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CAS Number: 13402-02-3

SMILES : O=C(OCCCCCCCCCCCCCCCC)C=C

CHEM : 2-Propenoic acid, hexadecyl ester

MOL FOR: C19 H36 O2

MOL WT : 296.50

------------------------------ EPI SUMMARY (v4.10) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 8.09

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 348.12 (Adapted Stein & Brown method)

Melting Pt (deg C): 80.45 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 4.33E-005 (Modified Grain method)

VP (Pa, 25 deg C) : 0.00577 (Modified Grain method)

Subcooled liquid VP: 0.000146 mm Hg (25 deg C, Mod-Grain method)

: 0.0195 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 0.001574

log Kow used: 8.09 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 0.0011938 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Acrylates

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 6.48E-003 atm-m3/mole (6.57E+002 Pa-m3/mole)

Group Method: 7.92E-003 atm-m3/mole (8.02E+002 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.073E-002 atm-m3/mole (1.087E+003 Pa-m3/mole)

VP: 4.33E-005 mm Hg (source: MPBPVP)

WS: 0.00157 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 8.09 (KowWin est)

Log Kaw used: -0.577 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 8.667

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.8890

Biowin2 (Non-Linear Model) : 0.9912

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.9825 (weeks )

Biowin4 (Primary Survey Model) : 3.9180 (days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.9340

Biowin6 (MITI Non-Linear Model): 0.9507

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.7799

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.0195 Pa (0.000146 mm Hg)

Log Koa (Koawin est ): 8.667

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 0.000154

Octanol/air (Koa) model: 0.000114

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.00554

Mackay model : 0.0122

Octanol/air (Koa) model: 0.00904

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 30.7288 E-12 cm3/molecule-sec

Half-Life = 0.348 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 4.177 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 0.175000 E-17 cm3/molecule-sec

Half-Life = 6.549 Days (at 7E11 mol/cm3)

Fraction sorbed to airborne particulates (phi):

0.00886 (Junge-Pankow, Mackay avg)

0.00904 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 4.747E+004 L/kg (MCI method)

Log Koc: 4.676 (MCI method)

Koc : 2.159E+005 L/kg (Kow method)

Log Koc: 5.334 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Total Kb for pH > 8 at 25 deg C : 9.224E-003 L/mol-sec

Kb Half-Life at pH 8: 2.381 years

Kb Half-Life at pH 7: 23.812 years

(Total Kb applies only to esters, carbmates, alkyl halides)

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 2.991 (BCF = 980.2 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 0.3684 days (HL = 2.336 days)

Log BCF Arnot-Gobas method (upper trophic) = 1.563 (BCF = 36.55)

Log BAF Arnot-Gobas method (upper trophic) = 2.525 (BAF = 335.3)

log Kow used: 8.09 (estimated)

Volatilization from Water:

Henry LC: 0.00792 atm-m3/mole (estimated by Group SAR Method)

Half-Life from Model River: 1.884 hours

Half-Life from Model Lake : 164.9 hours (6.873 days)

Removal In Wastewater Treatment:

Total removal: 94.03 percent

Total biodegradation: 0.78 percent

Total sludge adsorption: 93.20 percent

Total to Air: 0.05 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.837 7.93 1000

Water 21.9 360 1000

Soil 73 720 1000

Sediment 4.27 3.24e+003 0

Persistence Time: 461 hr

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