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CAS Num: 065652-28-0

SMILES : O=C(OC)C(CCC=C1CCC=C(C)C)(C1)C

CHEM : 3-Cyclohexene-1-carboxylic acid, 1-methyl-3-(4-methyl-3-pentenyl)-, m

ethyl ester

MOL FOR: C15 H24 O2

MOL WT : 236.36

------------------------------ EPI SUMMARY (v4.00) --------------------------

Physical Property Inputs:

Water Solubility (mg/L): ------

Vapor Pressure (mm Hg) : ------

Henry LC (atm-m3/mole) : ------

Log Kow (octanol-water): ------

Boiling Point (deg C) : ------

Melting Point (deg C) : ------

Log Octanol-Water Partition Coef (SRC):

Log Kow (KOWWIN v1.67 estimate) = 5.73

Boiling Pt, Melting Pt, Vapor Pressure Estimations (MPBPWIN v1.43):

Boiling Pt (deg C): 296.47 (Adapted Stein & Brown method)

Melting Pt (deg C): 56.47 (Mean or Weighted MP)

VP(mm Hg,25 deg C): 0.0012 (Modified Grain method)

VP (Pa, 25 deg C) : 0.16 (Modified Grain method)

Subcooled liquid VP: 0.00235 mm Hg (25 deg C, Mod-Grain method)

: 0.314 Pa (25 deg C, Mod-Grain method)

Water Solubility Estimate from Log Kow (WSKOW v1.41):

Water Solubility at 25 deg C (mg/L): 0.3627

log Kow used: 5.73 (estimated)

no-melting pt equation used

Water Sol Estimate from Fragments:

Wat Sol (v1.01 est) = 6.4736 mg/L

ECOSAR Class Program (ECOSAR v1.00):

Class(es) found:

Esters

Henrys Law Constant (25 deg C) [HENRYWIN v3.20]:

Bond Method : 2.50E-003 atm-m3/mole (2.53E+002 Pa-m3/mole)

Group Method: Incomplete

For Henry LC Comparison Purposes:

User-Entered Henry LC: not entered

Henrys LC [via VP/WSol estimate using User-Entered or Estimated values]:

HLC: 1.029E-003 atm-m3/mole (1.043E+002 Pa-m3/mole)

VP: 0.0012 mm Hg (source: MPBPVP)

WS: 0.363 mg/L (source: WSKOWWIN)

Log Octanol-Air Partition Coefficient (25 deg C) [KOAWIN v1.10]:

Log Kow used: 5.73 (KowWin est)

Log Kaw used: -0.991 (HenryWin est)

Log Koa (KOAWIN v1.10 estimate): 6.721

Log Koa (experimental database): None

Probability of Rapid Biodegradation (BIOWIN v4.10):

Biowin1 (Linear Model) : 0.6253

Biowin2 (Non-Linear Model) : 0.8817

Expert Survey Biodegradation Results:

Biowin3 (Ultimate Survey Model): 2.6049 (weeks-months)

Biowin4 (Primary Survey Model) : 3.5823 (days-weeks )

MITI Biodegradation Probability:

Biowin5 (MITI Linear Model) : 0.5924

Biowin6 (MITI Non-Linear Model): 0.5624

Anaerobic Biodegradation Probability:

Biowin7 (Anaerobic Linear Model): -0.0997

Ready Biodegradability Prediction: NO

Hydrocarbon Biodegradation (BioHCwin v1.01):

Structure incompatible with current estimation method!

Sorption to aerosols (25 Dec C)[AEROWIN v1.00]:

Vapor pressure (liquid/subcooled): 0.313 Pa (0.00235 mm Hg)

Log Koa (Koawin est ): 6.721

Kp (particle/gas partition coef. (m3/ug)):

Mackay model : 9.57E-006

Octanol/air (Koa) model: 1.29E-006

Fraction sorbed to airborne particulates (phi):

Junge-Pankow model : 0.000346

Mackay model : 0.000765

Octanol/air (Koa) model: 0.000103

Atmospheric Oxidation (25 deg C) [AopWin v1.92]:

Hydroxyl Radicals Reaction:

OVERALL OH Rate Constant = 180.4652 E-12 cm3/molecule-sec

Half-Life = 0.059 Days (12-hr day; 1.5E6 OH/cm3)

Half-Life = 0.711 Hrs

Ozone Reaction:

OVERALL Ozone Rate Constant = 86.000000 E-17 cm3/molecule-sec

Half-Life = 0.013 Days (at 7E11 mol/cm3)

Half-Life = 19.189 Min

Reaction With Nitrate Radicals May Be Important!

Fraction sorbed to airborne particulates (phi):

0.000556 (Junge-Pankow, Mackay avg)

0.000103 (Koa method)

Note: the sorbed fraction may be resistant to atmospheric oxidation

Soil Adsorption Coefficient (KOCWIN v2.00):

Koc : 2890 L/kg (MCI method)

Log Koc: 3.461 (MCI method)

Koc : 1.069E+004 L/kg (Kow method)

Log Koc: 4.029 (Kow method)

Aqueous Base/Acid-Catalyzed Hydrolysis (25 deg C) [HYDROWIN v2.00]:

Total Kb for pH > 8 at 25 deg C : 6.186E-003 L/mol-sec

Kb Half-Life at pH 8: 3.551 years

Kb Half-Life at pH 7: 35.505 years

(Total Kb applies only to esters, carbmates, alkyl halides)

Bioaccumulation Estimates (BCFBAF v3.00):

Log BCF from regression-based method = 3.444 (BCF = 2783 L/kg wet-wt)

Log Biotransformation Half-life (HL) = 0.0727 days (HL = 1.182 days)

Log BCF Arnot-Gobas method (upper trophic) = 2.648 (BCF = 444.2)

Log BAF Arnot-Gobas method (upper trophic) = 2.664 (BAF = 461.5)

log Kow used: 5.73 (estimated)

Volatilization from Water:

Henry LC: 0.0025 atm-m3/mole (estimated by Bond SAR Method)

Half-Life from Model River: 1.929 hours

Half-Life from Model Lake : 150 hours (6.248 days)

Removal In Wastewater Treatment:

Total removal: 91.30 percent

Total biodegradation: 0.71 percent

Total sludge adsorption: 87.31 percent

Total to Air: 3.27 percent

(using 10000 hr Bio P,A,S)

Level III Fugacity Model:

Mass Amount Half-Life Emissions

(percent) (hr) (kg/hr)

Air 0.0318 0.261 1000

Water 11.7 900 1000

Soil 86.4 1.8e+003 1000

Sediment 1.88 8.1e+003 0

Persistence Time: 720 hr

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