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CAS Number: 49763-69-1

SMILES : O=Cc(ccc(c1)CCCCCC)c1

CHEM : Benzaldehyde, 4-hexyl-

MOL FOR: C13 H18 O1

MOL WT : 190.29

------------------------------ EPI SUMMARY (v4.10) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.68 estimate) = 4.71

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 289.42 (Adapted Stein & Brown method)

Melting Pt (deg C): 49.69 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.00203 (Modified Grain method)

VP (Pa, 25 deg C) : 0.27 (Modified Grain method)

Subcooled liquid VP: 0.00342 mm Hg (25 deg C, Mod-Grain method)

: 0.456 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.42):

Water Solubility at 25 deg C (mg/L): 4.626

log Kow used: 4.71 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 5.6641 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Aldehydes (Mono)

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 6.11E-005 atm-m3/mole (6.19E+000 Pa-m3/mole)

Group Method: 1.86E-004 atm-m3/mole (1.88E+001 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.099E-004 atm-m3/mole (1.113E+001 Pa-m3/mole)

VP: 0.00203 mm Hg (source: MPBPVP)

WS: 4.63 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 4.71 (KowWin est)

Log Kaw used: -2.602 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 7.312

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 1.1047

Biowin2 (Non-Linear Model) : 1.0000

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 3.0245 (weeks )

Biowin4 (Primary Survey Model) : 3.9704 (days )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.7327

Biowin6 (MITI Non-Linear Model): 0.8664

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): 0.1618

Ready Biodegradability Prediction: YES

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.456 Pa (0.00342 mm Hg)

Log Koa (Koawin est ): 7.312

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 6.58E-006

Octanol/air (Koa) model: 5.04E-006

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.000238

Mackay model : 0.000526

Octanol/air (Koa) model: 0.000403

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 25.1776 E-12 cm3/molecule-sec

Half-Life = 0.425 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 5.098 Hrs

Ozone Reaction:

No Ozone Reaction Estimation

Fraction sorbed to airborne particulates (phi):

0.000382 (Junge-Pankow, Mackay avg)

0.000403 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 374.3 L/kg (MCI method)

Log Koc: 2.573 (MCI method)

Koc : 2000 L/kg (Kow method)

Log Koc: 3.301 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.01):

Log BCF from regression-based method = 2.777 (BCF = 597.9 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 0.5253 days (HL = 3.352 days)

Log BCF Arnot-Gobas method (upper trophic) = 3.036 (BCF = 1088)

Log BAF Arnot-Gobas method (upper trophic) = 3.049 (BAF = 1118)

log Kow used: 4.71 (estimated)

Volatilization from Water:

Henry LC: 0.000186 atm-m3/mole (estimated by Group SAR Method)

Half-Life from Model River: 5.75 hours

Half-Life from Model Lake : 178.4 hours (7.433 days)

Removal In Wastewater Treatment:

Total removal: 67.85 percent

Total biodegradation: 0.58 percent

Total sludge adsorption: 64.70 percent

Total to Air: 2.57 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 1.44 10.2 1000

Water 21.3 360 1000

Soil 76.9 720 1000

Sediment 0.33 3.24e+003 0

Persistence Time: 403 hr

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