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CAS Number: 67923-86-8

SMILES : CC=C(C)CC=C(C)CC(OCCCCCCCCCCC(C)C)OCCCCCCCCCCC(C)C

CHEM : Isotridecane, 1,1'-[(3,6-dimethyl-2,6-octadienylidene)bis(oxy)]bis-

MOL FOR: C36 H70 O2

MOL WT : 534.96

------------------------------ EPI SUMMARY (v4.00) --------------------------

Physical Property Inputs:

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Vapor Pressure (mm Hg) : ------

Water Solubility (mg/L): ------

Henry LC (atm-m3/mole) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = 15.47

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPVP v1.43):

Boiling Pt (deg C): 524.02 (Adapted Stein & Brown method)

Melting Pt (deg C): 188.01 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 4.41E-010 (Modified Grain method)

VP (Pa, 25 deg C) : 5.88E-008 (Modified Grain method)

Subcooled liquid VP: 2.24E-008 mm Hg (25 deg C, Mod-Grain method)

: 2.98E-006 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 2.604e-011

log Kow used: 15.47 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 5.3496e-007 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Neutral Organics

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 6.27E-001 atm-m3/mole (6.35E+004 Pa-m3/mole)

Group Method: 2.87E-001 atm-m3/mole (2.91E+004 Pa-m3/mole)

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.192E+001 atm-m3/mole (1.208E+006 Pa-m3/mole)

VP: 4.41E-010 mm Hg (source: MPBPVP)

WS: 2.6E-011 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 15.47 (KowWin est)

Log Kaw used: 1.409 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 14.061

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : -0.2019

Biowin2 (Non-Linear Model) : 0.0000

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 1.9996 (months )

Biowin4 (Primary Survey Model) : 3.0564 (weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.0740

Biowin6 (MITI Non-Linear Model): 0.0221

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.3082

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 2.99E-006 Pa (2.24E-008 mm Hg)

Log Koa (Koawin est ): 14.061

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 1

Octanol/air (Koa) model: 28.2

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.973

Mackay model : 0.988

Octanol/air (Koa) model: 1

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 235.1319 E-12 cm3/molecule-sec

Half-Life = 0.045 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 0.546 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 86.000000 E-17 cm3/molecule-sec

Half-Life = 0.013 Days (at 7E11 mol/cm3)

Half-Life = 19.189 Min

Reaction With Nitrate Radicals May Be Important!

Fraction sorbed to airborne particulates (phi):

0.98 (Junge-Pankow, Mackay avg)

1 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 2.631E+008 L/kg (MCI method)

Log Koc: 8.420 (MCI method)

Koc : 1.999E+009 L/kg (Kow method)

Log Koc: 9.301 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Rate constants can NOT be estimated for this structure!

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 0.500 (BCF = 3.162 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 3.6721 days (HL = 4700 days)

Log BCF Arnot-Gobas method (upper trophic) = -0.049 (BCF = 0.8933)

Log BAF Arnot-Gobas method (upper trophic) = 0.342 (BAF = 2.2)

log Kow used: 15.47 (estimated)

Volatilization from Water:

Henry LC: 0.627 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 2.362 hours

Half-Life from Model Lake : 219.7 hours (9.155 days)

Removal In Wastewater Treatment:

Total removal: 94.04 percent

Total biodegradation: 0.78 percent

Total sludge adsorption: 93.26 percent

Total to Air: 0.00 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.00725 0.247 1000

Water 13.9 1.44e+003 1000

Soil 86.1 2.88e+003 1000

Sediment 0.00199 1.3e+004 0

Persistence Time: 1.62e+003 hr

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