 (KowWin est)

Log Kaw used: -3.499 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 7.399

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.9972

Biowin2 (Non-Linear Model) : 0.9997

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.7306 (weeks-months)

Biowin4 (Primary Survey Model) : 3.7042 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.6492

Biowin6 (MITI Non-Linear Model): 0.7507

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.2154

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 1 Pa (0.0075 mm Hg)

Log Koa (Koawin est ): 7.399

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 3E-006

Octanol/air (Koa) model: 6.15E-006

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.000108

Mackay model : 0.00024

Octanol/air (Koa) model: 0.000492

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 85.2399 E-12 cm3/molecule-sec

Half-Life = 0.125 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 1.506 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 13.650000 E-17 cm3/molecule-sec

Half-Life = 0.084 Days (at 7E11 mol/cm3)

Half-Life = 2.015 Hrs

Fraction sorbed to airborne particulates (phi):

0.000174 (Junge-Pankow, Mackay avg)

0.000492 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 288.6 L/kg (MCI method)

Log Koc: 2.460 (MCI method)

Koc : 712.9 L/kg (Kow method)

Log Koc: 2.853 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 2.240 (BCF = 173.8 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 0.4902 days (HL = 3.092 days)

Log BCF Arnot-Gobas method (upper trophic) = 2.705 (BCF = 506.8)

Log BAF Arnot-Gobas method (upper trophic) = 2.707 (BAF = 508.8)

log Kow used: 3.90 (estimated)

Volatilization from Water:

Henry LC: 7.76E-006 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 104.9 hours (4.372 days)

Half-Life from Model Lake : 1260 hours (52.49 days)

Removal In Wastewater Treatment:

Total removal: 25.99 percent

Total biodegradation: 0.28 percent

Total sludge adsorption: 25.39 percent

Total to Air: 0.32 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.0627 1.21 1000

Water 20 900 1000

Soil 79.6 1.8e+003 1000

Sediment 0.327 8.1e+003 0

Persistence Time: 973 hr

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