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CAS Number: 6924-68-1

SMILES : n1c(C(=O)OCC)cncc1

CHEM : 2-Ethylpyrazine carboxylate

MOL FOR: C7 H8 N2 O2

MOL WT : 152.15

------------------------------ EPI SUMMARY (v4.00) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = 0.27

Log Kow (Exper. database match) = 0.28

Exper. Ref: YAMAGAMI,C ET AL. (1990A)

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 233.16 (Adapted Stein & Brown method)

Melting Pt (deg C): 43.69 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.0425 (Modified Grain method)

VP (Pa, 25 deg C) : 5.66 (Modified Grain method)

Subcooled liquid VP: 0.0628 mm Hg (25 deg C, Mod-Grain method)

: 8.38 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 4.28e+004

log Kow used: 0.28 (expkow database)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 4.4852e+005 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Esters

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 2.50E-008 atm-m3/mole (2.53E-003 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.988E-007 atm-m3/mole (2.014E-002 Pa-m3/mole)

VP: 0.0425 mm Hg (source: MPBPVP)

WS: 4.28E+004 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 0.28 (exp database)

Log Kaw used: -5.991 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 6.271

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.8493

Biowin2 (Non-Linear Model) : 0.9928

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 3.0031 (weeks )

Biowin4 (Primary Survey Model) : 3.8572 (days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.6777

Biowin6 (MITI Non-Linear Model): 0.8004

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.6681

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 8.37 Pa (0.0628 mm Hg)

Log Koa (Koawin est ): 6.271

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 3.58E-007

Octanol/air (Koa) model: 4.58E-007

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 1.29E-005

Mackay model : 2.87E-005

Octanol/air (Koa) model: 3.67E-005

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 1.7360 E-12 cm3/molecule-sec

Half-Life = 6.161 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 73.934 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Fraction sorbed to airborne particulates (phi):

2.08E-005 (Junge-Pankow, Mackay avg)

3.67E-005 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 31.01 L/kg (MCI method)

Log Koc: 1.491 (MCI method)

Koc : 25.87 L/kg (Kow method)

Log Koc: 1.413 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Total Kb for pH > 8 at 25 deg C : 3.776E-002 L/mol-sec

Kb Half-Life at pH 8: 212.462 days

Kb Half-Life at pH 7: 5.817 years

(Total Kb applies only to esters, carbmates, alkyl halides)

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 0.500 (BCF = 3.162 L/kg wet-wt)

Log Biotransformation Half-life (HL) = -1.5333 days (HL = 0.02929 days)

Log BCF Arnot-Gobas method (upper trophic) = 0.001 (BCF = 1.002)

Log BAF Arnot-Gobas method (upper trophic) = 0.001 (BAF = 1.002)

log Kow used: 0.28 (expkow database)

Volatilization from Water:

Henry LC: 2.5E-008 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 2.889E+004 hours (1204 days)

Half-Life from Model Lake : 3.153E+005 hours (1.314E+004 days)

Removal In Wastewater Treatment:

Total removal: 1.86 percent

Total biodegradation: 0.09 percent

Total sludge adsorption: 1.76 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.445 148 1000

Water 24.9 360 1000

Soil 74.6 720 1000

Sediment 0.0777 3.24e+003 0

Persistence Time: 662 hr

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