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CAS Number: 77286-42-1

SMILES : CC(=CCCC(=O)C)CCC=C(C)CCC1C(O1)(C)C

CHEM : (5E,9E)-12-(3,3-dimethyloxiran-2-yl)-6,10-dimethyldodeca-5,9-dien-2-o

ne

MOL FOR: C18 H30 O2

MOL WT : 278.44

------------------------------ EPI SUMMARY (v4.00) --------------------------

Henry LC (atm-m3/mole) : ------

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Water Solubility (mg/L): ------

Physical Property Inputs:

Vapor Pressure (mm Hg) : ------

Melting Point (deg C) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = 5.26

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 341.82 (Adapted Stein & Brown method)

Melting Pt (deg C): 90.70 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 9.78E-005 (Modified Grain method)

VP (Pa, 25 deg C) : 0.013 (Modified Grain method)

Subcooled liquid VP: 0.000421 mm Hg (25 deg C, Mod-Grain method)

: 0.0561 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 0.5265

log Kow used: 5.26 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 4.29 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Epoxides, mono

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 4.60E-006 atm-m3/mole (4.67E-001 Pa-m3/mole)

Group Method: 1.17E-007 atm-m3/mole (1.19E-002 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 6.805E-005 atm-m3/mole (6.896E+000 Pa-m3/mole)

VP: 9.78E-005 mm Hg (source: MPBPVP)

WS: 0.526 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 5.26 (KowWin est)

Log Kaw used: -3.726 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 8.986

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.0905

Biowin2 (Non-Linear Model) : 0.0014

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.3406 (weeks-months)

Biowin4 (Primary Survey Model) : 3.2606 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.3940

Biowin6 (MITI Non-Linear Model): 0.1436

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.4968

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.0561 Pa (0.000421 mm Hg)

Log Koa (Koawin est ): 8.986

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 5.34E-005

Octanol/air (Koa) model: 0.000238

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.00193

Mackay model : 0.00426

Octanol/air (Koa) model: 0.0187

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 185.5086 E-12 cm3/molecule-sec

Half-Life = 0.058 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 0.692 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 86.000000 E-17 cm3/molecule-sec

Half-Life = 0.013 Days (at 7E11 mol/cm3)

Half-Life = 19.189 Min

Reaction With Nitrate Radicals May Be Important!

Fraction sorbed to airborne particulates (phi):

0.00309 (Junge-Pankow, Mackay avg)

0.0187 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 2832 L/kg (MCI method)

Log Koc: 3.452 (MCI method)

Koc : 8701 L/kg (Kow method)

Log Koc: 3.940 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Total Ka (acid-catalyzed) at 25 deg C : 1.447E+000 L/mol-sec

Ka Half-Life at pH 7: 55.430 days

(Total Ka applies to epoxide(s) only)

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 3.138 (BCF = 1373 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 0.4449 days (HL = 2.785 days)

Log BCF Arnot-Gobas method (upper trophic) = 3.019 (BCF = 1045)

Log BAF Arnot-Gobas method (upper trophic) = 3.049 (BAF = 1119)

log Kow used: 5.26 (estimated)

Volatilization from Water:

Henry LC: 4.6E-006 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 214.1 hours (8.92 days)

Half-Life from Model Lake : 2475 hours (103.1 days)

Removal In Wastewater Treatment:

Total removal: 84.40 percent

Total biodegradation: 0.72 percent

Total sludge adsorption: 83.66 percent

Total to Air: 0.03 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.012 0.26 1000

Water 17.2 900 1000

Soil 80 1.8e+003 1000

Sediment 2.76 8.1e+003 0

Persistence Time: 1.07e+003 hr

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